Chemistry Part II

Chapter # 06: Transition Elements

Total marks: 74
Q.I. (A) Fill in the blanks. 17
One of the test for chloride ion, which is done with the help of K2Cr2O7 and H2SO4 is called -------- Prevention of corrosion is very important because --------------- of annual production of iron is eaten
away.
The entrapped bubbles of gases, in molten steel are called ---------------------------- they are removed
by using aluminum.
Bessemer converter is -------------------------- shaped vessel made up of steel plates.
Steel is manufactured by two well known processes that is ------------------------- & ----------------------.
The percentage of carbon is minimum in ----------------------- iron & maximum in --------------- iron.
The atomic radii of d-block elements ------------------------- from left to right, but the variation is not
prominent.
The property of paramagnetic is due to ----------------- electrons.
The presence of ----------------- in a metal promotes corrosion.
In an aqueous solution, chromates and dichromates exist in the form of ----------------.
Elements of 2-B and 3-B are called ------------------------- transition elements.
While naming the transition metal complexes, the negative ligands end in ------ while positive ligands
end in ium.
The semi-solid mass during the manufacture of wrought iron, taken out in the form of balls is called
-------------------------.
Temperature for the open hearth furnace is maintained around --------------------.
When the tin coated iron sheets are passed through the roller, the process is called ----.
Chromates are the salts of -------------------- while dichromates are the salts of ---------.
All the dichromates are strong ----------------- agents.

Q.I. (B) Multiple Choice Questions. 15

As percentage of C increases in iron its hardness:
(a) increases (b) decreases (c) remain same (d) can not be predicted
Transition elements form complexes due to reason they have:
(a) colored compounds (b) vacant d-orbital (c) large nuclear charge (d) small cation size
Which of following cation has maximum unpaired electrons?
(a) Ni+2 (b) Co+2 (c) Mn+2 (d) Fe+2
The strength of binding energy of transition elements depends upon:
(a) no. of unpaired electrons (b) no. of electrons (c) no. of protons (d) no. of neutrons
Which is the formula of tetra amine chloronitro platinum (IV) sulphate?
(a) [Pt(NH3)4(NO2)Cl]SO4 (b) [Pt Cl (NO2)(NH3)4]SO4 (c) [Pt (NO2) Cl(NH3)4]SO4 (d) none
Which of the following is a typical transition metals:
(a) Sc (b) Co (c) Ra (d) Y
Group 4-B of transition elements contains:
(a) Cr, Mo, W (b) Zn, Cd,Hg (c) Fe, Ru, Os (d) Mn, Te , Re
Coordinate no. of Pt in [Pt Cl(NO2)(NH3)4]-2
(a) -2 (b) 4 (c) 6 (d) 1
The highest oxidation state of Mn is there in which of the following compound:
(a) K2MnO4 (b) KMnO4 (c) methane (d) propane
Which one of the following catalyses the rusting of iron:
(a) H+ (b) Zn (c) Fe (d) O2
Bessemer converter is used for the manufacture of:
(a) steel (b) cast iron (c) wrought iron (d) pig iron
What is pig iron:
(a) cast iron (b) impure sulphide ore of iron (c) wrought iron (d) Alloy of steel
Puddling process is used in the manufacture of:
(a) Wrought iron (b) steel (c) cast iron (d) pig iron
Stainless steel contain iron and:
(a) Al (b) Cr (c) Ag (d) Cu
Chromyl chloride test is performed to confirm:

(a) Cl- (b) SO4-2 (c) PO4-3 (d) Cr+3

Q.I. (C) Column Matching.

In the following chart, there are nine points. Match information of column A
with the column B and complete it in column C.
(12)
1.
Column A
Column B
Column C
CrO4-2
Trigonal
Medium steel
Tetrahedral
MnSiO3
Rails
Bronze
Cutting tools
Absorption of light
Slag
Steel manufacture
Zn & Al
CaSiO3
Zn &Cu
SiO2
Color
2
3
d sp
Open hearth process
Non stoichiometric
Slage
Mechanical properties
Acidic lining
Interstitial compounds
octahedral
Iron oxides
Binding energy
spaces
2.
(4)
Column A
Column B
Column C
Cu Ag Au
Outer transition elements
2
3
d sp
Coinage metals
Mechanical properties depends
Octahedral
upon
Dolomite
Trigonal bipyramidal
Binding energy
Electron affinity
Basic lining
Acidic lining

SUBJECTIVE
Q.2 Write a brief and concise answer for each question.

20

How KMnO4 & H2SO4 act as oxidizing agent? 2

Give the uses of KMnO4. 2
Give the structure of dichromate ion. 2
What is Para magnetism? 2
What are chelates? 2
What is stadelers process for preparation of KMnO4? 2
What is sacrificial corrosion? 2
Define corrosion. 2
What do you means by cathode coating? 2
What are chromate & dichromates? 2

Q.3 Describe the Open Hearth process for steel manufacture. 6