A review on manufacturing technique for Functionally Graded Materials

Amit Joshi (Department of Mechanical Engineering, GBPEC, Pauri)

Abstract
Designing FGMs allows manipulation of many material properties or new functions. Various
production methods are available for manufacturing graded structures such as casting,
deposition, laser cladding, combustion synthesis and powder metallurgy. There is also an
increased interest in devising new material systems and versatile methods of fabrication. Due to
recent advancements in the method of processing FGMs, they have gain popularity due to better
properties variation, volume fraction variation, economical and easy manufacturability. This
paper reveals the various developments in the manufacturing processes.
Key words: FGM, Powder metallurgy, electrophoresis, electromagnetic separation, spark
plasma, laser assisted manufacturing, novel methods.

Introduction
Further development in science and technology will depend upon the development of new
materials that can withstand severe conditions. There are two approaches: (a) create a new
material that differs completely from advanced materials currently in use, (b) develop an
advanced material with new functions. Composites can fulfill these requirements, especially
composites which have new functions. Due to that reason, many special composites have been
designed to eliminate the macroscopic boundary in laminated type materials. These are the
motivations for the development of functionally graded materials (FGM). Functionally graded

material concept was first proposed at Sendai, Japan in 1984. FGM on its simplest structure
consist of one side and a second material on the other side and an intermediate layer whose
structure, composition and morphology vary smoothly from one material to the other at the
micron level. FGM are multifunctional materials used for producing components that require
functional performance which is variable within the component. This is basically termed as
engineering the transition in micro/nano structures thus enhancing the overall performance of the
component. FGMs have some advantages such as:

Provide multi-functionality
Provide ability to control deformation, dynamic response, wear, corrosion, etc and ability

to design for different complex environments.

Provide ability to remove stress concentrations.
Provide opportunities to take the benefits of different material systems (e.g. ceramic and
metals)

Human bone is a good example of FGM found in nature. It is a mix of Collagen (ductile protein
polymer ) and hydroxyapatite (brittle calcium phosphate ceramic). The yellow marrow consisits
of fat which contributes to the weight and the red marrow is where the formation of red blood

cells occur. A gradual increase in the pore distribution from the interior to the surface can pass on
properties such as shock resistance, thermal insulation, catalytic efficiency, and the relaxation of
the thermal stress. The distribution of the porosity affects the tensile strength and the Youngs
modulus.

Historical Background of FGM: Already in 1972, the usefulness of functionally graded

composites was recognized in theoretical papers by Bever and Duwez and Shen and Bever.
However, their work had only limited impact, probably due to lack of suitable production
methods for FGMs at that time. It took 15 more years until systematic research on manufacturing

processes for functionally graded materials was carried in the framework of a national research
program on FGMs in Japan. In the year 1987 a large national project was commenced in Japan,
entitled Research on The Basic Technology for the Development of Functionally Gradient
Material for the Thermal Stress aimed for development of superheat-resistant materials for the
propulsion system of an air-frame of space frame. Since then, a major part of the research work
on FGMs was dedicated to processing of these materials and a large variety of production
processing of these materials and a large variety of production methods has been developed.
1. Powder Metallurgy Technique: It is a process by which fine powdered materials
are blended, pressed into a desired shape (compacted), and then heated (sintered) in a
controlled atmosphere to bond the contacting surfaces of the particles and establish the
desired properties. The process, commonly designated as P/M, readily lends itself to the
mass production of small, intricate parts of high precision, often eliminating the need for
additional machining or finishing. There is little material waste; unusual materials or
mixtures can be utilized; and controlled degrees of porosity or permeability can be
produced. The properties of powder metallurgy products are highly dependent on the
characteristics of the metal (or material) powders are used. Some important properties
and characteristics include chemistry and purity, particle size, size distribution, particle
shape and the surface texture of the particles.
By powder metallurgy route namely three types of gradient can be processed [1]:
(i)

Porosity and pore-size gradient: Porosity gradients may be created either by the
deposition of powder mixtures with different particle shape or varying the deposition
parameters including the use of space holders. Pore-size gradients in general are

produced by the variation of particle size. The different sintering behavior of the
powders requires special attention to manage the problems of part distortion but may
(ii)

also be used to produce a porosity gradient.

Gradients in chemical composition of single phase materials: The deposition of
powders with a continuous change in the composition of the mixture during sintering
will lead to a single phase material with a smooth change in the distribution of

(iii)

elements if the phase diagram shows solubility over the chosen range of composition.
Gradients of the volume content of phases and grain size gradients in two or
multiphase materials: The phase diagram of such a multi-component system is
characterized by no or limited solubility. Here grain growth of the soluble phase
during the heat treatment has to be taken into account, in particular if a liquid phase is
used for activated sintering. The microstructure of resulting FGM consists of two or
more phases with gradients in volume content or in grain size which were
predetermined during the deposition of the powders. The combination phases can
include metal-metal, metal-ceramic, and ceramic-ceramic systems. Microstructural
gradients can also be produced by controlling the phase equilibrium during liquidphase sintering with gradients of the components.

In general, step wise gradient and continuous gradient can be obtained by powder metallurgy
technique. For step wise gradient researchers has use dry P/M approach which involves
stacking of different layers, with various combination and orientation, of mixtures powders in
a die, usually done manually, of uniform thickness and distribution and then pre-compaction
is done to a desired level, after stacking of powder, cold isostatic pressuring (CIP) is done
followed by sintering process (Consolidation). Sintering of the powder is an important step as
gradient in the liquid phase can easily be destroyed so utmost care should be taken for

building the gradient. Most of the materials have different sintering behavior which is
affected by many other parameters like powder grain size, composition and porosity of the
mixture in use and also with the difference in coefficient of thermal expansion (CTE).
The various approaches used in wet P/M processes are centrifugal casting, wet powder
spraying, slip casting, gravity sedimentation, and slurry dipping process. Use of binders for
green body stabilization is generally needed in wet P/M technique which is then pull-up at
the time of sintering so as to make continuous gradient in the process.

Various materials being fabricated by Powder metallurgy technique:

Lot of combination of materials was successfully being fabricated by P/M technique.
Use of FGM in orthopedics and dentistry is reported in order to promote bone in-growth into
prosthetic implants. Hydoxyapatite (Ca10 (PO4)6(OH)2, (HA) is a bioactive material and reacts
with the living bone to give a strong bond that can resist high stresses. Various combination
of HA and other high toughness material were being investigated. Bishop et al. has used HATi combination FGM by P/M route. His study was mainly concentrated to the manufacturing
and macrostructure of FGM without detailed factors affecting the microstructure
characteristic and mechanical behaviour. It was Chu Chenglin et.al. [2] Who give a detailed
procedure of fabrication, analyzed microstructure, phase constitution, density and mechanical
properties and fracture behavior of this FGM. He by his experiment suggests that with the
increase in Ti content fracture behavior varies and can be controlled by Ti matrix. R. Roop
Kumar et.al [3] found success in fabrication of graded bioactive coating of HA/TiO 2 by P/M
process and mechanical properties of HA-TiO2-Ti FGM was measured using a nanoindenter. Coating of 230m was successfully obtained by this coating technique. Fumio

