Beruflich Dokumente
Kultur Dokumente
1 1 A+
MASTERING ESSAY QUESTION IN PAPER 3
Experiment 1 (Chapter 2)
Experiment 2 (Chapter 4)
Aim:
To investigate the effect of the presence of impurity to the melting point
of naphthalene (becomes lower)
Aim:
To investigate the reaction of alkali metals in water
Aim:
To investigate the reactions of alkali metals with oxygen / chlorine
Problem statement:
How does
Problem statement:
How does reactivity of Group 1 elements change when they react with water?
Problem statement:
How do alkali metal react with oxygen / chlorine?
Variables:
Manipulated:
Responding:
Fixed (controlled):
Variables:
Manipulated: types of alkali metal
Responding: reactivity of alkali metal
Fixed (controlled): size of alkali metal
Variables:
Manipulated: types of alkali metals
Responding: reactivity of alkali metals
Fixed (controlled): oxygen gas
Hypothesis:
Hypothesis: When going down Group 1, alkali metal becomes more reactive
in water.
Materials:
Materials: red litmus paper, distilled water, paper, filter paper, small
lithium,sodium and potassium
Materials: 3 gas jar filled with oxygen, red litmus paper, paper, filter paper,
small lithium,sodium and potassium
Apparatus:
Procedure:
Procedure:
1) A piece of lithium removed from the bottle with apair of forceps.
2) A small piece of lithium is cut using a knife.
3) The paraffin oil on the surface of lithium is removed by using a
piece of filter paper.
4) The piece of lithium is placed into a water through half-filled with
cold distilled water using pair of forceps.
5) When the reaction stops, a piece of red litmus paper is put into the
solution formed.
6) All changes occured are recorded.
7) Steps 1 to 6 is repeated using potassium and sodium respectively
to remove lithium.
Apparatus: gas jar spoon, gas jar cover, small knife, Bunsen burner, pair of
forceps
Procedure:
1) A piece of lithium removed from the bottle with a pair of
forceps.
2)
A small piece of lithium is cut using a knife.
3) The paraffin oil on the surface of lithium is removed by using a
piece of filter paper.
4) The piece of lithium is placed in a gas jar spoon.
5) The lithium is start to burn when heated.
6) The burning lithium quickly lowered into a gas jar filled with
oxygen.
7) When recations stops, 20cm3 of distilled water is poured into
gas jar and shaken well.
8) A piece of red litmus paper is put into solution formed.
9) All changes that occured are recorded.
10) Steps 1 to 9 is repeated using potassium and sodium
respectively to remove lithium.
SPM 2008
Experiment 3 (Chapter 4)
PREPARED
1 1 A+
Tabulation of data:
Experiment 7 (Chapter 6)
Tabulation of data:
Metal
Lithium
Sodium
Potassium
SPM 2007
Aim:
To construct the electrochemical series based on potential differences
Experiment
between
metals 4 (Chapter 4)
Aim:
Problem
statement:
To investigate
the reaction of halogens with iron
Can an electrochemical series of metals be constructed based on the
potential
difference between two metals?
Problem statement:
How does reactivity of halogens change when they react with iron
Variables:
Variables:
Manipulated:
pairs of metals
Manipulated:potential
types of halogens
Responding:
difference produced
Responding:
reactivity
halogens
Fixed
(controlled):
typeofand
concentration of electrolye
Fixed (controlled): iron
Hypothesis: The reactivity of halogens decreases down the group from
Hypothesis: The further apart the two metals in the electrochemical series,
chlorine to bromine when they react with iron.
the
greater potassium
the potential
difference
produced/voltage
produced.
Materials:
manganate
(VII)
crystal, concentrated
HCL, liquid
-3
bromine, iodine
crystals,
soda lime
andcopper
iron wool
Materials:
0.1 moldm
sulphuric
acid,
strip, lead, iron, zinc,
Apparatus:
test
tubes,
tubesand
holders,
Experiment
10test
(Chapter
2) rubbber stoppers, conical flask,
aluminium,
magnesium
strip,
paper
combustion tube, delivery tube, Bunsen burner, retort stand with clamp,
Aim:
Apparatus:
250 cm3 beaker, crocodile clips, voltmeter, and connecting
thistle funnle.
To investigate the role of water in showing their properties of alkalis
Procedure:
wires.
Procedure:
1) A little iron wool is placed in the middle of combustion tube
1) statement:
The
metal strips
are celaned with sanpaper.
Problem
and heated
strongly.
Is water
needed
for
an
alkali
showsulphuric
its
alkaliacid
properties?
2) A
beaker filled HCL/liquid
withtodilute
untilcrystal
two-thirds
Concentrated
bromine/iodine
is full.
heated
in teststrip
tube.as electrode A and copper strip as electrode B
3) gently
Magnesium
3)
Chlorine
gas/bromine
gas/iodine vapour liberated is passed
Variables:are dipped into dilute sulphuric acid.
through
the
heated
iron
wool
in the combustion
tube
4) The circuit
completed by
connecting
the metals to
a until no
Manipulated:
types ofis solvents
further
changes occur.
voltmeter.
Responding:
chnage in colour of red litmus paper
4)
The
excess
chlorine
gas/bromine
vapour is absorbed
Fixed
type
alkali
and
litmusgas/iodine
paper
5)(controlled):
The reading
of of
voltmeter
produced
is recorded.
by soda lime.
6) The metal strip that acts as the negative terminal is determined
5) All
changes
and
Hypothesis:
alkali are
willobserved
only show
itsrecorded.
alkaline properties when dissolve
andan
recorded.
in water
7) Step 1 to 6 are repeated using aluminium, zinc, lead, iron, and
to replace
as atest
electrode
Materials:copper
dry ammonia
gasmagnesium
stoppered in
tube,A.
ammonia gas
Tabulation of data:
dissolved in propanone, aqueous ammonia solution and red litmus paper.
-terminal
Pair of metal
Voltage
Halogens + terminal
Observation
Zn/Cu Chlorine
Mg/Cu Bromine
SPM
CHEMISTRY
SEMINAR 2015
Al/Cu
Iodine
BY:Ag/Cu
MS PHUAN
Fe/Cu
Observation
Tabulation of data:
Metal
Observation
Lithium
Sodium
Experiment 8 (Chapter 6)
Potassium
Experiment 9 (Chapter 7)
Aim:
To construct the electrochemical series using the principle of
displacement
Experiment
of metals
5 (Chapter 6)
Aim:
Problem
statement:
To investigate
the effect of concentration of ions on the selective discharge
How
canatthe
series of hydrochloric
metals be constructed
based on the
of ions
theelectrochemical
electrodes of aqueous
acid
displacement
metals?
Problem statement:
How does the concentration of ions in hydrochloric acid affect the discharge of
Variables:
ions at the anode?
Variables: metal strips/salt solution used
Manipulated:
Manipulated:deposition
concentration
of chloride ions
Responding:
of metals
Responding:
ion discharged
at theofanode
Fixed
(controlled):
concentration
salt solution
Fixed (controlled): type of electrode
Hypothesis: When the concentration of chloride ion is higher, then the chloride
Hypothesis: The greater the number of metals that can be displaced by a metal
ion will be preferentially discharged.
from
their solutions,
series.
-3 higher is its position in the electrochemical
Materials:
1.0 moldmthe
hydrochloric acid, 0.001 moldm-3 hydrochloric
acid
-3
Materials: 1.0 mol dm of magnesium nitrate, zinc nitrate, lead nitrate, copper
Apparatus:
batteries,
carbon
wires, ammeter,
Experiment
11
(Chapter
7) connecting
SPMsandpaper
2009
nitrate,
magnesium,
zinc,
leadelectrodes,
and copper
strips,
electrolytic cell, tet tube, blue litmus paper, wooden splinter and matches
Aim:
Apparatus: test tubes, test tube rack
To investigate the relationship between pH values with molarity of acid
Procedure:
Procedure:
1) An electrolytic cell filled with 1.0 moldm-3 hydrochloric acid until
Aim:
To investigate the role of water in showing their properties of acids
Experiment 6 (Chapter 6)
Aim:
Problem
statement:
To investigate
the effect of the type of electrodes on the products of
Iselectrolysis
water needeoffor
an acidcopper(II)
to show itssulphate
acidic properties?
aqueous
solution.
