Beruflich Dokumente
Kultur Dokumente
1.
General Formula : CnH2n+2 (number of atoms, n = 1,2,3......)
2. They are saturated hydrocarbons;
each carbon atom is bonded to four other atoms by
single covalent bonds.
3. The members of the family, ending with name ane.
Number of carbon
atoms
(n)
Name
Molecular formula
CnH2n+2
Molar
mass
(g mol-1)
Physical state at
room
temperature
Methane
C1H2x1+2 = CH4
16
Gas
Ethane
C2H2x2+2 = C2H6
30
Gas
Propane
C3H2x3+2 = C3H8
44
Gas
Butane
C4H2x4+2 = C4H10
58
Gas
Pentane
C5H2x5+2 = C5H12
72
Liquid
Hexane
C6H2x6+2 = C6H14
86
Liquid
Heptane
C7H2x7+2 = C7H16
100
Liquid
Octane
C8H2x8+2 = C8H18
114
Liquid
Nonane
C9H2x9+2 = C9H20
128
Liquid
10
Decane
C10H2x10+2 = C10H22
142
Liquid
No. of isomers
Methane
HCH
CH4
Ethane,
C2H6
Propane,
C3H8
Butane,
C4H10
H H
HCCH
H H
H H H
HCCCH
H H H
H H H H
HCCCCH
H H H H
n-butane
H
H
H
H C C C H
H HCH H
H
2 - methyl propane
Pentane,
C5H12
H H H H H
HCCCCCH
H H H H H
n-pentane
H
H
H H
H C C C C H
1
2
3
4
H HCH H H
H
2-methyl butane
H HCH H
H C C C H
H HCH H
H
2,2-dimetyl propane
Hexane,
C6H14
H H H H H H
HCCCCCCH
H H H H H H
n-hexane
H
H
H H H
H C C C C C H
H HCH H H H
2 - methyl pentane
H H
H
H H
H C C C C C H
H H HCH H H
H
3 - methyl pentane
H
H HCH H H
H C C C C H
H HCH H H
H
2,2 - dimethyl butane
H
H
H H CH
H
H C C C C H
H HCH H
H
H
2,3 - dimethyl butane
Physical Properties
Physical properties of alkanes
i.
cannot conduct electrity
ii.
less dense than water
iii.
dissolve in organic solvents, insoluble in water
iv.
low melting and boiling points
Conclusion:
- molecule held together by weak intermolecular forces
- properties of covalent compound
- gradually steady increase as the number of carbon in alkane
increases
Chemical Properties
Pg 38
Reactivity of alkanes
1.
Not reactive/unreactive because saturated hydrocarbon
2. Did not decolourized purple solution of acidified potassium
manganate(VII)
3. Did not decolourized reddish brown solution of bromin water
4. Neutral.
Combustion of alkanes
1.
In the presence of sufficient oxygen, alkanes burns to form carbon dioxide and water. complete combustion
Chemical equation:
i.
ii.
CH4
+
O2
CO2
CH4 + 2O2 CO2 + 2H2O
C2H6
iii.
iv.
H2O
O2
2CO2
+ 3H2O
C4H10 + 13/2 O2
4CO2
C6H14
Answers
i. CH4
ii. C2H6
2 x C2H6
2C2H6
+ 7/2
+ 19/2 O2
2O2
CO2
7 O2
2
7 O2
2x 2CO2
iii.
C4H10
+ 13/2 O2
iv.
C6H14
+ 19/2 O2
7H2O
+ 2H2O
2CO2
+ 2 x 7 O2
2
+
6CO2
5H2O
3H2O
+ 2x 3H2O
4CO2
6H2O
4CO2
5H2O
6CO2
7H2O
C3H8
C5H12
C7H16
C8H18
C9H20
C10H22
i. CH4 + 3/2 O2
2CH4 + 3 O2
ii. CH4 + O2
CO + 2H2O
2CO + 4H2O
C + 2H2O
Halogenation
1.
The reaction is between alkane dan chlorine.
