D1.

A continuous, steady-state distillation column with a total condenser and a part

separating methanol from water at one atmosphere (see Table 2-7 for data). The fee
kmol/h. The feed is 55 mol% methanol and 45 mol% water. We desire a distillate pro
90 mol% methanol and a bottoms product that is 5 mol% methanol. Assume CMO.
a. If the external reflux ratio L/D = 1.25 plot the top operating line.
b. If the boilup ratio /B = 2.0 plot the bottom operating line.
c. Step off stages starting at the bottom with the partial reboiler. Use the optimum f
Report the optimum feed stage and the total number of stages.
d. Plot the feed line. Calculate its slope. Calculate q. What type of feed is this?

componente
metanol
agua

D
B
Z
55 52.9411765 2.05882353
45 5.88235294 39.1176471
100 58.8235294 41.1764706

XD
0.55
0.45

0.9
0.1

A)
Ln/D = R

1.25

XD

XB

0.9
0.9

0.9
0

1.2

0.55
0.55

0.55
0

0.8

0.05
0.05

0.05
0

0.6
0.4
0.2

LOR
LOR

B)

m
b
0.55555556
X
Y
0.9
0
Lm/B
B
Lm
Vm

b
2

X
LOS

0.9
0.4

2
41.1764706
82.3529412
41.1764706

m
LOS

0.4

-0.05

0 0.1 0.2
-0.2
1.2
1
0.8
0.6
0.4
0.2

Y
0.05

-1.66533453693773E-016

0.05

-1.66533453693773E-016

0 0.1 0.2
-0.2

0.4
0.2

0.5

-1.66533453693773E-016

0.95

0 0.1 0.2
-0.2

C)
LOR
LOS
interseccion

LOA

D)
X

Y
0.55
0.55
0.31153846 0.57307692
m
b
-0.09677419 0.60322581

LOA

LOA

=_ X + _
=/(1)X - /(1)
m= Pendiente
q/(q-1)
q=
q= <0-1>

N
x

0.9
0.9
0.31153846 0.57307692
0.05
0.05
0.31153846 0.57307692
0.55
0.55
0.31153846 0.57307692

LOS

0.4
-0.05

X
Y
0.31153846 0.57307692
X

LOR

m
b
0.55555556
2

-0.09677419
-0.09677419
0.08823529
Parcialmente vaporizada
8.82 `Liquido
91.2% Vapor

cambio

0.9
0.76
0.76
0.6
0.6
0.4
0.4
0.25
0.25
0.12
0.12
0.04
0.04

otal condenser and a partial reboiler is

Table 2-7 for data). The feed rate is 100
er. We desire a distillate product that is
methanol. Assume CMO.
ating line.

eboiler. Use the optimum feed stage.

t type of feed is this?

XB
0.05
0.95

1.2
1
XY

0.8

X=Y

0.6

XD

0.4

0.2

LOR

XB

33453693773E-016
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.2
1.2
1
XY

0.8

X=Y

0.6

XD
Z

0.4

XB

0.2

LOS

3453693773E-016
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.2

0.4

0.2

LOS

XB

3453693773E-016
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
-0.2

1.2

y
0.9
0.9
0.82222222
0.82222222
0.73333333
0.73333333
0.62222222
0.62222222
0.45
0.45
0.19
0.19
0.03

1
0.8

0.6

0.4

0.2

-1.66533453693773E-016

-0.2

0 0.10.20.30.40.50.60.70.80.9 1

n de etapas
etapa optima

6
3

y
0
0.02
0.04
0.06
0.08
0.1
0.15
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.95
1

volatilidad
0
0.134
0.23
0.305
0.365
0.418
0.517
0.579
0.665
0.729
0.779
0.825
0.87
0.915
0.958
0.979
1

7.58198614
7.16883117
6.87529976
6.61023622
6.46391753
6.06556246
5.50118765
4.6318408
4.03505535
3.52488688
3.14285714
2.86813187
2.69117647
2.53439153
2.45363409

no cte

0 0.10.20.30.40.50.60.70.80.9 1

XY
X=Y
XD
Z
XB
LOR
LOS
LOA
Column K
N

a. A distillation column with a total condenser is separating acetone from etha

concentration of xD = 0.90 mole fraction acetone is desired. Since CMO is valid
constant. If L/V is equal to 0.8, find the composition of the liquid leaving the fif
the total condenser.
b. A distillation column separating acetone and ethanol has a partial reboiler th
equilibrium contact. If the bottoms composition is xB = 0.13 mole fraction acet
boilup ratio /B = 1.0, find the vapor composition leaving the second stage abov
reboiler.
c. The distillation column in parts a and b is separating acetone from ethanol a
= 0.13, L/V = 0.8, and /B = 1.0. If the feed composition is z = 0.3 (all concentr
fraction of more volatile component), find the optimum feed plate location, tot
stages, and required q value of the feed. Equilibrium data for acetone and etha
(Perry et al., 1963, pp. 134) are

