Set A

FIITJEE ALL INDIA iNTERNAL TEST SERIES
CHEMISTRY, MATHEMATICS & PHYSICS

SET A
APT - 1
CODE: 080086.1
Time Allotted: 3 Hours
Ai2TS - 4
Maximum Marks: 201
Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
You are not allowed to leave the E xamination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR sheet
before attempting the paper. Wrong CODE or no CODE will give wrong results.
CLASS - XII
A.
General Instructions
B.
Filling of OMR Sheet
C.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Sections.
Section-1 is Chemistry, Section-2 is Mathematics and Section-3 is Physics.
Each section has two parts: Part-A & Part-B
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment
No. and write in ink your Name, Test Centre and other details at the designated places.
OMR sheet contains alphabets, numerals & special characters for marking answers.
Marking Scheme For All Parts.
Part-A (01 06) contains 6 Multiple Choice Questions which have only one correct answer. Each
question carries +3 marks for correct answer and 1 mark for wrong answer.
Part-A (07 09) contains 3 Assertion-Reasoning (multiple choice questions) which have only one
correct answer. Each question carries +3 marks for correct answer and 1 mark for wrong answer.
Part-A (10 15) contains 2 Paragraphs. Based upon paragraph, 3 Multiple Choice Questions have
to be answered. Each question has only one correct answer and carries +4 marks for correct answer
and 1 mark for wrong answer.
Part-B (01 02) contains 2 Matrix Match Type question containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each
question carries +8 marks for all correct0020answer. For each correct row +2 marks will be awarded.
There may be one or more than one correct choice. No marks will be given for any wrong match in any
question. There is no negative marking.
Name of the Candidate : ____________________________________________

Batch : ___________________ Date of Examination : ____________________
Enrolment Number : _______________________________________________
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Website: www.fiitjee.com, Mail : aiits@fiitjee.com
2
AI2TS-4-(APT-1)-SET-A-CMP-XII
ALL INDIA iNTERNAL TEST SERIES
SECTION 1 (Chemistry)
PART A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1.
X g
Y g Z g
Equal moles of X, Y and Z gases are present in the above equilibrium which is established at 9 atm
o
and 100 C. What is the equilibrium constant Kp of the reaction?
(A)
6 atm
2.
Which of the following acid salt on Kolbes electrolysis produces ethylene(C 2H4)?
(A)
CH3CH2COONa
(B)
9 atm
(C)
3 atm
(D)
4.5 atm
CH 2COONa
(B)
CH 2COONa
CH 2CH 2COONa
CHCOONa
(C)
(D)
CH 2CH 2COONa
CHCOONa
3.
Which of the following is not obtained by heating hydrated borax, Na2B4O7.10H2O?
(A)
Na2B4O7(anhydrous)
4.
The strongest reducing agent out of the following is:
(A)
NH3
5.
Which of the following reaction is called calcination in metallurgy?
(B)
(B)
NaBO2
(C)
PH3
(C)
B2O3
AsH3
(D)
NaBO3
(D)
BiH3
(C)
ZnO C
Zn CO
2PbS 3O2
2PbO 2SO2
CuCO3 .Cu OH 2
2CuO CO2 H2O
(D)
FeO CO
Fe CO2
6.
Which of the following gases are produced when crystals of NaBr is added to concentrated H2SO4?
(A)
HBr and SO2
(A)
(B)
(B)
Br2 and SO2
(C)
HBr and H2S
(D)
Br2 and H2S
Space for rough work
FIITJEE
3
(Assertion-Reasoning Type)
ONLY ONE is correct. Examine the two statements carefully and decide if the Assertion (A) and the Reason (R)
are individually true and if so, whether the Reason (R) is the correct explanation for the given Assertion (A).
7.
Assertion(A):
Reason (R):
Assertion: Sodium phenoxide is more reactive than phenol towards electrophilic

substitution reaction which takes place in a polar solvent
Phenoxide ion contains less number of hydrogen atoms than that of phenol.
(A)
(B)
(C)
(D)
Assertion (A) is True, Reason (R) is true, Reason (R) is a correct explanation for Assertion (A).
tatement-1 is True, Reason (R) is true, Reason (R) is NOT a correct explanation for Assertion (A).
Assertion (A) is True, Reason (R) is False.
Assertion (A) is False, Reason (R) is True.
8.
Assertion(A):
Reason (R):
The solubility of Be(OH)2 in water increases by adding NH4Cl to its saturated

