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Here we provide a few selected examples of practical situations involving conduction heat
transfer processes. Examples are selected somewhat arbitrarily and partly reflect my own
experience.
Perishable foodstuffs can be preserved by freezing. The food is frozen by refrigeration at
sufficiently low temperature. Since the freezing rate affects the desirable characteristics of
the food, food engineers are interested in controlling the freezing process in order to obtain
optimal food characteristics such as flavor and nutritional value.
Thermal energy is internally generated in microelectronic devices by the electric current
passing through them. The resulting heat must be dissipated to prevent malfunction of the
device. Microelectronic engineers want to determine conduction heat transfer rates inside
microelectronic packages in order to design them reliably.
Pressurized water nuclear reactors produce energy by radioactive disintegration of ceramic fissile material contained inside fuel rods. The generated energy is conducted through
the cladding of the fuel pin and transferred onto a primary water circuit for subsequent
transfer onto a steam circuit. Nuclear engineers are interested in controlling the rate of conduction heat transfer through the cladding in order to prevent its potentially catastrophic
failure.
Domestic heating requirements raise steeply during the winter in northern latitudes. Ideally, we would like to maintain a comfortable warm interior at the lowest possible price.
Construction and material engineers are interested in using construction materials that produce the lowest rates the conduction heat transfer.
A common processing method using in the metallurgical industry is continuous casting.
Steel, copper and aluminum are routinely produced using this technology. The process is
used to convert refined liquid metal into solidified ingot. Liquid metal is poured into a chilled
reciprocating mold on one end and the (partially solidified) ingot is extracted on the other
end. For the metal to freeze heat must be conducted through the solidified shell in contact
with the mold and though the mold wall. Continuous casting engineers are interested in
1
Temperature is a measure of the degree of hotness at a point in a material and is a macroscopic manifestation of the potential and kinetic energies of the constituent molecules. When
temperature differences exist between two distinct points in a medium the result is the transport of thermal energy downhill the temperature gradient. The rate of energy transport has
the units of energy per unit time (J/s = W ). The amount of thermal energy crossing a unit
area per unit time while flowing in the direction of decreasing temperature is the heat flux
vector
q = kT.
Here, q is the heat flux (W/m2 ), T is the temperature (K), is the gradient operator and k
is the thermal conductivity of the medium (W/mK). The term T is thus the temperature
gradient vector.
The thermal conductivity is the rate of thermal energy transfer per unit area and per
unit temperature gradient. Thermal energy is transported within a solid by the electrons
and the phonons (lattice vibrations) inside the material. The transport of energy is hindered
by the presence of imperfections or by any kind of scattering sites.
Thermal conductivities of solids at room temperature vary from 0.1 W/mK for good insulators (e.g. asbestos) up to 400 W/mK for good conductors (e.g. silver). The conductivity
changes mildly with temperature except at very low temperatures where it can acquire very
large values. For instance, pure copper at 10 K has a conductivity of about 20,000 W/mK.
Note that if there is macroscopic transport of matter (e.g. fluid flow) inside the body,
the mass flow makes an additional contribution to the transport of energy (convective heat
transfer). This contribution is disregarded when studying conduction heat transfer.
The heat equation is a differential statement of thermal energy balance. The thermal energy
content E (J) of a material body can change only if (i) energy is removed/added through
its bounding surface or (ii) energy is generated or absorbed within the body.
Consider a small volume element V inside a material undergoing heat conduction processes. The rate of change of thermal energy per unit volume H (in W/m3 ) at a point inside
the volume is
H
H =
t
where H is the enthalpy or heat content per unit volume of material in J/m3 . From thermodynamics, the following relationship expresses the accumulated enthalpy in a material
resulting from increasing its temperature from T1 to T2 ,
Z
H=
T2
T1
Cp dT
where and Cp are, respectively the density (in kg/m3 ) and specific heat (in J/kgK) of the
material. More complex H T relationships are also possible.
Introducing the above H T relationship, the rate of change of thermal energy then
becomes
T
H = Cp
t
3
Now, the net outflow of thermal energy through the bounding surface A of volume V is
given by the divergence theorem as
Z
A
q ndA =
Z
V
qdV
Finally, the rate of internal heat generation/absorption at a point in the body (W/m3 )
is assumed given as g(r, t).
The thermal energy balance equation for the volume V is
Z
V
H
dV =
t
Z
V
[ q + g(r, t)]dV
However, since the integrals are equal the arguments are also equal and the most general
form of the differential thermal energy balance equation is
H
= q + g(r, t)
t
and is called the heat equation.
More restrictive forms of the heat equation are
Cp
T
= kT + g(r, t)
t
k
Cp
is the thermal diffusivity of the material (in m2 /s) and measures the speed of penetration
into the body of an applied thermal load at its surface. Values of range from 0.1 106
for cork to 300 106 for potassium.
The following are commonly used forms of the heat equation
Cp
T
T
T
T
=
(k
)+
(k
) + (k
)+g
t
x x
y y
z z
1
T
1 T
T
T
=
(kr
) + 2 (k
) + (k
)+g
t
r r
r
r
z z
4
1
1
T
1
T
T
T
= 2 (kr2
)+ 2
(k sin
)+ 2 2
(k
)+g
t
r r
r
r sin
r sin
1
a T
a T
a T
T
= [
(k 2
)+
(k 2
)+
(k 2
)] + g
t
a u1 a1 u1
u2 a2 u2
u3 a3 u3
in general orthogonal curvilinear coordinates (u1 , u2 , u3 ), where a1 , a2 , a3 are the scale factors
and a = a1 a2 a3 .