Problem statement:
How does the type of electrodes affect the type of products formed during
Variables:
the electrolysis
Variables: types of solvent
Manipulated:
Manipulated:change
types in
of colour
electrodes
Responding:
of blue litmus paper
Responding:
typestype
of product
Fixed
(controlled):
of acidat anode
Fixed (controlled): type of electrolyte
Hypothesis: When copper electrodes are used instead of carbon
Hypothesis: an acid will show its acidic properties when dissolves in water.
electrodes, the types of products formed at the anode are different
Materials: 0.1 moldm-3 Copper (II) sulphate solution
Materials: glacial ethanoic acid, distilled water, dry propanone, blue litmus
Apparatus:
batteries,
copper8)electrodes, connecting wires,
Experiment
12 carbon,
(Chapter
paper
ammeter, electrolytic cells, sandpaper, wooden splinter and matches
Aim:
Apparatus: test tube, droppers, tets tube rack
To construct the ionic equation for the concentration for the formation
Procedure:
of lead(II) chromate(VI)
Procedure:
1) Two carbon electrodes are cleaned with sandpaper.
1) statement:
The
are clened with sandpaper.
Problem
it is strips
half full.
3
What
is
the
relation
between
pH
values
with
molarity
ofnitrate,
an acid?
2)
og magnesium
nitrate,
zinc
nitrate,
lead
copper
nitrate
2) 5cm
The circuit
is completed
by connecting
the
electrodes
to the switch,
solution
poured
into 4 separate tubes.
ammeter,areand
batteries.
3)
strip
of magnesium
is placed into each of the solutions.
3) AThe
switch
is turned on.
Variables:
4)
on the deposition of metals are recorded.
4) Observation
Anymolarity
observation
is recorded.
Manipulated:
of acid
5)
Steps 1 to 4 are repeated using zinc, lead and copper to replace
Responding:
pH
values
5) magnesium
The gas produced at anode and cathode are collectedand tested
strip.
Fixed (controlled):
typeblue
of acid
with a moist
litmus paper and a lighted wooden splinter,
The gas produced at the anode and cathode are collected and tested
glowingacids
wooden
splinter
and
splinter.
-3 lighted wooden
Materials: with
hydrocloric
of 1.0
mol dm
, 0.1 mol dm-3, 0.01
mol dm-3,
Tabulation
Tabulationof
of data:
data:
0.001 mol dm-3
Metal
strip
Mg(NO3)
Zn(NO3)2Observation
Pb(NO3)2
Cu(NO3)2
Electrolyte
Magnesium
Anode
Cathode
Zinc
1.0 HCL
2
Lead
0.001 HCL
Copper
1)
Three test tubes are labelled as A, B, and C. They are placed in
Problem
2) statement:
The Copper (II) sulphate solution is poured into an electrolytic
How to construct
ionic equation for the formation of lead(II)
test tubean
racks.
cell with carbon electrodes until it is half full.
chromate(VI)?
2) 1cm3 of glacial ethanoic acid is placed into each test tubes usind
3) aThe
circuit is completed by connecting the electrodes to the
dropper.
switch,
ammeter, and batteries.
3
Variables:
3) 2cm of distilled water is added to test tube B.
4)
Thevolumes
switch
isofturned
onnitrate
foor 15
min.
Manipulated:
lead(II)
solution
4) 2cm3 of dry propanone
added to test tube C.
Responding:
height
of
yellow
precipitate
5) AAll
observation
at the
anode,
cathode
andinto
electrolyte
5)
piece
of dry blue
litmus
paper
is placed
each testare
tube.
Fixed (controlled):
recorded.volumes of potassium chromate(VI) soution
6) Any changes that occur are observed and recorded.
6) Gas produced at anode is collected and tested with glowing
Hypothesis:wooden
as the volume
splinter.of potassium chromate(VI) solution increases,
the height of the yellow precipitate increases untill all the lead (II) nitrate
7) Step 1 to 5 is repeated using copper electrodes
has reacted.
Materials: 0.5 mol dm-3 lead (II) nitrate solution and o.5 mol dm-3
Tabulation
Tabulationofofdata:
data:
potassium chromate (VI) solution
Test tube
Observation
Electrode
Observation
A
Anode
Cathode
Electrolyte
CarbonB
PREPARED
CopperC
1 1 A+
Aim:
Experiment
(Chapter
9) SPM 2003/05
Apparatus: test13
tubes
and droppers
To investigate the effect of concentration on the rate of reaction
Aim:
ToProcedure:
compare the hardness of pure metal and its alloy
1) A piece of dry litmus paper is put into a stoppered test tube of
Problem statement:
dry ammonia gas and the test tube is then stoppered back
How does the concentration of reactant affect the rate of reaction?
immediately.
Problem statement:
2) harder
The effect
of the
dry ammonia gas on the red litmus paper is
Are alloys
than pure
metal?
recorded.
( is bronze harder
than copper )
Variables:
3) Another piece of dry red litmus aper is put in 5cm3 of aqueous
Manipulated:ammonia
concentration
of sodium
thiosulphate
solution
solution
in aseparate
test tube.
Variables:
Responding:
time
taken
for
the
cross
X
to
disappear
4) Step
of materials
the experiment
is repeated
Manipulated:
types3 of
to make
the metalusing
blockammonia dissolved
Fixed (controlled):
concentration
dilute
sulphuric
acid solution.
in propanone
todent
replace
aqueous
ammonia
Responding: diameter
of the
made
by a steel
ball bearing
Fixed (controlled): size of steel ball bearing
Hypothesis: When the concentration of sodium thiosulphate is higher, the
higher the rate of reaction
Hypothesis: Bronze is harder than copper
Materials: 0.2 mol dm-3 sodium thiosulphate solution, 1.0 mol dm-3
sulphuric acid and distilled water
Materials: copper block, bronze block, ball beraing, cellophane tape and
3
Tabulation10cm
of data:
thread
Apparatus:
and 100cm3 measuring cylinders, 100cm3 conical flask,
Condition
of
Inference
white paper markedammonia
with cross X andObservation
stopwatch
Apparatus: metre rule, retort stand with clamp, 1 kg weight
Procedure:
Procedure:
1)
1)
Aim:
Experiment
14 (Chapter
9) and
SPM
2003
Apparatus: pH meter,
100cm3 beakers,
100cm
measuring cylinder
To investigate the effect of temperature on the rate of reaction
Aim:
Procedure:
To
compare the rate
of rusting between iron, steel and stainless steel
1) 30cm3 of 1.0 mol dm-3 hydrochloric acid is put in dry beaker.
Problem
statement:
2) The probe of a pH meter that has been washed with distilled water
How does theistemperature
3 rate of reaction? -3
immersed inaffect
30 cmthe
of the 1.0 mol dm hydrochloric acid.
Problem statement:
3) theThe
on iron,
the pH
meter
recorded.
How does
ratepH
of values
rustingshown
between
steel
andisstainless
steel differ?
4) The pH values of hydric acid solutions with different molarities
Variables: are measured one by one in dry beakers as in steps 1 to 3.
Manipulated: temperature of sodium thiosulphate solution
Variables:
Responding: time taken for the cross X to diasappear
Manipulated: types of nails(iron, steel, stainless steel)
Fixed (controlled): concentration of sodium thiosulphate solution
Responding: rate of rusting
Fixed (controlled): size of nails
Hypothesis: The higher the temperature of the reactant, the higher the rate of
reaction
Hypothesis: pure iron rusts faster than steel while stainless steel does not rust
Materials:
0.1 mol dm-3 sodium thiosulphate solution and 1.0 mol dm-3
easily
sulphuric acid
Materials: iron nail, steel nail, stainless steel nail, 5% jelly solution and
Tabulation
of data:flask, 10cm3 measuring
potassium
hexacyanoferrate(III)
solution and
sandpaper
Apparatus:
conical
cylinder,
thermometer, stopwatch,
-3
Molarities
(mol
dm
)
pH values
white paper marked with cross X, wire gauze, tripod stand,
and Bunsen
Apparatus:
1.0
burner.
test
tubes
0.1
Procedure:
Procedure:
0.01
1)
0.001
1) Three test tubes are half filled with jelly solution and are labelled
as A, B and C.
