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Introduction to Combustible Dust Hazards and Mitigation for IHs


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Protecting Worker Health

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Introduction to Combustible Dust
Hazards and Mitigation for IHs

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Protecting Worker Health

Introduction to Combustible
Dust Hazards and Mitigation
for Industrial Hygienists
Gary Q. Johnson, P.E.
Workplace Exposure Solutions LLC
December 10, 2013

Agenda

Conditions for dust deflagrations


Combustible dust tests
Explosion protection equipment
Dust collection equipment
Combustible dust procedures
Summary
Combustible Dust Hazards and
Mitigation

What Dusts Are Combustible?

OSHA Website general description


(www.osha.gov/dts/shib/shib073105.html)
The vast majority of natural and synthetic

organic materials, as well as some metals, can


form combustible dusts.
A combustible dust explosion hazard may exist in
a variety of industries, including: food (e.g.,
candy, starch, flour, feed,) plastics, wood, rubber,
furniture, textiles, pesticides, pharmaceuticals,
dyes, coal, metals (Al, Cr, Fe, Mg, Zn,) and fossil
fuel power generation.
Combustible Dust Hazards and
Mitigation

Dust Explosion Pentagon


Fire Triangle
plus Two
Heat or
Ignition

Chemical Chain
Reaction
Oxidant
(Air)

Fuel

New Fire Triangle


Combustible Dust Hazards and Mitigation

Animation of Dust Explosion


Hayes Lemnertz Incident

US Chemical Safety Board

Combustible Dust Hazards and


Mitigation

10

FLASH FIRE SEQUENCE WITH FLAMMABLE VAPORS ~ 3 SECONDS DURATION

SERIOUS BURNS BECAUSE CLOTHES IGNITE


(~500 F) FROM FLASH FIRE (>1500 F)

Combustible Dust Hazards and


Mitigation

11

Combustible Dust Hierarchy of Controls

Design it out substitution? Not likely


Engineering controls explosion
protection and dust collection
equipment
Administrative controls
housekeeping, hot work, equipment
maintenance, Management of Change,
emergency response, training
PPE flame resistant garments
Combustible Dust Hazards and
Mitigation

12

Light weight
Flame Resistant
Garments

Protection comes from preventing


ignition of clothing in a flash fire
undergarments should also be flame
resistant so the elastic will not melt into
your skin from the heat
Courtesy Bulwark
Protective Apparel

FRG after fire fabric did not


support burning

Work with vendors to determine what heat flux rating (ie,


kcal/sq.cm.) FRG is appropriate.
13

Combustible Dust Testing


Defines These Hazards

Ease of ignition of dust cloud

Minimum Explosible Concentration


Minimum Ignition Energy
Minimum Ignition Temperature, Layer,
Cloud

Pressure consequences of a dust


deflagration

Kst, deflagration index (Pmax, dP/dt)


Combustible Dust Hazards and
Mitigation

14

Example combustible dusts (NFPA 68)


(higher number higher pressure explosion)

Hazard
Class

Kst

Pmax

(bar-m/sec)

(bar)

ST-1

<200

10

powdered milk,
charcoal, sulfur,

Moderate (?)
explosion

ST-2

zinc

200-300

10

cellulose, wood
flour, methyl
acrylate

Strong
explosion

ST-3

Some examples

>300

12

anthraquinone,
aluminum,
magnesium

Very strong
explosion

20 liter sphere
Courtesy Fauske
Assoc.

Greater hazard? Small qty ST-3 or Large qty ST-1

Combustible Dust Hazards and Mitigation

15

Minimum Explosible Concentration


The minimum concentration of combustible dust suspended in air,
measured in mass per unit volume that will support a deflagration.
(lower concentration higher hazard)

IH
Range

Dust

MEC Dust

Sugar

200

Aluminum

30

Cellulose

80

Magnesium

30

10-3

Dust
Deposit

Explosible
Range

10-2

10-1

MEC

10

101

102

103

104

105

106

MASS OF POWDER/DUST PER UNIT VOLUME [g/m 3]


Source: Dust Explosions in the Process Industries, Second Edition, Rolf K Eckhoff
Combustible Dust Hazards and Mitigation

16

Static Electrical Ignition Potential?


(lower MIE easier ignition)
Minimum Ignition Example materials
Energy range, mJ
25 - 50

ABS resin, aluminum,


cellulose, cinnamon, coal,
corn flour, paper dust,
sugar, wheat starch

10 - 25

Aluminum stearate, epoxy


resin, sulfur

< 10

Bisphenol-A, red
phosphorus, polyethylene,
thorium, zirconium
Combustible Dust Hazards and
Mitigation

MIE Tester, Mike


3 apparatus
Courtesy Fauske
Assoc.
17

Minimum Ignition Energy (MIE) (mJ)


Predicts the ease and likelihood of ignition of a dispersed
dust cloud. Lower number is greater risk of ignition.
MIE (mJ)

Recommended Precaution per BS 5958

500

Low sensitivity to ignition. Ground plant below this level.

100

Consider grounding personnel below this level.

25

The majority of ignition incidents occur below this level.

10

High sensitivity to ignition. Consider restrictions on the use of high resistivity


non-conductors below this level.

Extremely sensitive to ignition at this level. Handling operations should be such


that they minimize the possibility of suspending the powder in air. Dissipate or
discourage charge operations.

Combustible Dust Hazards and


Mitigation

18

Layer and Dust Cloud Ignition


Temperature (C) Examples
(Lower Temp Easier ignition)

Layer

Courtesy Fauske Assoc.