Watari et.al [4] has successfully fabricated HA/Ti FGM by P/M and the specimen of this
FGM is implanted into femora of ten week old Wistar strain rats to evaluate their
biocompatibility. The test shows positive result of this implant with the help of EPMA
elemental mapping method. In the further development in this field Lydia Helena Wong et al.
[5] fabricate tricalcium phosphate and fluoroapatite composites by dry P/M technique. In its
test he found that this composite become porous so if implanted the graded FA/-TCP would
become graded porous FA, which would be desirable for both bone ingrowth and bone
bonding. SivaPrasad Katkam et al. [6] successfully fabricate an FGM of HA and Ag 2O using
a microwave processing by gradually changing the composition of calcium phosphates from
the surface to the interior. By X-ray powder diffraction study it was found that the sintered
samples contain tricalcium phosphate (-TCP) and Ag gradually decreases with increasing
depth from the surface. He compare the FGMs formed by both microwave processing and by
conventional heat treatment and found that microwave processed FGM have more amount of
TCP and Ag on the surface (bioactive material) and thus have greater compositional control
in FGM fabrication by microwave processing. M.Bram et al. [7] introduces a prototype of an
acetabular cup made of titanium powders provided as biomedical implant in hip replacement.
The place holder method is attractive for the production of highly porous titanium implants.
Titanium is a well known implant material due to its biocompatibility. The open porosity
enhances the structural and functional bonding between implant surface and human bone.
Moreover this method of making highly porous functional parts with open porosity by
application of powder metallurgy can be used where the functional porosity is required. In
this method he uses titanium powder and the place holder material mixed in a volumetric
ratio of 26:74 and compact the mixture in a cylindrical die under 400MPa pressure and green

compact is machined by lathe to the spherical form of a cup taking into account the shrinkage
allowance followed by sintering in vacuum. The place holder must be removed at
temperatures below 150C to avoid strong increase of impurities like oxygen, carbon or
nitrogen.
Molybdenum is a good electrical and thermal conductor whereas mullite is an electrical
insulator and has a very low thermal conductivity. FGM of Mullite and molybdenum having
a large number of possible applications in electronics and microelectronics, in thermal barrier
coatings or in electrical conductor/insulator components was made by researchers. A.P.
Tomsia et al. [8] fabricate mullite/Mo FGM cylinders by pressure slip casting. In his work he
processed FGM by dipping the powders in ethyl alcohol slurry and advised not to use water
based slurries which make a homogeneous mullite/Mo composite instead of FGM. In the
mean time Bartlome et al. [9] again used the same combination with varying the grain size of
molybdenum, but the focus of this work was to evaluate the processing, mechanical
properties and microstructural properties. R Sivakumar et al. [10] developed a new modified
technique of centrifugal molding to produce mullite-molybdenum FGM. Here he used
alcohol based slips of binder and dispersant and a faster drying rates was employed for
graded cylinder in partial vacuum to avoid drying cracks. In this process of centrifugal
molding technique graded specimen are prepared by instant mix rather than mixing of premixed composite powder. He claimed to have a uniform gradation of Mo along radial
direction by this process. Gang Jin [11] also synthesizes this Mullite/Mo FGM by pulsed
electric current sintering (PECS) technique. In which the layered powder is sintered by a
pulsed electric current sintering apparatus at 150C/min rate up-to 1500 and 20MPa
pressure. The thermo-mechanical properties of mullite/Mo system were checked and found to

have a gradient distribution. Mullite/Mo FGM was fabricated by Shuheng Chen et al.[12] by
powder stacking process followed by vacuum sintering at 1500C. Author claimed that the
mullite/Mo FGM has well densified graded distribution with absence of new phase.
Ceramic-metal and ceramic-ceramic FGMs show promise for hypothesized applications such
as thermoelectric converters, graded solid oxide fuel cells, graded piezoelectrics, heat sinks
for fusion reactors, electrically insulating joints, and thermal barrier skins for light weight
space-planes. Zirconia/stainless steel continuous graded material was fabricated by S.Lopez
Esteban et.al [13] which can be used in electromechanical sensors, wearing sensors. Here
pressure slip casting is used for gradation in the structure. In his work author measures the
Vickers hardness and dielectric constant at various points in the gradient and through which
he found the percolation threshold (metal/insulator) location. Jingchuan Zhu et.al [14]
developed ZrO2-NiCr FGM by powder metallurgy. He found that cold forming and sintering
behavior of FGM strongly depends on the compositional variation. The shrinkage of ZrO 2 is
more at the high NiCr alloy matrix. This shrinkage difference should be controlled to develop
perfect FGM. Vickers hardness change with the composition change but the bending strength
does not change monotonically. J. Ma et.al [15] has developed a Ti/TiO2 FGM and studied
the effect of particle size and SiC additive on the sintering of the FGM. SiC as a sintering aid
has been shown to provide a greater enhancement in the sinterability of the TiB 2 layer and
resulted in a great improvement in both the flexural strength and toughness of the FGM. The
starting particle size improves the densification of the TiB2 ceramics and hence of the overall
FGM system. Al-(Al3Ti + Al3Ni) FGMs were fabricated by Yoshimi Watanabe and Tatsuru
Nakamura [16] by centrifugal method. Detail observation on the orientation of Al 3Ti platelets
and the size of Al3Ni granular particles were performed. The wear resistance of the FGM was

measured and the density of FGM is found smaller than that of Al-Al3Ni FGMs so these can
be used for transportation of parts subjected to harsh tribological conditions. Centrifugal
casting method was employed by R. Rodriguez-Castro [17] for the fabrication of Al
A359/SiCp where different casting rotational speeds were utilized while keeping all other
casting conditions constant. He found that with the increase in rotational speed volume
fraction profiles vary and high concentration were obtained at the outer circumference for
maximum angular speed and the concentration of particles was homogeneous due in part to
engulfment promoted by the high relative velocity between the solidification front and the
particles, and also due to the elevated cooling rates developed in this case. But with varying
the rotational speed the microporosity also get increased. In his study he found that the
matrix structure is modified in the reinforced region as a consequence of solidification taking
place rapidly and in very restricted spaces and also due to breaking of dendrites by the
combined loading action of accelerated particles and loaded dendrites. Quench modification
of the eutectic structure was observed, going from a fully modified structure at the opposite
side of the casting. In continuation with this FGM in his other paper R. Rodriguez-Castro et
al. studied the mechanical behavior including tensile and fracture properties of the same
FGM Al A359/SiCp composite. The effect of SiC particulate reinforcement on strengthening
of A359 Al alloy was limited up to a certain volume fraction. At the high cooling rate zone
(0.2-0.3 volume fraction of SiC) an improvement in tensile strength is seen due to uniform
distribution of reinforcement. Fracture toughness of the FGM composite was low for small
crack length due to limited dissipation of energy on contrary to this with longer crack lengths
the material surrounding the crack tip was more able to plastically deform thus fracture
toughness of the composite get increased. J.Q.Li [19] and his co-author fabricate YSZ-NiCr

