Surfactants For Industrial Applications

Exactly your chemistry.
Division Functional Chemicals
Surfactants
for Industrial
Applications
Nonionic and Anionic Emulsifiers, Copolymerizable

Surfactants, Dispersing Agents and Defoamers
Contents
Surfactants from Clariant

What we offer for industrial customers
Alkyl polyethyleneglycol ether

4
Product Range
13
phosphoric acid esters

Alkyl phosphonic acids
13
Alkyl polyethylene glycol
13
ether carboxylic acid

Nonionic Surfactants
Fatty acid condensates
Alkyl ethoxylates
(fatty acid isethionates, methyl taurides,
Nonylphenol ethoxylates
sarkosin and sarkoside)
Tributylphenol ethoxylates
Alkyl benzene sulphonates, Ca-salts
Tristyrylphenol ethoxylates
13
13
Alkyl alkoxylates
10
Copolymerizable Surfactants
Ethylene oxide-propylene
10
Vinyl ether alkoxylates
oxide block polymers
(PO-EO-block polymers)
14
Fatty acid polyethyleneglycol esters
11
Allyl ether alkoxylates
Fatty acid polyglycerol esters
11
(PO-EO-block polymers)
14
Fatty acid polyglycerol
11
Allyl polyoxyalkylene sulphates
14
Castor oil ethoxylates
11
Dispersing Agents
15
Sorbitan ester ethoxylates
11
Wax emulsifiers
11
ester ethoxylates
Anionic Surfactants
Defoamers
Fluorine containing defoamers
16
Silicone containing defoamers
16
Silicone and fluorine-free defoamers
16
Secondary alkyl sulphonates
12
Olefin sulphonates
12
Alkyl sulphates
12
Alkyl ether sulphates
12
Emulsifiers for emulsion
Alkyl aryl ether sulphates
12
polymerization
Polyglycol ether sulphates
12
Sulphosuccinic acid esters
12
Fatty alkyl amine sulphosuccinamates
12
Alkyl phosphoric acid esters
12
Registered trademark of Clariant
17

What we offer for industrial customers
Clariants Division Functional Chemi-
Production and sales
Research and development
cals is one of the world's leading
Our surfactants are manufactured at our
In addition to the product range we offer
manufacturers of surfactants and po-
production sites in Gendorf/Burgkirchen
our customers comprehensive advice
lyglycols. The product range encom-
and Wiesbaden (Germany), Tarragona
and technical service. Our application
passes anionic, nonionic, cationic and
(Spain), Charlotte (USA), Clear Lake
laboratories assist you in developing
amphoteric surfactants. These include
(USA), Mexico City (Mexico), Coatza-
modern system solutions and help you to
raw materials for detergents and
coalcos (Mexico), Maracay (Venezuela),
select the products that are suitable
cleaners, cosmetics and special pro-
Sao Paulo (Brazil), Zarate (Argentina)
for your applications.
ducts for chemical and industrial
and elsewhere, and are available world-
applications.
wide through our sales organization.
This brochure presents a selection
Our product range is constantly being

expanded by intensive research and
development work and is thus geared to
of our products for chemical and indu-
the requirements of our customers as
strial applications.
well as to optimization of the production

methods.
Quality and environment
Clariants Functional Chemicals Division
in Germany has established a quality
management system in accordance
with ISO 9001 in the production, research & development and marketing
sectors. All products are subject to
strict quality control in our analytical
department to ensure our high quality
standard.
To safeguard environmentally friendly
operations the environment management system in accordance with the eco
audit regulations (EEC 1836/93) was

introduced at Gendorf/Burgkirchen
The largest production
site of Division
Functional Chemicals:
Clariant Gendorf/
Burgkirchen.
(Germany), our largest production site.
Production site of
Division Functional
Chemicals in Tarragona
(Spain).
Besides the existing range Clariant
Industrial Applications of Surfactants
Our service: new emulsifiers
Surfactants are used as wetting agents,
from the laboratory to production
offers smaller sample amounts of
emulsifiers and dispersing agents
In selecting suitable emulsifier systems
non-commercial products for labora-
for different chemical and industrial
preliminary trials are necessary to
tory investigations. These include
applications. Clariant offers products for
determine the stability of the monomer
nonionic emulsifiers based on alcohol
the following fields:
emulsion and polymer dispersion and
ethoxylates, which are synthesized in
Emulsifiers for emulsion polymerization
the properties of the polymer films.
our development laboratory. If requi-
Dispersing agents for pigment pre-
We will gladly supply product samples
red, almost any alcohol can be reac-
from our commercial range for these
ted with the desired amount of ethylene
preliminary trials.
oxide and a sample provided.
parations, coatings, inks and paints
Wetting agents for hard surfaces,

ceramics, wood, plastics and metals
Emulsifiers for micro- and macro
Our production know-how permits

rapid scale-up of new products from
emulsions of fats, hydrocarbons and
the laboratory to the production stage.
silicon oils
Development products are thus
Emulsifiers for polyolefin wax

emulsions
Wetting agents for electroplating

processes
Surfactants for the building industry

Emulsifiers for bitumen emulsions
Auxiliaries for the sugar industry
Defoamers
rapidly available commercially. We