aqueous solution.
2+
Be ion reacts with NH3 to form Be(NH2)2 which drives the solubility equilibria
towards forward direction.
(A)
(B)
(C)
(D)
Assertion (A) is True, Reason (R) is true, Reason (R) is a correct explanation for Assertion (A)
Assertion (A) is True, Reason (R) is true, Reason (R) is NOT a correct explanation for Assertion (A)
9.
Assertion(A):
Reason (R):
(A)
(B)
(C)
(D)
Assertion (A) is True, Reason (R) is true, Reason (R) is a correct explanation for Assertion (A)
Assertion (A) is True, Reason (R) is true, Reason (R) is NOT a correct explanation for Assertion (A).
H2O is more acidic than H2S.

Presence of hydrogen bond is not observed in H2S
FIITJEE
4
(Comprehension Type)
This section contains 2 paragraphs. Based upon each paragraph 3 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Questions 10 to 12
Read the paragraph carefully and answer the following questions:
Y
C
P
(in mm)
A
B
X
V (in mL)
One mole of an ideal gas undergoes the above cyclic process (ACBA) through three paths. The pressure
and volume at the points A, B and C are given above with mm and mL units respectively.
10.
Along which of the following path/paths, the work done by the gas is zero?
(A)
(C)
AC
BA
11.
Which of the following path or paths involve(s) compression of the gas?
(A)
AC
12.
At which of the following point the temperature is maximum?
(A)
(B)
(D)
(B)
(B)
CB
(C)
(C)
CB
both C B and B A
BA
(D)
A C and B A
(D)
Both A and B

A black powder(A) when heated with NaCl and Conc. H2SO4 gives off a greenish yellow gas(B). The
gas (B) on passing through liquor ammonia liberates N 2 and on passing through boiling KOH yields
compounds one of which when heated with the black powder evolves oxygen gas.
13.
The black powder(A) is:
(A)
Pb3O4
14.
Which of the following is gas(B)?
(A)
Cl2
15.
Which compound on heating with (A) (which behaves as a catalyst), evolves oxygen gas?
(A)
KCl
(B)
(B)
(B)
MnO2
HCl
KClO3
(C)
Cr2O3
(D)
PbS
(C)
SO2
(D)
O2
(C)
K2CO3
(D)
K2C2O4
FIITJEE
5
PART B
(Matrix Match Type)
This section contains 2 Matrix Match questions. Each question has statements given in 2 columns. Statements in the
first column have to be matched with statements in the second column.
1.
Match the following
Column 1
Column 2
(A)
Al2O3.2H2O
(P)
Concentrated by froth flotation process
(B)
Cu2S
(Q)
Undergoes calcination
(C)
PbS
(R)
Undergoes roasting
(D)
PbCO3
(S)
Undergoes self-reduction
(T)
The metal is refined by electrolytic process
2.
Match the following
Column 1
Column 2
CHO
CHO
(A)
(P)
Fehlings solution test
(Q)
Tollens reagent test
(R)
Iodoform test
(S)
FeCl3 test
(T)
Lucas test
and
CHO
COCH 3
(B)
and
OH
OH
(C)
and
CHO
OH
(D)
CH
CH3
and
FIITJEE
6
SECTION 2 (Mathematics)
PART A
1.
Let P be any point on the plane lx my nz p and Q be a point on the line OP such that OP.
2
OQ = p . The locus of the point Q is
(A)
lx my nz p x y z
(B)
lx my nz p x y z
(C)
p lx my nz x y z
(D)
x y z p
2.
The four lines drawn from the vertices of any tetrahedron to the centroid of the opposite faces meet
in a point whose distance from each vertex is k times the distance from each vertex to the opposite
face, where k is
(A)
1/3
3.
P, Q, R, S are four coplanar points on the sides AB, BC, CD, DA of a skew quadrilateral. The
product
(B)
(C)
1/2
(D)
3/4
5/4
AP BQ CR DS
equals
.
.
.
PB QC RD SA
(A)
-2
(B)
(C)
4.
The plane lx my 0 is rotated about its line of intersection with the x O y plane through an angle
-1
(D)
. Then the equation of the plane is lx my nz 0 , where n is
l2 m2 cos
5.
If sinx 2 cos x 3, x 0, 2 ([.] denotes the greatest integer function), then x belongs to
(A)
5
,
4
6.
In a ABC, tan A tan B tan C = 9. For such triangles, if tan2 A tan2 B tan2 C then
(A)
3
9. 3 27
(B)
(B)
5
, 4
27
(C)
(C)
(C)
l2 m2 tan
(B)
l2 m2 sin
(A)
, 2
4
3
9. 3
(D)
(D)
(D)
None of these
4 , 2
27
FIITJEE
7
7.
Assertion(A):
Equation of the polar to the sphere x2 y2 z2 1 with respect to the point (1, 2, 3)
is x 2y 3z 1
Reason (R):
The point (1, 2, 3) lies outside the sphere x2 y2 z2 1
(A)
(B)
(C)
(D)
Assertion(A) is true, Reason (R) is true, Reason (R) is correct explanation of Assertion(A)
Assertion(A) is true, Reason (R) is true, Reason (R) is not correct explanation of Assertion(A)
Assertion(A) is true, Reason (R) is false
Assertion(A) is false, Reason (R) is true
8.
Assertion(A):
3 3 4
If A 2 3 4 , then adj (adj A) = A
0 1 1
Reason (R):
n1
adj adjA A
, A be n rowed non singular matrix
(A)
(B)
(C)
(D)
9.
Assertion(A):
If positive numbers a1,b1,c 1 are in AP, then product of roots of equation

