SAFETY DATA SHEET

SAFETY DATA SHEET

English

Product:

USA

FS: 4300-219
Last Revision: April 27th, 2015
1.
1.1.

Page: 1 / 4
Version: 05

Product and Company Identification

Product Identifier
Product Name
Product Form
(C.A.) Propantes SinterLite

Synonym
Bauxite
Bauxite
(Al2O3.xH2O),
(Al2O3.xH2O),
Sintered
Calcined

Substance

Common Name
Bauxite
(Al2O3.xH2O),
Calcined

1.2.

Relevant identified uses of the substance or mixture and uses advised against
Recommended Use
Hydraulic Fracturing
Use advised against
No information available

1.3.

Details of the supplier of the safety data sheet

Company
Minerao Curimbaba Ltda.
Rodovia Poos de Caldas / Caldas - Km 10
Address
Poos de Caldas

-Telephone No.

For further information

2.

00 35 3729 7600
Brazil
00 35 2107 8000
www.curimbaba.com.br

CEP 37701-970
Minas Gerais

CAS #
92797-42-7

Brazil
+ 55 35 2107 8128
+ 55 35 9839 7449

-Emergency Phone No.

English

Product:
FS: 4300-219
Last Revision: April 27th, 2015

2.1.

Classification of the substance or mixture

2.2.

Label Elements
GHS Label Elements
Signal Word

HMIS Hazard Rating for products:

- Not classified as dangerous according

to - ABNT NBR 14725:2012
- GHS Global Harmonized System HazCom

First Aid Measures

Description first aid measures
Inhalation
P304 + P340
Skin contact P332 + P352

5.

Firefighting Measures

IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If skin irritation occurs: Wash with plenty of water.
IF IN EYES: Rinse cautiously water with water for several minutes. Remove
P305 + P351 + P338
contact lenses, if present and easy to do. Continue rinsing.

Eye contact
P337 + P313
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED: Rinse mouth.
P301 + P330 + P314
Ingestion

Get medical advice / attention if you fell unwell.

4.2. Most important symptoms and effects, both acute and delayed
- No specific symptoms noted
Indication of any immediate medical attention and
- No further relevant information available
4.3.
special treatment needed

-Hazard pictograms
-Hazard statements

5.2.

6.

Not Applicable
Not Applicable

6.2.

-Symbol of Alert : NFPA 704

6.3.
7.
7.1.

7.2.

2.3.

Other hazards which do not result in classification Not Applicable

3.
3.1.

Composition / Information on Ingredients

Substance
Common Name
Synonym
Bauxite (Al2O3.xH2O),
Bauxite (Al2O3.xH20),
Sintered
Calcined
Two Stage Phenolic
Phenolic Resin
Resin
hexamethylenetetramine

3.2.

Mixture

Hexamine

CAS
Number

EINECS
Number

Concentration
%

92797-42-7

296-578-9

Balance

9003-35-4
100-97-0

Not Applicable

In case of Fire: Use agents suitable for surrounding fire

to extinguishing.
Specific Hazards arising from the Substance or Mixture
- Product Nonflammable, none in particular.
As in any fire, wear self-contained breathing
Special protective equipment and precautions for fire-fighters apparatus and full protective gear .
Accidental Release Measures
P280 + Wear protective gloves/eye protection.
Personal Precautions,
P284
In case of inadequate ventilation, wear respiratory protection.
Protective Equipment and
In case of damage to the packaging and / or spill, the
Emergency Procedures
product leaves the floor slippery. Wear boots.
Environmental Precautions
Product inert to the environment Class II B
Remove the material spilled manually using a shovel stuff;
Methods and material for
If it is in large quantities, use machines shovel loaders for the
containment and cleaning up
removal of material.
Handling and Storage
Wear protective gloves/eye protection.
P280 + P284
Precaution for Safe
In case of inadequate ventilation, wear respiratory protection.
Handling
Possible dust emission at the time of handling
Conditions for Safe
Store keeping the product stored in the original unopened packaging with
P401 + P402 identification in a clean location; Stacking up three pallets or big bags . Store in
Storage, including
incompatibilities
a dry place.
Exposure Control and Personal Protection
Control Parameters
Other
MAK (DE)
Bauxita (Al2O3.xH2O),calcinada
6 mg/m3
5 mg/m 3
Appropriate Engineering Controls
Use natural ventilation system
Personal Protective Measures, including personal protective equipment (PPE)

5.1. Suitable extinguishing media

6.1.
Not Applicable
Not Applicable

Page: 2 / 4
Version: 05

4.
4.1.

5.3.

Hazard Identification

USA

8.
8.1
8.2
8.3
-

Hands Protection

P280

Wear
gloves.

Eye Protection

P280

Respiratory
Protection

P284

< 3.5
<1

P370 + P378

protective

-Foot Protection

Wear
boots.

protective

Wear eye protection.

-Skin Protection
and Body

Suitable clothes to
work.

In case of inadequate
ventilation, wear
respiratory protection.