will gladly advise you of what we
can do for you.
Product range
The following product range provides
New development products, which
a selection of our products and contains
will extend our product range, are not
nonionic and anionic surfactants used
yet included in this list.
as emulsifiers and wetting agents,

and further more dispersing agents and
defoamers.
Trade name
Chemical name
Active content Appearance (20C) Cloud point (C) HLB value
Alkyl ethoxylates
Alkyl polyglycol ether with 11 EO
ca. 80 %
liquid
Emulsogen EPN 217
ca. 70 %
liquid
ca. 17
Emulsogen EPN 287
ca. 70 %
liquid
ca. 18
Emulsogen EPN 407
ca. 70 %
liquid
ca. 18
Emulsogen LCN 050
ca. 100%
liquid
67 70 (2)
ca. 11
Emulsogen LCN 070
ca. 100%
liquid
54 56 (1)
ca. 13
Emulsogen LCN 088

Emulsogen LCN 118
ca. 80%
ca. 80 %
liquid
liquid
ca. 15
62
65 (1)*
ca. 13
62
65 (3)*
ca. 15
71 (3)*
ca. 16
Emulsogen LCN 158
ca. 80 %
liquid
69
Emulsogen LCN 217
ca. 70 %
liquid
ca. 17
Emulsogen LCN 287
ca. 70 %
liquid
ca. 18
Emulsogen LCN 407
ca. 70 %
liquid
ca. 18
75 (3)
ca. 15
Emulsogen 3896
Fatty alcohol ethoxylate
ca. 100 %
waxy
73
Genapol C 050
Coconut fatty alcohol ethoxylate with 5 EO
ca. 100 %
liquid
71 74 (2)
ca. 10
Genapol C 100
Coconut fatty alcohol ethoxylate with 10 EO ca. 100 %
paste
89 92 (1)
ca. 14
waxy
76
78 (3)
ca. 16
77
79 (3)
ca. 17
53
55 (2)
ca. 8
64
66 (2)
ca. 10
70
73 (2)
ca. 11
53
59 (1)
ca. 12
59 (1)*
ca. 12
Genapol C 200
Genapol C 250
Genapol LA 030
62 65 (3)*
Emulsogen EPN 118
Genapol LA 040
Genapol LA 050
Genapol LA 070

C12 / C14 fatty alcohol ethoxylate with 3 EO
ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
waxy
liquid
liquid
liquid
liquid
Genapol LA 079
ca. 90 %
liquid
53
Genapol V 4463
C12 / C14 fatty alcohol ethoxylate with 10 EO ca. 100 %
waxy
(1) 1
g in 100 cm 3 distilled water
(2) 5
g in 25 cm 3 25 % aqueous BDG
(3) 1
g in 100 cm 3 10 % aqueous NaCl solution * relative to the active substance
ca. 14
Trade name
Chemical name
Active content Appearance (20C) Cloud point (C)
Oleyl alcohol ethoxylate with 2 EO
ca. 100 %
HLB value
Alkyl ethoxylates
Genapol O 020
Genapol O 050
Genapol O 080

ca. 100 %
ca. 100 %
liquid
35 38 (2)
liquid
67
69 (2)
ca. 9
>
40 (1)
ca. 11
liquid paste
ca. 5
79 81 (2)
Genapol O 100
ca. 100 %
paste
> 75 (1)
49
Genapol O 150
ca. 100 %
waxy
71 73 (3)
ca. 13
76 (3)
ca. 15
Genapol O 200
ca. 100 %
waxy
74
Genapol O 300
ca. 100 %
waxy
Genapol OA 040
Genapol OA 070
Genapol OA 080
C14 / C15 oxo alcohol ethoxylate with 4 EO

ca. 100 %
ca. 100 %
ca. 100 %
ca. 12
51 (3)
liquid
paste
paste
ca. 17
51 +/-
1,5 (2)
ca. 9
72
74 (2)
ca. 12
76
80 (2)
ca. 12
80 (2)*
ca. 12
Genapol OA 089
ca. 90 %
liquid
76
Genapol OX 050
ca. 100 %
liquid
63 64,5 (2)
ca. 10
Genapol OX 060
ca. 100 %
liquid paste
64 67 (2)
ca. 11
liquid paste
ca.
73 (2)
ca. 12
75
78 (2)
ca. 13
62
65 (1)
ca. 14
62
65 (1)*
ca. 14
Genapol OX 070
Genapol OX 080
Genapol OX 100
Genapol OX 109
(1) 1

(2) 5
(3) 1
ca. 100 %
ca. 100 %
ca. 100 %
ca. 90 %
paste
paste
liquid

Alkyl ethoxylates to be continued on page 8
Product range
Trade name
Chemical name
Active content Appearance (20C) Cloud point (C) HLB value
Alkyl ethoxylates continued from page 7