2. Takes place under sunlight/ultra violet light.
3. Carbon-hydrogen bonds broken and new carbon-halogen bonds
are formed. One or more hydrogen atoms in alkanes molecule may be subtituted by halogen.
4. Halogenation is substitution reaction.
Chlorination of methane
First stage;
HCH
Second stage;
H
H
H C Cl
;
Third stage
H
Cl
H C Cl
Fourth stage;
H
Cl
H C Cl
Cl
+Cl-Cl
Cl2
Cl2
Cl2
CCl4
+
4HCl
H
|
H C Cl + HCl
|
H monochloromethane
Cl
|
H C Cl + HCl
|
H dichloromethane
Cl
|
H C Cl + HCl
|
Cl trichloromethane
Cl
|
Cl C Cl + HCl
|
Cl tetrachloromethane
2.
3.
ethenes
No. of
carbon atom
Name
Molecular formulae
Molar mass /
g mol-1
None
Ethene
C2H4
28
Gas
Propene
C3H6
42
Gas
Butene
C4H8
56
Gas
Pentene
C5H10
70
Liquid
Liquid
Liquid
Liquid
Liquid
10
Liquid
4.
Propene
C3H6
H H
CC
H H
H
H
CCCH
H H H
Butene,
C4H8
H
H H
CCCCH
H H H H
but -1- ene
H
H
HCCCCH
H H H H
but -2- ene
H
H
C C C H
H HCH H
H
2-methyl propene
Pentene,
C5H10
H
H H H
CCCCCH
H H H H H
pent -1- ene
H H
H
HCCCCCH
H H H H H
pent -2- ene
H
H H
C C C C H
H HCH H H
H
2-methylbut -1- ene
H H
H
H
C C C C H
H
HCH H
H
3-methyl but -1- ene
H
H H
H C C C C H
H HCH
H
H
2-methyl but -2- ene
Hexene,
C6H12
12
H
H H H H
CCCCCCH
H H H H H H
H
H H H
HCCCCCCH
H H H H H H
H H
H H
HCCCCCCH
H H H H H H
H
H H H
C C C C C H
H HCH H H H
H
H
H H
C C C C C H
H H HCH H H
H
H
H
H
C C C C C H
H H H HCH H
H
H H H
H C C C C C H
H HCH
H H
H
H H
H C C C C C H
H H HCH H H
H
H
H
HC C C C C H
H H H HCH H
H
H
H H H
C C C C C H
H HCH H H H
H
HCH H
C C C C H
H
H HCH H
H
H
HCH H
H
C C C C H
H
H HCH H
H
HCH
H
H
H C C C C H
H HCH
H
Physical Properties
Physical properties of alkenes (similar to alkanes)
i.
cannot conduct electrity
ii.
less dense than water
iii.
obeys like dissolve like;
insoluble in water
v.
low melting and boiling points, gradually steady increase as the number of carbon in alkene increases
Chemical Properties
Reactivity of alkenes
1.
Alkenes is more reactive because the presence of double covalent bond, (unsaturated hydrocarbon)
2. Alkenes decolourized purple solution of acidified potassium
manganate(VII)
3. Alkenes decolourized reddish brown solution of bromin water
4. Neutral.
Combustion of alkenes
.
Addition Reaction
The carbon-carbon double bond is converted into
(5.2)
H
H
H
H
C=C
H H
Alkenes
(Unsaturated)
1.
XY
X CCY
Molecule
H
Alkanes
(Saturated)
Addition of hydrogen
Mixture of alkenes gas/vapour and hydrogen gas, is passed through platinum or nickel at 180 oC. The process is known as
catalytic Hydrogenation.
Catalyst: platinum or nickel
C=
H
Ethene
Chemical equation:
H2
Hydrogen
C2H4 + H2
C2H6
Ni/Pt
H C C H
180oC
Ethane
2.
Addition of halogens
The process is known as halogenation
H
C=C
H
Ethenes
(unsaturated)
Br Br
Bromine
Br C C Br
1,2-dibromoethanes
C2H4Br2
[HW-notes book]
Q1: Write a chemical equation reaction between but-1-ene with
bromine water. Show the structural formula as well.