2
101
x x 2b
101
101
Reason (R):
0 R has ve sign.
n
If a, b, c are in H.P, then
a c
2
n
n
AM HM
2bn an cn 0
2b101 a101 c101 0
(A)
(B)
(C)
(D)
FIITJEE
8
Suppose direction cosines of two lines are given by ul vm wn 0 and al2 bm2 cn2 0, where u,
v, w, a, b c are arbitrary constants and l, m, n are direction cosines of the lines.
On the basis of above information, answer the following questions:
10.
For u v w 1, both lines satisfies the relation
(A)
b c
(B)
l
l
c a 2c b c 0
m
m
(C)
a b
(D)
All of the above
11.
nn
a b
For u v w 1, If 1 2
, then
n
2b a b 0
l
l
2
(A)
m
2a c a 0
n
n
l12
l
m1m2
l1l2
b c
c a
(B)
b c
m1m2
l1l2
c a
b c
(C)
12.
For u v w = 1 and if lines are perpendicular, then
(A)
abc 0
(B)
ab bc ca 0
(C)
m1m2
l1l2
a b
c a
ab bc ca 3abc
(D)
(D)
m1m2
l1l2
c a
a b
ab bc ca abc
FIITJEE
9

If n positive integers taken at random and multiplied together, then the chance that the last digit of the
product would be on the basis of above information, answer the following questions:
13.
1, 3, 5, 7 or 9 is
(A)
2

5
14.
(B)
(B)
2 1
5
5 4
10
(D)
5 4
10
(C)
2

5
1

2
(D)
2

5
(D)
5 is
n
(A)
(C)
2 1
5
15.
1, 3, 7 or 9 is
n
(A)
1

2
5 4
10
(B)
2 1
5
(C)
10 8 5 4
n
10
FIITJEE
10
PART B
(Matrix Match Type)
1.
Match the following
Column 1
(A)
(B)
(C)
(D)
Column 2
If Acute and obtuse angle bisectors of the

planes 2x y 2z 3 0 and
3x 2y 6z 8 0 are represented by A and
O, then
If acute and obtuse angle bisectors of the planes
x 2y 2z 3 0 and 2x 3y 6z 8 0
are represented by A and O, then
The acute and obtuse angle bisectors of the
planes 2x y 2z 3 0 and
6x 2y 3z 8 0 are represented by A and
O, then
If distance of A from point (2, 3, 4) is
(P)
A : 32x 13y 23z 3 0
(Q)
O : x 5y 4z 45 0
(R)
A : 23x 13y 32z 45 0
(S)
O : 4x y 5z 45 0
(T)
A :13x 23y 32z 3 0
38 3
574
then A is
2.
Match the following
Column 1
Let f x max 1 sin x, 1,1 cos x ,x 0,2
Column 2
(P)
g f 1 1
(B)
1 x
x 1, 1 and
1 x
3x x3
g x
, then
2
1 3x
(Q)
f g 0 0
(C)
Let f x 1 x 2 and g x x x 2 , then
(R)
f g 0
(D)
f x x 1 and g x x , then
(S)
g f 0
(T)
gf
(A)
and g x max 1, x 1 , x R, then