1 cm3 of potassium hexacyanoferrate (III) solution is added to
every test tube.
3) An iron nail, a steel nail and a stainless steel are polished with
sandpaper to remove any rust formed. The nails are then placed in
the three test tubes labelled A, B and C respectively.
4) All test tubes are allowed to stand for 2 days before they are
examiined.
Experiment 20 (Chapter 12)
5) Changes occurred on the nail are observed and recorded.
Aim:
To investigate the effect of other metals on rusting
2)
Tabulation
of data:
Problem statement:
tube types of metals
Type
nail with iron affect
Observation
HowTest
do different
inof
contact
rusting?
A
Iron nail
B
Steel nail
C
Stainless steel nail
SPM 2010
Aim:
Experiment
Apparatus: test 15
tubes(Chapter
of the same10)
size, test tube rack, 50cm3 burette, retort
Tostand
investigate
the and
effect
of catalyst on the rate of recation
with
clamp
ruler
Aim:
ToProcedure:
investigate the effect of total surface area of the reactant on the rate
1.
7 test tubes of same size are labelled from 1 to 7. They are
of
reaction
Problem
statement:
placed on test tube rack.
How does
catalyst
affect
the rate
of 0.5
reaction?
2.statement:
A burette
is filled
with
moldm-3 potassium chromate (VI)
Problem
-3
5.0 moldm
the of
potassium
chromate
(VI)the
solution
How does thesolution.
total exposed
surfaceofarea
a solid reactant
affect
rate ofis
reaction? placed into each test tube.
Variables:
3.
Another burette is filled with 0.5 moldm-3 lead (II) nitrate
Manipulated:solution.
amount of catalyst used
Variables:
4.
lead
(II) nitrate
solutiongiven
fromoff
theatburette
is added
into each of
Responding:
the volume
of oxygen
half-minute
intervals
Manipulated:the
size
of marble
7 test
tubes.ofchips
Fixed (controlled):
volume
hydrogen peroxide
Responding:
rate mixture
of reaction
5.
The
in each test tube is stirred using glass rod. A yellow
Fixed (controlled):
temperature
precipitate
is formed in each test tube.
Hypothesis:
of decomposition
hydrogen
6. The
The rate
test tubes
are left asideoffor
about anperoxide
hour. increases
when the
of catalyst
used is increased
7. amount
The height
of precipitate
in each test tube is measured using
Hypothesis: When the total surface area of marble chips increases, the rate
-3 The colour above the precipitate in each test tube is
metre
rule.
Materials:
mol dm
hydrogen peroxide nad manganese(VI) oxide
of
reaction0.2
increases
observed and recorded.
3
Materials: 80cm 0.1moldm-3 hydrochloric acid, 2g large marble chip, 2g
Tabulation
of
data:water
small
marble
chip,
Apparatus:
measuring
cylinder, conical flask, delivery tube, rubber stopper,
Test
tube
1 2 3 4 5 6 7
retort stand, clamp
and burette.
3
-3
Apparatus:
50cm
measuring
cylinder, 150cm3 conical flask, stopper with
Volume of
0.5 moldm
potassium
delivery
tube,(VI)
basin,
burette, electronic balance, stopwatch
chromate
solution
Procedure:
Procedure:
Volume of 0.5 moldm-3 lead (II)
1) Using
a measuring cylinder, 25 cm3 of 0.2 mol dm-3 hydrogen
nitrate
solution.
1) Fill
a burette with water and invert it over water in a basin.
peroxide
is measured into a conical flask and 0.5 g of
Height
precipitate
2) ofmanganese(VI)
Clamp
the burette vertically
using
a retort
stand.peroxide.
Records its
is added
to the
hydrogen
Colour of
solution aboveoxide
precipitate
initial reading.
2) The conical flask
is immediately closed with a stopper fitted
3) Measure
40cm3 of 0.1 moldm-3 hydrochloric acid, HCL using a
with delivery tube and the stopwatch is started simultaneously.
measuring
Transfergently.
the acid into a conical flask.
The conicalcylinder.
flask is swirled
4)
Weigh 2g of large marble chips. Put them into the conical flask.
3) The total volume of oxygen gas given off is determined from
Close the conical flask immediately with astopper which is
joined to the delivery tube and start the
1 stopwatch.
5)
Record
the
burette
reading
at
intervals
seconds
the
burette
reading
at
intervals
of
foruntil
4 the
Experiment 21 (Chapter 13)
2of 30minute
reaction stops.
Aim:
6) minutes.
Repeate
1 to 6 using of
2gvarious
of smallliquid
marblealcohol
chips to
To determine
the the
heatsteps
of combustion
replace 2g of large marble chips.
4) The experiment is repeated using 0.20 g of manganese(VI)
oxide
instead of 0.50 g of manganese(VI) oxide.
Tabulation
of data:
Problem statement:
DoesTimes
alcohol with more carbon atoms per molecule have a higher heat of
Burette reading
combustion?
Volume gas
9)
Tabulation of data:
Tabulation of data:
PREPARED
1 1 A+
Variables:
Manipulated: type of rubber
Responding: lenght of rubber strip
Fixed (controlled): size of rubber strip, mass of weight
Variables:
Manipulated: different metal in contact with iron
Responding: presence of blue colouration//rusting
Fixed (controlled): clean iron nails
Variables:
Manipulated: different types of alcohol
Responding: heat oof combustion
Fixed (controlled): volume of water, copper can
Hypothesis: the higher the number of carbon atoms in the molecules, the
higher the heat of combustion
Apparatus: retort stand and clamp, bulldog clip, metre rule, weights
Procedure:
1) Hang both rubber strips using bulldog clips.
2) Measure the initial lenght of both rubber strips.
3) Hang 10g weight to the end of each rubber strip.
4) Remove the weight and measure the lenght of both rubber strips.
5) Repeat steps 2 to 4 using 20g, 30g, 40g and 50g weights to
replace the 10g weights.
6) Record the data.
Procedure:
1) Clean all the five iron nails, magnesium ribbon, strips of copper,
zinc and tin with sandpaper.
2) Coil four nails tightly with magnesium ribbon, strips of cooper,
zinc and tin each.
3) Place all the iron nails in separate test tubes.
4) Pour the same volume of hot jelly containing potassium
hexacyanoferrate(III) solution and phenolphthalein indicator int
the test tubes in a test tube rack and leave them aside for a day.
5) Record the observation.
Tabulation of data:
Tabulation of data:
Methanol
Ethanol
Propan-1-ol
Butan-1-ol
PREPARED
1 1 A+
Pair of metals
Fe
Fe + Zn
Fe + Cu
Fe + Mg
Fe + Sn
inference
Unvulcanised rubber
Vulcanised rubber
PREPARED
1 1 A+
FORMAT (4541/3)
TIME
1 HOURS
TYPE OF INSTRUMENT
STRUCTURE ITEM
OPEN RESPONSE ITEM
REPORT ITEM
NUMBER OF
QUESTION
2 OR 3 COMPULSORY
CONSTRUCT
MARKS
QUESTION 1 & 2
QUESTION 3
33
17
QUESTION 1 & 2 :
SOME COMMAND WORDS
1. To differentiate between products and observation
Observation: describe what you observed
Products: names in full , not formula.
2.Examples of observation:
- solid or precipitated formed. ( colur must be mentioned)
-solid is soluble / insoluble in named reagent
-gas released ( gas colour must be stated )
-change in colour : state the initial and final colour
incorrect
correct
clear solution
no reaction seen
hydrogen gas released
movement shown by ammeter
purple colour solution disappear
product of electrolysis at cathode:
SPM CHEMISTRY SEMINAR 2015
BY: MS PHUAN
PREPARED
1 1 A+
PREPARED
1 1 A+
Temperature (C)
Time, t(s)
1/time (s-1)
PREPARED
1 1 A+
CHAPTER 2: MATTER
Heating
Coolin
g
Boiling
point
Time, s
PREPARED BY: MS
1 1 A+
to
t1
t2
Example:
Graph shows the heating curve of element X.
Describe the graph in terms of states of matter, particle arrangements and changes in energy.