[HW-exercises book]
Q2: Halogenation process is best used to differentiate between
alkanes and alkenes. Explain how it can be done?
[notes: refer to SAB]
3.
H
(saturated)
ii. When
HCl
Hydrogen chloride
1.
2.
H C C Cl
Monochloroethanes
H H
(Saturated)
4.
C2H5Cl
Alkenes
(Unsaturated)
+ H2O
[fromacidified
KMnO
4]
CC
[O]
OH OH
alkanes-diol compound
(Saturated)
Example;
H
C=
C + H2O + [O]
Ethene
(Unsaturated)
H C C H
OH OH
Ethane-1,2-diol
(Saturated)
H
H
H C C = C + H2O + [O]
H
H H
HH
H CC C H
H OH OH
Propene, C3H6
Propane-1,2-diol
5. Steam
(Hydration process)
1. Alkenes react with steam to produce equivalent alcohol
at the temperature of 300 oC and in the pressure of 60
atmosphere.
2. Reactions catalyst by concentrated phosphoric acid, H3PO4.
3. This method is one of the industrial preparation to produce
alcohol.
H H
C=C
H H
Ethene
C2H4
+ HOH
H C C H o
Q: Use but-1-ene
C4H8 + H2O C4H9OH / C4H10O
H H
300 C, 60 atm
H PO4 H OH
Steam
H2O
Ethanol
C2H5OH @ C2H6O
Polymerization
5.3
Polymer : Large molecules made up from many identical
repeating sub-units called monomers, which joined
together by covalent bond.
Homologous Series
Differences:
Properties
Alkanes
Alkenes
It burned with a more sooty yellow
flame
The reddish-brown colour of
bromine water decolourised
The purple colour of acidified
potassium manganate(VII)
solutions was decolourised
Dropper
Test tube
Test tube A
Test tube B
Procedure;
1. The apparatus shown above is prepared.
2. 2-5 cm3 bromine water is measured with measuring
cylinder 5ml and poured into a test tube.
3. A few drops of liquid from bottle A is put/added with
dropper into the test tube, and shake.
4. Obsevation is recorded.
5. The experiments is repeated by replace the liquid from
bottle A with bottle B.
Observation:
Test Tube
Observation
Inference
Liquid
in bottle A
Contains alkane
Liquid
in bottle B
Contains alkene
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ALCOHOL
3.
Alcohol contains the hydroxyl group, -OH as their functional group. [notes: not hydroxide ion, OH - , alcohol not is alkaly ]
4.
5.
6.
Name
Methanol
Ethanol
very important
Mr
12+3+
16+1
= 32
12x2 + 5 +16
+ 1 = 46
Molekul Formula
CH3OH
@
CH4O
C2H5OH
@
C2H6O
Propan-1-ol
60
C3H7OH
Butan-1-ol
74
C4H9OH
C5H11OH
Pentan-1-ol
88
Hexan-1-ol
102
: HEXAN-3-OL
C6H13OH
Structural formula
H
|
H C OH
|
H
H
H
|
|
H C C OH
|
|
H
H
H
H H
|
|
|
H C C C OH
|
|
|
H
H H
Naming Alcohol
1. Find the longest continous carbon chain containing OH.
Number the carbon beginning at the end nearer to the OH, write the number in front of the ending ol.
Locate the alkyl group (branch chain), give number to the carbon and named the alkyl group. Put the number in front of the
group.
CH3
: methyl
C2H5 atau
CH2CH3
: ethyl
C3H7 atau
CH2CH2CH3
: propyl
-
(ii)
OH
(iii)
OH
: C7H15OH
: 4-methyl hexan-3-ol
(iii)
OH
(iv)
C2H5
OH
Formula : C9H19OH
Name
: 5-ethyl heptan-3-ol
Physical Properties
1. Liquid at room temperature. (pg. 62) [ no gas]
2. Simple alcohol are very soluble in water, infinite solubility.
Methanol, ethanol dan propan-1-ol is miscible in all proportions
(terlarut campur dengan air dalam semua kadaran).
The rest of the alcohol less soluble or insoluble.