Genapol T 080
Genapol T 110
Tallow fatty alcohol ethoxylate with 8 EO
ca. 100 %
Tallow fatty alcohol ethoxylate with 11 EO ca. 100 %
waxy
83 85 (2)
ca. 11
waxy
84
90 (1)
ca. 13
60
63 (3)
Genapol T 150
waxy
71 73 (3)
ca. 14
Genapol T 200
waxy
75 77 (3)
ca. 15
waxy
77
79 (3)
ca. 16
77
79 (3)
ca. 16
Genapol T 250
Genapol T 250 p
powder
Genapol T 500
waxy
ca. 18
Genapol T 500 p
powder
ca. 18
Genapol T 800
waxy
ca. 19
Genapol T 800 p
powder
Genapol UD 030
C11 oxo alcohol ethoxylate with 3 EO
ca. 100 %
liquid
ca. 19
37
41 (2)
69 (2)
ca. 9
Genapol UD 050
ca. 100 %
liquid
66
Genapol UD 079
ca. 90 %
liquid
52 55 (1)*
ca. 13
Genapol UD 080
ca. 100 %
liquid
62 65 (1)
ca. 13
Genapol UD 088
Genapol UD 110
Genapol X 020
Genapol X 050
Genapol X 060
Genapol X 080
Genapol X 089

ca. 80 %
ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
ca. 90 %
liquid
liquid paste
liquid
liquid
liquid
liquid
liquid
ca. 11
62
65 (1)*
ca. 13
62
65 (3)
ca. 15
25
30 (2)
ca. 6
59
62 (2)
ca. 10
64
66 (2)
ca. 11
>
45 (1)
ca. 13
74
76 (2)
> 45 (1)*
ca. 13
74 76 (2)*
62 65 (1)
Genapol X 090
ca. 100 %
liquid
Genapol X 158
ca. 80 %
liquid
ca. 15
Genapol X 250
ca. 100 %
waxy
ca. 18
Genapol X 307
ca. 70 %
liquid
ca. 17
Genapol X 407
ca. 70 %
liquid
ca. 18
Genapol X 1000
ca. 100 %
solid
ca. 19
Genapol X 1003
ca. 35 %
liquid
ca. 19
Genapol X 1005
ca. 50 %
liquid
ca. 19
Genapol 1879
C13 oxo alcohol ethoxylate
ca. 40 %
liquid
ca. 15
Genapol 3214
C13 oxo alcohol ethoxylate
ca. 25 %
liquid
ca. 18
(1) 1
(2) 5
(3) 1
ca. 13
Trade name
Chemical name
Active content
Appearance (20C)
Cloud point (C)
HLB value
ca. 100 %
liquid
36 38 (2)
ca. 9
liquid
61
63 (2)
ca. 11
32
34 (1)
ca. 12
Nonylphenol ethoxylates
Arkopal
N 040
Arkopal N 060
Arkopal N 080
Nonylphenol ethoxylate with 4 EO

ca. 100 %
ca. 100 %
liquid
76 78 (2)
Arkopal N 090
Arkopal N 100
Arkopal N 110
Arkopal N 130
Arkopal N 150
Arkopal N 200
Arkopal N 208

ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
ca. 80 %
liquid
52 54 (1)
ca. 13
liquid
62
65 (1)
ca. 13
71
74 (1)
ca. 14
83
86 (1)
ca. 14
92
95 (1)
ca. 15
61
63 (3)
liquid
liquid paste
paste
paste
liquid
70 73 (3)
70
73 (3)*
75 (3)
ca. 16
ca. 16
Arkopal N 230
ca. 100 %
waxy
73
Arkopal N 238
ca. 80 %
liquid
73 75 (3)*
ca. 16
Arkopal N 300
ca. 100 %
waxy
76 78 (3)
ca. 17
Arkopal N 307
ca. 70 %
liquid
ca. 16
76
78 (3)*
ca. 17
78 (3)*
ca. 17
Arkopal N 308
ca. 80 %
liquid
76
Arkopal N 1000
ca. 100 %
waxy
ca. 100 %
liquid
53 56 (2)
ca. 10
liquid
60
68 (2)
ca. 11
44 (1)
ca. 13
ca. 19
Tributylphenol ethoxylates
Sapogenat
T 060
Sapogenat T 080
Tributylphenol ethoxylate with 6 EO

ca. 100 %
Sapogenat T 110
ca. 100 %
liquid
42
Sapogenat T 130
ca. 100 %
liquid
62 64 (1)
ca. 14
Sapogenat T 139
ca. 90 %
liquid
62 64 (1)*
ca. 14
64 (3)
Sapogenat T 180
ca. 100 %
waxy
61
Sapogenat T 300
ca. 100 %
waxy
ca. 17
Sapogenat T 500
ca. 100 %
waxy
ca. 18
ca. 100 %
liquid
23 27 (2)
ca. 7
Tristyrylphenol ethoxylate with 10 EO ca. 100 %
liquid
65 69 (2)
ca. 10
liquid
58
62 (1)
ca. 13
60 (3)
ca. 14
ca. 15
Tristyrylphenol ethoxylates
Emulsogen
TS 050
Emulsogen TS 100
Emulsogen TS 160
Tristyrylphenol ethoxylate with 5 EO
Emulsogen TS 200
waxy
55
Emulsogen TS 290
waxy
67 69 (3)
ca. 15
Emulsogen TS 540
waxy
72 74 (3)
ca. 17
Emulsogen TS 600
waxy
(1) 1
(2) 5
(3) 1
g in 100 cm 3 10 % aqueous NaCl solution *relative to the active substance
ca. 17
Product range
Trade name
Chemical name
Active content
Appearance (20C) Cloud point (C) HLB value
Alcohol EO-PO adduct
ca. 100 %
liquid
Alkyl alkoxylates
Genapol EP 0244
33,5 36,5 (2)
(former name Genapol 2822)
Genapol EP 2424
ca. 20 (1)
ca. 100 %
liquid
25 27 (2)
ca. 100 %
liquid
42 44 (2)
Oxoalcohol EO-PO adduct
ca. 100 %
liquid
31 33 (2)
ca. 100 %
liquid
39 41 (2)
ca. 100 %
liquid
27,5 31 (1)
ca. 100 %
liquid
39 42 (1)
ca. 100 %
liquid
> 25 (1)
Genapol EP 2464
Genapol EP 2544
Genapol EP 2552
Genapol EP 2564
Genapol EP 2584
Genapol PL 120
31 34 (2)
Ethylene oxide-propylene oxide block polymers
Emulsogen 4084
Genapol PF 10
Genapol PF 20
Genapol PF 40
EO-PO block polymer with 60 % EO