Combustible Dust Hazards and
Mitigation

Cloud
Page 19

Measured Properties of Combustible Dusts and


how the data is used sample sizes 0.5 -2.0 kg
Property

Definition

ASTM Test
Method

Application

KSt

Dust deflagration index,


bar-m/sec

ASTM E 1226

Measures the relative explosion severity &


pressure compared to other dusts.

ASTM E 1226

Used to predict the severity of the


explosion consequences and to design
explosion protection for enclosures

Maximum rate of pressure


rise

ASTM E 1226

Predicts the violence of an explosion. Used


to calculate Kst

MIE

Minimum ignition energy,


milli-Joules

ASTM E 2019

Predicts the ease and likelihood of ignition


of a dispersed dust cloud.

MEC

Minimum explosible
concentration, gm/m3

ASTM E 1515

Measures the minimum amount of dust,


dispersed in air, required to spread an
explosion. Analogous to the lower
flammability limit (LFL) for gas/air mixtures
but there is no UFL test for dusts.

MIT-Layer

Minimum Ignition
Temperature Dust layer

ASTM E 2021

Measures surface temperature that will


ignite a layer of dust

MIT-CLoud

Minimum Ignition
Temperature - Cloud

ASTM E 1491
Measures surface temperature that will
Combustible Dust Hazards
ignite a and
dispersed dust cloud.
Mitigation
Page 20

Pmax Maximum explosion

overpressure generated in
the test chamber

(dp/dt)max

10

Sieved Sample As received,


through 40 mesh screen (420 um)
Material passing through 20
mesh but not through 40 mesh
screen

Material larger
than 20 mesh

Material passing through 40


mesh but not through 200 mesh
screen

Combustible Dust Hazards and


Mitigation

Material passing
through 200 mesh
screen
21

Factors that Change Dust Ignitability


Property & Change
Risk increases as the value:

Kst

MIE

Particle size distribution DECREASES


Dust chemistry (ie, PVC vs polyethylene)
Dust moisture content INCREASES
Dust concentration optimal range
Dust cloud turbulence INCREASES
Oxygen content INCREASES
Dust cloud temperature INCREASES
Initial dust cloud pressure INCREASES
Hybrid mixtures dust cloud with flammable
vapors or gases
Combustible Dust Hazards and
Mitigation

22

11

Questions CD Hazards, Testing

Combustible Dust Hazards and


Mitigation

OSHA CD Inspections
& Violations Issued
Oct. 2007-Oct. 2012

23

2500

INSPECTIONS
2000
1500
1000

2272

500
653
0

Federal

State

9000
8000

7625
VIOLATIONS

7000

6000
5000

Federal

4000

State

3000

2000

2356
1432

1827

1000
0

Serious

Combustible Dust Hazards and


Other Than Serious
Mitigation

24

12

Distribution of Federal
Violations

Combustible Dust Hazards and


Mitigation

25

Some Combustible Dust NEP Findings


1.

2.

3.

4.

5.

Hazardous dust
accumulations
Unrated electrical equipment
and Powered Industrial
Trucks
Dust collectors inside
buildings - no explosion
protection systems.
Deflagration isolation systems
not provided
The horizontal surfaces not
minimized to prevent
accumulation of dust on
surfaces.

Combustible Dust Hazards and


Mitigation

26

13

Explosion Vent Problems

Combustible Dust Hazards and


Mitigation

27

Some Combustible Dust NEP Findings


6.

7.

8.

9.

10.

Dust collector exhaust recycled through duct work back


into the work area without protection.
Magnetic separators and tramp metal separators not
installed or not functioning to prevent foreign material
entering into process stream.
Explosion vents on bucket elevator(s) and dust collectors
were directed into work areas and not vented to a safe,
outside location.
Equipment (such as grinders and shakers) not designed to
minimize escape of dust into the surrounding work area.
Ductworks used in transporting combustible dust were
not constructed of metal, not bonded or grounded.
Combustible Dust Hazards and Mitigation

28

14

Some Combustible Dust NEP Findings


11.

12.

13.

14.

15.

Hot work performed in the combustible dust


handling areas without hot work procedures.
Silos, legs of bucket elevators were not
equipped with explosion relief venting.

it on
Depos t Wall
Dust
of Duc
Inside

Enclosureless dust collection systems were


allowed indoors where they were connected to
sanders having mechanical feeds and did not
follow other reqmts.

Welding on Outside
of Duct Wall

Compressed air used to clean up the


combustible dust accumulation in the presence
of ignition sources.
Portable Vacuum Cleaners were not approved
for Class II locations.

Combustible Dust Hazards and


Mitigation

29

Set Explosion Control Strategy


Process Hazard Analysis NFPA 654

Based on hazardous
characteristics of dust
PHA-documented, thorough
analysis and risk mitigation
strategy for:

The facility
The process
Associated fire and explosion
hazards

Retain PHA for life of process


Update PHA every 5 years
Other NFPA Stds: 664 Wood, 484
Combustible Dust Hazards and
Metal, 61 Agriculture & Food
Mitigation

30

15

Accident Scenarios to Assess

Explosion within process equipment

Ignition sources (frictional heating, smoldering dust layers,


electrostatic sparks)
Equipment with dust clouds > MEC (blenders, driers, size reduction)
Dust collectors have dust clouds > MEC (> 40% of incidents))

Explosion propagation interconnected equipment


(spark or deflagration)
Secondary explosions (fuel in dust accumulations,
often more significant than primary explosion)

{Zalosh, et al, Safely Handle Powdered Solids, Chemical Engineering Progress


Magazine, Dec. 2005}

NEW: ADD FLASH FIRE SCENARIO AND


DETERMINING OPERATOR PROTECTION
Combustible Dust Hazards and
Mitigation

31

NFPA 654-2013
Key Definition Changes (Ch.3)