functionally graded materials interlayer by hot pressing process. He found that the relative
density of the interlayer decreases as the YSZ content increases in the interlayer. By
conducting thermal cycling test the YSZ reach layer shows cracks after 2 thermal cycles
which can propagate anywhere in this region independently. By increasing the thickness of
interlayer the cracks generated are retired to a greater extent even after 10 thermal cycles.
When the interlayer thickness was increased to 2 mm no spallation was found in the joint
even after 30 thermal cycles and shear strength is also retained. O. Eso and his coauthor [20]
succeeded to manufacture WC-Co FGM by liquid phase sintering and discussed about the
various factors, which can be used to influence the migration of liquid during sintering like
gradients in grain size, carbon and cobalt content and sintering time. Author has explained
the effect of these factors based on the roles of capillary force and phase reactions. He found
that liquid phase cobalt migrates in the direction of carbon diffusion during liquid phase
sintering, which will lead to a continuous cobalt gradient in the final sintered microstructure
while maintaining Stoichiometric carbon content of sintered products. Al/SiC FGM were
produced by powder metallurgy route, exhibit microstructures with homogneneous
distribution of fragmented and clustered SiC particles in Al matrix by Mandira Bhattacharya
et al. [21] and had studied microstructure, porosity content and microhardness along with
effective flexural strength, thermal fatigue behavior and thermal shock resistance.
Ceramic materials are difficult to machine so in order to enhance the machinability of
materials we can use FGM as one of the solution. Ruigang Wang et al. [22] has developed a
new concept for manufacturing FGM of such ceramics by using Si 3N4/h-BN and
Al2O3/LaPO4 material combination. Here in this process they employed layers of different
materials on the core layer in different proportion on either side of the core layer. So by using

this processing technique they were able to fabricate the above two FGMs and thereby
enhancing the machinability and fracture toughness of ceramics.
FGMs can also be used in Plasma Facing Components (PFCs) in nuclear reactors where they
are imposed to very high heat and high neutron flux generated by plasma. Various
combinations were tried by researchers for a suitable material combination for PFCs. ChangChun Ge et al. [23] fabricate three combinations for PFCs of SiC/C, B 4C/Cu and W/Cu by
three different processing technologies and some primary results of plasma relevant
characteristic of these materials were reported. Combination of SiC/Cu material for PFCs
was reported by Yun-Han Ling et al [24]. The author has tested this material under plasma
condition and found that the chemical sputtering and thermal desorption is less as compared
to the materials used earlier. Ultra high pressure is employed in order to prevent macro
diffusion between SiC and Cu. A.H. Wu et al. [25] has fabricated SiC/C FGM by hot pressing
and then simultaneous step sintering of SiC and C so as to get FGM without micro-pores and
high thermal conductivity as compared to SiC/C prepared by CVI and CVD. So it can be
employed as first wall materials for fusion reactors. He also checked their samples for
thermal shock and fatigue and observed that they did not detect any micro-crack and flaw
under hundred times plasma erosion conditions. W/Cu FGM was manufactured by Wei-ping
Shen et al. [26] for plasma facing components. FGM mock-ups were manufactured by
resistance sintering under ultrahigh pressure or three times hot pressing. W/Cu FGM was also
successfully fabricated by Zhang-Jian Zhou et al. [27] by a novel one step method named
resistance sintering under ultra-high pressure without the addition of any sintering additive.
The density observed of this FGM was 97% of theoretical density. A special experimental
set-up is employed to fabricate the W/Cu FGM in which the green compacts of FGM having

five layered W/Cu were quasi isostatic loaded followed by alternating current flow to the
sample to heat the sample by Joule heating. In another study Bin-Bin Liu et al. [28] fabricate
W-Cu graded heat sink materials with nearly full density by particle size adjustment and
solid state hot press when the parameters like sintering temperature of 1060C, pressure of 85
MPa and holding time of 3 hr were maintained.
Defect free sintering of powders by injection molding technique was introduced by D.F.
Heaney et al. [29] on his research paper where the dilatometer study of various alloys is
studied to predict their compatibility during sintering. This was accomplished by comparing
the individual shrinkage versus temperature behavior of the candidate system. Based on his
study two materials 316L stainless steel/ Boron and Fe-10Cr steel/B were fabricated by
injection molding followed by sintering in vacuum. In his research he observed that for better
sintering of two materials by PIM components require one material to mimic the
densification behavior of the other material also the net shrinkage of the compacts after
sintering should be equal.
Piezoelectric actuators and sensors have novel applications for micromechanical systems
(MEMS) and smart material systems, especially in the medical and aerospace industries.
Piezoelectric composites with functional gradients are novel devices which can successfully
overcome the inherent structural defect in conventional piezoelectric bending-type actuators
resulting from the use of epoxy binder. The FGM piezoelectric device is a monolithic
structure, which has no mechanically weak junction or interface and also substantially
reduces discontinuous stress during operation. Thus longevity and reliability are enhanced. In
this regard Denger Jin [30] has developed a PZT/ZnO/PZT FGM piezoelectric bimorph
composite, in which ZnO ceramic was used as an internal electrode and also as a component

to modify the distribution of functional gradients. The author had claimed that it is a
piezoelectric device promising large displacement, high reliability and long longevity. Kenta
Takagi et al. [31] fabricate PZT/Pt piezoelectric composite FGM in which seven layers with a
centre symmetric composition profile, in which the compositions from the central layer to the
surface layer were stepwise, changed. He found that the piezoelectric constants decrease
monotonously but the dielectric constant remarkably increases as the Pt content increases.
The main drawback of this FGM is that the Pt is a novel material and is very costly.
Y.Gelbstein et al. [32] summarizes the design considerations, preparation techniques and
characterization methods of graded p-type Pb1-xSnxTe samples with equi-wide layers and with
an optimal Z envelope. In this research the potential for increasing the thermoelectric
efficiency, using functionally graded materials based on Pb1-xSnxTe was explored by
understanding the characteristics and the mechanisms of the annealing processes. The
researcher claimed that the thermoelectric properties of this FGM are comparable to those of
single crystals.
Transition metal silicides have been the focus of extensive investigations for high
temperature applications including structural materials for turbine blades, engines and other
applications at temperature exceeding 1500K. For industrial use a toughness of about 10MPa
m1/2 is required and for turbine applications a fracture toughness of 15-20 MPam 1/2 is desired.
Various attempt have been reported to fabricate FGM using high melting point silicides of
niobium. Ellen M. Heian et al. [33] synthesize Nb 5Si3/Nb functionally graded composites
using elemental powders of niobium and silicon in Stoichiometric ratio. They used a custom
build apparatus where the powder layers are subjected to uniaxial pressure in argon
atmosphere and AC electric current was passed through the die and sample to heat the sample

until a chemical reaction is initiated. The author has claimed the enhancement in fracture
toughness with increase in content of Nb.
Particulate metal matrix composite (PMMC) with a functionally graded characteristic are
used in many field. In an attempt Jian Zhang et al. [34] synthesize Al/Mg 2Si in-situ
composite by centrifugal casting with Mg2Si reinforcements in both the inside and the
outside wall of the tube specimen so as to get high inside wear-resistance. The density of
Mg2Si is less than Aluminum matrix so with this combination the hardness of the material
gets enhanced at the cost of reduced ductility at outer region. Li Sun et al. [35] has studied
the various processing parameters for the fabrication of alumina/zirconia FGM. In this
research Li Sun has varied various parameters such as the powder characteristics, compaction
load, interface profile, and temperature ramp/soak profiles in order to determine the optimum
parameters for eliminating cracks and decreasing camber. The sintering kinetics of the chosen
powder mixture was investigated under optimized experimental parameters and the
phenomenological constitutive models to describe the relationship between the densification
rate and the relative density were determined and compared.
Yoshimi Watanabe and Yasuyoshi Fukui [36] done microscopic study of Al-base intermetallic
compound-dispersed functionally graded materials fabricated by centrifugal method and
observed the microscopic features by several analytical techniques. Here three methods of
fabricating FGMs was introduced those are Al/Al3Ti FGM fabricated by the centrifugal solid
particle method, Al/Al3Ni and Al/Al2Cu FGMs fabricated by the centrifugal in-situ method
and Al/(Al3Ti+Al3Ni) hybrid FGM made by the simultaneous combination of both solidparticle and in-situ methods. He emphasize on the formation mechanism of graded
composition by the centrifugal method as a practical FGM fabrication method. Yoshimi