Isomerism
Similar to alkenes, isomerism in alcohol results from the branching of the carbon chain and the different location of the hydroxyl
group.
You only have to know the isomerism in propanol dan butanol.
Q : Draw 2 isomers for propanol and 4 isomers for butanol,
and dan named the isomers.
Propanol
Butanol
Propanol
H H H
H C C C OH
H H H
H H H
HCCCH
H OH H
Butanol
H H H H
H C C C C OH
H H H H
H H H H
HCCCCH
H H OH H
H
H
H
H C C C OH
H HCH H
H
OH
H
H C C C H
H HCH H
ETHANOL
1.
Preparation of ethanol.
i.
Laboratory preparation (fermentation)
ii. Industrial production (hydration process)
Making Ethanol Fermentation
1.
Two stages;
i.
Fermentation
ii.
Purification
- through fractional distillation at 78 oC
( boiling point of ETHANOL)
Fermentation of Glucose
1.
Yeast is added to sugar or starch.
2. Anaerobic process ( takes place in the absence of oxygen).
3.
Yeast releases enzymes. These enzymes break down the sugars/starch into glucose, C 6H12O6.
4. Zymase slowly decomposes the glucose to form ethanol and carbon dioxide.
C6H12O6 (aq)
Delivery tube
Conical flask
Beaker
Glucose + yeast
Lime water
Purification of Ethanol
1.
Ethanol produced from the fermentation process is impure, because its mix with the glucose solution.
Q : Draw labeled diagram to carry out the purification of ethanol
through fractional distillation process.
Thermometer
Fractioning
collum
Water out
Liebig
condenser
Retort stand
with clamp
Rounded
conical
Water
Product from
fermentation
Wire
gauge
XXXXXXXXXXXXXXX
Porcelain
chips
Bunsen
burner
Water in
Distillate
(Ethanol)
at 78 oC.
B: Porcelain chips is used to avoid the solution jumped/
effervesence (breaking bubbles)
C: To cooled the ethanol vapour to become liquid.
Q: Named the process in Liebig condenser.
A: Condensation
Q: What is the properties of ethanol
A: Properties;
-
colourless
volatile
good organic solvent
miscible with water
highly flammable
antiseptic
chemically reactive
As a solvent in perfumes/cosmetics
As a thinner in varnish, ink
As a cleaner for compact disc.
As a fuel for transport
As a raw material for the manufacture of vinegar,
As a raw material to make industrial product such as
antiseptic and cough syrup.
@ C2H4
CH2 = CH2 +
H3PO4
concentrsted
H2O
300 o C, 60 atm
C2H5OH
CH3CH2OH
Chemical Properties
1. Combustion
i.
ii.
C2H5OH
+ 3O2
Ethanol
Oxygen
Q: Write combustion equation for hexanol
2CO2
+
Carbon
dioxide
+ 9O2
Oxygen
6CO2
+
Carbon
dioxide
C6H13OH
hexanol
2. Oxidation
i. Ethanol can be oxidised into ethanoic acid by an oxidising agent.
3H2O
Water
7H2O
Water
CH3CH2OH + 2[O]
Etanol
Q: Show the structural
formula for the equation above.
H
H
|
|
H C C OH + 2[O]
|
|
H
H
(ii)
Acidified potassium dichromate(VI), K2Cr2O7
(orange to green)
Q: Draw a labeled diagram for the process.
CH3COOH +
Ethanoic acid
H2O
H
O
|
H C C OH + H2O
|
H
Ethanol +
potassium dikromat(VI) +
dilute sulfuric acid
Heat
Cold
water
Distillate
(ethanoic acid)
Colourless
Vinegar smell
Blue litmus paper turns red (acidic properties)
3. Dehydration
ALCOHOL
ALKENE
- H2O
3.
