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AIEEE Home Practice Test - 4/2012


TIME : 3.00 Hrs

M.M. : 360

Read the following Instructions very carefully before you proceed.

The paper contains a total of 90 questions

Section - I : Chemistry, Section - II : Physics & Section - III : Mathematics.

Each question carries 4 Marks. - 1 will awarded for every wrong answer (Negative Marking).

For answering a question an ANSWER SHEET is provided separately.

Please follow the directions in the question paper. Please darken the entire circle that corresponds
to your answer for each question. Use only HB pencil to mark answer, and erase pencil marks
completely to make a change.

Do not scribble anything on the answer sheet.

Please Fill your Roll Number & Personal Information Properly in the space provided in the ANSWER SHEET.

Wrong way of filling


A B C D

A B C D

Right way of filling


A B C D

Please fill the following information


REGISTRATION NO.
NAME
Invigilators Signature

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SECTION - I (Chemistry)

30 4 = 120

1.

In a hydrogen like sample two different types of photons A and B are produced by electronic transition. Photon
B has its wavelength in infrared (long) region. If photon A has more energy than B, then the photon A may
belong to the region :
I.
Ultraviolet
II.
Visible
III.
Infrared (short)
The correct option is :
(A)
I
(B)
II
(C)
I, II
(D)
I, II, III

2.

Two glass bulbs A and B are connected by a very small tube (of negligible volume) having stop cock. Bulb A
has a volume of 100 cm3 and contains gas while bulb B is empty. On opening the stop cock, the pressure in A
fell down by 60%. The volume of bulb B must be :
(A)
200 mL
(B)
150 mL
(C)
250 mL
(D)
100 mL

3.

The direct conversion of A to B is difficult, hence it is carried out by the following shown path :
C

D
B

S A
C 50

S C
D 30

The entropy change for the process A


B is :
(A)
100
(B)
60
(C)

S B
D 20

100

(D)

60

1
1
NO(g)
N 2 (g) O2 (g)
2
2
If pressure is increased by reducing the volume of the container then :
(A)
Total pressure at equilibrium will change
(B)
Concentration of all the components at equilibrium will change
(C)
Concentration of all the components at equilibrium will remain same
(D)
Equilibrium will shift in the toward direction

4.

For the reaction :

5.

{X}

NaBH4

H2C

B2H6/H2O

{Y} . {X} and {Y} are :

HO
(A)

H2C

O (B)

OH, H2C

OH

OH, H2C

HC
OH
HO

(C)

6.

Both are H2C

OH

(D)

Which is of the following is a non-reducing sugar ?


(A)
Lactose
(B)
Fructose
(C)

Both are

OH

H2C

Cellobiose

(D)

Sucrose

7.

Which of the following is incorrect statement ?


(A)
Aspirin is both an analgesic and antipyretic.
(B)
Ampicillin is a natural antibiotic.
(C)
Sulphadiazine is a synthetic antibacterial.
(D)
Some disinfectants can be used as antiseptics at low concentration.

8.

How many times a solution of pH = 2 has higher acidic nature than the solution of pH = 6 ?
(A)
10000
(B)
12
(C)
1/10000
(D)
4

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9.

Which of the following electrolytes is least effective in causing of flocculation of ferric hydroxide sol ?
(A)
K 4 [Fe CN 6 ] (B)
K 2Cr2 O4
(C)
KBr
(D)
K 2SO 4

10.

Which of the following statement is incorrect ?


(A)
Geometrical isomers are diastereomers.
(B)
Enantiomers have same chemical and physical properties.
(C)
Conformers are inter convertable to each other.
(D)
3-methyl hexane shows optical isomerism.

11.

Which of the following compounds having highest and lowest melting point respectively ?
I.
CsF
II.
LiF
III.
HCl
IV.
HF
The correct option is :
(A)
II, III
(B)
I, IV
(C)
IV, III
(D)
II, I

12.

Which of the following statement is incorrect for the complex Na 3 Co NO2 6 ?


(A)
Diamagnetic nature
(B)
d2sp3 hybridisation
(C)
High spin complex
(D)
Primary valency of Co +3

13.

Which compound is prepared by the following reaction ?


Ni Vessel

Xe F2
(1 : 5 volume ratio)
673K, 56atm

XeF4

(D)

XeOF2

In which of the following sp hybridisation occurs ?


I.
SF4
II.
SF2
III.

OF2

IV.

XeF4

The correct option is :


(A)
I, IV

(A)
14.

15.