ca. 100 %
ca. 100 %
ca. 100 %
ca. 100 %
waxy
68 70 (3)
ca. 12
liquid
34
37 (2)
ca. 2
55
58 (2)
ca. 4
66
69 (2)
ca. 8
72 (3)
ca. 16
liquid
liquid
Genapol PF 80 p
ca. 100 %
powder
69
Genapol ED 3030
Ethylenediamine EO-PO block polymer
ca. 100 %
liquid
52 55 (2)
ca. 9
Ethylenediamine EO-PO block polymer
ca. 100 %
liquid
27 30 (2)
ca. 6
ca. 100 %
liquid
36 39 (2)
ca. 100 %
liquid
ca. 100 %
liquid
(former name Genapol B)
Genapol ED 3060
(former name Genapol PN 30)
End capped Alkylethoxylates
10
Genapol BE 2410
Lauryl ethoxylate with 10 EO,

butyl-end capped
Genapol BE 2805
Coconut fatty alkyl ethoxylate

with 5 EO, butyl-end capped
Genapol BE 2810
Coconut fatty alkyl ethoxylate

with 10 EO, butyl-end capped
(1) 1
(2) 5
(3) 1
39 42 (2)
Trade name
Chemical name
Active content
Appearance (20C)
C12 / C14 fatty acid polyglycol ester with 10 EO
ca. 100 %
liquid
Genagen O 060
ca. 100 %
liquid
Genagen O 100
ca. 100 %
liquid
Genagen O 150
ca. 100 %
liquid
Genagen S 250
Stearic acid polyglycol ester with 25 EO
ca. 100 %
waxy
Fatty acid polyethyleneglycol esters

Genagen
C 100
Fatty acid polyglycerol esters

Emulsogen OG
Diglycerol oleate
ca. 100 %
liquid
Hostacerin DGI
Diglycerol diisostearate
ca. 100 %
liquid
Hostacerin DGMS
Diglycerol monostearate
ca. 100 %
pellets
Hostacerin TGI
Polyglycerol diisostearate
ca. 100 %
liquid
Fatty acid polyglycerol ester ethoxylates

Hostacerin DGSB
Diglycerol distearate ethoxylated with 4 EO
ca. 100 %
waxy
Hostacerin DGL
Diglycerol laurate ethoxylated with 10 EO
ca. 100 %
liquid
Emulsogen EL 200
Castor oil ethoxylate with 20 EO
ca. 100 %
liquid
Emulsogen EL 360
ca. 100 %
liquid
Emulsogen EL 400
ca. 100 %
liquid
Emulsogen EL 540
ca. 100 %
liquid
Emulsogen HCO 040
Hydrogenated castor oil ethoxylate with 40 EO
ca. 100 %
paste
Emulsogen HCO 060
ca. 100 %
paste
Emulsogen HCP 049
ca. 090 %
liquid
Lauroyl sorbitane ethoxylate with 20 EO
ca. 100 %
liquid
Emulsogen P
Alkylethoxylate
ca. 100 %
paste
Emulsogen PN extra
Mixture of different alkyl ethoxylates
ca. 100 %
paste
Castor oil ethoxylates
Sorbitane ester ethoxylate

Emulsogen 4156
Wax emulsifiers
(1) 1
(2) 5
(3) 1
11
Anionic Surfactants
Product range
Trade name
Chemical name
Active content
Appearance (20C)
Secondary alkyl sulphonates (Secondary alkane sulphonates)