CH3CH2OH
Ethanol
H
H
|
|
HCCH
|
|
H
OH
CH2 = CH2
Ethene
H2O
H H
|
|
H C C H + H2O
Glass wool
soaked with
ethanol
Porcelain
chips
Ethene
gas
Heat
Heat
Delivery
tube
Water
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CARBOXILIC ACID
General formula CnH2n+1COOH
One hydrogen atom is replaced with functional group COOH
Test
tube
Retort
stand
with
clamp
Formula: HCOOH
Formula: CH3COOH
H C OH
H O
|
H C C OH
|
H
CARBOXYL GROUP
Carboxyl group plays a vital role to gives acidic properties to carboxilic acid families.
CH3COOH
Ethanoic
acid
H+ + CH3COOHydrogen Ethanoate
ion
ion
Name
Methanoic acid
Molecular formula
C0H2(0)+1COOH
Structural
formula
Mr
H C OH
46
= HCOOH
60
H
O
|
H C C OH
|
H
74
H
H
O
|
|
H C C C OH
|
|
H
H
C1H2(1)+1COOH
1
Ethanoic acid
Propanoic acid
= CH3COOH
[C2H4O2]
C2H2(2)+1COOH
= C2H5COOH
Butanoic acid
Carbon number 1
O
C
O
Example 1:
H
H
H
C
COOH
H
H
C4H8O2 / C3H7COOH
C H
H
Name: 2-methylpropanoic acid
Example 2:
H
CH3
COOH
Carboxyl carbon: carbon number 1
C2H5
Name: 2-methylbutanoic acid
Example 3:
H
C2H5
COOH
Name: 2-ethyl pentanoic acid
C3H7
Example 4:
H
C3H7
COOH
Name: 2-ethyl pentanoic acid
C2H5
Ethanoic Asid
Can be prepared through oxidation of an ethanol.
Chemical equation:
H H
H C C OH + 2[O]
K2Cr2O7 solutions
+
dilute H2SO4
reflux
H O
H C C OH + H2O
This is carried out by refluxing ethanol with an oxidising agent such as acidified potassium dichromate(VI) or potassium
manganate(VII) solution.
Tissel tube
Water out
Retort
stand
Label the
diagram please
Liebig condenser
Water
in
Wire
gauge
xxxxxxxxxxxxxx
Heat
Physical Properties
- pH less than 7
- sharp or unpleasant smell
- turn moist blue litmus paper to red
- colourless liquid
Chemical Properties
Acid Properties
- Only hydrogen atom in the carboxyl group,
[-COOH] can ionize in water to produce
hydrogen ions, H+.
CH3COOH
Ethanoic
acid
CH3COO- + H+
CH3COOEthanoate Hydrogen
ion
ion
2CH3COOH + Mg Mg(CH3COO)2 + H2
Ethanoic acid
Magnesium ethanoate
2CH3COOH + Zn Zn(CH3COO)2 + H2
Ethanoic acid
Zink ethanoate
6CH3COOH + 2Al 2Al(CH3COO)3 + 3H2
Ethanoic acid
Aluminium ethanoate
Concentrated
H2SO4
Carboxilic acid + Alcohol Ester +
Carboxilic acid reacts with alcohol to
produce an ester and water.
Water
2. Effective Practise pg 75
1, 2, 3
[exercise book]
ESTER
General formula CnH2n+1COOCmH2m+1
R
R
CnH2n + 1C OH + CmH2m+1OH
Esterification
- Carboxilic acid reacts with alcohol to produce
ester and water.
- The functional group of ester is carboxilate
group.
- Concetrated sulphuric acid is catalyst.
- Carboxilic acid losses OH and
- Alcohol losses H
- The bond that break up will rejoin again
(carboxilic acid)
(alcohol)
Break up
and rejoin
CnH2n + 1 C
Derived from
carboxilic acid
O
Carboxilate
group, -COO-
CmH2m+1
Derived from
alcohol
Naming Ester
- Name of ester consists of two parts, the name
of alcohol part is given first and followed by
the acid part.