Sample answer:
Stage
to t1
State of matter
Liquid
t1 - t 2
Liquid
gaseous
t2 t3
Gaseous
Particles arrangement
The particles are close to each other.
The particles arrangement is not orderly.
Some of particles are close to each other
and some far apart.
The particles arrangement is not orderly.
The particles are far away from each other.
The particles arrangement is not orderly.
Changes in energy
The kinetic energy increases
The kinetic energy is constant
The kinetic energy increases
Atom
Proton number
No. of electron
Valence electron
Number of neutron / nucleon number
Chemical properties
Physical properties
No. of occupied shell
X
6
6
4
6/ 12
Y
6
6
4
8 /14
similar
different
similar
6p
6p
c) Procedure
- Weigh and record the mass of combustion tube
SPM CHEMISTRY SEMINAR 2015
PHUAN
PREPARED BY: MS
1 1 A+
Result :
- combustion tube with porcelain dish = a g
- combustion tube with porcelain dish + copper (II)
oxide = b g
-combustion tube with porcelain dish + copper = c g
- mass of copper = ( c- a) g , Mass of oxygen = ( b- c ) g
Calculation:
Element / atom
Mass (g)
Number of mole
Simplest ratio of mole
Cu
x
x / 64
O
y
y / 16
Precaution :
1. The flow of H2 must be continuous during
cooling to prevent hot copper metal from
oxidized.
2. Allow hydrogen gas flow into the tube for 5
10 minutes to unsure air totally removed. The
mixture H2 and air may cause an explosion.
3. To determine all air totally removed, collect the
air and place lighted splinter, the gas burn quietly.
[To prepare H2]
4. Zn + 2HCl ZnCl2 + H2
5. Anhydrous calcium chloride to dry the H2 gas.
6. CuO + H2 Cu + H2O
Element / atom
Mass (g)
Number of mole
Simplest ratio of mole
Mg
x
x / 24
O
y
y / 16
Precaution :
1. Clean Mg ribbon with sand paper to remove the
layer of oxide on its surface.
2. Lift / raise the lid at intervals to allow air in
3. When Mg ribbon start to burn, cover the crucible
with lid to avoid the white fume produced from
being escape to the air.
4. Repeat the process heating, cooling and
weighing to make sure all magnesium is
completely reacted with oxygen.
5. 2Mg + O2 2MgO
11
PREPARED BY: MS
1 1 A+
Na2O
+1
CuI
+1
Sodium oxide
Does not have roman number
because sodium has only one
oxidation number
(b) The reactivity of Group I elements increases down the group, whereas the reactivity of
elements decreases down the group.
(12 marks)
Group 17
Explanation
Change in proton number
Change in number of electrons and electron filled shells
Change in atomic size/radius/diameter
Strength of electrostatic attraction between nucleus and
valence electron
Tendency to
6 To become
7 Reactivity
Group I
Increases
Increases
Increases
Decreases /weaker
Group 17
Increases
Increases
Increases
Decreases /weaker
Releases electron
increases
Positive ion
Increases
Attract t/ accept
electron decreases
Negative ion
Decreases
(2) Explain how the melting point of Group 1 elements change down the group (4 marks)
decreases gradually
Reason
atomic size increases
metallic bonding between the atoms become weaker
Less energy is required / needed to overcome this metallic bonding.
(3) Chemical properties of element in group 17
I
II
III
12
PREPARED BY: MS
1 1 A+
To
Soda
produce
III
lime
Hot iron wool
II
Example: Compare the reactivity of reactions between chlorine and bromine with iron. [Diagram III]
Reactio
n
A
Reactants
Iron + chlorine gas
Observation
The hot iron wool ignites rapidly with a bright flame.
A brown solid is formed.
The hot iron wool glows moderately with fast.
A brown solid is formed.
Sample answer:
a) Chemical equation: 3Cl2 + 2Fe 2FeCl3
b) The reactivity of reaction A is higher than reaction B.
c) The atomic size of chlorine is smaller than bromine.
d) The forces of attraction of the nucleus toward the electrons are stronger.
e) It is easier for chlorine atom to attract/receive electron.
(4) Across period 3, atomic radius (atomic size) decreases / electronegativity increases. Explain.
a) Proton number increases by one unit.
b) The number of valence electrons in each atom increases.
c) Positive charge of the nucleus increases, thus
d) Nuclei attraction on valence electron increases.
e) Atomic radius (atomic size) decreases
f) Tendency to receive electron increases (to form negative ion) thus electronegativity increases.
(5) Chemical properties of the oxide of element across Period 3 changes from basic oxide to
amphoteric oxide to acidic oxide.
Basic oxide sodium oxide (Na2O)
Amphoteric oxide Aluminium oxide (Al2O3)
Acidic oxide sulphur dioxide, SO2
CHEPTER 5: CHEMICAL BOND
(a) Group 1 elements react with Group 17 elements to produce compounds that have high melting points.
(4 marks)
The points are:
Ionic compound produced
Because involve transfer of electrons between metal atom and non metal atom.
Metal atom donates valence electron to form positive ion, non metal atom accepts electron to
negative ion.
The oppositely charged ions are held together by strong electrostatic force.
More heat energy is needed to overcome the strong force of attraction.
Formation of ionic compound (metal [Group 1,2 & 13] and non metal [ Group 14, 15, 16& 17])
SPM CHEMISTRY SEMINAR 2015
PHUAN
13
PREPARED BY: MS
1 1 A+
Sample answer:
1 Electron arrangement of atoms ( Na , 28.1 ; Cl 2.8.7 ) // valence electrons
2 To achieve stable / octet electron arrangement
3 Atom ( Na) releases one / valence electron to form sodium ion, Na+
4 Half equation ( Na Na+ + e)
5 Atom (Cl) gain / accept electron to form chloride ion, Cl6 Half equation ( Cl + e Cl- )
7 Oppositely charged ion, Na+ & Cl- are attracted to one another by strong electrostatic force of
attraction to form ionic compound, NaCl
8 Diagram
Formation of covalent compound (nonmetal)
1 electron arrangement of the atom /valence electrons
2 to achieve duplet /octet electron arrangement
3 Atom (Carbon) contributes 4 electrons while (H) atom contributes 1 electron (for sharing).
4 one ( Carbon ) atom share 4 pairs of electrons with 4 (H) atoms to form covalent compound ,
CH4 / ratio
5 diagram
Compare the physical properties of covalent and ionic compound
Properties
Melting and
boiling
Electrical
conductivit
y
CHAPTER 6: ELECTROCHEMISTRY
1. Factor that affect the electrolysis of an aqueous solution
a position of ions in the electrochemical series (cathode)
b concentration of ions in the electrolyte - halide ( Chloride, bromide and iodide)
c type of electrodes used in the electrolysis ( anode metal )
Application
(i) Electroplating
anode electroplating metal ( less electropositive metal / Cu, Ag, Ni )
cathode metal /object to be electroplated
electrolyte - solution that contains the metal ions of electroplating metal
(ii) Purification
SPM CHEMISTRY SEMINAR 2015
PHUAN
14
PREPARED BY: MS
1 1 A+
2. To construct the electrochemistry based on tendency to release electron /potential differences voltaic cell/ Electrochemical cell.
lead
copper
Copper(II)
Cell P
Cell Q
4. Compare and contrast cell P and Q. Include in your answer the observation and half equation for the
reaction of the electrodes in both cells.