Hostapur
SAS 30
Secondary alkyl sulphonate, Na salt
ca. 30 %
liquid
Hostapur SAS 60
ca. 60 %
paste
Hostapur SAS 93
ca. 93 %
waxy pellets
Olefin sulphonates
Hostapur OS liquid
C14 / C16 alpha-olefin sulphonate, Na salt
ca. 42 %
liquid
Hostapur OSB
C14 / C16 alpha-olefin sulphonate, Na salt
ca. 90 %
powder
Emulsogen EPA 1954
C12 / C14 alkyl sulphate, Na salt
ca. 30 %
liquid
Emulsogen LS
C12 alkyl sulphate, Na salt
ca. 15 %
liquid
Emulsogen EPA 073
Alkyl ether sulphate with 7 EO, Na salt
ca. 28 %
liquid
Emulsogen LCA 073
Alkyl ether sulphate with 7 EO, Na salt
ca. 28 %
liquid
Alkyl sulphates
Alkyl ether sulphates
Emulsogen LA 083
Alkyl ether sulphate with 8 EO, Ammonium salt
ca. 30 %
liquid
LRO liquid
C12 / C 14 alkyl ether sulphate with 2 EO, Na salt
ca. 27 %
liquid
Genapol LRO paste
ca. 68 %
paste
Emulsogen ZRO liquid
ca. 27 %
liquid
Zeliquid LP 2
Lauryl ether sulphate with 3 EO, ammonium salt + organ. solvent
ca. 50 %
liquid
BV conc.
Tributyl phenol ether sulphate with 7 EO, Na salt
ca. 50 %
paste
Hostapal BV liquid
Tributyl phenol ether sulphate with 7 EO, Na salt
ca. 17 %
liquid
Polyalkylene glycol ether sulphate, ammonium salt
ca. 50 %
liquid
Emulsogen SB 10
Diisodecyl sulphosuccinate, Na salt +IPA
ca. 65 %
liquid
Emulsogen SF 8
Diisooctyl sulphosuccinate, Na salt
ca. 50 %
liquid
Genapol
Alkyl aryl ether sulphates

Hostapal
Polyglycol ether sulphates

Emulsogen PF 20 S
Sulphosuccinic acid esters
Fatty alkyl amine sulphosuccinamates

Emulsogen OLS
Octyl amine sulphosuccinamate, Na salt
ca. 36 %
liquid
Emulsogen TAS
Tallow alkyl amine sulphosuccinamate, Na salt
ca. 36 %
liquid
Phosphoric acid mono esters

Hostaphat CC 100
12
Cetyl phosphoric acid ester, acid form
ca. 100 %
powder
Phosphoric acid di esters

Hostaphat L 327
Phosphoric acid ester of lauryl ethoxylate (2 EO)
ca. 95 %
liquid
and polyethylene glycol

Phosphoric acid mono/di esters
Hostaphat MDAH
Mono-/di-2-ethylhexyl phosphoric acid ester, acid form
ca. 98 %
liquid
Hostaphat CG 120
Mono-/diisostearyl phosphoric acid ester, acid form
ca. 90 %
liquid
Hostaphat CS 120
Mono-/distearyl phosphoric acid ester, acid form
ca. 92 %
wax
Hostaphat 1306
Isotridecyl polyoxethyl (6 EO) phosphoric acid mono/diester,
ca. 96 %
liquid
acid form
Trade name
Chemical name
Active content
Appearance (20C)
Phosphoric acid mono/di/tri esters

Emulsogen DMR
Stearoyl polyoxyethylene phosphate
ca. 100 %
flakers
Hostaphat B 310
Tributoxyethyl phosphate, acid form
ca. 87 %
liquid
Hostaphat KL 340 D
Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt
ca. 90 %
liquid
Hostaphat KL 340 N
Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt
ca. 90 %
liquid
Hostaphat KW 340 D
Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt
ca. 90 %
liquid
Hostaphat KW 340 N
Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt
ca. 90 %
liquid
ca. 100 %
waxy
ca. 75 %
liquid
Alkyl phosphonic acids

Hostaphat OPS 100
n-Octane phosphonic acid
Hostaphat OPS 75
n-Octane phosphonic acid + organ. solvent/water
Alkyl polyethylene glycol ether carboxylic acids

Emulsogen CLA 020
Fatty alcohol polyoxyethylene carboxylic acid with 2 EO
ca. 90 %
liquid
Emulsogen CLA 030
ca. 90 %
liquid
Emulsogen CLA 050
ca. 90 %
liquid
Emulsogen CLA 070
ca. 90 %
liquid
Emulsogen CLA 110
ca. 90 %
liquid
Emulsogen COA 070
ca. 90 %
liquid
Emulsogen COL 020
ca. 90 %
liquid
Emulsogen COL 050
ca. 94 %
liquid
Emulsogen COL 080
ca. 90 %
liquid
Emulsogen COL 100
ca. 90 %
liquid
Coconut fatty acid isethionate, Na salt
ca. 65 %
flakes
ca. 40 %
paste
Fatty acid isethionates

Hostapon SCI-65
Fatty acid methyl taurides

Arkopon T Teig 8015
Oleic acid methyl tauride, Na salt
Hostapon CT Teig
Coconut fatty acid methyl tauride, Na salt
ca. 30 %
paste
Hostapon TPHC
Oleic acid methyl tauride, Na salt
ca. 60 %
powder
Fatty acid sarkosin and sarkoside

Arkomon SO
Oleyl sarkosin
ca. 95 %
liquid
Medialan LD
Lauroyl sarcoside, Na salt
ca. 30 %
liquid
Alkyl benzenesulphonates, Ca-salts