Example: i. Ethanoic acid + methanol
methyl ethanoate + water
Chemical equation:
CH3COOH
H
O
|
H C C OH
|
H
CH3COOH
(Etanoic acid)
H
|
H C OH
|
H
CH3OH
(Methanol)
H
O
H
|
|
H C C O C H + H2O
|
|
H
H
CH3COOCH3
(Methyl ethanoat)
Water
CH3COOH
H
O
|
H C C OH
|
H
Ethanoic acid
H
H
|
|
H C C OH
|
|
H
H
Ethanol
H
O
H
H
|
|
|
H C C O C C H + H2O
|
|
|
H
H
H
ethyl etanoat
Water
HCOOH
H C OH
Methanoic acid
H
H
|
|
H C C OH
|
|
H
H
Ethanol
O
H
H
|
|
H C O C C H + H2O
|
|
H
H
Ethyl metanoat
Air
Methyl methanoate
From carboxilic acid
From alcohol
Methanoic acid
Methanol
H C OH
H
|
H C OH
|
H
Break up and rejoin
O
H
|
H C O C H + H2O
|
H
ii. Pentyl propanoate
Try now
methyl metanoate
Air
Prophyl ethanoate
From carboxilic acid
From alcohol
Ethanoic acid
H O
|
H C C OH
|
H
Propanol
H
H H
|
|
|
H C C C OH
|
|
|
H
H H
Break up and rejoin
H
O
H H
H
|
|
|
|
H C C O C C C H + H2O
|
|
|
|
H
H
H
H
propyl ethanoate
Water
Tissel tube
Water
out
Uniform
heating
Water
bath
Porcelain chip
To prevent
bumping and
ensure smooth
boiling
How to carry out this process?
[Success pg 378]
After boiling, Liebig condenser is rearranged
To carry out the fractional distillation at
74oC 78oC to collect ethyl ethanoate.
Liebig
condenser
Water
in
XXXXXXXXXXXXXXX
To cold the
ethanol and
ethanoic acid
Ethanol +
ethanoic acid +
concentrated
sulphuric acid
Uses of ester
Exercise:
Effective Practise pg 84 no. 1-3
[Ex. Books]
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PETROLEUM
( Hydrocarbon)
Cracking process
ETHENE
C2H4
Alumina, Al2O3
(heated)
Hydration
process
Concentrated phosphoric acid,
H3PO4 300 oC, 60 atmosphere
GLUCOSE
C6H12O6
Nickel/platinum
180 oC
Dehydration
process
i. Heated porcelain
chips/ porous pot
Oxyge
Com
Fermentation
process
ETHANOL
C2H5OH
Yis (zymase)
30 oC
Oxidation
process
Acidified potassium manganate(VII)/
Acidified potassium dichromate(VI)
HOT SPOT
SPM09
Catalytic
hydrogenation process
ETHANOIC ACID
CH3COOH
FATS
Fats and oils are chemically similar, but differ in physical states.
Oxygen, O2
Combustion
process
Concentrated
sulphuric acid,
H2SO4
Esterification
process
MEM
DIAG
IT W
Fats
: - found in animals
- solid in room temperature
- butter and tallow (types of fat)
Oil
: - fats from plants
- liquid in room temperature
- palm oil, coconut oil, sunflower oil
- Fats and oil are mixtures of different esters.
- Fats are formed from 3 molecules of longchain carboxylic acids called fatty acids
with 1 molecules of alcohol called glycerol.
OH C R1
O
OH C R2
O
OH C R3
H
H C OH
H C OH
H C OH
Formation of a fat molecule
Fatty acids
- R1 , R2 , R3 contains
12 to 18 carbon
atoms per molecule
- R1 , R2 , R3 are three
alkyl groups which
may be the same or
different
- group: carboxilic acid
Glycerol
- propane-1,2,3-triol
- group: alcohol
H C OH
H C OH
H C OH
Break up
and rejoin
+
Break up
and rejoin
Break up
and rejoin
OH C R1
O
OH C R2
O
OH C R3
H
O
H C O C R1
H C O C R2
H C O C R3
+ 3H2O
Saturated Fats
Fats contain esters of glycerol and saturated fatty acids.
- Example:
i. Tristearin
( glycerol + stearic acid)
ii. Tripalmitin (glycerol + palmitic acid)
Tristearin
H
O
H C O C (CH2)16 CH3
H C O C (CH2)16 CH3
H C O C (CH2)16 CH3
H
Tripalmitin
H
O
H C O C (CH2)14 CH3
H C O C (CH2)14 CH3
H C O C (CH2)14 CH3
H
- Animal fats have large proportions of
saturated fats.
