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1154
[water][air]/H c
[air]/H c
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
REPORTS
REPORTS
front extending some 1100 km from the Guatemala-Mexico border to central Costa Rica. Volcanoes tend to occur as large composite volcanic
centers, with an average spacing of 25 km
which is less than the spacing at other subduction zones (18, 19). There is no geophysical
Table 1. Nitrogen and helium isotope and relative abundance characteristics of Central American volcanic gases. Guatemala samples were taken
in May 2001, Costa Rica samples in January, March, and July 2001. Type
code: GF, gas from fumarole; GS, gas from (hot) spring; GW, gas from
Volcano/location
Guatemala
Zunil
Zunil
San Marcos
La Cimarron
Volcan Fuego
Summit
Amatitlan-Pacaya
Lake Shore
Hot water dyke
Laguna de caldera
Laguna de caldera
(2nd well)
Tecuamburro
Laguna Ixpacho
Duplicate (L.I.)
Sulfur mine
Moyuta
Las Guineas
Mirram El
Volcan
Costa Rica
Poas
Crater 1/01
Crater 3/01
Crater 7/01
Crater 7/01
Turrialba
Summit 1/01
Summit 7/01
Irazu
Summit landslide
1/01
evidence for sediment accretion along the Central American arc, implying that the bulk of the
sediments on the downgoing Cocos Plate are
subducted into the mantle (2023). Deep sea
drilling sites off Guatemala/El Salvador (site
495) and Costa Rica (site 1039) have revealed
N2
(mmol/
mol)
N2/He
1.9 0.5
4.69 0.05
0.006
GS
1.3 0.4
2.23 0.03
87.7
GF
5.7 0.2
93.8
GS
76.4
Lat. (N)
Long.
(W)
Temp.
(C)
Type
15N ()
14
46.693
91
30.542
93.0
GF
nd
nd
94.7
14
28.590
90
52.816
14
28.395
14
27.074
14
24.695
14
24.695
90
36.140
90
38.572
90
35.807
90
35.807
14
11.577
14
11.577
14
09.129
90
25.394
90
25.394
90
24.871
14
03.215
14
00.541
Nitrogen source
%S
15NC
()
5139 524
0.69
0.29
0.02
92.3
6.07
0.034
6691 682
0.78
0.20
0.02
91.4
5.97
6.95 0.06
0.090
2227 227
0.09
0.85
0.05
94.0
6.28
0.5 0.4
6.72 0.07
1.595
9748 994
GS
2.1 0.2
6.22 0.06
2.324
4385 447
0.65
0.32
0.03
91.8
6.01
stm
GW
1.0 0.5
7.31 0.07
0.001
1393 142
0.68
0.22
0.10
67.7
3.12
stm
GW
3.1 0.4
7.60 0.08
0.001
1870 191
0.43
0.49
0.07
87.2
5.47
77.8
GS
6.3 0.3
6.39 0.07
0.325
8200 836
0.09
0.90
0.00
99.5
6.94
77.8
GS
5.9 0.3
6.38 0.06
0.468
7734 789
0.14
0.85
0.01
99.3
6.91
93.1
GF
0.7 0.5
5.39 0.06
1.015
24,899 2539
90
05.831
90
06.068
85.9
GF
4.3 0.4
7.39 0.06
0.519
6042 616
0.36
0.63
0.02
97.6
6.72
80.7
GM
1.8 0.3
7.36 0.09
6629 676
0.72
0.26
0.02
93.6
6.24
10
11.883
10
11.883
10
11.883
10
11.883
84
13.719
84
13.719
84
13.719
84
13.719
76.0
GF
1.9 0.3
7.10 0.10
0.020
101 10
0.00
0.26
0.75
25.7
1.91
92.2
GF
2.7 0.4
7.22 0.07
0.023
268 27
0.43
0.01
0.56
1.9
4.78
92.8
GF
2.4 0.5
7.14 0.07
0.037
373 38
0.52
0.01
0.48
4.89
GF
3.0 0.6
7.15 0.07
0.021
156 16
0.01
0.16
0.83
16.3
3.04
10
01.156
10
01.156
83
45.937
83
45.937
89.6
GF
0.4 0.3
7.74 0.07
0.102
643 66
0.56
0.22
0.23
48.4
0.81
89.7
GF
1.0 0.3
8.10 0.10
0.068
866 88
0.80
0.00
0.20
4.78
9
59.723
83
47.308
88.5
GF
1.7 0.4
7.24 0.06
0.537
1483 151
0.59
0.31
0.10
76.4
4.16
108
duction process and specifically on the N isotope systematics of the volcanic arc of Central
America.
Central America is the site of active subduction of the Cocos Plate beneath the Caribbean
Plate. Resulting volcanism occurs along a linear
*Corrected for the effects of air-derived helium (55). Error quoted at the 1 level.
Percentage of sediment-derived nitrogen in binary sediment-mantle mixture.
Measured
nitrogen isotope ratios are corrected for air contamination using 15NC f 15NM (1 f )15NS, where 15NM 5 , 15NS 7, and f is the fraction of mantle-derived
nitrogen [calculated from penultimate column: f 1 (%S/100)].
Estimated value derived by projecting data point onto M-S mixing curve (N2/He 200 for Poas crater 1/01;
Average of three other ratios at same locality.
N2/He 312 for Poas crater 7/01; N2/He 750 for Turrialba).
1155
little regional variation in the sedimentary sequences on the oceanic plate: The sediment
column consists of 175 m of hemipelagic,
diatom-rich mud overlying 250 m of pelagic
carbonates (20, 21, 24, 25). Both units are geochemically distinct and contribute to volcanic
sources along much of the strike of the arc (24,
26). In Costa Rica, however, the low 10Be contents of arc magmas suggest that the hemipelagic portion of the sedimentary column is underplated to the overriding Caribbean Plate,
leaving only the pelagic carbonates to contribute
to the slab flux (27). This variation in the
amount and type of sediment involved in petrogenesis makes Central America an ideal locality
to investigate details of the transfer of N into the
mantle and the associated effects on N2/He and
15N ratios.
We measured N concentrations, N2/He ratios, and N and He isotopic compositions of gas
discharges of three volcanic centers in Costa
Rica and six volcanic regions in Guatemala
(Table 1) (28). The majority of samples have
3
He/4He ratios in the range 5 to 8 RA, (where RA
is the 3He/4He value of air 1.4 106),
indicating that both segments of the arc sample
He primarily from the mantle wedge (29, 30). In
contrast, the N isotope systematics and N2/He
ratios vary between Guatemala and Costa Rica.
The Guatemalan volatiles have 15N values that
Fig. 1. Geothermal uids from
Guatemala (lled circles) and
Costa Rica (open circles) compared with possible end member
compositions for air (AIR), mantle (M), and sediment (S). Dotted
lines reect air addition to mixtures of mantle and sediment
end members (solid line), with
percentages representing the
amount of sediment in the sediment-mantle binary mix. N-isotope end members from (17,
13, 14); N2/He from (54).
10 6
AIR
N2 /He
10 5
10 4
95%
10 3
70%
10
10 1
50%
-6
-4
-2
15 N ()
1156
10
0.2%
He/ He (R C /RA )
0.5%
1%
5%
MORB
mantle
7%
Zunil
4
K=70
San Marcos
Sediments
-6
-4
-2
0
15
Nc ()
REPORTS
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
REPORTS
1157