patoskie (rp22856) HW 14 Thermo 3 vanden bout (50985)

This print-out should have 25 questions.

Multiple-choice questions may continue on
the next column or page find all choices
before answering.
001 10.0 points
A 100 g sample of ice at 10 C is added to
500 g water at 90 C in an insulated container.
What is the final temperature after thermal
equilibrium is reached?
1. 20 C
2. 90 C
3. 60 C

of ice at 20 C completely to liquid water at

38 C.
Answer in units of kJ
004 10.0 points
...greater change in disorder in this problem really just means greater change in entropy. Unfortunately, we have yet to purge
our questions from this old term of disorder.
Remember, when disorder is mentioned, we
really mean dispersal of energy. Now answer
the following true or false question:
For a given transfer of energy, a greater
change in disorder occurs when the temperature is high.

4. 40 C

1. False

5. 0 C

2. True

002 10.0 points

The specific heat for liquid argon Ar() is
20.8 J
25.0 J
and
gaseous
Ar(g)
is
. The
mol C
mol C
enthalpy of evaporation is 6506 J/mol. How
much energy is required to convert 1 mole of
liquid Ar from 5 C below its boiling point to
1 mole of gaseous Ar 5 C above its boiling
point?

005 10.0 points

Place the following in order of increasing entropy.
1. liqiud, solid, and gas
2. solid, liquid, and gas
3. gas, liqiud, and solid

1. 6960 J

4. solid, gas, and liqiud

2. 6555 J

5. gas, solid, and liqiud

3. 6735 J
4. 6290 J
5. 6495 J
003 10.0 points
Consider the specific heats
H2 O(s) = 2.09 J/g C,
H2 O () = 4.18 J/g C, and
H2 O(g) = 2.03 J/g C.
The heat of fusion for water is 334 J/g and
its heat of vaporization is 2260 J/g. Calculate
the amount of heat required to convert 70 g

006 10.0 points

Which substance has the lower molar entropy?
1. KCl(aq) at 298 K and 1.00 atm
2. KCl(s) at 298 K and 1.00 atm
3. They are the same
4. Unable to determine
007 10.0 points
Calculate the standard entropy of vaporiza-

patoskie (rp22856) HW 14 Thermo 3 vanden bout (50985)

tion of ethanol at its boiling point 352 K. The
standard molar enthalpy of vaporization of
ethanol at its boiling point is 40.5 kJ mol1 .
1. +115 JK1 mol1
2. +513 JK1 mol1
3. 40.5 kJK1 mol1

010 10.0 points

For the four chemical reactions
I) 3 O2 (g) 2 O3 (g)
II) 2 H2 O(g) 2 H2(g) + O2 (g)
III) H2 O(g) H2 O()
IV) 2 H2 O() + O2 (g) 2 H2 O2 ()
which one(s) is/are likely to exhibit a positive
S?

4. +40.5 kJK1 mol1

1. All have a positive S.

5. 115 JK1 mol1

2. III and IV only

008 10.0 points

Suppose that 140 g of ethanol at 22 C is mixed
with 255 g of ethanol at 75 C at constant
atmospheric pressure in a thermally insulated
vessel. What is the Ssys for the process?
The specific heat capacity for ethanol is 2.42
J/g K.
Answer in units of J/K
009 10.0 points
Consider the following processes. (Treat all
gases as ideal.)
I) The pressure of one mole of oxygen gas
is allowed to double isothermally.
II) Carbon dioxide is allowed to expand
isothermally to 10 times its original volume.
III) The temperature of one mole of helium
is increased 25 C at constant pressure.
IV) Nitrogen gas is compressed isothermally
to one half its original volume.
V) A glass of water loses 100 J of energy
reversibly at 30 C.
Which of these processes leads to an increase
in entropy?
1. III and V
2. II and III
3. I and II
4. V
5. I and IV

3. II only
4. I and II only
5. I, III and IV only
011 10.0 points
For the evaporation of water from an open
pan at 25 C, the values of S for the water,
the surroundings, and the universe must be,
respectively,
1. None of these is correct.
2. positive, positive, positive.
3. positive, negative, zero.
4. positive, negative, positive.
5. negative, negative, negative.
012 10.0 points
Consider the unbalanced reaction
Al2 O3 (s) + CO(g) Al(s) + CO2 (g)
Species