Flash Fire. A fire that spreads rapidly through a diffuse fuel,


such as dust, gas, or the vapors of an ignitable liquid, without
the production of damaging pressure.
Dust Explosion Hazard Area. A room or building volume
where an unvented deflagration of the entrainable dust
mass can result in a pressure exceeding the strength of the
weakest structural element not intended to fail.
Dust Flash Fire Hazard Area. An area where combustible
dust accumulation on exposed or concealed surfaces, outside of
equipment or containers, can result in personnel injury from
thermal dose during a dust deflagration, as well as any
areas where dust clouds of a hazardous concentration exist
during normal operation. A propagating deflagration yields a
flash fire through the hazard area.
Combustible Dust Hazards and
Mitigation

32

16

Dust overhead,
over an ignition
source

How Little Dust for an


Explosion?

Dust MEC = 30
grams/cubic
meter
Dust cloud 2
meters diameter,
5 meters long

Mass of dust in
perfectly
distributed dust
cloud?

V =pi x D2/4 x
L=3.14 x 22/4 x
5= 15.7m3
Mass =15.7 m3 x
30 gr/m3=471
gm x 1#/454gm=
1.04 pounds

Combustible Dust Hazards and


Mitigation

33

Dust Explosion Pentagon:


Multiple Strategies to Reduce Risk
Heat or ignition source:
prevent flames static
electricity, sparks,
smolders
Dispersion of
dust particles:
prevent dust
layer getting
airborne relief
device vent path

Combustible dust
(fuel): prevent
accumulation
design,
housekeeping

Confinement of dust
cloud: building &
equipment designed
to safely contain or
vent

Oxidizer (oxygen
in air): reduce O2
Combustible Dust Hazards and
with inert gas
Mitigation

34

17

Ignition Sources
Stronger
Open flame
Welding arc
Gas or dust
explosion
Electrical short or
arc
Friction
Mechanical spark
(tramp metal)

Combustible Dust Hazards and


Mitigation

35

Static Electricity Types


Brush discharge

Spark discharge

Up to 1000 mJ

Propagating brush
discharge

Corona discharge
Up to 1000 mJ

Courtesy Crohmiq Co.


Up to 1 mJ

Combustible Dust Hazards and


Mitigation

Up to 40 mJ

Bulk brush
discharge

Up to 1000 mJ

36

18

Ignition Sources

Sierra Pacific Infrared Thermography

Less strong
Static sparks
Cigarettes
Hot surfaces
internal
combustion
engines
Smoldering
embers
Overheated
electrical
equipment
Combustible Dust Hazards and
Mitigation

37

Grounding , Bonding-Dissipate Static Electrical Charges

Jumper Wire
Courtesy J.O.A.

Clamp together
Courtesy Jacob Tubing

Metal strip under


rubber
Courtesy Morris
Coupling Co.

Dust drum bonding


cable with alligator clip
Combustible Dust Hazards and
Mitigation

Flanges and
bolts on metal
ducts < 106
ohms British
study
38

19

Big Bags or Flexible Intermediate


Bulk Containers (FIBC) Applications
(consider contents, environment)
Type FIBC

Comb.
Solids?

Flam.
Vapors?

MIE, mJ

Exclusions

OK

No

> 1000

Conductive
solids

OK

NO

>3

Conductive
solids

C (grounding
tab, < 108 )

OK, conductive OK if present


solids OK

> 0.14

Ground resist.
< 25

D (static
dissipating
construction)

OK

> 0.14

Conductive
solids

OK flammable
atmospheres

TYPES B, C, & D: tested & verfied safe for intended use by recognized
organization in accordance with IEC 61340-4-4, Electrostatics Part 4-4, Standard
Test Methods for Specific Applications Electrostatic Classification of FIBCs
Combustible Dust Hazards and Mitigation

39

Electrical Classification Class II for


Combustible Dusts
Class II
Group

Type Dust

Temp. Lim.,
Temp. Lim., F,
Normal Opns, Abnormal Opns,
oF/oC
oF/oC

Metal

392/200

392/200

F
G

Carbonaceous

302/150
248/120

392/200
329/165

Flour, grain, wood,


plastics, chemicals

Division 1: combustible dust normally present that could product


explosive or ignitable mixtures, mechanical failure might cause
mixtures, electrically conductive dusts
Division 2: airborne combustible dust not normally present, comb.dust
layer on electrical equipment may interfere with heat dissipation
Combustible Dust Hazards and Mitigation

40

20

Class II Electrical Equipment Enclosures

Cour. Thomas.net

Division 1
dust
incendive
proof?
(NEMA 12)
Courtesy
Crouse Hinds

TEFC-courtesy
wegelectrical
motors

Division 2
dust tight?

Combustible Dust Hazards and Mitigation

Div. 1 or 2
purge retrofit as
per NFPA 496?
Courtesy PepprlFuchs

41

Questions Regulatory,
Ignition Sources

Combustible Dust Hazards and


Mitigation

42

21

Dust Explosion Pentagon:


Multiple Strategies to Reduce Risk
Heat or ignition source:
prevent flames static
electricity, sparks,
smolders
Dispersion of
dust particles:
prevent dust
layer getting
airborne relief
device vent path

Confinement of dust
cloud: building &
equipment designed
to safely contain or
vent

Combustible dust
(fuel): prevent
accumulation
design,
housekeeping

Combustible Dust Hazards and


Mitigation

Oxidizer (oxygen
in air): reduce O2
with inert gas

43

Explosion Pressure Profile


Pmax

Unvented

Pressure

Vent too small

Vessel
strength

Explosion pressure
rapidly builds beyond
typical vessel yield
strength
Vent or suppress
pressure less than
Preduced to

Preduced
Pstat
Correct Vent

Time

2/3 yield strength


no deformation
Yield strength - allow
deformation

Combustible Dust Hazards and


Mitigation

44

22

Important to Get the Design


Right the First Time!