A)
DATOS:
Ln/Vn=
q (liquido)=
entonces R/(R+1)=
R=

componente
acetona
etanol

0.8
1
0.8
4
F

F
60
40
100

100

58

XD

0.9
0.9

0.9
0

0.6
0.6

0.6
0

LOR

0.1428571429 0.14285714
0.1428571429
0

LOS

XB

ETAPAS
1
2
3

42

LOR
LOS

LOA

0.582
-0.582

0.6456
0.6456

0.9
0.85
0.85
0.79
0.79
0.72

0.9
0.9
0.86
0.86
0.812
0.812

N
1.2

0.8

0.6

0.72
0.63
0.63
0.52
0.52
0.36
0.36
0.18
0.18
0.07
0.07

4
5
6
7
8

0.8

0.756
0.756
0.684
0.684
0.57462069 CAMBIO
0.57462069
0.39144828
0.39144828
0.18537931
0.18537931
0.05944828

0.6

0.4

0.2

0
0

0.1

Entonces el % de liquido en la 5 etapa es de 0.

B)

b. A distillation column separating acetone and ethanol has a

equilibrium contact. If the bottoms composition is xB = 0.13 m
boilup ratio /B = 1.0, find the vapor composition leaving the s
reboiler.

DATOS:
Vm/B=
q=

1
1.1

D
100

m
LOR
LOS
X

27.8

b
0.5530546624 0.27974277
2
-0.13
Y
0.2831777778 0.43635556

componente
acetona
etanol

20
80
100

72.2

1.1

XD

XB

ETAPA

N
1
2
3

0.6258992806
0.42
0.42
0.28
0.28
0.21

0.62589928
0.62589928
0.51202572
0.51202572
0.43459807
0.43459807

1.2

0.8

0.6

0.8

0.21
0.12
0.12

0.29 CAMBIO
0.29
0.11

0.6

0.4

Entonces el % de vapor en la 2 etapa es de 0.512

0.2

0
0

0.1

0.2

0.3

C)

c. The distillation column in parts a and b is separating aceton

= 0.13, L/V = 0.8, and /B = 1.0. If the feed composition is z =
fraction of more volatile component), find the optimum feed p
stages, and required q value of the feed. Equilibrium data for
(Perry et al., 1963, pp. 134) are
DATOS:
Ln/Vn=
entonces R/(R+1)=
R=
Vm/B=

0.8
0.8
4
1

componente
acetona
etanol

m
LOR
LOS

0.18
-0.13

Y
0.2583333333

30
70
100

D
100 22.0779220779

b
0.8
2

XD

Z
0.3866666667
XB

ETAPA

N
1
2

0.9
0.86
0.86
0.809
0.809

0.9
0.9
0.868
0.868
0.8272

1.2

0.8

0.6

3
4
5
6
7
8
9

0.74
0.74
0.66
0.66
0.56
0.56
0.44
0.44
0.31
0.31
0.21
0.21
0.12
0.12

0.8272
0.772
0.772
0.708
0.708
0.628
0.628
0.532
0.532
0.428
0.428
0.29 CAMBIO
0.29
0.11

0.8

0.6

0.4

0.2

0
0

0.1

0.2

0.3

0.4

Posee 9 etapas
La alimentacion se encuentra

ting acetone from ethanol. A distillate

sired. Since CMO is valid, L/V =
he liquid leaving the fifth stage below

X
0
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.5
0.6
0.7
0.8
0.9
1

has a partial reboiler that acts as an

0.13 mole fraction acetone and the
g the second stage above the partial

acetone from ethanol and has xD = 0.9, xB

is z = 0.3 (all concentrations are mole
feed plate location, total number of
ta for acetone and ethanol at 1 atm

B
54
4
58

Z (supu)
6
36
42

Ln
1

1.2
1
0.8
0.6
0.4
0.2
0
0

0.1

0.2

0.3

0.4

0.5

XB
0.9 0.14285714
0.1 0.85714286

0.6
0.4

Vn
232

Vm

Lm

290

290

332

1.2

0.8
0.18
1.14482759 -0.02068966
0.9
0.582

XD

Y
0
0.262
0.348
0.417
0.478
0.524
0.566
0.605
0.674
0.739
0.802
0.865
0.929
1

0.9
0.6456

1
0.8
0.6

0.14285714 0.14285714
0.582
0.6456
0.6
0.582

0.6
0.6456

0.4
0.2
0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.2

1
X-Y
0.8

X=Y
XD

0.6

Z
XB

1
X-Y
X=Y

0.8

XD
Z

0.6

XB
LOR
LOS

0.4

LOA
N

0.2

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

en la 5 etapa es de 0.52

tone and ethanol has a partial reboiler that acts as an

mposition is xB = 0.13 mole fraction acetone and the
mposition leaving the second stage above the partial