Cell P
Electrical chemical
+ve / anode: copper (OXIDATION)
SPM CHEMISTRY SEMINAR 2015
PHUAN
Characteristics
Cell Q
Energy change
Chemical electrical
Electrode
+ve/cathode: copper
15
PREPARED BY: MS
1 1 A+
Ions present in
the electrolyte
Half equation
( ECS)
Observation
(ECS)
16
PREPARED BY: MS
1 1 A+
Procedure:
1. Rinse a burette with a small amount hydrochloric acid 0.1 mol dm-3 .
2. Clamp the burette on retort stand.
3. Fill the burette with hydrochloric acid 0.1 mol dm-3 .Adjust the meniscus level of acid to a reading at 0.
4. Record the initial burette reading.
5. Pipette 25.0 cm3 of potassium hydroxide 0.1 mol dm-3 into conical flask.
6. Add two drop of phenolphathalein.
7. Add hydrochloric acid 0.1 mol dm-3 carefully. Swirl the conical flask during the process.
8. When the colour of the mixture turn paler, add hydrochloric acid drop by drop.
9. Stop adding the hydrochloric acid as soon as the solution turns colourless.
10. Record the final burette reading.
11. Repeat steps 1-10 twice. Tabulate your reading.
MAVA =
Result :
Titration
Final burette reading, cm3
Initial burette reading, cm3
Volume of hydrochloric acid 0.1 mol dm-3 , cm3
calculate the mass of solute ( mole = 0.1 x 100/1000 , 0.01 = mass/ 40)
weigh 0.4g of NaOH in weighing bottle using digital balance / electronic balance
pour into a beaker, rinse the bottle with distilled water.
dissolve NaOH with a little ( 10 20 cm3 )distilled water.
transfer the mixture into volumetric flask 100 cm3 rinse the beaker with distilled water.
pour the washings into volumetric flask 100 cm3
add distilled water, shake well
add distilled water drop by drop to finally bring the volume of solution to the 100 cm3 mark /
calibration mark.
17
PREPARED BY: MS
1 1 A+
Health
CHAPTER 8 SALT
A salt is a compound formed when the hydrogen ion, H+ from an acid is replaced by a metal ion or an
ammonium ion, NH4+
Preparation of soluble salt
acid + reactive metal(Zn / Mg) salt + H2 / 2H+ + Mg Mg2+ + H2
18
PREPARED BY: MS
1 1 A+
Observation
Chemical equation
Ionic equation
Action of heat on salt
Carbonate oxide metal (base) + CO2 except Na, K and NH4+
Example: CuCO3 CuO + CO2
Nitrate oxide metal + nitrogen oxide + oxygen except Na, K, (2NaNO3
Example : 2Mg(NO3)2 2MgO + 4NO2
+ O2
(Brown gas)
2NaNO2
+ O2 )
Ammonium chloride ammonia gas + hydrogen chloride gas, (NH4Cl NH3 + HCl )
Confirmatory test for cation and anion
1 State the material / chemical / reagent
2 procedure
3 observation
4 conclusion
Example: You are given a bottle of ammonium chloride solution. Describe chemical test to
verify the cation and anion.
a
OR
4
5
6
19
PREPARED BY: MS
1 1 A+
1
2
3
4
5
6
7
Aim : To construct the ionic equation for the formation of lead (II) chromate(VI)
[Continuous variation method]
Apparatus
: Test tubes of the same size, test tube rack, burette, retort stand with
clamp, ruler, glass rod, dropper.
: 0.5 mol dm-3 potassium chromate (VI) solution, 0.5 mol dm-3 lead (II)
nitrate solution.
Procedure
:
1. Seven test tubes of the same size were labelled from number 1 to 7. They were placed in a test
tube rack.
2. A burette was filled 0.5 mol dm-3 lead (II) nitrate solution, 5.00 cm3 of the lead (II) nitrate
solution was run into each the seven tubes.
3. Another burette was filled with 0.5 mol dm-3 potassium chromate (VI) solution.
4. Potassium chromate (VI) solution from the burette was added into each of the seven test tubes
according to the volumes specified in the table.
5. The mixture in each test tube was stirred with a clean glass rod.
6. The test tubes were left aside for about an hour.
7. The height of the precipitate in each test tube was measured. The colour of the solution above the
precipitate in each test tube was observed and recorded.
Material
Results:
Test tube
Volume of 0.5 mol
dm-3
Pb(NO3)2 /cm3
Volume of 0.5 mol
dm-3
K2Cr O4 /cm3
Height of precipitate
(cm)
Colour of solution
above the precipitate
5.00
5.00
5.00
5.00
5.00
5.00
5.00
1.00
2.00
3.00
4.00
5.00
6.00
7.00
0.60
1.20
1.80
2.40
3.00
3.00
3.00
colourless
colourless
colourless
yellow
yellow
colourless
colourless
Paper 2
Discussion
The volume of 0.5 mol dm-3 potassium chromate (VI), solution required to exactly react with 5.00 cm3 of
0.5 mol dm-3 lead (II) nitrate solution is 5.00 cm3.
SPM CHEMISTRY SEMINAR 2015
PHUAN
20
PREPARED BY: MS
1 1 A+
Calculation:
Number of moles lead (II) ions = MV
= 0.5 x 5.00/1000 = 0.0025 mol.
Number of moles chromate (VI) ions = MV
= 0.5 x 5.00/1000 = 0.0025 mol.
Simplest mole ratio of lead (II) ions : chromate (VI) ions
0.0025 : 0.0025
1 : 1
Discussions:
1. A yellow precipitate of lead (II) chromate (VI) is formed in each of the seven test tubes.
2. The height of the precipitate increases gradually from test tubes 1 to 5 because more and more lead (II)
chromate (VI) is formed due to the increasing amount of potassium chromate (VI) added to the test tubes.
3. The colour of solution above the precipitate in test tubes 1 to 4 are colourless due to the excess lead (II)
nitrate.
4. The colour of solution above the precipitate in test tubes 6 to 7 is yellow due to the excess potassium
chromate (VI).
5. Ionic equation: Pb2+ + Cr2O72- PbCr2O7
Conclusion:
As / when the volume of potassium chromate (VI) solution used increases, the height of the precipitate
increases until it achieves a maximum height.
CHAPTER 9 : MANUFACTURED SUBSTANCES IN INDUSTRY
1. Contact process: manufactured sulphuric acid
Stage
1
Equation
SO2
S + O2
2SO2 + O2 2SO3
3
4
Explanation
Sulphur is burned in the excess of oxygen gas to produce sulphur
dioxide gas.
SO2 is then heated in excess oxygen gas, catalyst Vanadium (V)
oxide, 1 atm and 450 550 o C , to produce sulphur trioxide gas.
Gas sulfur trioxide dissolve in sulphuric acid to produce oleum
Oleum is added to water to produce sulfuric acid
Gas SO3 is not dissolve in water to produce H2SO4 straight away because the reaction will produce
a lot of heat which is dangerous( cause the forming of acid fumes)
Usage of sulphuric acid:
To manufacture fertilizer, soap and detergent
To make explosive material, paint / pigment, polymer
As metal cleaner and electrolyte in car battery.
2. Haber Process
SPM CHEMISTRY SEMINAR 2015
PHUAN
21
PREPARED BY: MS
1 1 A+
N2 +
3H2
2NH3
Condition: Catalyst: iron, temperature: 450 550 oC, Pressure 200 500 atm
Usage: to manufacture fertilizer
2NH3 + H2SO4 (NH4 )2 SO4
3NH3 + H3PO4 (NH4 )3 PO4
NH3 + HNO3 NH4NO3
3. High percentage of nitrogen is a good fertilser for plants. How to calculate %N in fertiliser?
urea CO(NH2)2 and ammonium nitrate (NH4NO3), which one is a better fertiliser?
[ RAM : N,14; C,12 ;O,16; H,1]
Sample answer:
% N in Urea = mass of nitrogen / RMM urea x 100
= 2x14 / 60 x 100 = 46.67%
% N in NH4NO3 = 2x14 / 80 x 100 = 35.00 %
Urea is a good fertilizer than ammonium nitrate, because the percentage of nitrogen in urea higher than
ammonium nitrate.
4. Describe how toxic waste product from factory affects the quality of the environment. Your description
should include the following aspects. Source, process and effect.
Sample answer:
1. [Source] sulphur dioxide gas produced by factory or burning of fossil fuels
2. [process ] sulphur dioxide gas dissolves in rain water / water to form acid rain,
2SO2 +O2 + 2H2O 2H2SO4]
3. [effect ] toxic waste / acid flows to into lakes and rivers, acid rain lowers the pH value of water,
soil and air.
4. Fish and other aquatic organisms die.
5. acid rain corrodes concrete buildings and metal structures
6. acid destroys trees in forest
7. Acid rain reacts with minerals in soil to produces salt which are leached out the top soil.
8. Plants die of malnutrition and diseases.
9. Soil becomes acidic, unsuitable for growth of plants and destroys the roots of plants.
10. sulphur dioxide causes respiratory problems in humans.
5
POLIMER: - large molecules made up of identical repeating sub-units of monomers which are
joined together by covalent bonds.