Combustible Dust Hazards and


Mitigation

Courtesy Rembe Co.

45

Explosion
Containment
Pressure CONTAINMENT
10-12 bar (150-180 psig)
Pros

no additional protection on
vessel
indoor applications

Cons

still need to isolate


connected equipment with
high pressure design to
isolation device
ASME pressure vessel &
high capital costs
Combustible Dust Hazards and
Mitigation

Courtesy Glatt Air


Techniques

46

23

Venting - Explosion Doors


door safety
cage if near
walkway

Door weight = 2.5 #/sq.ft


(NFPA 68) so its mass does
not impede venting
Adv: Does not need to be
replaced after venting
Courtesy Philadelphia
Safety Door
Combustible Dust Hazards and

Disadv: Door sizes maybe


larger than
panels/membranes

Mitigation

47

Venting Explosion Panels,


Rupture Disks
Domed panels
resist pressure
cycling better
than flat panels
4-20x longer

Courtesy BS&B
Safety Systems

Domed panel, courtesy


Fenwal

Rupture discs, courtesy Fike

Combustible Dust Hazards and


Mitigation

48

24

Vented Explosions Are Violent!

Courtesy Rembe Co.

Combustible Dust Hazards and


Mitigation

49

Explosion Vent Design Safe Discharge Zone

D = K(V/n)1/3

Example:

Courtesy Fenwal

D dist. in front, m
K flame length factor, K=10
(metal dust), K=8 (chem.,
agric. dusts)
V volume vented enclosure,
m3
n number of vents
Flame width = D
2 vents
V= 60 m3 (1980 ft3)
Chemical dust, K = 8
D=24.5 m = 80 ft in front of
vent

Combustible Dust Hazards and Mitigation

50

25

Indoors Venting Considerations


Blast Deflector Plate Design
(NFPA 68, section 6.6)

Prevent ice & snow from


adding weight to vent
vendor options

-size: 175% vent area


-45-60o angle , centered on vent
-Distance, 1.5x vent diameter

Max vent duct length


as per NFPA 68,
(<10 ft)

-Strong mounting
-Limited to enclosures smaller
than 20 m3 (706 ft3)

Combustible Dust Hazards and Mitigation

51

Safe Vent Discharge Location?


Explosion Venting

Emergency Exit Doors

Rotate dust collectors, blast


deflector plates

Combustible Dust Hazards and


Mitigation

Page 52

26

Dont Make Your Own Explosion


Vent Panels! (Plastic bags too strong)

Courtesy Rembe Co.

Combustible Dust Hazards and


Mitigation

53

Building Damage Limiting


Construction Wall Vent Panels

Courtesy BS&B Safety Systems


Combustible Dust Hazards and
Mitigation

54

27

Flameless Two parts of device


Rupture disk to relieve
Vent
pressure

Mesh screen to contain and


quench flame front
Advantages:
Indoor protection

Disadvantages:
capital cost
may not be suitable for high
Kst dusts
building pressure impact?

Courtesy Fenwal

hot gases safety zone 6-12 ft


Combustible Dust Hazards and
Mitigation

55

Flameless Vent Operation

Courtesy Rembe Co.


Combustible Dust Hazards and
Mitigation

56

28

Fire Sprinklers in Dust Collector

Risk decision puts


out fire without
operator intervention
Collector rated for
20w.c. filled with
sprinkler water it
would collapse!
Water dump valves to
drain water
Challenge getting an
air tight dump valve
Combustible Dust Hazards and
Mitigation

3 dia.
check
valve

Courtesy Donaldson Corporation

57

Explosion Chemical Suppression


Active Protection requires sensors &
high speed control to initiate
Advantages:
Indoor applications
Prevents growth of explosion and
aftermath
Disadvantages:
Product contamination (perhaps
moot with fire)
Ongoing vendor inspection and
maintenance costs
-Quarterly
-2 hr downtime
-$800-1000/day

Courtesy Fenwal

Interlock suppression controls with


equipment protected permissive on

Combustible Dust Hazards and


Mitigation

58

29

Reinforce Mounting for


Suppression Canisters

Courtesy Fenwal

Combustible Dust Hazards and


Mitigation

59

Chemical Suppression Lockout


- Remove permissive
insert magnetic
switch
- Install lockout blank
flange
- Install lockout cable
and locks

Courtesy Fenwal

Combustible Dust Hazards and


Mitigation

60

30

Explosion Suppression vs. Venting

Equipment indoors

Not enough vent area on


equipment

vent duct not practical

High Kst or hybrid dust


Low Preduced

No safe place to vent


Toxic dusts cannot be
discharged to atmosphere
via a vent
Flame propagation through
interconnection

Courtesy Fike

suppression on equipment isolation suppression controlled


by same controls

Combustible Dust Hazards and


Mitigation

61

Spark Detection & Extinguishing

Courtesy BS&B

Wide belt sanders generate sparks


Combustible Dust Hazards and
Mitigation

62

31

Abort Gates

Courtesy Imperial Systems

Combustible Dust Hazards and


Mitigation

Combustible Dust Hazards and Mitigation

63

64

32

Equipment DEFLAGRATION ISOLATION


Isolation devices
needed:

To protect workers
working near dust
controlled
equipment

To prevent pressure
piling on upstream
equipment such as a
cyclone before a
baghouse

One of the most


common gaps in
explosion protection
equipment
Combustible Dust Hazards and
Mitigation

Courtesy Fenwal

65

Passive ISOLATION: Flame Front Diverter


Passive device
-Locate close to
collector
-Vent to safe
location
Advantages:
-Passive
-Self closing
possible
Disadvantages:
-Directional
-System d/p
-Kst < 200

Courtesy J.O.A.