Watanabe and Shin Oike [37] employs in situ Al-Al 2Cu FGMs fabricated by the centrifugal
in situ method using hypoeutectic, eutectic and hypereutectic Al-Cu alloys and origin of the
graded composition in FGMs is discussed. J.Q.Li et al. [38] conceptualize a new 5 layered
FGM of YSZ-NiCrAl using the Al 2O3-NiCrAl composite with 25, 52.2 and 75 vol% Al 2O3
as interlayers. The Al2O3-NiCrAl composite was fabricated by mixing NiO, Al and Cr
powders and then reactive hot pressing. No cracking was found in the FGM after 10 thermal
cycles upto 1000C. Alumina-Nickel FGM was fabricated by Michael L.Pines et al. [39] by
pressureless sintering and porosity and shrinkage were measured and models were developed
to understand both the nature of the porosity during sintering and the sintering behavior of
the FGM. Al-Cu-Fe ternary alloy was casted by centrifugal in situ method to fabricate a new
type of functionally graded material (fiber dispersed FGM) by Watanabe et al. [40] having
four different phases of Al, Al2Cu, Al7Cu2Fe () and Al13Fe4 phases. The shape of phase
was fiber (needle) and is increasing towards the outer region of the ring and its orientation
and aspect ratio varied in the rings in a gradually graded manner. Al-Al 3Ni in situ
intermetallic composite was fabricated by T.P.D. Rajan et al. [42] by vertical centrifugal
casting. In his experiment Al-Ni alloys with varying percentage of nickel 10-40% were
employed and he finds that by using Al-20wt% Ni it gives the best microstructure.

2.

Electrophoretic deposition:

The potential of the electrophoretic deposition

(EPD) technique for the realization of unique microstructure and novel (and complex)
material combinations in a variety of morphologies and dimensions is being increasingly
appreciated by material scientists. Although the basic phenomena involved in EPD are
well known and have been the subject of extensive theoretical and experimental research

there is general agreement in the scientist community that further R&D work needs to be
done to develop a full, quantitative understanding of the fundamental mechanism of EPD
to optimize the working parameters for a broader use of EPD in materials processing.
EPD is a combination of two processes, electrophoresis and deposition[42].
Electrophoresis is the motion of charged particle in a suspension under the influence
of an electric field gradient. It was discovered by the Indian scientist G.M.Bose in the
1740s in a liquid-siphon experiment. The Russian Scientist Reuss, was the first to
observe electric field-induced motion of clay particles in the water. The second process is
deposition, i.e., the coagulation of particles into a dense mass. In Electrophoretic
deposition, powder particles are charged in suspension and are deposited on an electrode.
The suspension rate of particles is varied during the process and the sintering of various
layers of varying composition occurs at different temperatures.
EPD needs a stable suspension with particles charged so as to respond to an applied
electric field. Therefore only electrostatic and electosteric stabilization are appropriate for
suspensions to be electrophoretically deposited. The oxide particles which are present in
the surface of material are usually covered by amphoteric hydroxyl groups. These when
suspended in a electrolyte suffer reaction with the H +/or OH- of a suspension liquid,
depending on the suspension pH[42]. The reactions are as follows:
MOH(surface) + OH- = MO-(surface) + H2O
MOH(surface) + H+ = MOH2+(surface)
According to these equations, there is an intermediate pH where the number of positively
and negatively charged surface groups are equal thus resulting in zero surface charge.
The profile can be controlled precisely by controlling the deposition current density,
second component flow rate, suspension concentration etc.
The setup for deposition of material is shown in figure:

(a) EPD setup

(b) Detail of the

deposition cell
In typical EPD deposition there are two electrodes one positively charged and other negatively
charged. The suspension of one ceramic/metal is put in the deposition cell than by varying the
suspension of other ceramic/metal we can deposit an FGM either at the two electrodes which
depends on the pH of suspension. EPD is a cheap and simple technique to fabricate complicated
ceramic shapes.

Various materials being fabricated by Electrophoretic deposition technique:

Lot of work in EPD has been done and lot of research is still going on. Sarkar and Nicholsan [43] are the
first to demonstrate the EPD can be successfully use for fabrication of laminated and functionally graded
materials. C. Kawai and S. Wakamatsu [44] fabricate C/C based composite by having one side rich with
C/C composite and the other with C/SiC side. The author has claimed to achieve a specific strength and
oxidation resistance of the FGM approximately 1.8 times and equal to those of the C/SiC composite.
Partho Sarkar et al. [42] synthesize Al 2O3/YSZ, Al2O3/MoSi2, Al2O3/Ni and YSZ/Ni FGMS by constant
current Electrophoretic deposition. Here author cited suspension stability by famous DLVO theory and

proposed an alternative mechanism for deposition based on EPD mechanism and lyosphere
distortion/thinning. WC-Co FGM was produced by S.Put [45] by using EPD from a suspension of hard
metal powder in acetone, with variable cobalt content. Dense FGM plates with closed porosity and a Co
gradient from 4 up to 17 wt% were obtained in this process by pressure-less sintering at 1290C and
1340C. One important observation in this process is that when this FGM was pressure-less sintered at
1400C for one hr in order to get dense FGM the gradation get disappeared and a homogeneous but fully
dense material is obtained. In another experiment Put et al. [46] produce a ZrO 2-WC graded FGM plate of
3535 mm, with a WC gradient from 0 wt% up to 55 wt% by EPD. After hot pressing the thickness of
plate was 2mm with a gradient of 1mm width. Author has developed an kinematic model in order to
predict the gradient profile based on Hamakers equation. Further continuation S. put et al. [47] developed
an FGM with an outer layer of pure Al 2O3, a central homogeneous Al 2O3/ZrO2 composite layer and
intermediate continuously graded layers by means of EPD from a suspension of acetone and butylamine
and subsequent sintering in air. Moreover, a symmetrically graded Al 2O3/ZrO2/Al2O3 FGM disk with a
diameter of 25mm and a thickness of 4mm were also engineered, containing Al 2O3-rich edges and a ZrO2Al2O3 core. Ceramic-metal WC-Co FGM disk of 25mm diameter and thickness of 4mm after sintering
was also produced with a cobalt gradient from 4 to 17wt%.
FGM can also be used as a substitute to coating where the coating thickness is of range 1-150m which
limits the coated material life subjected to wearing like in cutting tools and moreover there is a sharp
interface between coating and substrate, often causing delamination during operation also thermal stress
induced during the operation is itself a problem. These problems can be addressed by using FGM, in
which the thermal stresses can be reduced and the coating adherence can be improved by providing a
continuously gradual transition in microstructure between the two elastically dissimilar materials. Stijn
Put et al. [48] produce an functionally graded hard-metals with a continuously graded symmetrical
profile. An FGM of WC-Co-Ti(C,N) with a gradient in cobalt and Ti(C,N) by means of electrophoresis
and subsequent cold isostatic pressing and liquid phase sintering is reported. For creating a symmetric

gradient profile an EPD model is analyzed and based on that experiment is done which has excellent
correlation with the prediction of gradation.