Synthetic polymer
Polythene
Polypropene
Polyvinyl chloride, PVC
Perspex
Monomer
Ethene
Propene
Chloroethene
Methylmethacrylate
22
Uses
Plastic bags, plastic container
Piping, car batteries
Artificial leather, water pipe
Safety glass, reflectors
PREPARED BY: MS
1 1 A+
monomer ( ethene)
polymer (polyethene)
ALLOY
An alloy is a mixture of two or more elements with a certain fixed composition in which the major
component is a metal.
1. The composition , properties and uses of some alloy
Alloy
Bronze
Composition
Cu
Tin
Brass
Cu
Zinc
Iron
Carbon
Steel
Stainless
steel
Duralumi
n
Pewter
Iron
Carbon
Chromium
Aluminium
Copper
Magnesium
manganese
Tin, Copper
antimony
Properties
-Hard and strong
-does not corrode easily
-has shiny surface
-harder than copper
Hard and strong
-shiny
-strong
-does not rust
-light
-strong
-lustre, shiny
-strong
Uses
-in building of statue or monuments.
-in making of medals
-swords and artistic material
-in making of musical instruments and
kitchenware
-in construction of buildings and bridges
-in building of the body of cars and railway
tracks
-in making of cutlery
-in making of surgical
instrument
-in building of the body of aeroplane and
bullet trains
In making of souvenirs
23
PREPARED BY: MS
1 1 A+
How does the rate of rusting between iron, steel and stainless steel differ?
Hypothesis
Iron rust faster than steel and steel rust faster than stainless steel.
Variables
Manipulated : Iron, steel and stainless steel.
Responding : intensity / amount of dark blue colour / rate of rusting
Fixed
: size of nail, concentration of solution, duration of rusting
Procedure:
1. Clean the nails with sand paper (to removed the rust from all the nails)
2. Place the iron nail, steel nail and stainless steel nail into the test tube A, B and C respectively.
3. Prepare a 5 % jelly solution by adding 5 g jelly to 100 cm3 of boiling water. Add a few drop of
potassium hexacyanoferrate (III) solution.
4. Pour the hot jelly into the test tubes until all the nails are fully immersed.
5. Leave the nails for 3 days.
6. Observe and record the intensity of the dark blue colour.
Test tube
Tabulation of data
A
B
C
Paper 2
Conclusion
1. The concentration of Fe2+ ions in the test tube A is higher than in test tube B. No Fe2+ ions are present
in test tube C.
2. The rate of rusting in test tube A is higher than that in test tube B. No rusting takes place in test tube C.
Alloy slow down the rate of rusting.
Properties, composition and uses different type of glass
Type
Fused glass
Soda lime
glass
Borosilicat
e
Properties
-Very high softening point
-Highly heat resistant
-Does not crack when temperature changes
-very resistant to chemical reactions
-difficult to be shaped
-low softening point
-does not withstand heating
-break easily
-less resistant to chemical reactions
-easy to be shaped
- cracks easily with sudden change in temperature
-lower thermal coefficient
-heat resistant
- Does not crack when temperature changes
24
Chemical
compositio
n
SiO2
Uses
Lenses, telescope
mirrors, optical fibres,
Laboratory glassware.
SiO2
CaCO3 /
Na2CO3
SiO2
B2O3
Na2O
Laboratory glassware,
cooking utensils.
Automobile
PREPARED BY: MS
1 1 A+
Lead glass
headlights.
SiO2
PbO
CaO
Decorative items,
crystal glass ware,
lens, prism, chandelier
Composite Materials is a structural material that is formed by combining two or more different
substances such as metal, alloys, glass, ceramics and polymers.
Composite
material
Reinforced
concrete
Superconductor
Component
Steel
Properties of
composite
Stronger, high tensile
strength does not
corrode easily, can
withstand higher
applied forces and
loads, cheaper.
Copper(II)oxide
, barium oxide
Insulators of electricity
Conducts electricity
Generators,
transformers,
electric cable,
amplifiers,
computer parts
MRI
Water storage
tanks, small boat,
helmet
Sensitive to light :
darkens when light
intensity is high,
becomes clear when
light intensity is low.
Photochromic
optical lens, camera
lens, car
windshields, optical
switches, light
intensity meters.
Concrete
Fibre glass
Photochromic
glass
Glass of high
refractive index
Glass
Properties of
component
Hard but brittle, low
tensile strength
Polyester plastic
Glass
Silver chloride
or silver
bromide
Sensitive to light
25
Uses of
components
Construction of
framework for
highway, bridges
and high-rise
building
PREPARED BY: MS
1 1 A+
26
PREPARED BY: MS
1 1 A+
Note:
1. Catalyst a substance which alters the rate of chemical reaction while remains chemically
unchanged at the end of reaction.
2. Observable changes for measuring the rate of reaction.
(a) volume of gas liberated
(b) precipitate formation
(c) change in mass during reaction, colour ,temperature, pressure
1. Catalyst (Manganese (IV) oxide)
a) Decomposition of sodium chlorate (V), 2NaClO3 2NaCl + 3O2
b) Decomposition hydrogen peroxide ,
2H2O2 2H2O + O2
2. Catalytic converters in the car exhaust system contain rhodium, platinum or chromium (III) oxide
Cr2O3.
Example:
1. Aim: To investigate the effect of temperature of sodium thiosulphate Na2S2O3 solution on the rate of
reaction
Problem Statement:
How does temperature of sodium thiosulphate Na2S2O3 solution affect the rate of reaction?
Hypothesis:
When the temperature of sodium thiosulphate Na2S2O3 solution increases, the rate of reaction increases.//
the higher the temperature of sodium thiosulphate solution, the higher the rate of reaction.
Variables:
Manipulated :Temperature of sodium thiosulphate solution.
Responding :Rate of reaction/ Time taken for the cross X to disappear from the sight.
Fixed
: Concentration and volume of sulphuric acid, concentration and volume of sodium
thiosulphate solution.
Apparatus : 150 cm3 connical flask, 50 cm3 measuring cylinder,10cm3 measuring cylinder, stopwatch,
thermometer, Bunsen burner, tripod stand, wire gauze.
Materials: 0.2 mol dm-3 sodium thioulphate solution, 1.0 mol dm-3 sulphuric acid, white paper marked
X
at the centre.
Procedure:
1. 50 cm3 of 0.2 mol dm-3 sodium thiosulphate solution is measured using measuring cylinder and poured
into a conical flask.
2. The temperature of the solution is measured with a thermometer.
3. The conical flask is placed on a white paper marked`X`.
SPM CHEMISTRY SEMINAR 2015
PHUAN
27
PREPARED BY: MS
1 1 A+
4. 5 cm3 of 1 mol dm-3 sulphuric acid is measured and then poured quickly and
carefully into the sodium thiosulphate solution.
5. The stopwatch is started immediately and the conical flask is swirled.
6. The mark `X` is viewed / observed vertically from above.
7.The stopwatch is stopped as soon as the mark disappear from sight.
8.Time taken is recorded.
9. Steps 1 to 9 are repeated by using the different temperature of sodium thiosulphate solution.
Data and Observation
Experimen
t
1
2
3
4
5
Temperature ,
(oC)
28
35
40
45
50
1/ time taken ,
1/t ( s-1)
Discussion
Based on plotted graph: [ calculation ]
The higher the temperature of sodium thiosulphate, the shorter the time taken for crossX to disappear
from the sight.
The rate of reaction directly proportional to the temperature of sodium thiosulphate solution used. //
As the temperature sodium thiosulphate solution increases, the time taken decreases. Therefore the rate of
reaction increases.
Conclusion :
The rate of reaction increases as the temperature sodium thioulphate solution increases.
28
PREPARED BY: MS
1 1 A+
Observation
Effervescence occurred. The glowing wooden splinter relight.
No effervescence. The glowing wooden splinter did not relight.