Combustible Dust Hazards and


Mitigation

-Not tight seal


66

33

Passive ISOLATION: Back Draft Damper


Normal flow
direction
(conceptually a
check valve)

Tested for up to Kst


= 300 dusts (ST-2
class) depending on
duct diameter

Heavy duty
damper slams
shut with
deflagration
pressure wave
normally
hangs open 60o
against 25o
valve seat

Courtesy Rembe
Combustible Dust Hazards and
Mitigation

Routinely inspect for cleanliness


potential for dust fouling

67

Backdraft Damper Operation

Courtesy Rembe

Combustible Dust Hazards and


Mitigation

68

34

Passive Isolation: Mechanical Path

Rotary airlock
valve (tight
construction, 6
vanes or more)

Screw conveyors
Powder chokes

Rotary Air
Lock Valve

Combustible Dust Hazards and


Mitigation

69

Isolation Fast Acting Valves

Gate valve full opening design

Located far enough from collector


to allow for time delay between
sensing an explosion and sending
a signal to close the valve.
Advantage

Disadvantage

Courtesy Fenwal

Full isolation of flame front


Prevent product cross contamination
Capital cost ($1200-1400/inch
diameter) MAX SIZE 24
Stronger duct between valve and
collector (3-8 meters)
Routine test cycling of valve may
require replacement parts

Combustible Dust Hazards and


Mitigation

70

35

Active Isolation:
Pinch Valves

Courtesy CV Technologies

How it works
1. Housing installed into ductwork.
2. Inflatable bladder rapidly
activates to close the line.
3. Air receiver tank provides
inflation energy.
4. Controller manages and monitors
valve operation.
5. Sensor (not shown) triggers
activation of valve closing.
- Clean side application
- Lower differential pressure rating
than float valve
Combustible Dust Hazards and
Mitigation

Courtesy Rembe

71

Explosion Protection Design Standards

NFPA 68-2012

Explosion vent doors, vent panels, flame


arresting vents, flame front diverters

NFPA 69-2008

Explosion prevention: chemical


suppression, limiting oxidants (inerting)
Explosion isolation: high speed valves,
rotary airlock valves
Fire prevention: spark detection and
extinguishing, abort gates
Combustible Dust Hazards and
Mitigation

72

36

Dust Explosion Pentagon:


Multiple Strategies to Reduce Risk
Heat or ignition source:
prevent flames static
electricity, sparks,
smolders
Dispersion of
dust particles:
prevent dust
layer getting
airborne relief
device vent path

Combustible dust
(fuel): prevent
accumulation
design,
housekeeping

Confinement of dust
cloud: building &
equipment designed
to safely contain or
vent

Combustible Dust Hazards and


Mitigation

Oxidizer (oxygen
in air): reduce O2
with inert gas

73

Oxidant Concentration Reduction


(NFPA 69: Explosion Prevention)

Nitrogen
molecule

Inerting gases to reduce


oxygen from normal 19.5%
to 8-10% (actual value
depends on dust Limiting
Oxidant Concentration test)
Nitrogen most common,
some use of carbon dioxide
Requires oxygen monitor
and controls to ensure
continual low oxygen level

Advantages

Preventive technique
Avoids product
contamination

Disadvantages

Asphyxiation
hazard next to

inerted equipment if it
goes positive
adequate alarms and
controls?
Nitrogen use
operating expense if
no recycling possible

Combustible Dust Hazards and Mitigation

74

37

Questions Explosion
Protection Equipment

Jahn Foundry
Phenolic Resin

Combustible Dust Hazards and


Mitigation

75

Dust Explosion Pentagon:


Multiple Strategies to Reduce Risk
Heat or ignition source:
prevent flames static
electricity, sparks,
smolders
Dispersion of
dust particles:
prevent dust
layer getting
airborne relief
device vent path

Combustible dust
(fuel): prevent
accumulation
design,
housekeeping

Confinement of dust
cloud: building &
equipment designed
to safely contain or
vent

Combustible Dust Hazards and


Mitigation

Oxidizer (oxygen
in air): reduce O2
with inert gas
76

38

Housekeeping

Blowdowns for inaccessible or


unsafe locations (precautions
to prevent flash fire)

Clean accessible areas with


vacuum, etc. so dust accum. <
threshold dust accum.
Compressed air hoses pressure
relief nozzles 30 psig max
pressure
All energized electrical equipment
NEMA 12
Ignition sources, hot surfaces
shutdown or removed from area

Housekeeping procedures
Dust Hazards and
documented CombustibleMitigation

Courtesy Rembe Co.

77

Safe sweeping

Courtesy Rembe Co.