XeF2

(B)

XeF6

(C)

(B)

Which is not a polymer ?


(A)
Sucrose
(B)

II, III

(C)

Only I

(D)

All

Enzyme

(C)

Starch

(D)

Teflon

16.

An organic compound X on reduction gives compound Y which on reaction with chloroform and potassium
hydroxide forms Z. The compound Z on catalytic reduction gives N-methylaniline. The compound X is :
(A)
Nitrobenzene (B)
Nitromethane (C)
Methylamine (D)
Aniline

17.

Among the following compounds the decreasing order of reactivity towards electrophilic substitution is :

CH3

(A)
(C)
18.

19.

I
II > I > III > IV
IV > I > II > III

II

OCH3

CF3

III
(B)
(D)

IV
III > I > II > IV
I > II > III > IV

In HS, I, RNH2, NH3 order of proton accepting tendency will be :


(A)

I > NH3 > RNH2 > HS

(B)

NH3 > RNH2 > HS > I

(C)

RNH2 > NH3 > HS > I

(D)

HS > RNH2 > NH3 > I

A compound formed by elements X and Y crystallizes in a cubic structure in which the X atoms are at the
corners of a cube and the Y atoms are at the face-centres. The formula of the compound is :
(A)
XY3
(B)
X3Y
(C)
XY
(D)
XY2

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20.

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The radioactive isotope

60
27 Co

which is used in the treatment of cancer can be made by (n, p) reaction. For this

reaction the target nucleus is :


59
28 Ni

(A)

60
27 Co

(B)

60
28 Ni

(C)

(D)

60
27 Co

21.

A solid compound X on heating gives CO2 gas and a residue. The residue mixed with water from Y in water,
a clear solution, Z is obtained. On boiling Z compound X is reformed. The compound X is :
(A)
Ca(HCO3)2
(B)
CaCO3
(C)
Na2CO3
(D)
K2CO3

22.

Aniline in a set of reactions yielded a product (S).


NH2

NaNO2

HCl

CuCN

The structure of the product (S) would be :


(A)
C6H5CH2NH2
(C)
C6H5NHOH
23.

H2
Ni

(B)
(D)

HNO2

C6H5NH CH2CH3
C6H5CH2OH

Which one of the following compounds is most acidic ?


OH

(A)

ClCH2CH2OH (B)

OH

(C)

OH

(D)
H3 C

O2N

24.

The vapour pressure of two liquids P and Q are 80 and 60 torr, respectively. The total vapour pressure of
solution obtained by mixing 3 mole of P and 2 mol of Q would be :
(A)
140 torr
(B)
20 torr
(C)
68 torr
(D)
72 torr
CN

25.

+ CH3 MgBr
OCH3

H3O+

P. The product P in the above reaction is :

OH
CH

CO CH3

COCH3

COOH

CH3
CH3

(A)

(B)

OH

(C)

OCH3

(D)

26.

4.5 g of aluminium (atomic mass = 27 gm/mol) is deposited at cathode from Al3+ solution by a certain quantity
of electric charge. The volume of hydrogen produced at STP from H+ ions in solution by the same quantity of
electric charge will be :
(A)
22.4 L
(B)
44.8 L
(C)
5.6 L
(D)
11.2 L

27.

Which of the following statement is (are) correct ?


I.
A metal in its highest oxidation state acts as an oxidant
1
II.
In the reaction : F2 O 2
OF2 , oxygen is an oxidant
2
III.
The oxidation number of Ni in Ni(CO)4 is zero
IV.
Copper metal can be oxidised by Zn2+ ions
(A)
Only I
(B)
I and III both (C)
II and III both (D)

I, II, III, IV

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28.

Given that :
I2 2e
2I ; E 0 0.54V

Br2 2e
2Br ; E 0 1.09 V

Which of the following is correct ?

29.

(A)

I ions will be able to reduce bromide ions

(B)
(C)
(D)

Br ions will be able to reduce iodine


Iodine will be able to reduce bromine
Bromine will be able to reduce iodide ions

Potassium salt of succinic acid on electrolysis gives (X). (X) on reaction with :
(A)
PhH in presence of HF BF3 gives styrene
(B)
(C)
(D)

30.

CHCl3 in presence of peroxide gives 1, 1-dichloro cyclopropane


HOCl followed by reaction with NaOH gives expoxy ethane
All are correct

Which of the following complex will show geometrical as well as optical isomerism ?
(A)
[Pt(NH3)2Cl2] (B)
[Pt(NH3)2Cl4] (C)
[Pt(en)3]4+
(D)
[Pt(en)2Cl2]

SECTION - II (Physics)
31.