- They have high melting point and solids at
room temperature.
Unsaturated Fats
- Fats contain esters of glycerol and
unsaturated fatty acids.
Example:
i. Triolein
H
O
H
- Plant or vegetable oils contain a large
proportions of unsaturated fats.
- They have lower melting points and are
liquids at room tempoerature.
Prepared by;
Kamal Ariffin Bin Saaim
SMKDBL
http://kemhawk.webs.com
Natural Rubber
Latex
Long chain
rubber
molecules
Negatively-charge
protein membrane
Rubber
particle
Polymerization of Isopropene
Isoprene
Isoprene
Isoprene
H CH3 H H + H CH3 H H
+ H CH3 H H
CCCC
CCCC
CCCC
H
H
H
H
H
H
polymerization
H CH3 H H
H CH3 H H
H CH3 H H
C C C C C C C C C C C C
H
H
H
H
H
H
Rubber particle
+
+
When an acid is added, the hydrogen ions, H+ neutralize the negative charges on the protein membrane.
+
+
Vulcanization of rubber
Properties of rubber can be improved through vulcanization.
Vulcanization is a process whereby rubber is reacted with sulphur to improved its properties.
Elasticity
Properties
Vulcanised rubber
More elastic
Unvulcanised rubber
Less elastic
Hardness
Harder
Softer
Tensile strength
Stronger
Weaker
Resistance to heat
Resistance to oxidation
Easily oxidized
Q: Why?
CC
CC
CC
CC
CC
vulcanisation
CC
CC
S
S
CC
CC
Natural rubber
S
C
S
C
Rubber molecules
S
C
Vulcanised rubber
C
S
S
S
CC
C
S
S
C
Cross-linkage of
sulphur atoms
Home Work
Review Questions
i.
ii.
iii.
pg 100 - 102
objective (no. 1-8)
subjective questions (1 and 2)
essay (no. 1c)
Before
45 mm
45 mm
During
59 mm
60 mm
45 mm
After
Diagram 2
Plan an experiment to compare one characteristic shown in Diagram 2 for both types of rubber.
Your planning should include the following aspects:
(a) Aim of the experiment
(b) All the variables
(c) Statement of the hypothesis
(d) List of substances and apparatus
(e) Procedure of the experiment
(f ) Tabulation of data
[17 marks]
Answer
(i) Problem statement:
Does vulcanized rubber is more elastic than
unvulcanized rubber?
(a) Aim:
To compare the elastic properties between vulcanized
rubber and unvulcanized rubber.
(b)
List of variable:
Manipulated variable = Type of rubber
(c) Hypothesis:
Vulcanized rubber is more elastic than unvulcanized
rubber. // sk3
50 mm
Clip
Rubber strip
Retort stand
with clamp
Thread
Weight 50 g
(vi) Procedure :
1. Clip is used to hung the strip of vulcanized rubber.
2. The original length of the vulcanized rubber is
measured.
3. A weight of 50 g is hung on the strip of vulcanized
rubber.
4. The increased in length of the vulcanized rubber
strip is measured.
5. The weight is removed.
6.
The final length of the vulcanized rubber strip is
measured.
7.
Step 1 to 6 are repeated using unvulcanized rubber.
(vii) Tabulation:
Original
length /mm
Increase in
length /mm
Vulcanized rubber
45
59
14
45
unvulcanized rubber
45
60
15
50
HOT SPOT
SPM 2008
Prepared by;
Kamal Ariffin B Saaim
SMKDBL
Manipulated variable:
Action to be taken:
Responding variable:
Action to be taken:
Fixed variable:
Action to be taken:
Alumina,
Alumina,AlAl
2O
2O
3 3
CC
(ce)
(ce)
CC
(g)(g)
9H
9H
20 20
2H
2H
6 (g)
6 (g)+ +CC
7H
7H
14 14
Panas
Panas
Nonana
Nonana
Etana
Etana
Heptena
Heptena