The Vickers hardness and fracture toughness is also

measured of the sample which was found to increase continuously from 16.1GPa in the bulk material to
18.1GPa on the edge while fracture toughness reduces along the same direction from 8.8 to 6.6 MPam 1/2.
Author suggests that EPD model and colloidal shaping technique can be used to engineer the slope, width
and composition of the gradient by changing the EPD processing parameters and concentration of the
suspension.
By EPD evolution of gases like hydrogen is a problem also the thickness of gradient is very small to
overcome such difficulty J Tabellion and R. Clasen uses ion permeable membrane thus dividing the
electrophoresis chamber into two chambers that contain the suspension and another fluid, respectively.
Deposition occurs at the membrane whereas the ions can pass the pores of the membrane so that
recombination of the ions and generation of gas bubble occurs at the electrodes with no gas bubbles
incorporated into the deposit. Based on this a in house EPD camber was used by the researcher and silica
glass and zirconia components were successfully manufactured having complex shapes like tubes or
structured parts.
G. Anne et al. [50] measured the strength and residual stresses of functionally graded Al 2O3/ZrO2 discs
prepared earlier by S.Put and his coauthors [47] also they studied the mechanism of that. In their work
they find the increase in biaxial strength from 288MPa for pure Al 2O3 discs to 513MPa for FGM also an
interesting thing which he get is that there is not a considerable effect on the compressive stress of FGM
by hot isostatic pressing but it get drastically increased upon surface material removal by grinding.
Zeolites have good gas adsorption capability. Zeolites have been well recognized for their unique ability
to absorb and separate gases, catalyse chemical reactions and selectively exchange cations in solutions.
These properties result from their uniform, well defined pore structure which promotes the adsorbents
chemical interactions that occur at discrete sites within their lattice. These chemical interactions either

generate or require heat, thus the application of zeolites for either endothermic or exothermic processes is
often limited by heat transfer into or from these insulator like alumino-silicates. FGM provide a new and
unique approach in managing heat transfer and maintaining temperature uniformity in either adsorptive or
catalytic applications of these molecular sieves. X. Wang et al. [51] conceptualize a FGM of 3A/5A
zeolites by electrophoretic deposition using acetone and n-butylamine.
For preparing biocompatible materials EPD process was successfully utilized in order to get a coating of
HA-silica-chitosan of graded composition and laminates by K.Grandfield and I.Zhitomirsky [52].
Coatings of 100m were successfully deposited with varying silica content.
In another work E. Garcia-Lecina et al. [53] Ni/SiC functionally graded coatings have been obtained by
electrochemical deposition of silicon carbide particles from nickel Watts baths with different
concentrations of SiC particles in solution. Electoacustic technique was employed to get zeta potential
and particle size from which effect of the concentration of SiC particles in solution on the amount of SiC
deposition was investigated. Higher the percentage of SiC particles in the electrolyte the higher the
percentage of SiC particles embedded in the nickel matrix, also SiC particles change the texture from
(100) to a mixed preferred orientation through (111) and (211) axes. Wear resistance also get increased
when incorporating SiC particles in the nickel matrix.

3. Spark Plasma Sintering:

Sintering as an art had origins that are thousands of years old. The

formation of bricks by heating clay bodies in an open pit fire is one of the earliest examples of sintering
practiced by ancient civilizations of Mesopotamia. The ancient Indians sintered metals and ceramics as
early as 3000BC. Understanding the basic phenomena and the important parameters governing sintering
has led to investigation on means to activate the process. The objective of these investigations was to
enhance mass transport to either make possible the sintering of extremely refractory materials or to lower
the temperature of consolidation. One of the methods of activating the sintering process involves the use
of electrical current. Although the recent widespread use of this approach has been generated by the

availability of commercially built devices, its origin is much older. Spark plasma sintering (SPS) method
enables the manufacture of dense materials in a short period at low sintering temperatures. SPS utilizes
the high energy of a high temperature plasma (discharge plasma) generated when pulse-formed electric
energy is applied to the space among fine particles. Then this heat treated at varying temperature and
pressure to give graded material.

Schematic Diagram of Spark Plasma Sintering Technique

SPS process utilizes pulsed high DC current along with uniaxial pressure to consolidate powders.
The sintering of powders under the simultaneous influence of a current and pressure is done in
SPS process. Powders are placed in a die (typically graphite) and heating is affected by passing a
current (typically pulsed DC) through the die and the sample (if latter is conducting) while a
pressure is applied on the powder. The characteristics which govern the SPS process are therefore
(a) high heating rate, (b) the application of a pressure, and (c) the effect of the current.

Various materials being fabricated by Spark Plasma Sintering

Hongo Huo et al.[54] fabricated functionally graded hydroxyapatite/yttria stabilized tetragonal zirconia
composites by spark plasma sintering in order to get multilayered FGM. The HA/Yttria stabilized TZP
composite exhibited much improved mechanical properties compared to the pure HA ceramics also with
increasing the sintering temperature higher mechanical properties are achieved. The bending strength of
the FGM nearly doubled to 200MPa as compared to pure HA ceramics when sintered at 1200C. Yu

Peng Lu et.al [55] reported an FGM with two layers of HA top coating/HA+TiO 2 bond coat
composite coating on Ti fabricated by plasma spraying. FGMs surface and interface
microstructure are studied before and after heat treatment. The author has claimed to probe into
the toughening and strengthening mechanism of TiO2 in the bond coat and to evaluate the effect
of the bond coat on the stress level of the HA top coating. H.Mishina et al. [56] fabricate
ZrO2/AISI316L functionally graded materials for joint prosthese. The powders are prepared by mixing
ZrO2 (3Y-PSZ) with 10-50vol% of AISI316L granules. In this experiment attempt were made to evaluate
the fabricated ZrO2/AISI316L FGMs to optimize the properties of the ductile metals and the highly
biocompatible ceramics while giving a high resistance to wear. The author suggests the thickness of FGM
layers should be more than 2mm so as to increase the fracture toughness and the wear resistance of the
FGM for better mechanical and biotribological properties.