Calsogen 3546
Tetrapropylene benzenesulphonate, Ca-salt in 2-ethyl hexanol
ca. 60 %
liquid
Calsogen 4814
n-Dodecyl benzenesulphonate, Ca-salt in 2-ethyl hexanol
ca. 60 %
liquid
Phenylsulfonate CA
Tetrapropylene benzenesulphonate, Ca-salt in isobutanol
ca. 70 %
pasty
Phenylsulfonate
Tetrapropylene benzenesulphonate, Ca-salt in solvent naphtha
ca. 40 %
viscous liquid
CA 100
and a nonionic surfactant, flash point > 100C
Phenylsulfonate CAL
n-Dodecyl benzenesulphonate, Ca-salt in isobutanol
ca. 70 %
pasty
ca. 62 %
liquid
Phenylsulfonate CAN Tetrapropylene benzenesulphonate, Ca-salt in isobutanol

and a nonionic surfactant
13
Copolymerizable Emulsifiers &

Speciality Monomers
Product range
Trade name
Chemical name
Active content
Appearance (20C)
Vinyl ether alkoxylates (PO-EO-block polymers)

Emulsogen R 109
Vinyl ether alkoxylate with 10 EO
ca. 90 %
liquid
Emulsogen R 208
ca. 80 %
liquid
Emulsogen R 307
ca. 70 %
liquid
Allyl ether alkoxylates (PO-EO-block polymers)

Emulsogen RAL 109
Allyl ether alkoxylate with 10 EO
ca. 90 %
liquid
Emulsogen RAL 208
ca. 80 %
liquid
Emulsogen RAL 307
ca. 70 %
liquid
Allyl polyoxyalkylene sulphates

Emulsogen APS 100
Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt
ca. 100 %
liquid
Emulsogen APS 104
Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt
ca. 40 %
liquid
ca. 100 %
liquid
ca. 90 %
liquid
Emulsogen APS 100 S Allyl polyoxyalkylene sulphate with 10 EO, Na salt

Allyl polyoxyarylene sulphates
Emulsogen APG 2019 Allyl phenylpolyol ether sulphate with 20 EO, ammonium salt
Methacrylic acid esters
14
Genagen M 750 MA
Methacrylic acid ester of polyethyleneglycol ether
ca. 100 %
pasty
Genagen M 1100 MA
Methacrylic acid ester of polyethyleneglycol ether
ca. 100 %
waxy
Genagen LA 070 MA
Methacrylic acid ester of C12/C14 fatty alcohol ethoxylate with 7 EO
ca. 100 %
liquid
Dispersing Agents
Product range
Trade name
Chemical name
Active content
Appearance (20C)
ca. 80 %
powder
ca. 95 %
powder
ca. 92 %
powder
ca. 80 %
powder
ca. 35 %
liquid
ca. 26 %
liquid
ca. 35 %
liquid
Naphthalene sulphonic acid - formaldehyde condensates

Dispersogen NN
Condensation product of formaldehyde and

naphthalene sulphonate, sodium salt, max. 20 % Na2SO4
Dispersogen R 5

Dispersogen 5338

Alkylphenol - formaldehyde - bisulphite condensates

Dispersogen 1494
Condensation product of formaldehyde, cresol, nonylphenol

and sodium bisulphite; contains NaCl
Dispersogen 1494 liquid
Condensation product of formaldehyde, cresol, nonylphenol

and sodium bisulphite; contains NaCl
Dispersogen P liquid
Condensation product of formaldehyde, cresol and

sodium bisulphite; contains NaCl
Novolac derivatives
Dispersogen 1728
Nonylphenol novolac polyoxyethylene sulphosuccinate,

Na salt
Dispersogen 2774
Nonylphenol novolac ethoxylate
ca. 100 %
liquid
Dispersogen 2774-1
Nonylphenol novolac ethoxylate in ethylene glycol
ca. 50 %
liquid
Dispersogen 2774-2
Nonylphenol novolac ethoxylate in propylene glycol
ca. 50 %
liquid
Tristyrylphenol derivatives, anionic

Dispersogen LFH
Tristyrylphenol polyoxyethylene phosphoric acid ester
ca. 96 %
liquid
Dispersogen LFS
Tristyrylphenol polyoxyethylene phosphoric acid ester,
ca. 92 %
liquid
Castor oil polyoxyethylene sulphosuccinic acid ester, Na salt
ca. 80 %
liquid
Stabilizer and dispersing agent for sodium silicate
n.n.
liquid
triethanolamine salt
Castor oil derivatives, anionic
Dispersogen 4387
Quaternary dispersing agents
Dispersogen SPS
in silicate paints
15
Defoamers
Product range
Trade name
Ionicity
Flash Point
Appearance (20C)
Application example
> 100C
liquid
FDA-approved defoamer for paper
Silicone containing defoamers

Antimussol 4752
nonionic
treatment and other industrial

applications
Antimussol V 4847
nonionic
> 100C
liquid
EPA-approved defoamer for crop

protection
Antimussol V 5282
nonionic
> 100C
liquid
defoamer for water miscible

formulations
Polyalkylene glycol based defoamers

Antimussol TW
nonionic
> 100C
liquid
emulsion polymers, water treatment
Antimussol V 5084
nonionic
> 100C
liquid
defoaming of surfactant formulations
Genapol PH 10
nonionic
> 100C
liquid
EO/PO block polymer for metal working

fluids and other industrial applications
Genapol PF 10
nonionic
> 100C
liquid
EO/PO block polymer for industrial

applications e.g. sugar refinement
Phosphate ester based defoamers

Antimussol TIP
anionic
ca. 27C
liquid
Phosphorus containing defoamer for

emulsion polymerization and other
industrial applications, water treatment
Mineral oil based defoamers