Sweep gently to
minimize airborne dust
Natural bristles (no
synthetic)
Aluminum or
conductive polymer
dust pans

Combustible Dust Hazards and Mitigation

78

39

Portable Vacuum Cleaners with


Combustible Dust Protection

Courtesy Vac-U-Max

courtesy Ruwac

Static dissipating features


Electric with Explosion Proof
-Drum grounding cable
blower and control switches
-Conductive vacuum and air hoses
-Conductive wheels
Combustible Dust Hazards and
Mitigation

79

Central Vacuum Cleaning Systems


System
components
-High vacuum
producer (6-12Hg
= 82-164 w.c.)
-Filter/receiver
-Pre-separator
(optional)
-Tubing branches
to use zones
-Hoses and tools

Combustible Dust Hazards and


Courtesy
Mitigation

Gardner Denver

80

40

Housekeeping Procedures

Layer Depth Criterion


(LDC) dust thickness
(density x area)
Hazard if > 5% of floor
area of confined area
include overhead
horizontal surfaces
up to 1,000 sq.ft.

Survey dust
deposition rates
Written procedure

Responsibilities
Safe methods
Routine and
special cleanup
Recordkeeping

Combustible Dust Hazards and


Mitigation

81

Dust collection system design


1 Minimize fugitive dust

Combustible Dust Hazards and


Mitigation

Open hoods have


lowest collection
efficiency
Better - Enclosed
process under dust
collection
Design as though
OEL < 1 mg/m3
Control smaller dust
sources discarding
bags at bag dump 82

41

Dust collection system design


2-adequate conveying velocity
V Q / A _( A * D 2 / 576 )

where :

A cross - sectional area of duct (ft )


D duct diameter (inches)
2

Q exhaust vo lume (ft 3 / min)


V velocity of airstream in duct (ft/min)

Hayes Lemnertz ducts

Dust Control Systems: 3500


to 4500 fpm (higher for
some dusts.)
Aerosol or other small
particle Control Systems:
2500 to 3500 fpm.
Combustible Dust Hazards and
Mitigation

83

8 visible clues of inadequate duct


conveying or transport velocity
1)

2)

3)

4)

5)

6)
7)

8)

Combustible Dust Hazards and


Mitigation

Duct does not get


larger after branch
entry
Unneeded ducts
blanked
Poor duct transitions
or merges
Excessive use of
flexible ducts
High dust collector
d/p
Blast gates changed
No system technical
documentation
No system
monitoring
84

42

Complete Dust Collection System


Explosion Protection Overview
Recirculation?
return air isolation

Electrical
Classification
Housekeeping to prevent
dust accumulations
Spark
resistant?
Conveying velocity

Hood
design

Static grounding

Inlet
isolation

Combustible Dust Hazards and


Mitigation

Explosion
vent,
suppress,
or contain
Static grounding
Internal, external
85

Review - Can a Dust Collector Be Indoors?


YES IF ONE OF THESE IN PLACE
Pressure containment
Short explosion vent duct to outdoors
Flameless vent
Chemical or Water Suppression
Volume < 8 cubic feet with no explosion
protection carefully considered risk decision
Sources: NFPA 654, 68, 69
Combustible Dust Hazards and
Mitigation

86

43

Combustible Dust Procedures

Ignition Control:
Emergency response:
enhanced hot work
fighting dust fires
permits, static
Management of Change:
grounding integrity,
internal design
electrical enclosures
standards, Process
Housekeeping
Hazard Analyses,
change procedures
Equipment
maintenance:
Flame Resistant
explosion protection,
Garments
dust collection,
Employee training
vacuum cleaning Combustible Dust Hazards and
Mitigation

87

Summary

Treat dust as guilty of being combustible unless


proven innocent
Conduct PHAs for your process live as long as
your process
Apply hierarchy of controls where a deflagration
hazard exists as per NFPA stds.
Maintain explosion protection and dust collection
equipment as per NFPA stds.
Implement a Combustible Dust Program
Use Management of Change
Reference materials follow
Copyright Gary Q.
Combustible Dust Hazards and Mitigation

Johnson 2013

88

44

Final Questions

Combustible Dust Hazards and


Mitigation

89

Reference: Other Combustible


Dust Regulations, Standards,
Guidelines
Gary Q. Johnson
December 2013

45

Literature to ID Comb. Dusts

(Use for setting direction, not design)

OSHA CD Safety Poster


NFPA 61 (Food, Agric.) table A.6.2.1
NFPA 68 (Expl.Vent) Annex F
NFPA 484 (Metals) in Annexes
NFPA 499 (Haz. Area Elec.) Table 4.5.2
BGIA (Europe table of ~ 4600 matls.)

http://www.dguv.de/ifa/Gefahrstoffdatenbanken/G
ESTIS-STAUB-EX/index-2.jsp
Combustible Dust Hazards and
Mitigation

91

US Chemical Safety Board


(http://www.csb.gov/combustible-dust-hazard-investigation/)

Combustible Dust Hazard Investigations

Hayes Lemnertz (aluminum dust)


CTA Acoustics (auto insulation phenolic resin)
West Pharmaceutical (polyethylene)
Jahn Foundry (phenolic resin)
Rouse Polymerics (rubber)
Ford River Rouge Coal Explosion

Imperial Sugar Company Dust Explosion and Fire


(sugar dust)
Hoeganaes Corporation Fatal Flash Fires (iron
dust)
Combustible Dust Hazards and
Mitigation

Page 92

46

OSHA Technical Manual

Section III: Chapter 3 - Ventilation Investigation


(http://www.osha.gov/dts/osta/otm/otm_toc.html)
Contents:
I.
Introduction
II.
Health Effects
III.
Standards and Codes
IV.
Investigation Guidelines
V.
Prevention and Control
VI.
Bibliography
Apdx
Apdx
Apdx
Apdx

III:3-1.
III:3-2.
III:3-3.
III:3-4.