Discussion:
Manganese (IV) oxide (MnO2) increases the rate of decomposition of hydrogen peroxide. Decomposition
of hydrogen peroxide produces oxygen gas. 2H2O2 2H2O + O2
SPM CHEMISTRY SEMINAR 2015
PHUAN
29
PREPARED BY: MS
1 1 A+
2methylpropane
C6H12O6
Fermention
C2H4Br2
C2 H 6
CH3COOH
C2H5OH
Br2
Carboxyl
Hydroxyl
Oxidation
H2
C2H4
+
C2H4(OH)2
KMnO4/ H ,
K2Cr2O7/ H
C2H5OH
C2H5Br
H2O
HX
A
d
H2SO4
CH3COO C2H5
Ethyl
i
- CH2- CH2-
t
i
Esterification
Double bond
between C
Cn H
2n+ 2
CnH2n
Cn H
30
2n+ 1
, n = 1,2 alkane
, n = 2, 3 alkene
OH, n = 1, 2 alcohol
PREPARED BY: MS
1 1 A+
KMnO4/H+ / K2Cr2O7/
H+
2. CH3COOH + C2H5OH
3. C2H4 + H2O
4. C6H12O6
H 2SO4,
cons
Yeast
2C2H5OH + 2CO2
Homologous
series
Alkane
General formula
CnH2n + 2 , n = 1,2..
Ethane
Alkene
CnH2n , n = 2..
Ethene
Alcohols
Hydroxyl group / - OH
Ethanol
Carboxylic
acid
CnH2n + 1 COOH, n =
0,1,2..
Functional group
31
Member , example
PREPARED BY: MS
1 1 A+
4. Your are required to prepare one namely ester by using ethanoic acid is one of the reactants. By using
a namely alcohol, describe one experiment to prepare the ester. In your description include the chemical
equation and observation involved.
Ester: ethylethanoate
Material: ethanol, etahanoic acid, water, concentrated sulphuric acid
Apparatus: Boiling tube / test tube, Bunsen burner, test tube holder, beaker
Procedure:
1. Pour 2 cm3 of ethanol into a boiling tube / test tube
2. Add 1 cm3 of ethanoic acid
3. Add 2 to 4 drops of concentrated sulphuric acid
4. Heat the mixture gently for about two minutes
5. Pour the mixture into a beaker containing water.
Observation: Sweet/ pleasant / fruity smell // insoluble in water
Chemical equation: CH3COOH + C2H5OH CH3COO C2H5 + H2O
32
PREPARED BY: MS
1 1 A+
4. Dehydration of alcohol
Diagram of set up of apparatus
1. Complete and functional
2. Labels of set up of apparatus correct
Procedure:
a) Place some glass wool in a boiling tube
b) Use a dropper to add propan-1-ol to wet the glass wool.
c) Clamp the boiling tube horizontally and placed unglazed porcelain chips in the mid section of
the boiling tube.
d) Heat the unglazed porcelain chips strongly.
e) Then heat the glass wool gently to vaporize the propanol.
f) [Description of the chemical test to the gas collected in the test tube.]
Add 1 cm3 of bromine water and shake well.
[Observation]:
Reddish brown colour of bromine decolourised
Or,
Add 1 cm3 of acidified potassium manganate(VII) solution and shake well.
[Observation]:
Purple colour of potassium manganate(VII) solution decolourised
Chemical equation: C3H7OH C3H6 + H2O
33
PREPARED BY: MS
1 1 A+
Observation
Latex coagulates immediately
Latex coagulates slowly
Rubber
particles
34
PREPARED BY: MS
1 1 A+
Unvulcanised rubber
Vulcanised rubber
Result / Data
Type of rubber
vulcanised
unvulcanised
Initial length , cm
Elasticity
Hardness
Elasticity
35
Unvulcanised rubber
Less harder
Less elastic
PREPARED BY: MS
1 1 A+
Stronger
Can withstand higher temperature
Less easily oxidized
Does not become soft and sticky easily
Tensile strength
Resistance to heat
Resistance to oxidation
Effect of organic solvent
Weaker
Cannot withstand higher
temperature
More easily oxidized
Become soft and sticky easily
Conclusion:
1
Vulcanised rubber is more elastic than unvulcanised rubber due to the presence of cross-linkage
of sulfur atoms between the rubber molecules. Vulcanised rubber could return to its original
length after removal of the weight.
Alkene ( hexene )
Hydrocarbon ( contain C and H atom)
Low melting and boiling point
Insoluble in water, soluble in organic solvent
Cannot conduct electricity
Density less than water
Completely combustion produce CO2 + H2O
, CnH2n , n= 2
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10 Identify test
1. Combustion, burn less soot flame.
(% of carbon per molecule is lower)
Chemical tests
2. add bromine water , brown colour
remains
3. add acidified KMnO4 , purple colour
remains
Rusting of iron
1. When iron exposed to water and oxygen
2. Iron atom releases 2 electrons to form iron (II) ion, Fe2+ / is oxidized to form iron (II) ion, Fe2+
3. Fe Fe2+ + 2e // (anode) [ oxidation]
4. Iron acts as reducing agent
SPM CHEMISTRY SEMINAR 2015
PHUAN
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3.
Procedure:
Five iron nails, magnesium ribbon, copper strip, zinc strip and tin strip were cleaned with sand
paper.
2.
Four iron nails were coiled tightly with the magnesium ribbon, copper strip, zinc strip and tin
strip
respectively.
All five iron nails were placed in separate test tube.
4.
The volume of hot jelly solution that was mixed with a little K 3Fe(CN)6 solution and
phenolphthalein indicator was poured into the each test tube to completely cover all the nails.
5.
The test tubes were kept in a test tube rack and were aside for a day.
6.
All observations were recorded.
Observation
Metal
Fe
Observation
Intensity of dark
blue colouration
Low
Intensity of pink
colouration
Condition of nail
The surface of the nail was partially covered with
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The nail in test tube A rusted a little. No rusting occurred to the nails in test tubes B and C .The nail in test
tube D rusted but the nail in test tube E rusted even more.
Discussion
1. Based on the observations magnesium and zinc metals inhibit rusting of iron, while copper and tin
metals speed up rusting of iron.
2. This is because magnesium and zinc are more electropositive than iron. Magnesium atom or zinc
atom releases its electron more easily than iron.
Mg Mg2+ + 2e
O2 + 2H2O + 4e 4OH3. Copper and tin are less electropositive than iron. Iron atom releases its electrons more easily than
copper atom or tin atom.
4. Fe Fe2+ + 2e
5. The less electropositive metals that in contact with iron, the faster the rusting of iron occurs.
6. The more electropositive metals that in contact with iron prevent iron from rusting.
Conclusion:
Rusting can be prevented when iron is in contact with a more electropositive metal. Rusting occurs
faster when iron is in contact with a less electropositive metal.
1. Displacement reaction Metal:
Example: Zn + CuSO4 ZnSO4 + Cu // Zn + Cu2+ Cu + Zn2+
a) Zn atom oxidized to Zn2+ , Zn Zn2+ + 2e
b) Oxidation number of Zn changes / increase from 0 to +2,
c) Zn acts as reducing agent.
d) Copper (II) ion reduced to Cu, Cu2+ + 2e Cu
e) Oxidation number of copper changes / decrease from +2 to 0
f) Cu2+ ion acts as oxidizing agent
Example:
An experiment is carried out to determine the relative position of three metals, silver, L and M, in the
electrochemical series.
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silver
nitrate
Experiment
silver
nitrate
L
nitrate
Observation
grey deposit
colourless solution
grey deposit
light blue solution
no change
Based on results, arrange the three metals in order of increasing electropositivity. Explain you answer.
Sample answer:
1. Silver, M and L
2. L can displace silver from silver nitrate solution.
3. L is more electropositive than silver // L is higher than silver in electrochemical series.
4. M metal can displace silver from silver nitrate solution.
5. M is more electropositive than silver // M is higher than silver in the electrochemical series.
6. M cannot displace L from L nitrate solution.
7. M is less electropositive than L // L is higher than M in the electrochemical series.
2. Displacement of Halogen:
Aim: To investigate oxidation and reduction in the displacement of halogen from its halide solution.