32.

In the figure a block of mass M is at rest on the floor. The acceleration with which should a
boy of mass m climb along the rope of negligible mass, so as to jut lift the block from the
floor is :
(A)

m 1 g

(B)

m 1 g

(C)

M
m

(D)

m
M

B
a
m

A particle is moving along a path of radius 3 m such a way that the distance traversed along the circumference
is given by s
(A)

33.

30 4 = 120

t 2 t3

2
3 . The acceleration of the particle when t = 2 sec. is :

1.3 m/s2

(B)

13 m/s2

(C)

5 m/s2

Power supplied to a particle of mass 2 kg varies with time as P

12 m/s2

(D)

3t 2
2 watt. Here t is in second and velocity of

particle at t = 0 is v = 0. The velocity of particle at time t = 2s will be:


(A)
34.

(B)

4 m/s

(C)

2 m/s

(D)

2 2 m/s

A steel ring of radius r and cross-sectional area A is fitted onto a wooden disc of radius R(R > r). If the Youngs
modulus of steel is Y, then the force with which the steel ring is expanded is:
(A)

35.

1 m/s

R
AY
r

(B)

AY

R r
r

(C)

Y R r
(D)
A r

The circuit shown is constructed of resistors each of which has a


maximum safe power rating of 0.4 W. The maximum potential
difference that can be applied between a and b without damaging to any
of the resistors is :
(A)

10 V

(B)

(C)

2 20 V

(D)

20 V

20 V

Yr
AR

a
R1 50
R2 100

R3 100

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36.

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Four equal charges Q are placed at the four corners of a square of side a. The work done in removing a charge
Q from the centre of the square to infinity is :
(A)

37.

(B)

2 Q2
4 0 a

2 Q2
0 a

(C)

Q2
2 0 a

(D)

Two large parallel plates having equal and opposite charge Q are placed very close to each other
and distance between the plates is d. Find the work done by external agent to increase the
separation between plates by d (area of plates is A)
(A)

38.

zero

Q2d
2 A 0

(B)

Q2d
2 A 0

(C)

3Q 2 d
2 A 0

(D)

Q2 d
A 0

A bar magnet has a magnetic moment 2.5 JT 1 is placed in a magnetic field of 0.2 T. The work done in turning
the magnet from parallel to antiparallel position relative to the field direction is :
(A)

39.

0.5 J

(B)

1J

(C)

1.5 J

(D)

0J

A particle moves on the X-axis according to the equation x A B sin t . The motion is simple harmonic with
amplitude :
(A)

40.

(B)

(C)

A+B

A2 B 2

(D)

A ray of light passes from vacuum into a medium of refractive index , the angle of incidence is found to be
twice the angle of refraction. Then the angle of incidence is :
(A)

41.

cos 1 / 2

(B)

2 cos 1 / 2

(C)

2 sin1

2 sin1 / 2

(D)

-particle has a binding energy 7 MeV per nucleon and binding energy of deuteron 1H2 is 1.2 MeV per nucleon.
In the reaction 1 H 2 1H 2
2 He 4 Q energy released Q is :
(A)

42.

4.6 MeV

(B)

18.4 MeV

(C)

20.6 MeV

(D)

23.2 MeV

An object is cooled from 75 C to 65 C in 2 minutes in a room at 30 C . The time taken to cool the same object
from 55 C to 45 C in the same room in minutes is :
(A)

43.

(B)

(C)

(D)

A rod length l slides down along an inclined plane and the ground as shown in the figure. At any instant the
velocity of end B is v, then the velocity of end A at the same instant will be :
(A)
(C)

V sin
sin

(B)

V cos (D)

V cos

cos

V cos

44.

Four spheres, each of mass m and radius r are placed with their centres on the four corners of a square of side
b. The moment of inertia of the system about any side of the square is :
(A)
(C)

4
5
8
5

mr 2 mb 2

(B)

mr 2 4mb 2

(D)

8
5
4
5

mr 2 2mb 2
mr 2 2mb 2

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45.

A large open tank has two holes in the wall. One is a square hole of side L at a depth y from the top and the
other is a circular hole of radius R at a depth 4y from the top. When the tank is completely filled with water, the
quantities of water flowing out per second from both the holes are the same. Then, R is equal to :
(A)

46.

47.

49.

51.