Ventilation Primer
Glossary
OSHA, Consensus Standards
Troubleshooting an Exhaust System
Combustible Dust Hazards and
Mitigation

Page 93

OSHA Ventilation Regulations

29 CFR 1910.94

A) Abrasive Blasting
B) Grinding, Polishing, and Buffing
C) - Spray Finishing

29 CFR 1910.106 Flammable and


Combustible Liquids
29 CFR 1910.1450 Laboratory
Chemical Safety
Combustible Dust Hazards and
Mitigation

Page 94

47

OSHA Resources

Website:
http://www.osha.gov/dsg/combustibledust/index.html

Combustible Dust National Emphasis Program


Status Report on Combustible Dust National Emphasis Program,
October 2009

Other useful documents see last slides of presentation copies of


complete document in web posting

Advanced Notice of Proposed Rule Making Combustible


Dust Postings: Docket # 2009-0023 (178 postings)

http://www.regulations.gov/ - search on Combustible Dust and


there are over 1700 postings

Combustible Dust Hazards and


Mitigation

95

Safety and Health Information Bulletin


www.osha.gov
Purpose
Background
Elements of a Dust Explosion
Facility Dust Hazard
Assessment
Dust Control
Ignition Control
Damage Control
Training
References
9 pages
Issued 7/2005

Combustible Dust Hazards and


Mitigation

96

48

OSHA
Combustible
Dust Safety
Poster
1 page
Issued 2008

Combustible Dust Hazards and


Mitigation

97

OSHA Fact
Sheet

Explosions overview
Prevention
Dust Control
Ignition Control
Injury and Damage
Control
2 pages

Issued 3/2008
Combustible Dust Hazards and
Mitigation

98

49

Combustible Dust
Hazard
Communication
Introduction
OSHAs Hazard Communication
Standard
Identifying and Controlling the
Potential for Dust Explosions
MSDS Preparation
Product Labels
Training & Information
References
OSHA Assistance
Regional Offices
21 size pages
Combustible Dust Hazards and
Issued 2009
Mitigation

99

OSHA Guidance
Combustible Dust
Fire Fighting
(2013)
Inform firefighters of hazards from
Combustible Dust fires
Useful tool for site emergency planning
and fire department interaction

Combustible Dust Hazards and


Mitigation

100

50

National Fire Protection Association


(NFPA) Standards
GENERAL:
68: Guide for Venting of Deflagrations
69: Std. on Explosion Prevention Systems
91: Std. for Exhaust Systems for Air Conveying of
Vapors, Gases, Mists, and Noncombustible Particulate
Solids (incorporated by reference into NFPA 61, 484,
654, 655, 664)
499: Recommended Practice for the Classification of
Combustible Dusts and of Hazardous (Classified)
Locations for Electrical Installations in Chemical
Process Areas

Combustible Dust Hazards and


Mitigation

Page 101

National Fire Protection Association


(NFPA) Standards
INDUSTRY SPECIFIC
61: Standard for the Prevention of Fires and Dust Explosion
in Agricultural and Food Processing Facilities
85: Boiler and Combustion Systems Hazards Code
86: Standard for Ovens and Furnaces
484: Standard for Combustible Metals
654: Std. for the Prevention of Fire and Dust Explosions
from the Manufacturing, Processing, and Handling of
Combustible Particulate Solids
655: Standard for Prevention of Sulfur Fires and Explosions
664: Standard for the Prevention of Fires and Explosions in
Wood Processing and Woodworking Facilities
Combustible Dust Hazards and
Mitigation

Page 102

51

Standards Combustible Dust

NFPA 652 (NEW)


Fundamentals (in
development)

NFPA
654

NFPA 61 Standard for the Prevention of


Fires and Dust Explosions in Agricultural and
Food Processing Facilities.
NFPA
NFPA 484 Standard for Combustible
484
Metals
NFPA 654 Standard for the Prevention of
Fire and Dust Explosions from
Manufacturing, Processing, and Handling of
NFPA
Combustible Particulate Solids
61
NFPA 655 Standard for Prevention of
Sulfur Fires and Explosions
NFPA 664 Standard for the Prevention of
Fire and Explosions in Wood Processing and
Woodworking Facilities.
Combustible Dust Hazards and

NFPA
655

NFPA 652

Mitigation

NFPA
664

103

ANSI/AIHA Z9 Standards
(http://www.asse.org/shoponline/standards.php)

Z9.1 Open Surface Tanks Ventilation and Operation


Z9.2 - Fundamentals Governing the Design and
Operation of Local Exhaust Systems
Z9.3 - Standard for Spray Finishing Operations
Safety
Code for Design, Construction, and Ventilation
Z9.4 - Abrasive-Blasting Operations
Ventilation and
Safe Practices for Fixed Location Enclosures
Z9.5 - Standard for Laboratory Ventilation
Z9.6 - Exhaust Systems for Grinding, Polishing, and
Buffing
Z9.7 - Recirculation of Air from Industrial Process
Exhaust Systems Combustible Dust Hazards and
Mitigation

Page 104

52

ANSI/AIHA Z9 Standards
(http://www.asse.org/shoponline/standards.php)

Z9.9 BSR/AIHA (Draft) Portable Ventilation Systems


Z9.10 ANSI/AIHA -2008 Fundamentals Governing the
Design and Operation of Dilution Ventilation
Systems in Industrial Occupancies
Z9.11 ANSI/AIHA 2008 Laboratory Decommissioning
Standard

Z9.12 BSR/AIHA Design, Operation, and Maintenance


of Combustible Dust Collection Systems (in process)
Z9.13 BSR/AIHA Design, Operation, Testing, and
Maintenance of Laminar Flow Fume Hoods
Z9.14 BSR/AIHA Methodology for Certification of a Biosafety
Level - 3 (BSL-3) Lab
Combustible Dust Hazards and
Mitigation

Page 105

Industrial Ventilation, A Manual of


Recommended Design, 28th Edition, ACGIH,
2013 (Now in Imperial and SI Units)
1.
2.
3.