-Thermal Risks

Not Applicable

SAFETY DATA SHEET

E nSg pl ios oh

Product:

USA

FS: 4300-219
Last Revision: April 27th, 2015
.9

Physical and Chemical Properties

Appearance:
Solid
Color:
Black
Melting Point:
1861'C
Initial Boiling Point and and boiling range:
Flash Point
Not Applicable

.0
1
10.1.
10.2.
10.3.
10.4.
10.5.
10.6.
11.
11.1.
12.
12.1.
12.2.
12.3.
12.4.
12.5.
12.6.
.3
1

Page: 3 / 4
Version: 05

Waste from Residues /Unused Products

Regulatory Information
Safety, Health and Environmental Regulations Specific for the Chemical in question
Sara Hazard Category
Immediate (Acute) Health Hazard: No
- Delayed (Chronic) Health Hazard: No
Fire Hazard: No
- Reactivity Hazard: No
- Sudden Release of Pressure: No
Sara Section 313 Notifications
- Delayed (Chronic) Health Hazard: No
This product does not contain toxic chemicals subject to the reporting requirements of Section 313 of Title
III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372
- TSCA All components of this product are listed, automatically included, or are exempt from listing on the TSCA inventory
15.2. Chemical Safety Assessment
Not Applicable
15.1.
-

.6
1

Other Information

Not Available
Not Available

Issuing Date: March 03rd, 2011

Revision Date: April 27th, 2015

Requires no special procedures for sampling

Not recommended for use in foods, drugs and cosmetics
The information and recommendations found herein apply only to this product, and not combined with any other material
Failure to follow the above information, exempts Minerao Curimbaba responsibility for the misuse of the product
All figures expressed in this document are typical values, variations may occur
The data given are based on the current state of our knowledge
It is the buyer's responsibility before using any product to verify the data in operating conditions and determine
whether the product is suitable for their purposes
The SDS of the product can be requested by the customer of Minerao Curimbaba through
e-mail sds@grupocurimbaba.com.br

OCNS - E

Disposal Considerations
13.1. Waste Treatment Methods
-

Not Classified
Not Classified as hazardous
This product is not hazardous for transport by land, under the
Transport Hazard Classes
conditions required by law.
Packing group, if applicable
Not Classified as hazardous
Environmental Hazards
Not Classified as hazardous
Special Precautions for User
Not Classified as hazardous
Transport in Bulk according to Annex II of MARPOL 3/78 and the IBC Code
Not Applicable
U. S. Department of Transportation [DOT]
Not Classified

.5
1

P501

Dispose of contents/container of solid inorganic residue in

accordance with local/regional/national /international regulation.

Page: 4 / 4
Version: 05

Transportation Information
UN Number
UN Proper Shipping Name

- NL HMCS
OCNS - E
Categoria E
Not Available
Not Available
Not Available
Do not contain any PBT or vPvB substances
Not Available

USA

FS: 4300-219
Last Revision: April 27th, 2015

- Form:
Spherical Grains
- pH:
Neutral
Not Applicable

Toxicological Information
Information on toxicological effects This substance has no evidence toxicological effects
Acute Toxicity
Not Available
Severe Ocular Injuries / Eye Irritation Not Available
Corrosion/Irritation Skin
Not Available
Respiratory or skin sensitization
Not Available
Not Available
Mutagen city in Germ Cells
- Carcinogenicity
Not Available
Toxicity to reproduction
-Aspiration hazard
- Single Exposure
Not Available
Toxicity to specific target organs
- Repeated Exposure
Not Available

E npgol oi s h
S

Product:

.4
1

- Odor:
odorless
- Freezing Point:
Not Applicable
- Evaporation Rate:
Not Applicable
- Upper /Lower Flammable or
Not Flammable
Not Applicable
Flammability:
Explosive Limits:
Vapor Pressure
-Vapor Density
Not Applicable
Not Applicable
Apparent Density
-Bulk Density
3.20 g/cm3
1.82 g/cm3
Solubility (indicating the solvents)
-Water Solubility
Insoluble
Acid Solubility
5g of sample in 100mL of 12HCl + 3%HF / 30minutes, Temperature 66'C [150.8F]:
6.50%
Partition coefficient - n-octane / water
Not Applicable
Auto-Ignition Temperature (spontaneous)
Not Applicable
Decomposition Temperature
- Viscosity
Not Applicable
Not Applicable
Stability and Reactivity
Reactivity
Not Applicable
Chemical Stability
Product Stable
Possibility of Hazardous Reactions
Not Applicable
Conditions to avoid
Not Applicable
Incompatibles Materials
Not Applicable
Hazard Decomposition Products
Not Applicable

Ecological Information
Ecotoxicity
Persistence and Degradability
Bioaccumulative Potential
Mobility in Soil
Results of PBT and vPvB assessment
Other Adverse Effects

SAFETY DATA SHEET

-Version: 00
-Version: 05

-Original issue
-Reason: Update based on the GHS

Literature References

ABNT NBR 14725:2012

IUCLID Dataset of Bauxite (Al2O3.xH2O),calcined

Legend to Abbreviations
CAS:
Chemical Abstract Service
- SDS
Safety Data Sheet
EINECS:
European Inventory of Existing Commercial chemical Substances
ESIS:
European Chemical Substances Information System
Ficha de Informao de Segurana
Harmonized Materials Identification System
FIS:
- HMIS:
GHS
Global Harmonized System
-HazCom
Hazard Communication
MAK (DE):
Der MAK-Wert
-NFPA 704:
National Fire Protection Association
OCNS
Offshore Chemical Notification Scheme
-PPE
Personal Protective Equipment

MARPOL

PBT
SARA
cm3:

GHS HazCom
ESIS Result for EC# 296-578-9

Regulations for the Control of Pollution -IBC International Code for the Construction and Equipment of
by Noxious Liquid Substances
Ships carrying Dangerous Chemicals in Bulk
Persistent, Bioaccumulative and Toxic
-vPvB very Persistent and very Bioaccumulative
Superfund Amendments and Reauthorization Act
-TSCA Toxic Substances Control Act (USA)
Cubic Centimeter
- g:
Gram
- mg: Milligram
- 'C:
Degree Celsius