Antimussol 4846 N
anionic
> 100C
liquid
Phosphorus containing defoamer for

emulsion polymers and other industrial
applications
Antimussol V 5348
nonionic
> 150C
liquid
emulsion paints, coatings, pigment

preparations
16

Diagram: emulsion polymerization
Emulsifiers are substances that become

active at interfaces. They perform a
number of tasks in the complex system
of emulsion polymerization. For example
they enable the water-insoluble monomers to be distributed extremely finely
in the aqueous phase and stabilize the
polymer dispersion produced from it.
Clariant emulsifiers are used to manufacture a variety of polymer systems:
In the polymerization of vinyl acetate

to homopolymers or co- and ter-
Polymer Particle
polymers together with other vinyl

esters, acrylates, vinyl chloride
and ethylene
In the polymerization of pure acrylate

and styrene-acrylate dispersions
In the manufacture of butadienestyrene latices
In the manufacture of polyvinyl

chloride using the emulsion polymerization process
In the manufacture of butadieneExplanation:
styrene rubber
In the manufacture of ABS plastic

Protective Colloid
Molecules
The diagram beside shows a model of

the complex interactions involved in the
stabilization of the polymer particles.
OH Groups
Emulsifier Molecules
17

Apart from stabilizing the monomer
Vinyl acetate dispersion, model formulation
emulsion, emulsifiers have a great
Composition
Concentration
Water
influence on the properties of the poly-
Tylose
mer dispersions. These include important

parameters such as particle size and
32.02 %
1.06 %
H 200 YG4
0.26 %
Borax
particle size distribution of the polymer
Emulsogen
EPA 073
0.91 %
particles, viscosity, electrolyte stability,
Emulsogen
EPN grade
1.51 %
frost resistance of the dispersion, film-
0.11 %
Acetic acid 98 %
Nipacide
forming properties and many other
0.15 %
CI 15 (preservative)
application properties of the polymer
Initiator solution (to liquor)
4.50 %
dispersion.
Monomer mixture (to liquor)
5.30 %
Initiator solution (stock batch)
6.48 %
Monomer mixture (stock batch)
47.70 %
The slightest changes to the polymerization system can lead to considerable variations in the dispersion properties. To ensure consistent quality of
the polymer dispersion, our emulsifiers
Monomer mixture
VeoVa
are subject to strict quality control.
10, Shell1)
25 %
Vinyl acetate
75 %
Initiator solution
The influence of the nonionic emul-
Potassium peroxodisulphate
1.17 %
Water
98.83 %
sifier on the dispersion properties

was investigated by means of a model
The Emulsogen EPN grades investigated are nonionic emulsifiers based on an
formulation for a polyvinyl acetate
oxoalcohol with different degrees of ethoxylation.
dispersion.
1)
Nonionic emulsifier
Degree of ethoxylation
Emulsogen EPN 118
11 mol ethylene oxide
Emulsogen EPN 207
Emulsogen EPN 287
Emulsogen EPN 407
VeoVa 10 is a registered trademark of Shell for 2,2-dimethyloctanoic acid vinyl ester
The two graphs that follow on page 8

show the influence of the degree of
ethoxylation of the fatty alcohol ethoxylates on the viscosity of the dispersion
18
and on the particle size. The emulsifier

concentrations were kept constant.
Influence of the emulsifier on the viscosity of a vinyl acetate/ VeoVa 10 dispersion
Viscosities of
Emulsogen-containing
polymer dispersions
(vinyl acetate/ VeoVa 10)
Tylose H 200 YG4 (1.06 %);
Emulsogen EPA 073
(0.91 %)
Influence of the emulsifier on the particle size2) of a vinyl acetate/ VeoVa 10 dispersion
Particle size of polymer

dispersions (vinyl
acetate/ VeoVa 10) with:
Tylose H 200 YG4 (1.06 %);
Emulsogen EPA 073
(0.91 %); Emulsogen EPN
grades (1.51 %)
2)
Determined by turbidity
measurements, these
values are not absolute
but indicate a tendency
Not only the constitution of the emul-
illustrate this effect on the viscosity
sifier but also its concentration has
of the dispersion by means of the model
an influence on the properties of the
formulation vinyl acetate/ VeoVa 10.
dispersion. The next four graphs
19

Influence of the concentration of Emulsogen EPN 118 on the viscosity of the dispersion
Viscosities of Emulsogen
EPN 118-containing
polymer dispersions
(vinyl acetate/ VeoVa 10);
Tylose H 200 YG4
(1.06 %); Emulsogen
EPA 073 (0.91 %)
Viscosities of
Emulsogen EPN 207containing polymer
dispersions (vinyl
acetate/ VeoVa 10);
Tylose H 200 YG4
(1.06 %); Emulsogen
EPA 073 (0.91 %)
20
EPN 287-containing
polymer dispersions
Tylose H 200 YG4
(1.06%); Emulsogen
EPA 073 (0.91%)
EPN 407-containing
polymer dispersions
Tylose H 200 YG4
(1.06 %); Emulsogen
EPA 073 (0.91 %)
21