4.

5.

6.
7.

Exposure Assessment
Preliminary Design
Principles of
Ventilation
General Industrial
Ventilation
Design Issues
Systems
Design Issues - Hoods
Fans

8.

9.

10.
11.

12.
13.

Air Cleaning
Devices
LEV System Design
Calculation
Procedures
Supply Air Systems
Energy
Considerations
Cost Estimating
Specific Operations

Combustible Dust Hazards and


Mitigation

Page 106

53

ACGIH Industrial Ventilation Manual


Chapter 13 Specific Operations
13.05-Battery Charging
13.10-Clean Rooms
13.15-Filling Operations
13.20-Foundry Operations
13.25-Gas Treatment
13.30-Kitchen Equipment
13.35-Laboratory Ventilation
13.40-Low Volume-High
Velocity Exhaust Systems
13.45-Machining
13.50-Material Transport
13.55-Metal Melting Furnaces

13.60-Mixing
13.65-Moveable Exhaust
Hoods
13.70-Open Surface Tanks
13.72 Push-Pull Ventilation
13.75-Painting Operations
13.80-Mech.Surface Cleaning
and Finishing
13.85-Vehicle Ventilation
13.90-Welding and Cutting
13.95-Woodworking
13.99-Miscellaneous
Combustible Dust Hazards and
Mitigation

Page 107

Industrial Ventilation, A Manual of


Recommended Practice for Operation &
Maintenance, 1st Edit., ACGIH, 2007
1.
2.
3.

4.
5.

Construction & Project


Management Phase
Commissioning and
Proof of Performance
Testing and
Measurement of
Ventilation Systems
Balancing Duct Systems
with Dampers
Ventilation System
Monitoring &
Maintenance

6.

7.

8.

9.

Monitoring &
Maintenance Air
Cleaning Devices
Troubleshooting
Ventilation
Systems
Modifying
Industrial
Ventilation
Systems
Operator Skills
and Training

Combustible Dust Hazards and


Mitigation

Page 108

54

Air Movement and Control


Association (AMCA)

200: Air Systems


201: Fans and Systems
202: Troubleshooting
203: Field Performance Measurements
of Fan Systems
410: Recommended Safety Practices for
Air Moving Devices
Combustible Dust Hazards and
Mitigation

Page 109

Factory Mutual Global


Property Loss Prevention Data Sheets

Insurance company guidance, not a standard.


(Referenced in CD NEP.) Available for free
download at:

http://www.fmglobal.com/fmglobalregistration/

PLPDS pertinent to combustible dusts

No. 7-76, Prevention and Mitigation of Combustible


Dusts and Explosions (2006)
No.7-73, Dust Collectors and Collection Systems (2008)
No. 10-3, Hot Work Management
Combustible Dust Hazards and
Mitigation

110

55

National Institute for Occupational Safety


and Health (NIOSH) Publications

Occupational Health Guidelines for Chemical


Hazards
http://www.cdc.gov/niosh/81-123.html

Hazard Control
http://www.cdc.gov/niosh/hazcommn.html

Hazards Identification
http://www.cdc.gov/niosh/hidlist.html

Site Index
http://www.cdc.gov/niosh/siteindx.html#alpha

Combustible Dust Hazards and


Mitigation

Page 111

Industrial Ventilation Design Guidebook


(1600 pgs,$200) (http://www.invent.hut.fi/)
1.
2.
3.

4.
5.

6.
7.

8.

INDUSTRIAL AIR
TECHNOLOGY
TERMINOLOGY
DESIGN METHODOLOGY
OF INDUSTRIAL AIR
TECHNOLOGY
PHYSICAL FUNDAMENTALS
PHYSIOLOGICAL AND
TOXICOLOGICAL
CONSIDERATIONS
TARGET LEVELS
PRINCIPLES OF AIR AND
CONTAMINANT
MOVEMENT
INSIDE AND AROUND
BUILDINGS
ROOM AIR CONDITIONING

9.
10.
11.
12.
13.
14.
15.
16.

AIR-HANDLING PROCESSES
LOCAL VENTILATION
DESIGN WITH MODELING
TECHNIQUES
EXPERIMENTAL
TECHNIQUES
GAS-CLEANING
TECHNOLOGY
PNEUMATIC CONVEYING
ENVIRONMENTAL
ASSESSMENT
ECONOMIC ASPECTS

Combustible Dust Hazards and


Mitigation

Page 112

56

U.S.EPA

Hazardous Air Pollutants

Maximum Achievable Control Technology (MACT) Rules


Status

http://www.epa.gov/ttn/atw/hapindex.html

http://www.epa.gov/ttn/atw/112j/info/112(j)-table2.html

Integrated Risk Information System

http://www.epa.gov/iris/index.html

Pollution Prevention

Pollutants/Toxics

http://www.epa.gov/opptintr/p2home/
http://www.epa.gov/ebtpages/pollutants.html

Treatment/Control

EPA Method 204 Criteria For and Verification of a


Permanent or Temporary Total Enclosure

http://www.epa.gov/ebtpages/treatmentcontrol.html

Combustible Dust Hazards and


Mitigation

Page 113

Thank you!
Upcoming AIHA Webinar
ISO 45001 A Global OH&S Management System Standard
Monday, December 16, 2013
2:00 PM ET - 3:30 PM ET

This session will begin promptly at the scheduled start time.


We appreciate your patience.

Protecting Worker Health

57

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