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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
Trade name
4,4'-DICHLORODIPHENYL SULFONE
1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses of the Substance/Mixture
-
Monomer
Signal word
- Warning
Hazard statements
- H319
- H413
Precautionary statements
General
- None
Prevention
- P264
- P273
- P280
Response
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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
-
- P337 + P313
Storage
- None
Disposal
- P501
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/ attention.
CAS-No.
80-07-9
GHS Classification
Eye irritation , Category 2 ; H319
Chronic aquatic toxicity , Category
4 ; H413
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.2 Mixture
-
Flush eyes with running water for several minutes, while keeping the eyelids wide open.
If eye irritation persists, consult a specialist.
In case of ingestion
-
4.2 Most important symptoms and effects, both acute and delayed
In case of inhalation
Effects
- Mechanical irritation from the particulates generated by the product.
- Thermal decomposition can lead to release of hazardous gases and vapors
In case of skin contact
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Concentration [%]
>= 99 - <= 100
4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
Effects
- Mechanical irritation from the particulates generated by the product.
In case of eye contact
Effects
- Mechanical irritation from the particulates generated by the product.
In case of ingestion
Effects
- Low ingestion hazard.
4.3 Indication of any immediate medical attention and special treatment needed
-
no data available
powder
Foam
Water
Water spray
Carbon dioxide (CO2)
None
Combustible material
In a fire, the polymer melts, producing droplets which may propagate fire.
Once started, a fire will tend to self extinguish (see section 9).
Risk of dust explosion.
Heating can release hazardous gases.
Further information
-
4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
-
no data available
Hygiene measures
-
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Value type
TWA
Value
0.8 mg/m3
Basis
Solvay Acceptable Exposure Limit
4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
8.2 Exposure controls
Control measures
Engineering measures
- Provide local ventilation appropriate to the product decomposition risk (see section 10).
- Provide appropriate exhaust ventilation at places where dust is formed.
- Refer to protective measures listed in sections 7 and 8.
Individual protection measures
Respiratory protection
- When workers are facing concentrations above the exposure limit they must use appropriate certified respirators.
- Use only respiratory protection that conforms to international/ national standards.
Hand protection
- When handling hot material, use heat resistant gloves.
Eye protection
- Safety glasses with side-shields
- Dust proof goggles, if dusty.
Skin and body protection
- Long sleeved clothing
Hygiene measures
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Protective measures
- When using do not eat, drink or smoke.
Form: granular
Physical state: solid
Colour: off-white
Odour
odourless
Odour Threshold
no data available
pH
Not applicable
Melting point/range
148.3 C
397 C
Flash point
Not applicable
no data available
The product is not flammable., May form combustible dust concentrations in air
Flammability/Explosive limit
Explosiveness:
Risk of dust explosion.
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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
Auto-ignition temperature
no data available
Vapour pressure
0.0000007 hPa
Vapour density
1.51
Density
no data available
Solubility
Water solubility :
0.86 mg/l ( 20 C)
Thermal decomposition
no data available
Viscosity
no data available
Explosive properties
no data available
Oxidizing properties
no data available
Polymerisation
Hazardous polymerisation does not occur.
Oxidizing agents
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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
-
Carbon monoxide
The release of other hazardous decomposition products is possible.
no data available
Skin corrosion/irritation
no data available
no data available
no data available
Mutagenicity
Genotoxicity in vitro
no data available
Genotoxicity in vivo
no data available
Carcinogenicity
bis(4-chlorophenyl) sulphone
Rat
Oral
Exposure time: Prolonged exposure
no observed effect
Mouse
Oral
Exposure time: Prolonged exposure
no observed effect
Rat
Oral
NOEL parent: 500 mg/kg
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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
STOT
STOT - single exposure
STOT - repeated exposure
bis(4-chlorophenyl) sulphone
no data available
Oral - Rat
NOAEL: 1.5 mg/kg
Target Organs: Liver
Oral - Mouse
NOAEL: 1.5 mg/kg
Target Organs: Liver
Aspiration toxicity
Further information
bis(4-chlorophenyl) sulphone
no data available
non-significant hydrolysis,
t 1/2 (Hydrolysis)
Half-life indirect photolysis: > 1 y
Biodegradation
Biochemical Oxygen Demand (BOD)
bis(4-chlorophenyl) sulphone
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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
12.3 Bioaccumulative potential
Bioconcentration factor (BCF)
bis(4-chlorophenyl) sulphone
suspected bioaccumulation
Water
low solubility and mobility
Soil/sediments
adsorption on mineral and organic soil constituents
no data available
no data available
Ecotoxicity assessment
Chronic aquatic toxicity
bis(4-chlorophenyl) sulphone
Empty containers.
Dispose of as unused product.
For unused and uncontaminated product, the preferred options include sending to a licensed, permitted: recycler,
reclaimer, incinerator or other thermal destruction device or industrial landfill.
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4,4'-DICHLORODIPHENYL SULFONE
Revision Date 24.03.2015
Note: The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of
transport regulations for hazardous materials, it would be advisable to check their validity with your sales office.
Status
Listed on Inventory
Listed on Inventory
Listed on Inventory
Listed on Inventory
Listed on Inventory
Listed on Inventory
not determined
H319
H413
Information contained in this material data sheet is believed to be reliable but no representation, guarantee or warranties of any kind
are made as to its accuracy, suitability for a particular application or results to be obtained from them. It is up to the
manufacturer/seller to ensure that the information contained in the material safety data sheet is relevant to the product
manufactured/handled or sold by him, as the case may be the Government makes no warranties expressed or implied in respect of
the adequacy of this document for any particular purpose.
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