The following graphs on this page show
amount of coagulate and the water ab-
the effect of the emulsifier system on the sorption of the polymer film.
Influence of the emulsifier on the amount of coagulate in a vinyl acetate/ VeoVa 10 dispersion
Amount of coagulate in
polymer dispersions
with: Tylose H 200 YG4
(1.06 %); Emulsogen
EPA 073 (0.91 %);
Emulsogen EPN grades
(1.51%)
Method: Filtration of the

dispersion through
m screen, then
a 100-
filtration of the filtrate
through the finer
m screen.
40-
Influence of the emulsifier on the water absorption of a dispersion film based on vinyl acetate/ VeoVa 10
Water absorption of
polymer dispersions
with: Tylose H 200 YG4
(1.06 %); Emulsogen
EPA 073 (0.91 %);
Emulsogen EPN grades
(1.51%)
22
This information is based on our present

knowledge and is intended to provide
general notes on our products and
their uses. It should not therefore be
construed as guaranteeing specific
Our products are constantly upgraded
properties of the products described
on the basis of the latest research re-
or their suitability for a particular appli-
sults. Products may occasionally be
cation. Any existing industrial property
deleted in the course of updating the
rights must be observed. The quality
sales range. Development products
of our products is guaranteed under
that have reached the production stage
our General Conditions of Sale.
are not included in this list.
February 2004
23
Exactly your chemistry.

Clariant GmbH
Division Functional Chemicals
Industrial Performance Chemicals
Research & Development
Worldwide
65926 Frankfurt, Tel.: +49-69-305-6308, Fax: +49-69-305-16504
Marketing
Europe
65840 Sulzbach, Tel.: +49-6196-757-7437, Fax: +49-6196-757-8945
USA & Canada
Mount Holly NC 28120, Tel.: +1-704-822-2514, Fax: +1-704-822-2193
Mexico
53500 Naucalpan, Tel.: +52-55-5329-1877, Fax: +52-55-5387-3248
Latin America
04795-900 So Paulo SP, Tel.: +55-11-5683-7413, Fax: +55-11-5683-7694
China
Tsuen Wan, Hong Kong, Tel.: +852-2406-4189, Fax: +852-2506-1636
Japan
Tokyo 113-8662, Tel.: +81-3-5977-7934, Fax: +81-3-5977-7893
South-East Asia
Tangerang, Jakarta, Tel.: +62-21-5579-3656, Fax: +62-21-5579-7139
Internet: www.ipc.clariant.com
DSB&K
Chadstone Vic 3148, Tel.: +61-3-9254-1092, Fax: +61-3-9254-1011
EBR 5216 E 02/04
Australia/New Zealand

Surfactants For Industrial Applications

Hochgeladen von

Dokumentinformationen

Originaltitel

Copyright

Verfügbare Formate

Dieses Dokument teilen

Dokument teilen oder einbetten

Freigabeoptionen

Stufen Sie dieses Dokument als nützlich ein?

Sind diese Inhalte unangemessen?

Copyright:

Verfügbare Formate

Surfactants For Industrial Applications

Hochgeladen von

Copyright:

Verfügbare Formate

Exactly your chemistry.

Division Functional Chemicals

Nonionic and Anionic Emulsifiers, Copolymerizable

Surfactants from Clariant

Alkyl polyethyleneglycol ether

phosphoric acid esters

Alkyl polyethylene glycol

ether carboxylic acid

Fatty acid condensates

(fatty acid isethionates, methyl taurides,

sarkosin and sarkoside)

Alkyl benzene sulphonates, Ca-salts

Vinyl ether alkoxylates

oxide block polymers

Fatty acid polyethyleneglycol esters

Allyl ether alkoxylates

Fatty acid polyglycerol esters

Fatty acid polyglycerol

Allyl polyoxyalkylene sulphates

Castor oil ethoxylates

Sorbitan ester ethoxylates

Silicone containing defoamers

Silicone and fluorine-free defoamers

Secondary alkyl sulphonates

Surfactants from Clariant

Alkyl ether sulphates

Emulsifiers for emulsion

Alkyl aryl ether sulphates

Polyglycol ether sulphates

Sulphosuccinic acid esters

Fatty alkyl amine sulphosuccinamates

Alkyl phosphoric acid esters

Registered trademark of Clariant

Surfactants from Clariant

Production and sales

Research and development

cals is one of the world's leading

Our surfactants are manufactured at our

In addition to the product range we offer

manufacturers of surfactants and po-

production sites in Gendorf/Burgkirchen

our customers comprehensive advice

lyglycols. The product range encom-

and Wiesbaden (Germany), Tarragona

and technical service. Our application

passes anionic, nonionic, cationic and

(Spain), Charlotte (USA), Clear Lake

laboratories assist you in developing

amphoteric surfactants. These include

(USA), Mexico City (Mexico), Coatza-

modern system solutions and help you to

raw materials for detergents and

coalcos (Mexico), Maracay (Venezuela),

select the products that are suitable

cleaners, cosmetics and special pro-

Sao Paulo (Brazil), Zarate (Argentina)

for your applications.

ducts for chemical and industrial

and elsewhere, and are available world-

wide through our sales organization.

This brochure presents a selection

Our product range is constantly being

of our products for chemical and indu-