Hf0
kJ/mol

S0
J/mol K

Al2 O3
CO
Al
CO2

1676.0
110.5
0.0
393.5

50.92
197.6
28.3
213.6

patoskie (rp22856) HW 14 Thermo 3 vanden bout (50985)

Estimate G at 298 K if 5 moles of
Al2O3 (s) is reacted.
Answer in units of kJ
013 10.0 points
For the vaporization reaction
Br2 () Br2 (g)
0

at a certain pressure, H = 30 kJ/mol and

S 0 = 0.099 kJ/mol K. At what lowest
temperature will this process be spontaneous?
Answer in units of K
014 10.0 points
Use thermodynamic values from your books
Appendix Four for this problem. Youll need
to use the Hf and the S values. Your
answer will be close enough to pick the right
answer (2 sig figs worth) using our books numbers.
Estimate the minimum temperature at
which magnetite can be reduced to iron by
graphite.
Fe3 O4 (s) + 2 C(s) 2 CO2 (g) + 3 Fe(s)
Use standard thermodynamic data from tables.
1. 787 C
2. Magnetite will be reduced by carbon at
any temperature.

What is the entropy change for the reaction

C2 H2 (g) + 2 H2 (g) C2 H6 (g)
at 25 C, if

C2 H2 (g)
H2 (g)
C2 H6 (g)

S0

J

Kmol

Hf0

kJ
mol

200.94 226.73
130.68
0
229.6
84.68
J
Answer in units of
K mol
016 (part 2 of 4) 10.0 points
What is the enthalpy change for the reaction?
Answer in units of kJ/mol
017 (part 3 of 4) 10.0 points
Using the given data, find the standard reaction free energy of this reaction at 25 C.
Answer in units of kJ/mol
018 (part 4 of 4) 10.0 points
Assuming Hr and Sr are unaffected by
temperature changes, find the temperature at
which Gr is 0.
Answer in units of K
019 10.0 points
A friend says that as a plant grows and takes
an unordered set of molecules and puts them
in a highly organized system the second law
of thermodynamics is violated. Your best
response is that

3. 984 C
1. you must be thinking of the third law.
4. Magnetite cannot be reduced by carbon
at any temperature.

2. the plant is not at equilibrium and hence

the argument is invalid.

5. 535 C
6. 1790 C

3. while the entropy involved in the plant

growth decreased, the entropy in the universe
increased as a result of this process.

7. 670 C
015 (part 1 of 4) 10.0 points
In part 4 of 4 of this problem the terms Hr
and Sr are used. Remember that the subscript r is for reaction, just like rxn.

4. the second law applies only to chemical

systems and not biological systems.
020 10.0 points
Which of the following must be true of an

patoskie (rp22856) HW 14 Thermo 3 vanden bout (50985)

isolated system (a system which does not exchange energy or mass with its surroundings)
as a result of the Second Law of Thermodynamics?
1. S =

q
T

2. I only
3. I, III
4. III only

2. E = 0

5. I, II

3. Suniv > 0

6. II only

4. G < 0

7. II, III

021 10.0 points

In order for an endothermic reaction to be
spontaneous
1. heat must be supplied to the system.
2. the entropy increase in the system must
equal the entropy decrease in the surroundings.

024 10.0 points

Which one of the following reactions has a
positive entropy change?
1. 2 NH4NO3 (s)
2 N2 (g) + 4 H2 O(g) + O2 (g)
2. 2 SO2 (g) + O2 (g) 2 SO3 (g)
3. H2 O(g) H2 O()

3. endothermic reactions are never spontanteous.

4. nothing special is required; they are always spontaneous.
5. the entropy increase in the system must
be greater than the entropy decrease in the
surroundings.
022 10.0 points
All entropies of fusion are negative.

4. BF3 (g) + NH3 (g) F3 BNH3 (s)

5. N2 (g) + 3 H2 (g) 2 NH3 (g)
025 10.0 points
Calculate the normal boiling point of chloroform given that the standard entropy and enthalpy of vaporization of chloroform is +93.7
J/K/mol and 31.4 kJ/mol, respectively.
1. 450 K

1. False

2. 215 K

2. True

3. 375 K
023

10.0 points

Which of the following processes entropies

will increase as it proceeds from left to right?
I) NaCl(s) Na+ (aq) + Cl (aq)
II) CaCO3 (s) CaO(s) + CO2 (g)
III) H2 O() H2 O(s)
1. I, II, III

4. 405 K
5. 335 K