Let f x In
1
1
e 1
. 1
e 1
FIITJEE
11
SECTION 3 (Physics)
PART A
1.
A cylindrical vessel contains a liquid of density up to height h. The

liquid is closed by a piston of mass m and area of cross section A.
There is a small hole at the bottom of the vessel. The speed v with
which the liquid comes out of the hole is
(A)
2gh
(B)
2 gh
2gh
(D)
(A)
mg
A
If block A is moving horizontally with velocity vA then find the

velocity of block B at the instant as shown in the figure
hv A
2 x 2 h2
xv A
(B)
(C)
mg
mg
2 gh
A
(C)
2.
m,A
x 2 h2
xv A
2 x 2 h2
(D)
vA
B
hv A
2
x h
FIITJEE
12
3.
(A)
(B)
(C)
(D)
The given figure shows an inductor and resistance fixed

on a conducting wire. A movable conducting wire PQ
starts moving on the fixed rails from t = 0 with constant
velocity 1m/s. The work done by the external force on the
wire PQ in 2 seconds is
16J
32J
48J
64J
L=2H
B=2T
R=2
v=1m/s
=2m
4.
There are two radioactive nuclei A and B. A is an alpha emitter and B is a beta emitter.
If their disintegration constants are in the ratio 1 : 2, then the ratio of number of atoms of A and B at
any time t so that probabilities of getting alpha and beta particles are same at that instant
(A)
2:1
5.
A gas containing hydrogen like ions with atomic no Z, emits photons in transition n + 2 n, where n
= Z. There photons fall on a metallic plate and eject electrons having minimum de-Broglie
wavelength of 5. Find the value of Z if the work function of metal is 4.2 eV
(A)
6.
The wavelength of the characteristic X-ray K line emitted by a hydrogen-like element is

0.32 . The wavelength of K line emitted by the same element will be
(A)
0.24
(B)
(B)
(B)
1:2
0.27
(C)
(C)
(C)
0.32
(D)
(D)
(D)
0.48
FIITJEE
13
7.
Assertion(A):
Reason (R):
If the accelerating potential in an X-ray tube is increased, the wavelengths of the

characteristic X-rays do not change.
When an electron beam strikes the target in an X-ray tube, part of the kinetic energy
is converted into X-ray energy.
(A)
(B)
(C)
(D)
Assertion (A) is true, Reason (R) is true, Reason (R) is a correct explanation for Assertion (A)
Assertion (A) is true, Reason (R) is true, Reason (R) is not a correct explanation for Assertion (A).
Assertion (A) is true, Reason (R) is false.
Assertion (A) is false, Reason (R) is true.
8.
Assertion(A):
Reason (R):
Minimum deviation for a given prism does not depend on the refractive index of the
prism.
Deviation by a prism is given by = i1 i2 A and does not have the term .
(A)
(B)
(C)
(D)
9.
Assertion(A):
Reason (R):
(A)
(B)
(C)
(D)
If a proton and an electron, initially at rest, are accelerated through the same
potential difference, their final kinetic energies will be equal.
Mass of proton is about 1840 times the mass of electron.
FIITJEE
14
U
For a certain thermodynamic cycle undergone by an ideal gas the variation

of internal energy (U) with pressure (P) is as shown in the figure.
450
P
10.
Here the process A B must be
(A)
Isothermal
11.
The V-T diagram for the process will look as
(B)
Isochoric
(C)
(D)
Adiabatic
None of these
V
B
(A)
(B)
A
C
C
T
V
A
(C)
(D)
C
C
12.
The net work done in the cycle will be
(A)
Positive
(B)
Negative
(C)
Zero
(D)
Data insufficient
FIITJEE
15