Exercise Consider the problem of one-dimensional transient conduction heat transfer
inside a rod of cross sectional area A where energy is conducted along the direction of the
axis of the rod (x-axis). At some arbitrary interior point of the rod x introduce a control
volume of size x. Perform an energy balance over the control volume (i.e. accumulation =
input - output) and derive the one-dimensional heat equation.
Boundary Conditions
Boundary conditions are the representation of the thermal energy balance at the bounding
surface of the material. They measure heat exchange interactions between the material and
its surroundings in W/m2 . Common heat exchange mechanisms are convection
qconv = h(T T )
where h is the heat transfer coefficient (W/m2 K) and T is the bulk temperature of the
surrounding environment; radiation
qrad = (T 4 Tr4 )
where , and Tr are, respectively the emissivity of the material (-), the Stefan-Boltzmann
constant (= 5.729 108 W/m2 K 4 ) and the temperature of the far-field reflecting surfaces;
and heat supply from an external energy source, qsup .
The energy balance equation at the surface of the material is then
qn + qsup = qconv + qrad
Boundary conditions can sometimes be expressed in linear form. For example, if the
temperature at the surface is specified one obtains boundary conditions of the first kind.
Alternatively, if the heat flux at the surface is given, boundary conditions of the second kind
result. Next, if a (linear) relationship between surface heat flux and temperature is specified,
for example,
T
= h(T T )
n
we talk about boundary conditions of the third kind. Finally, at the surface of contact of
two solids an interface boundary condition can be stated in terms of an interfacial thermal
conductance.
k
Moving Solids
Moving material carries with it its thermal energy by mass flow. If the material is moving
along the x direction with velocity ux , the amount of thermal energy transported per unit
area per unit time is
qmass = Cp T ux
and the total heat flux (conduction plus mass transport) is
qx = k
T
+ Cp T ux
x
For a material containing a (known) velocity field u = (ux , uy , uz ) the energy balance equation becomes
T
+ u T ] = k2 T + g.
Cp [
t
This is sometimes called the convection-diffusion equation.
Anisotropic Media
In anisotropic materials thermal energy flows at different rates along different directions.
This is taken into account by assigning a second order tensor character to the thermal
conductivity. The x-component of the heat flux vector qx becomes
qx = (k11
T
T
T
+ k12
+ k13
)
x
y
z
and similarly for the other two directions. For orthotropic materials heat still travels at
different rates along different directions but the heat flux along any direction is driven only
by the temperature gradient along that direction, i.e. kij = 0 when i 6= j. The heat equation
then becomes
T
T
T
T
Cp
=
(kx
)+
(ky
) + (kz
) + g.
t
x
x
y
y
z
z
6
Composites are formed by bringing together into close contact distinct materials. The material properties of the assembly change discontinuously at the contact surface. Also, the
mechanical conditions of the contact at the interface affect the rate at which energy flows
across it. In general, the analysis of heat transfer at an interphase interface characterized by
its normal n and separating the two materials 1 and 2 requires specification of two conditions:
a) the heat flux balance
(k1 T1 ) n = (k2 T2 ) n
and the relationship between the temperatures on both sides of the interface T1 and T2
usually in terms of the contact conductance h, i.e.
(k1 T1 ) n = h(T1 T2 )
The so called perfect thermal contact condition simply states that at the interface h and
T1 = T2 . The above equations must be added to the stated initial and boundary conditions
of the particular problem at hand.
exp(x2 /4t)
4t
7
x exp(x2 /4t)
t 4t
hL
1
k
where L = V /A is a characteristic length and Bi, the Biot number is a measure of the ratio
of internal and external resistances to heat flow.
If the only mechanism for energy exchange with the surroundings is convection through
the bounding surface, the differential thermal energy balance equation (in W ) becomes
Cp V
dT
= hA(T T )
dt
10
Quantity
E
E/t
H
H/t
q
k
Cp
SI Units
J
W
J/m3
W/m3
W/m2
W/mK
kg/m3
J/kgK
m2 /s
W/m2 K
5.729 108 W/m2 K 4
English Units
1 BT U
1 BT U/hr
1 BT U/f t3
1 BT U/hrf t3
1 BT U/hrf t2
1 BT U/hrf to F
1 lb/f t3
1 BT U/lbo F
1 f t2 /hr
1 BT U/hrf t2o F
English Units
BT U
BT U/hr
BT U/f t3
BT U/hrf t3
BT U/hrf t2
BT U/hrf to F
lb/f t3
BT U/lbo F
f t2 /hr
BT U/hrf t2o F
0.173 108 BT U/hrf t2o R4
SI Units
1,055 J
0.29307 W
37,260 J/m3
10.3497 W/m3
3.154591 W/m2
1.7307 W/mK
16.02 kg/m3
4,186.8 J/kgK
2.5807 105 m2 /s
5.6782 W/m2 K
Exercise Verify all the units and unit conversions given in the tables above.