The Al2O3-Ti3SiC2 FGMs composite has been synthesized by SPS method by Luo Yongming [57]. The
presence of the Ti3SiC2 phase in the matrix has a profound influence on the properties of the composite.
The percolation threshold of this FGM was observed at 20-30wt% Ti 3SiC2 and due to it an increase in the
electrical conductivity from 10-4 to 105 Sm-1 followed by reduction in hardness was observed. Haibo Feng
et al. [58] successfully synthesized six layered Ti-Tib-TiB 2 FGM composite rapidly at relatively low
sintering temperature by spark plasma sintering. In these layers, the synthesized TiB were needle shape
and short agglomerated whiskers, and the volume proportion of agglomerated whiskers increased and the
size of the needle shape TiB decreased with the increasing of target TiB volume fraction.
Manchang Gui et al. [59] developed an Al-SiC FGM by plasma spraying. In his research thermal
conductivity of the composites sprayed with Al powders containing 55 and 75vol% SiC particles were
measured along with the mechanism of thermal transfer in the composites was discussed, and numerical
analyses were conducted based on theories of Maxwell and thermal boundary resistance. In this study
they found that interfacial gaps at the interface of Al/SiC and boundary of aluminum grains, porosity and
Fe impurity are three factors to degrade the thermal conductivity. Long ball milling time for feedstock
preparation and small SiC size cause further degradation of thermal conductivity and these factors can be
addressed by using hot process to improve the thermal conductivity of the composites.
Gurusamy Shanmugavelayutham and Akira Kobayashi [60] employ versatility of image analysis methods
for microstructural quantification for Thermal barrier coatings deposited with partially stabilized zirconia
(PSZ), alumina and zirconia alumina composite coatings by gas tunnel type plasma spraying. In gas
tunnel type plasma spraying torch spraying powder is fed inside plasma falme in axial direction from
centre electrode of plasma gun. The coating was formed on the substrate transverse at the sparaying
distance L. The thickness of all the coatings and the distribution of porosity along the cross section were
measured by image analysis. In plasma spraying, the microstructure of the coatings is strongly dependent
on the processing conditions. With increase in the alumina mixing ratio, the Vickers hadness of the high
hardness layer became large, which was changed from H v = 1083 to 1371 at the same time the porosity in

hardness layer was decreased which was changed from 33.7% to 7.65%. Here only nontransferable
tetragonal phase of ZrO2 were observed.
Dustin M. Hulbert et al. [61] developed B4C-Al FGM by spark plasma sintering and after that the boron
carbide compacts with large precipitous density gradients were melt infiltrated with pure Aluminum at
1180C for 10min in a 10-3 Pa to 10-4Pa vacuum. Prior to melt infiltration, X-ray diffraction data indicates
that the B4C compacts have some microstructural defects present and after melt infiltration some of the
defects are dissipated and small amounts of Al 3BC were present.

4. Electromagnetic Separation Method:

Application of electromagnetic force to material processing, so called Electromagnetic Separation
Method (EPM) has been recognized as a cutting edge technology, especially in the field of advanced
material processing. Because of the different conductivities between the primary phase (low electric
conductivity) and the metal melt, electromagnetic force (EMF) scarcely acts on the primary phase.
Thus, the primary phase is moved in the direction opposite to that of the EFM when the melted metal
with primary phase solidifies under an electromagnetic field. Archimedes force will act on the
primary particles because of the difference in the electrical conductivity between the primary particles
and the melt and its direction is opposite to the direction of EMF induced in the primary melt.

Schematic of Electromagnetic Separation Method

When the melt temperature is down below the liquidus temperature, primary particles will precipitate
from the parent melt and move in the direction of the resultant force to the one side of the sample.
With the temperature decreasing, primary particles precipitate continuously and regular distribution of
the primary particles precipitate continuously and regular distribution of the primary particles from
one side to the other is formed in the sample.

Various Materials fabricated by Electromagnetic separation method

Changjiang Song et al. [62] had produced in situ multi-layer FGMs using alloy with nominal
composition Al-22% Si-3.9% Ti-0.78%B by electromagnetic separation method. In this work three
layers of Al/Si/Ti, Al/Si eutectic structure and Al/Si/Ti are formed. The interfaces between the layers
are gradient transition in the microstructure from one layer to another in the in situ multilayer
composite samples by Electromagnetic Separation method. In continuation to its research work
Changjiang Song [63] and his fellow researchers fabricated Al/Mg 2Si functionally graded materials
and study the effects of the process parameters of the particle volume fraction distribution by the

ESM process. In this experiment the author elaborate that the emf, the melt solidification rate and the
alloy composition greatly affects the particle volume fraction. They also investigate that FGM can
only be produced when the emf reaches beyond a critical value. In another attempt Changjiang Song
et al. [64] fabricated Al/Si FGM by electromagnetic separation method. Investigation results show
that the microstructure of the sample changes from Al-Si hypereutectic structure to Al-Si eutectic
structure to Al-Si hypoeutectic structure from one side of the sample to the other side. In continuation
to this in the same year author [65] also developed Al/Al 3Ni FGM by ESM. The major axis of
primary Al3Ni particles tends to be perpendicular to the direction of the electro-particles Archimedes
force, however, in the opposite part, orientation arrangement of primary Al 3Ni particles is random. In
another work Chang-Jiang Song et al. [66] successfully fabricate Al/Mg 2Si FGM by electromagnetic
separation method. In this research the author get a difficulty in fabricating the FGM without other
additional elements due to the formation of primary Mg 2Si particle clusters and as such a smooth
gradient distribution is not achieved. Addition of Ti can give rise to precipitation of Al3Ti phase and
Al-Si-Ti intermetallic compound before the precipitation of primary Mg 2Si particles, which prevents
the formation of larger Mg2Si particle clusters and results in in-situ Al/Mg 2Si FGMs with a smooth
gradient distribution of primary Mg2Si particles.
Xiaoling Peng et al. [67] use the concept of magnetic separation to prepare ferromagneticnonmagnetic functionally graded material via slip casting. ZrO 2-Ni FGM with a continuously
changing composition was successfully fabricated using this method.
Qiang Wang et al. [68] fabricated Mn-Sb composites with a gradient structure in morphology and
composition towards the surface by high magnetic field gradient. The volume fraction of the
segregated phases strongly depended on the product of the magnetic flux density and its gradient.
This process creates new opportunities for the fabrication of more complex bulk hybrid materials in
situ. Tie liu et al. [69] fabricate MnSb/Sb-MnSb FGM using a semi-solid forming process under
magnetic field gradient. Mn-Sb alloy with a hypoeutectic composition was used to produce particle-

dispersed composite. During the process, the alloy was heated to a temperature lower than the
liquidus temperature of the alloy, where the dispersed phase remained solid in a liquid matrix. The
author investigated that MnSb particles could be controlled by the combination of the field gradient
and holding time also the direction along which the volume fraction of the particles increased could
be controlled artificially by adjusting the field gradient direction.