B
17.4
10.4
27.8

Ln

Z (supu)
2.6
69.6
72.2

Vn

XD
0.2
0.8

Vm

XB
0.63
0.37

0.13
0.87

Lm

34.4

62.2

72.2

144.4

0.63
0.63

0.63
0

LOR

0.63
0.63
0.28317778 0.43635556

0.2
0.2

0.2
0

LOS

0.13
0.13
0.28317778 0.43635556

0.13
0.13

0.13
0

LOA

0.2
0.2
0.28317778 0.43635556

X-Y
X=Y
XD
Z
XB
LOR

1
X-Y
X=Y

XD
Z

XB
LOR

LOS
LOA
N

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

d b is separating acetone from ethanol and has xD = 0.9, xB

feed composition is z = 0.3 (all concentrations are mole
find the optimum feed plate location, total number of
ed. Equilibrium data for acetone and ethanol at 1 atm

D
B
Z
19.8701299 10.1298701
2.20779221 67.7922078
22.0779221 77.9220779
B
R
77.9220779

XD
0.3
0.7

XB
0.9
0.1

0.13
0.87

Ln
Vn
Vm
Lm
4 88.3116883 110.38961 77.9220779 155.844156

0.9
0.9

0.9
0

LOR

0.9
0.9
0.25833333 0.38666667

0.3
0.3

0.3
0

LOS

0.13
0.13
0.25833333 0.38666667

0.13
0.13

0.13
0

LOA

0.3
0.3
0.25833333 0.38666667

X-Y
X=Y
XD
Z
XB

LOA

X-Y
X=Y
XD
Z
XB
LOR
LOS
LOA
N

0.1

0.2

0.3

0.4

0.5

0.6

mentacion se encuentra el la 8 etapa

0.7

0.8

0.9

=_ X + _
=/(1)X - /(1)
q/(q-1)
q

1.2
1

0.8
X-Y

0.6

X=Y

0.4

0.2
0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

X-Y
X=Y
XD
Z
XB
LOR
LOS
LOA

0.6

0.7

0.8

0.9

X-Y
X=Y
XD
Z
XB

0.8

0.9

a. Una columna de destilacin con un

destilado
concentracin de xD = 0,90 fraccin
constante. Si L / V es igual a 0,8, enco
debajo
el condensador total.
b. Una columna de destilacin que se
acta como una
contactos de equilibrio. Si la composi
relacin boilup / B = 1,0, encontrar la
de la parcial
rehervidor.
c. La columna de destilacin en las pa
0,9, xB
= 0,13, L / V = 0,8, y / B = 1,0. Si la c
concentraciones son mol
fraccin del componente ms voltil)
nmero total de
etapas y requiere valor q de la alimen
(Perry et al., 1963, pp. 13-4) son

X-Y
X=Y
XD
Z
XB
LOR
LOS
LOA
N

0.9

1.2

1
X-Y

0.8

X=Y
XD
Z

0.6

XB
LOR

0.4

LOS
LOA

0.2

0
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.2

1
X-Y

0.8

X=Y
XD
Z

0.6

XB
LOR

0.4

LOS
LOA

0.2

0
0

pendiente
interseccion
-2.08
0.924

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

_ X + _

/(1)X - /(1)
-2.08
0.67532468

olumna de destilacin con un condensador total se separa acetona a partir de etanol. Un

o
acin de xD = 0,90 fraccin molar de acetona se desea. Desde OCM es vlida, L / V =
e. Si L / V es igual a 0,8, encontrar la composicin del lquido que sale de la quinta etapa

nsador total.
olumna de destilacin que separa la acetona y el etanol tiene un rehervidor parcial que
mo una
s de equilibrio. Si la composicin de los fondos es xB = 0,13 moles fraccin acetona y la
boilup / B = 1,0, encontrar la composicin del vapor dejando la segunda etapa por encima
cial
or.
umna de destilacin en las partes A y B es separar acetona a partir de etanol y tiene xD =

L / V = 0,8, y / B = 1,0. Si la composicin de la alimentacin es z = 0.3 (todas las

aciones son mol
del componente ms voltil), encontrar la ubicacin de la placa de alimentacin ptima, el
total de
requiere valor q de la alimentacin. Datos de equilibrio de acetona y etanol a 1 atm
al., 1963, pp. 13-4) son

X-Y
X=Y
XD
Z
XB
LOR
LOS
LOA

.8

X-Y
X=Y
XD
Z
XB
LOR
LOS
LOA

0.9

r de etanol. Un

lida, L / V =
a quinta etapa

or parcial que

n acetona y la
tapa por encima

nol y tiene xD =

das las

tacin ptima, el

ol a 1 atm