(C)

(D)

40 mg
h

(B)

mg
h

(C)

mg
2h

(D)

20 mg
h

L
2
m
h

The radii of two soap bubbles are R1 and R2 respectively. The ratio of masses of air in them will be :
(atmospheric pressure is P0 and surface tension is s)
R13
R23

(B)

R23
R13

(C)

4S

P R R3
1 1

P 4S R23

R2

(D)

The potentiometer wire shown in figure has length 100 cm and resistance
500 . Balanced length for a cell having emf 12V is found to be 40 cm.
Then R is :
(A)
4000

(B)

3000

(C)

(D)

1000

1500

4S

P R R3
2 2

P 4S R13

R1

EP = 120V

In LC circuit the maximum charge on the capacitor is Q0. Find the maximum value of current in the circuit.
(Capacitance = C, and inductance = L)
Q0
2 LC

(B)

Q0
LC

(C)

2Q0
LC

(D)

3Q0
2 LC

Two waves are represented Y1 a sin kx t and Y2 a sin kx t


. Then their resultant amplitude

3
is :
(A)
a
(B)
2a
(C)
3a
(D)
2a

If one mole monatomic gas is mixed with one mole of a diatomic gas, the value of for the mixture is :
(A)

52.

2 L

(A)

(A)
50.

(B)

A block of mass m initially at rest is dropped from a height h on a massless pan attached to
a massless spring of force constant k. The maximum compression in the spring is h/4, then
spring constant k is (Assume the block stick with pan after collision)

(A)

48.

1.40

(B)

1.50

(C)

1.53

(D)

3.07

There are two pipes each of length 2 m, one is closed at one end and other is open at both ends. The speed of
sound in air is 340 m/s. The frequency at which both can resonate is :
(A)
340 Hz
(B)
510 Hz
(C)
42.5 Hz
(D)
None of these

Paragraph for Q.53 - 54


A tank of base area 4 m2 is initially filled with water up to height 2m An object of
uniform cross-section 2m2 and height 1 m is now suspended by wire into the tank,
keeping distance between base of tank and that of object 1m. Density of the object is
2000 kg/m3. Take atmospheric pressure 105N/m2 ; g = 10 m/s2.

A 2m 2 1m
1m
4m 2

8
53.

54.

55.

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The downwards force exerted by the water on the top surface of the object is :
(A)
2.0 105 N
(B)
2.1 105 N
(C)
2.2 105 N
(D)

2.3 105 N

The tension in the wire is :


(A)
0.1 105 N
(B)

0.4 105 N

0.2 105 N

(C)

0.3 105 N

(D)

A metallic wire bent into a right abc moves with a uniform velocity v as shown in the figure. B is the strength
of uniform magnetic field perpendicular outward the plane of triangle. The net emf is and emf along ab is :
(A)
zero, zero
b
B
(B)
zero, Bv (bc) with b positive
(C)
zero, Bv (bc) with a positive
v
(D)
Bv (bc) with b positive, zero
a

56.

In a Youngs double slit experiment, light consisting of two wavelengths 7000 and 6000 is used to obtain
interference fringes. If the distance between the two slits is 1 mm and the distance between the plane of slits and
screen is 100 cm, what is the minimum distance from central maximum where bright fringes due to both the
wavelength coincide ?
(A)
0.54 cm
(B)
0.62 cm
(C)
0.42 cm
(D)
0.28 cm

57.

A resistance and inductance are connected in series across a voltage, V 400 2 sin 240 t volt and current is
found to be 4 sin 240t / 4 amp . Then the values of inductance and resistance are :
(A)

58.

(B)

0.5 H , 60

(C)

Gm 2 2 1
r
Gm
r

(B)

2 1

(D)

5
12

H , 100

(D)

None of these

Gm
r
2 2Gm
r

A radioactive material decays by simultaneous emission of two particles with respective half-lives 1620 years
and 810 years. The time (in years) after which
(A)

60.

(C)

Four particles each of mass m, are placed at the vertices of square and are moving along a circle of radius r
under the influence of mutual gravitational attraction. The speed of each particle will be :
(A)

59.

0.25 H , 80

1080

(B)

2430

1
4

of the material remains is:


(C)

3420

The supply current in the following ideal diode (D2) circuit is :


(A)

0.75 mA

(B)

1.25 mA

(C)

4 mA

(D)

0.5 mA

(D)

+15V

4860
12k

D1

10 k
5k
10 k

D2
5k

3k

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SECTION - III (Mathematics)

30 4 = 120

10

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* * * * Vidyamandir wishes you the very best for AIEEE-2012 * * * *

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