5. Laser Assisted Manufacturing Technique:

Laser assisted manufacturing technique is applied for manufacturing functionally graded materials
coating. Various methods are conceptualized which employs laser and are discussed here:

(a) Laser Cladding: Laser cladding is a technique used to coat a substrate with a layer of other materials
to improve surface properties such as resistance to corrosion, erosion or wear. The process typically
involves blowing a powder mixture pneumatically into the laser melted zone. The processing parameters
such as laser power, transverse speed, and powder flow rate are controlled to achieve the required
thickness with minimum dilution from the substrate. The two main laser cladding (and alloying)
techniques are:
(i) Pre-Placed powder: here powder is preplaced on the substrate with a binding agent to stick the
powder into place until it is melted by the laser beam. The whole process is normally shrouded in
an inert gas such as argon. It has a small operating region of process parameters where low
dilution and a good fusion bond is possible.
(j) Blown powder: it has a much larger operating region. Powder is blown directly into a laser
generated melt-pool as it scans across the surface of the substrate. The powder melts and a clad
track is built up. Complete coverage is achieved by overlapping the tracks.
First research paper so far as with author knowledge is concern is reported by K. Mohammed Jasmin et
al. [70] for fabricating FGM of Al-SiC on a nickel alloy substrate (IN 625) having three successive tracks
were deposited to give a wide range of compositions progressing from inner to the outer regions. He uses

premixed aluminum and SiC powders. However, the accompanying changes in microstructure through the
3mm thick FGM were not fully satisfactory. J.H. Abboud et al. [71] produced functionally graded nickelaluminide and iron-aluminide coatings via laser cladding. The composition of each clad layer was tailor
made. Compositional control was achieved by keeping the powder flow of Ni or Fe constant and
changing the flow rate of Al. In-situ alloying occurs in the laser generated melt pool and compositional
control is exercised via the powder feeder rates. Functionally graded coatings (up to several mm in total
height) were produced by superimposition of a series of layers of different compositions. In further
research Abboud et al. [72] produced another functionally gradient titanium-aluminide composite by laser
cladding. 2mm thick FGM with a progressive increase in the Al content layers from 0 to 35%Al (50 at
%Al) were reported by vertically overlapping two clad layers using powder mixture of selected
compositions.
Y.T. Pie and J. TH. M. DE Hosson [73] uses one step laser cladding process to manufacture AlSi40
functionally graded coatings consisting of silicon primary particle surrounded by -Al dendritic halos.
Silicon exhibits a continuous increase in both size and volume fraction along with morphology changes
from bottom to top of the FGM tracks. In another research the author [74] studied the fivefold twining
and growth features of Sip with orientation imaging microscopy and electron microscopic examination. In
the FGM so produced of Al-40 wt% Si five-fold branched silicon particles were observed with maximum
particles in the upper region. These particles have grown from twinned decahedron nuclei. In another
research Pei et al. [75] produce SiC p/Ti6A14V FGM by laser melt injection where SiCp are injected just
behind the laser beam into the extended part of the laser melt pool by high beam scanning velocity. An
injection model based on finite element calculation is designed based on the temperature/viscosity field of
the laser pool for a deeper understanding of the mechanism of formation of FGM and based on the
calculations the experiment is conducted.
M. Riabkina-Fishman et al. [77] produced functionally graded tungsten carbide coatings on M2 high
speed tool steel by laser cladding with direct injection of WC powder into the melt pool. Single layer

coatings having four different types of structures with a wide alloying range of tungsten and carbon were
produced by varying laser beam power and beam transverse velocity. The author concluded that the
increase in the degree of alloying from layer to layer as well as the thickness of each layer can be varied
by changing the beam power, the beam travel velocity and the powder injection rate. With the increase in
tungsten content microhardness and wear resistance of the coating increases as compared to unalloyed
laser treated M2 steel. G. Pintsuk et al. [78] developed W/Cu FGM by both 3-D laser cladding and spark
plasma spraying in which he employs powders of Copper and tungsten along with a coating of copper.
Here for melting tungsten and copper powders different power of laser are employed owing to low
melting point of Cu as compared to W, thus for laser sintering of graded structure copper side is
assembled first.

(b)

Laser Engineered Net Shaping (LENS):

it is a technology that is gaining

importance and in early stages of commercialization. Its strength lies in the ability to fabricate fully dense
metal parts with good metallurgical properties at reasonable speeds. A high power laser is used to melt
metal powder supplied coaxially to the focus of the laser beam through a deposition head. The laser beam
typically travels through the centre of the head and is focused to a small spot by one or more lenses. The
X-Y table is moved in raster fashion to fabricate each layer of the object. Typically the head is moved up
vertically as each layer is completed. The laser beam may be delivered to the work by any convenient
means like right angle mirror or fiber optics. Metal powders are delivered and distributed around the
circumference of the head either by gravity, or by using an inert, pressurized carrier gas. Even in cases
where its not required for feeding, an inert shroud gas is typically used to shield the melt pool from
atmospheric oxygen for better control of properties, and to promote layer to layer adhesion by providing
better surface wetting. Most system uses powder feedstocks, but there has also been work done with
material provided as fine wires. In this case the material is fed off-axis to the beam. The building area is
usually contained within a chamber both to isolate the process from the ambient surroundings and to
shield the operators from possible exposure to fine powders and the laser beam. The laser power used

varies greatly, from a few hundred watts to 20KW or more, depending on the particular material, feed-rate
and other parameters. Objects fabricated are near net shape, but generally will require finish machine.
They are fully dense with good grain structure, and have properties similar to, or even better than the
intrinsic materials.

Weiping Liu and J.N. DuPont [78] fabricate crack free functionally graded TiC/Ti composite materials by
LENS with compositions changing from pure Ti to approximately 95 vol% TiC. Amit Bandyopadhyay et
al. [79] fabricate porous and functionally graded structures for load bearing implants. The author has
demonstrated that LENS can fabricate net shape, complex metallic implants with designed porosities up
to 70 vol% to reduce stress-shielding. The effective modulus of Ti, Ni-Ti, and other alloys was tailored to
suit the modulus of human cortical bone by introducing 12-42 vol% porosity. To minimize the wear
induced osteolysis, unitized structures with functionally graded Co-Cr-Mo coating on porous Ti6Al4V

were also made using LENS which showed high hardness with excellent bone cell-materials interactions.
In another research B. Vami Krishna and its co author [80] proposed novel design concepts coupled with
LENS method for fabricating metallic implants with three-dimensionally interconnected porosities down
to 70 vol%. It is shown that the porosities and mechanical properties of laser processed pure Ti structures
with interconnected porosity and/or novel internal architecture can be tailored by changing the LENS
process parameters. In another experiment B. Vami Krishna et al. [81] fabricated functionally graded
crack free coatings Co-Cr-Mo coating on Ti-6Al-4V alloy structures with metallurgical sound interface
using optimized LENS parameters with excellent reproducibility. Vitro biocompatibility test is conducted
and it shows that increasing the Co-Cr-Mo concentration in the coating reduced the live cell numbers after
14 days of culture on the coating compared with base Ti-6Al-4V alloy, however, coated samples always
showed better bone cell proliferation than 100% Co-Cr-Mo alloy. Author suggested that 50% Co-Cr-Mo
alloy surface provides the best combination of wear resistance and biocompatibility.

(c)Selective Laser Sintering:

It was developed in the late 1980s as layer manufacturing process

that was used for rapid prototyping. Later on it also becomes a common technology to produce products
for long term use. SLS have the potential to be ideal technique to automatically build complex
components using material gradation. SLS creates objects directly from CAD models using a layer-bylayer material deposition and consolidation approach. Thin layers of powders are successively deposited
and selectively fused using a computer-controlled scanning laser beam that scans patterns corresponding
to slices of the CAD model. With appropriately designed powder deposition systems, this approach
allows deposition systems; this approach allows successive layers but also within each layer, enabling the
manufacture of FGM components.