Procedure:
1. Pour 2m cm3 of potassium bromide solution into a test tube.
2. Add 2 cm3 of chlorine water to the test tube and shake the mixture.
3. Add 2 cm3 of 1,1,1-trichloroethane / tetrachlorometane to the test tube and shake the mixture
and leave it on the test tube rack
4. Record theobservation.
5. Repeat steps 1 to 4 using another halogens and halide solutions.
Tabulation of data:
Halogen
Chlorine
Bromine
Iodine
Halide
solution
SPM CHEMISTRY SEMINAR 2015
PHUAN
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Potassium chloride
Potassium bromine
Potassium iodide
X
/
/
X
X
2I- I2 + 2e (oxidation
bromine water
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3. Iron(III) ions gain electron to become iron(II) ions. Iron(III) ions are reduced.
4. Zinc atoms releases/ donates electrons to form zinc ions. Zinc atoms are oxidized.
(a: any suitable reducing agent)
5. Describe an experiment to investigate oxidation and reduction in the change of iron(II) ions to
iron(III) ions and vice versa.
(i)
Procedure:
1. Pour 2 cm3 of freshly prepared iron(II)sulphate solution into a test tube.
2. Using dropper, add bromine water drop by drop until no further changes are observed.
3. Heat slowly / gently
4. Add 3 drops of potassium hexacyanoferrate (II) solution / sodium hydroxide solution.
5. Dark blue precipitate // brown precipitate formed.
(ii) Changing of Fe3+ ions to Fe2+ ions
Procedure:
1. Pour 2 cm3 of iron(III)sulphate solution into a test tube.
2. Add half spatula of zinc / Mg powder to the solution.
3. Shake the mixture until no further changes are observed.
4. Filter the mixture.
5. Add 3 drops of potassium hexacyanoferrate (III) solution / sodium hydroxide solution into the filtrate.
6. Dark blue precipitate // green precipitate formed.
Reactivity series
1. reactive metal with oxygen
Ca
Mg
Al
C
Zn
Positions of
carbon and
hydrogen in
the reacting
series of
metal
H
Fe
2Mg + O2 2MgO
Produce
oxygen
SPM
CHEMISTRY SEMINAR 2015
PHUAN
Na
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1 1 A+
reducing
agent
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C + O2 CO2
C + CO2 2CO
C, CO2 , 2CO reduced the iron oxides to iron
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4. Heat of combustion heat releases when 1 mole of alcohol burnt completely in excess oxygen.
C2H5OH + 3O2 2CO2 + 3H2O
5. As the number of carbon atom per molecule increases, the heat of combustion increases, due to more
products formed (CO2 & H2O) . Therefore more heat released when more bonds are formed.
6. To determine heat of combustion (material and apparatus, procedure, tabulation of data, calculation,
observations, precautions).
Procedure:
1. (100 200) cm3 of water is measured using a measuring cylinder
2. and poured into a copper tin.
3. The initial temperature of water is measured and recorded, 1
4. A spirit lamp is filled with butanol/ other alcohol and weighed, x gram
5.The spirit lamp is light and put under the copper can.
6.The water is stirred continuously with a thermometer.
7.When the temperature of water increased by 30oC, the flame is put off.
8.The spirit lamp is weighed again, y gram
9.The highest temperature is recorded, 2
Results:
Mass of weight of spirit lamp + butanol /g
Final mass of spirit lamp + butanol /g
Mass of butanol used/g
Highest temperature of water /oC
Initial temperature of water /oC
Increased in temperature /oC
Calculation:
Heat change = mc
= 100 x 4.2 x (2 1)
=aJ
x
y
(x-y) // z
1
2
(1 - 2 ) // 3
aJ
(z/74)
Precautions:
1. Make sure the flame from the combustion of ethanol touches the bottom of the copper can // The
spirit lamp is placed very close or just beneath the bottom of the copper can.
2. Stir the water in the copper can continuously.
3. The spirit lamp must be weighed immediately (because the ethanol is very volatile).
4. A wind shield must be used during experiment.
Heat of displacement
Aim: To determine the heat of displacement of copper by zinc and iron
Procedure:
1. Measure 25 cm3 of 0.2 mol dm-3 of copper(II)sulphate solution and pour into a plastic cup / polystrene
cup.
2. Record the initial temperature of the solution.
3. Pour 0.5g of zinc powder into the solution.
4. Stir the mixture with thermometer
SPM CHEMISTRY SEMINAR 2015
PHUAN
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1 1 A+
Initial temperature, oC
Highest temperature, oC
Heat of precipitation
Aim: To determine the heat of precipitaion of silver chloride, AgCl
Apparatus: plastic cup, thermometer, measuring cylinder
Material : silver nitrate solution , 0.5 mol dm-3 , sodium chloride solution, 0.5 mol dm-3
Procedure:
1. Measure 20 cm3 0.5 mol dm-3 of silver nitrate solution and pour into plastic cup.
2. Measure and record the initial temperature of silver nitrate solution.
3. Measure 20 cm3 0.5 mol dm-3 of sodium chloride solution and pour into plastic cup.
4. Measure and record the initial temperature of sodium chloride solution.
5. Add the sodium chloride soltuions into the silver nitrate solution quickly and stir the mixture.
6. Measure and record the highest temperature of the reacting mixture.
Tabulation of data:
initial temperature of silver nitrate solution, oC
initial temperature of sodium chloride solution, oC
Average temperature of both solutions, oC
highest temperature of the reacting mixture, oC
Heat of precipitation is the heat released / heat change when one mole of precipitate is formed from
their ions in aqueous solution.
ammonium nitrate
(NH4NO3)
Calcium chloride or
magnesium sulphate
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(b) Another student carried out four experiments to investigate the cleansing effect of soap and detergent
on oily stains in soft water and hard water respectively.
2. Preparation of soap
Procedure
1 pour 10 cm3 palm oil ( vegetable oil ) into a beaker
2 add 50 cm3 of 5.0 mol dm-3 NaOH / KOH solution
3 heat the mixture for (10 minutes)
SPM CHEMISTRY SEMINAR 2015
PHUAN
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1 1 A+
4
5
6
7
8
9
stir
stop heating, add 50 cm3 distilled water and solid NaCl
boil the mixture for 5 minutes
cool
filter, wash / rinse
dry ( press the residue between filter papers
Test
10 Place a small amount of the residue into a test tube add distilled water, shake it well.
produce a lot of lather ( very foamy)
Observation : white solid, slippery and produce a lot of lather ( very foamy).
Chemical equation:
3. You are given liquid soap, sample of hard water, sample of soft water and other materials.
Describe an experiment to investigate the effect of cleaning action of the soap in different types of
water. You description must include example of hard water and soft water, observation and conclusion.
[10 marks]
Sample answer:
1. hard water : sea water
2. soft water : distilled water
Materials: liquid soap, sea water, distilled water, pieces of cloth with oil stain.
Apparatus: beaker (suitable container), glass rod, measuring cylinder
Procedure:
1. pour (100 200) cm3 sea water into a beaker/ suitable container
2. Add (10 20 ) cm3 liquid soap into the beaker.
3. stir the mixture
4. Place a piece of cloth with oil stain into the beaker.
SPM CHEMISTRY SEMINAR 2015
PHUAN
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1 1 A+
Detergent
Sodium carboxylate
Preparation
Saponification
1. sulphonation
2. neutralization
1. alkylation
2. sulphonation
3. neutralization
Function
To add fragrance to both the detergent and
fabrics
To remove protein stains such as blood
To convert stains into colourless
substances
To prevent the dirt particles removed from
51
Example
Amylases, proteases, celluloses, lipases
Sodium perborate
Carboxymethylcellulose (CMC)
PREPARED BY: MS
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Fillers
Optical whitening
Builder
Food additive
Type
Preservatives
Function
To slow down/ prevent the
growth of microorganism,
therefore food can kept for
longer periods of time
Examples
Salts/sugar: draws the water out of the cells of
microorganism and retards the growth of
microorganism.
Vinegar: provides an acidic condition that inhibits the
growth of microorganism.
NaNO3 (Burger)
Benzoic acid / sodium benzoate: to slow down the
growth of microorganism.
Antioxidants
Flavorings
Stabilizers
Thickeners
Dyes
Medicine
Type
Function
Example
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Effect on health
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Analgesic
Antibiotics
Psychotherapeuti
c
Aspirin
Paracetamol
Codeine
Penicillin
(Penicillium
notatum)
Streptomycin
Amphetamines
Barbiturate /
tranquilizer
chlorpromazine
haloperidol,
clozapine
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