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Second PUC Chemistry July, 2014 Question Paper

(i) ' The question papu tris ro*r.,,pa1.i: e/g,faro
"yrite

.bala.nced,

,cherRical
wherever required.

(iii)

61r,:626n1

r,.:, tions and draw lab,efied. diaryams

Use log tables and the simpre carcurators ifnecessary.

g.

(ril

$r,

co

compulsory.

(Use of scientifi c calculator, s isd,*la-ea)

::

PART-,A

Answer all of the f,ollowing

'

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1ffi41:istsiaarySolution?

.'. ,',

l0x1-10

&.tR;1

: .,'::

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Z. DefineMolarity.

Write the S.I. uniti of molar conductivily_

.p
ed

3.

(Answer each question in one word or in one

sentence)
1.:

;$,$i{

ib

PY- *,,

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,:]

Give an example of zero-order reaction.

$t[t161:r Physieal AdsorT{ian

5.

.t

..

..

Wrile the'composition of ,eopper matte,

-|

Write the structure of XeFo.

wn*atareFreons?

9.

' ' :

"'

Give the IUPAC name of CHTCHO.

10i

'N

thep"1$npresentinhair.

t'

li

I
l
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PART

II.

5x2:10

calculate the nurnber of atoms present in FCC crystar.

12.

What is Conosion ? Name one method to prevent

14.

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3.

Derive an expression for half-rife period of first order reaction.

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g.

11.

co

(Each question carries two marks)

Give reasons :

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(i) Actinoids show variable oxidation state

(ii) Zr Tnd,Hlhave almost identical radii
Explain Kolbe,s reaction.

16.

How are Carboxylic acids prepared from nitriles

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ed

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15.

What are antiseptics'? Give example.

18.

What are food preservatives ? Give an example.

17,

Answer any five of the following

PART _ C

5x3=15

III.

(Each question camies three marks)

l9'

Describe the three steps involved in the leaching

of bauxite to get pure alumina.

20.

How is ammonia manufactured by Haber,s process

21'

Describe the preparation ofiozonised oxygen with

an equation. Name the ozonised
produc1obtainedwherttheozoRe.reactswitlrte"a-s.lpr,ioe'

I
{

Code No.34 (NS)

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22. 'CornBlete

2Al + 3Ctr---->

(i)

the following.gquations

(ii).H2S+Clr7--+

co

", (iii) 8 NH3 + 3Ctr---->

g.

(excess)

dichromate prepared from chromite ore ?

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23. How is Potassium

lvVhy do transition elements

forur:comrplex compounds ?

Nmrethe,eleirtent which

,(

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state any three postulates of wemer theoiyof coofiination compounds.

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ed

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26. Using VBT account for geometry and maggetiiproperty of

Answer any three of the following

27. (al

(b)

28. (a)

[M(CN]ol]

PART * D
j

3x5=15

calculate the p'acking effielency.iu a siudg Dubic,lattice.

What is Frenkel defect ? Giveexarnple,

The vapour pressure of pure benzene at certain temperature is 0.850 bar.

39 grams of benzene (molar mass 78 grams), vapour pressure of the solution,

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24.

lV.

il

(b)

What happens to the solubility'of, tl, gas

in a liquia with:increase

29,:

in

temperature ? Give reason.

.(a) Describe the construcJion aad wo{ktng,dfitandarg hydrogen'electrode.

(b)StateFaraday'sSecondLawofElectrolysis..l.l-i4,'

. 1:

":-.

Code No.34 G{S)

. P.T.O.

9
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30' (a)

The rate df reaction increases by

2 tirnes when ttr" ternj"rature of flie
raised from 300 K to 310 K. calculate
the energy of activation.of the.reaction.

(b)

8.3 14

J/K/mole)

write any two differences between morecularity

and order of
what is coagulation of a sor ? Name two
methods by which

(b)

Lyophobic sol

g.

can be coagulated.

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What is Homogeneous Catalysis ?

Give example.

(b)

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Answer any four of the following (Each

question carries 5 marks)
I
32. (a) Mention the major product formed in the
folrowing reactions

(i)

CuHrBr +

(ii)

2-bromopen,*" alc KOH, A,

(iii)

CH3C/ + NaI dry acetone

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14* dry ether,

4x5=20

V.

co

31. (a)

(Given R

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write the equations for the steps in S*l mechanism

of conversio, of tert-

.p
ed

butylbromide into tert-butyl alcohol.

33. (a)

What is the effect

(i)
(ii)

of

erectron withdrawing group on acidity

of phenors.

erectron donating group on acidity

of arcohols

(iii)

(a)

Write equation for

w
(b)

boiling poi,t of arcohols on increasing

number of carbon atoms.
Give equation for Williarnsons ether
synthesis.

34.

(i)
(ii)
(iii)

(b)

the reaction between Carboxylic

acid and pC/r.
the reaction between formaldehyde
and conc

KoH.

the formation of oxime from car-bonyl

compou'd.

Explain aldol condensation with an example.

Code No.34 (NS)

10

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..1

CH

PoNu' PtNuoH ' n

35. (a) (i)

NaNO, .HC,

co

(ii) P-----,,i-Q
What are P and Q ? Name tlqe reaction occurring in step (i).

(b)
37., (a\

g.
,

Give an example of acidic a-amino acid.

Write the Haworth's structure of a

D(+) Glucose.

Name the monome,rs used for gettingfollow,irigpo.b4tgrs

(i) Pvc

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',',,1

I
.trat is Vulcanisation of rubber?

,
:

.p
ed

.,

'r

CodeNo.34 (NS)

1l

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L"h

l_ riI

I
2

(ii) Bakelitc
(b)

? ,

What'is denaturatiou of protein

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(i)
(ii)

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36. ,' (a)

Explain Carbylamine reaction with example.

(b)

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