FGMs by SLS have also been reported previously. Jespon et al.[82] created one dimensional FGMS by
SLS processing of blends of tungsten carbide and cobalt powders. In this work, FGMs were created in the
plane of each layer by carefully placing different blends contiguously and scanning the entire layer using
a laser. Beal et al. [83] reported the SLS processing of one-dimensional FGMs using blends of H-13 tool
steel and cooper powders. In this work, five different powder blends were deposited in the plane of a layer
using a multi-container feed hooper and processed by an Nd:YAG pulsed laser. Filter elements from metal
polymer powder compositions were fabricated by the LENS method by I.Shishkovsky et al. [84] Here in
his work permeability and porosity coefficients of synthesizing 3D parts were determined and dependence
on laser influence parameters and a polymer quantity are discussed. Haseung Chung and Suman Das [85]
produce functionally graded Nylon-11/silica nano-composites by selective laser sintering. They developed
SLS processing parameters for the different compositions by design of experiments (DOE). They reported
that particulate filled functionally graded polymer nano-composites exhibiting a one-dimensional
composition gradient can be successfully processed by SLS to produce three-dimensional components
with spatially varying mechanical properties in a single, uninterrupted process run.

6. Novel New Concepts For Fabricating FGM:

Various new methods were

conceptualized by researchers for synthesizing FGMs have their own peculiarity:

(a)Combustion synthesis: In 1967, Merzhanov and his cooperators raised the concept of SHS
and developed combustion synthesis. Combustion synthesis is a technique in which a material is
synthesized from a homogeneous reactant mixture of powders or a compact made of the reactant
powder mixture without further processing and involves two steps: mixing the reactant powder within
a certain stoichiometry and effecting the combustion synthesis reaction to produce the required
materials. Combustion synthesis or self propagating high temperature synthesis (SHS) methods are
known to be relatively advantageous due to lower energy consumption, shorter processing times and
better availability of starting materials. The ignition can be performed either locally at one point or by
heating the whole pellet up to the required ignition temperature of exothermic reaction.

The flow chart for manufacturing a FGM via SHS reaction coupled with simultaneous
densification
The control of the combustion temperature is an important issue in the combustion synthesis of FGMs.
The temperature must be sufficiently high everywhere to cause densification yet not so high to avoid

uncontrolled reactions. Because of the fast kinetics, it was reported that FGM fabrication by SHS is less
prone to homogenization. Therefore, the gradient structure is generally preserved.

(b)

Impeller Dry Blending Technique:

This novel method for manufacturing FGMs

was conceptualized by A.J. Ruys et al. [86] which offer the possibility of producing large bulk-FGMs of
a wide range of controllable continuous gradients and compositions. The impeller dry blending process
claims to offer large bulk FGMs with an easy control of continuous gradient and compositions. The
process of involves four steps: Feeding, blending, homogenization and deposition.
Feeding is done by two separate feed hoppers. Blending of the powders is done by using control gates
such that volume percentage of all the components is 100%. Homogenization of the blended powder mix
is done by impeller chamber. Deposition is done in the mold beneath the impeller. The uniqueness of this
process lies that controlled segregation and blending is achieved from this process. No binder is required
and the process is restricted to flat FGM parts. Author suggested use of hydrostatic shock forming so as
to get localized pressure more than 30GPa by explosive charge in order to get dense FGMs where the
constituents have a huge difference in their melting temperature such as in case of metal-ceramic.

(c)Gradient Slurry Disintegration and Deposition:

this innovative technique for

synthesizing free-standing, one dimensional FGM was given by M. Gupta, M. O. Lai and T. S. Srivatsan.
Here they successfully fabricate Al-Cu/SiC FGM by this technique. Here they use Al-Cu metals and
superheat them to 950C to ensure wettability of the reinforcing phase in the alloy melt followed by SiC
addition which is preheated up-to 950C and the mixture is stirred at 294 rpm to facilitate controlled
sedimentation of the SiC particulates. The slurry is then allowed to flow into a stream through a hole
drilled centrally in the crucible. The molten stream was disintegrated using argon gas jets and deposited
onto a metallic substrate.

Schematic of the gradient slurry disintegration and deposition technique

(d)

Differential Temperature Aging Technique: This new concept was given by S.

Bakshi, K. Chattopadhyay and S. Kumar [88] of Indian Institute of Science, Banglore (India). In this
technique they devised to produce a FGM in an originally homogeneous, Al-4.6Cu alloy specimen
utilizing a differential heat treatment technique. Most of the processing routes for the preparation of FGM
involve creation of composition gradients in the material over a length scale so as to get the desired
property gradient. The required gradient in functional properties can also be achieved through a variation
in microstructure without altering the composition of the bulk. In his work Bakshi et al. achieved the
functional gradient by giving a differential aging treatment to an age-hardenable alloy. The differential
aging leads to the development of a gradient in microstructure and hence in properties. For preparation of
FGM they first solutionzed the alloy specimen in an furnance and then quenching is done in water then
the specimen are immediately transferred to the temperature gradient furnace with varying temperature
gradient of 6C/mm in the range of 70C to 170C. The specimen is left for being differentially aged for

38 hours so as to get one side which is at 170C will be peak aged whereas, for the same time period the
material remains under aged to various degrees for the aging temperatures. Therefore in principle, a
differencial temperature aging may lead to a microstructural as well as hardness gradient across the
specimen cross section.

Experimental set-up for preparing FGM by differential age hardening

(e)Cast-Decant-Cast (CDC) process: this novel technique for production of light weight
functionally gradient alloys was proposed by Michelle Scanlan, David J. Browne and Andrew Bates
[89]. The procedure involves the introduction of the first liquid alloy A into a mould allowing it to
partially solidify against the mould walls, then decanting any unsolidified material, leaving of alloy A
against the mould wall. Alloy B is then introduced into the mould in a superheated state, partially
remelting the inner layer of alloy A, thus mixing with it and forming a smooth gradient between alloy
A and B. The author suggested three techniques associated with the CDC process:

turnover

technique- in which rectangular steel mould is fixed to a rotatable frame which enables the mould to
be inverted for the decanting step. Second technique is internal decant- here mould consists of a
reservoir, drainage channels, carbon rods and a steel core around which a functionally gradient hollow
cylinder will form. The carbon rods are used to plug the drainage channels to prevent alloy A draining

into the reservoir as a layer is forming. In the third method called low pressure technique the molten
materials are pressurized in an airtight vessel allowing it to rise up a tube into a mould. The material
is held under pressure in the mould until it is solidified.

Schematic apparatus for turnover technique

Schematic apparatus for internal cast decant

Schematic low pressure sequence for Cast Decant Method

Conclusion

This paper gives a basic insight for FGMs beginners. The main focus of this paper is on the main
techniques for developing FGMs and the resent advancement in them. Effort is made to cover all
the aspects of manufacturing FGM from various conventional as well as new methods. All
important materials used to make graded materials are deliberately tried to be cover in this work.

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