We have two radioactive nuclei A and B. Both convert into a stable nucleus C. Nucleus A converts into C
after emitting two -particles and three -particles. Nucleus B converts into C after emitting one -particle
and five -particles. A time t = 0, nuclei of A are 4 N0 and that of B are N0. Half-life of A (into the
conversion of C) is 1 min and that of B is 2 min. Initially number of nuclei of C are zero.
13.
If atomic numbers and mass numbers of A and B are Z 1, Z2, A1 and A2 respectively. Then
(A)
(C)
Z1 Z2 = 6
both (a) and (b) are correct
14.
What are number of nuclei of C, when number of nuclei of A and B are equal?
(A)
2 N0
15.
At what time rate of disintegrations of A and B are equal.
(A)
4 min
(B)
(B)
3 N0
6 min
(B)
(D)
(C)
(C)
A1 A2 = 4
both (a) and (b) are wrong
9No
2
8 min
(D)
5No
2
(D)
2 min
FIITJEE
16
PART B
(Matrix Match Type)
1.
Match the following
Y = youngs
modulus of rod
,m
A = area of
crossection of rod
Column 1
(A)
Stress at a distance x from lower end
(P)
(B)
Speed of longitudinal wave in rod
(Q)
Speed of transverse wave in rod at a

distance x from lower end
(R)
If elongation of rod is l then elastic pot.

energy in the rod will be
(S)
(C)
(D)
2.
Column 2
1 YA
2
F mgx
m
F
mgx
YA
m
In the production of X-rays by a Coolidge tube, the changes which can be made in its operation are
listed in Column-I. The possible effects of such changes are listed in Column-II.
Column 1
Column 2
(A)
Change in the current flowing through the

filament (emitter or cathode)
(P)
Harder or softer X-rays are produced
(B)
Change in the potential difference applied

across the tube
(Q)
Wavelengths of the characteristic X-rays

change
(C)
Change in the metal used as the target
(R)
Intensity of the X-rays change
(D)
Rotating the tube from a horizontal position

to a vertical position
(S)
Cut of wavelengths changes
(T)
No Change
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FIITJEE ALL INDIA iNTERNAL TEST SERIES

CHEMISTRY, MATHEMATICS & PHYSICS

Time Allotted: 3 Hours

Filling of OMR Sheet

Marking Scheme For All Parts.

Name of the Candidate : ____________________________________________

ALL INDIA iNTERNAL TEST SERIES

Which of the following is not obtained by heating hydrated borax, Na2B4O7.10H2O?

The strongest reducing agent out of the following is:

Which of the following reaction is called calcination in metallurgy?

HBr and SO2

Br2 and SO2

HBr and H2S

Br2 and H2S

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

Assertion: Sodium phenoxide is more reactive than phenol towards electrophilic

The solubility of Be(OH)2 in water increases by adding NH4Cl to its saturated

H2O is more acidic than H2S.

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

Which of the following path or paths involve(s) compression of the gas?

At which of the following point the temperature is maximum?

Paragraph for Questions 13 to 15

The black powder(A) is:

Which of the following is gas(B)?

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

Match the following

Concentrated by froth flotation process

The metal is refined by electrolytic process

Match the following

Fehlings solution test

Tollens reagent test

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

. Then the equation of the plane is lx my nz 0 , where n is

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

The point (1, 2, 3) lies outside the sphere x2 y2 z2 1

, A be n rowed non singular matrix

If positive numbers a1,b1,c 1 are in AP, then product of roots of equation

If a, b, c are in H.P, then

ALL INDIA iNTERNAL TEST SERIES

For u v w 1, both lines satisfies the relation

All of the above

For u v w = 1 and if lines are perpendicular, then

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

Paragraph for Questions 13 to 15

ALL INDIA iNTERNAL TEST SERIES

Match the following

If Acute and obtuse angle bisectors of the

A : 32x 13y 23z 3 0

A : 23x 13y 32z 45 0

A :13x 23y 32z 3 0

Match the following

Let f x max 1 sin x, 1,1 cos x ,x 0,2

Let f x 1 x 2 and g x x x 2 , then

and g x max 1, x 1 , x R, then

Space for rough work

ALL INDIA iNTERNAL TEST SERIES

A cylindrical vessel contains a liquid of density up to height h. The