Beruflich Dokumente
Kultur Dokumente
DOI 10.1007/s11581-015-1434-y
ORIGINAL PAPER
Received: 21 November 2014 / Revised: 17 March 2015 / Accepted: 29 March 2015 / Published online: 12 April 2015
# Springer-Verlag Berlin Heidelberg 2015
Introduction
The development of high energy density and environmentfriendly power sources for undersea application is essential
due to an increase in interest to utilize abundant marine resources, like biological, gas, and oil. Aluminum and magnesium metals have gained attention to use as anode materials
for power source in undersea applications. This is because of
their low atomic weight, high faradic capacity, standard electrode potential, and easy-to-use seawater as an electrolyte
[15]. Electrochemical systems based on magnesiumhydrogen peroxide (MgH2O2) fuel cells have high energy density
and can produce electricity by converting its stored chemical
energy [6, 7]. The MgH2O2 fuel cell has a theoretical voltage
of 4.14 V, and the corresponding half-cell and overall reaction
are as follows [5]:
* R. Balaji
rbalaji@arci.res.in
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especially on the development of catalyst for hydrogen peroxide reduction reaction [79]. Besette et al. [10] studied the use
of microfiber carbon electrode (MCE) covered by Pd/Ir as a
cathode in AlH2O2 fuel cells and obtained a maximum power density of 90 mW cm2 with Pd/Ir loading of 10 mg cm2.
Shu et al. [7] studied palladium-coated titanium foam cathodes for the MgH2O2 fuel cell, and the performance was
evaluated at different operating conditions. Further, they have
also studied the Mg-air fuel cell performance using a carbon
fiber felt cathode. Yang et al. [8] used nickel foam-supported
Pd/Ag as a cathode in the MgH2O2 fuel cell and achieved a
power density of 138 mW cm2 at 50 C.
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Thus, most of the studies are based on the development of highly active electrocatalyst for hydrogen peroxide reaction. To achieve better and stable fuel cell
performance, the material properties of cathode substrate
need to be considered. For optimized performance substrates with suitable porosity, high surface area, high
electrical conductivity, and high electrochemical activity
toward the reactions between redox species may be
used. Considering the above aspects, materials like
graphite and carbon in the form of porous structure
can be good electrode materials. These forms of materials are widely used in fuel cells and flow battery to
achieve optimized performance [11]. Hence, in this
study, an attempt has been made to use carbon felt
and carbon cloth as a cathode in the MgH2O2 fuel cell,
and its performance was studied with different operating
parameters.
Experimental
Materials
All chemicals (reagent grade) were obtained from M/s.
SRL Chemicals, India, and were used as received. Deionized water was used for all the experiments. The
anode was an AZ61 magnesium alloy supplied by
M/s. Omega Enterprises, India. The conductive carbon
fiber cloth (AvCarb 40) was procured from M/s. Ballard
Materials Products, USA, and the carbon felt of 4 mm
thick was procured from M/s. Nickunj Eximp (P) Ltd.,
India.
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Effect of temperature
The influence of operating cell temperature on the performance of the MgH2O2 fuel cell is studied at various operating temperatures ranging from 35 to 70 C, and the results are
The influence of hydrogen peroxide concentration on the performance of the fuel cell has been investigated by varying the
concentrations of H2O2 from 0.2 to 2.0 M, and the sulfuric
Fig. 4 Performance of the MgH2O2 cell at 35, 40, 50, 60, and 70 C;
anolyte, 0.6 M NaCl; catholyte, 2.0 M H2O2 +2.0 M H2SO4; flow rate,
50 ml min1; cathode, carbon felt; anode, MgAZ61 alloy
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Fig. 7 Performance of carbon felt cathode at flow rates of 20, 50, and
100 ml min1 at 70 C. Anolyte, 0.6 M NaCl; catholyte, 2.0 M H2O2 +
2.0 M H2SO4; cathode, carbon felt; anode, MgAZ61 alloy
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MgH2O2 fuel cell with carbon felt-based cathode was operated steadily for about 26 h under a given current density of
50 mA cm2.
Acknowledgments The authors would like to thank Dr. G.
Sundararajan, Director, ARCI, for his constant support and encouragement and the Department of Science and Technology, Government of
India, for financial assistance.
References
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Fig. 9 Performance of carbon felt cathode under constant current density
of 50 mA cm2 at a flow rate of 50 ml min1 at 60 C. Anolyte, 0.6 M
NaCl; catholyte, 2.0 M H2O2 +2.0 M H2SO4; cathode, carbon felt; anode,
MgAZ61 alloy
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Conclusion
In the present work, noble metal-free carbon-based cathode
was used in a MgH2O2 fuel cell. The MgH2O2 fuel cell with
carbon felt-based cathode shows a maximum power density of
91 mW cm2 under optimum operational conditions. The
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