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Introduction
2
2.1
Experimental
Sample
Fig.1
2.2
No.3
XU Si-yu et al.
Cp =
( As Ab )
ms
(1)
where As and Ab are the heat flows of the sample and blank,
respectively, ms is the amount of the sample, and is the
heating rate.
517
/(Kmin1)
T0/K
422.6
427.5
2.5
5.0
Hd/(Jg1)
1709
1834
Tp/K
492.0
498.6
7.5
432.4
487.4
502.6
1939
10.0
435.6
490.9
505.3
1920
12.5
439.4
493.3
507.6
1942
15.0
442.3
494.6
510.4
1782
Table 2
Method
/(Kmin1)
Generalintegral
2.5
5
7.5
Ea/(kJmol1 lg(A/s1)
)
161.5
15.4
166.5
16.0
0.9864
0.9854
0.3613
0.3887
0.3940
165.4
15.9
0.9852
10
171.4
16.6
0.9845
0.426
12.5
176.2
17.1
0.9847
0.4079
15
0.3406
175.5
17.1
0.9872
MacCallum-
2.5
161.8
15.4
0.9876
0.0679
Tanner
167.0
16.0
0.9867
0.0730
7.5
0.0740
atava-estk
Agrawal
Fig.2
Te/K
474.8
483.0
165.9
15.9
0.9865
10
172.1
16.6
0.9859
0.0775
12.5
176.9
17.2
0.9860
0.0766
15
0.0640
176.2
17.1
0.9884
2.5
161.0
15.4
0.9876
0.0679
165.8
16.0
0.9867
0.0730
7.5
0.0740
164.9
15.8
0.9865
10
170.6
16.5
0.9859
0.0775
12.5
175.2
17.0
0.9860
0.0766
15
0.0640
194.5
17.0
0.9884
2.5
161.5
15.4
0.9864
0.3613
166.5
16.0
0.9854
0.3887
7.5
0.3940
165.4
15.9
0.9852
10
171.4
16.6
0.9845
0.4126
12.5
176.2
17.1
0.9847
0.4079
15
175.5
17.1
0.9872
0.3406
Mean
170.2
16.3
0.9862
0.2287
Flynn-Wall-Ozawa
178.2(EpO)
148.6(EeO)
Kissinger
179.5
Mechamism function
0.9987(EpO) 0.0010
0.9986(EeO)
17.7
0.9986
0.0056
f()(4/3)(1)[ln(1)]1/4
Fig.3
518
Vol.28
3.3
Thermal Ignition Temperature(TTIT) and
Critical Temperature of Thermal Explosion(Tb)
The thermal ignition temperature(Tbe0 or TTIT) was obtained by substituting EeO and Te0 into Eq.(4)[9,10], and the critical temperatures of thermal explosion(Tbp0 or Tb) was obtained
by substituting EpO and Tp0 into the equation. The values of TTIT
and Tb are 472.1 and 492.8 K, respectively. The values of Tb for
NGEC show that the threshold for ignition and thermal explosion is larger.
EO EO 2 4 EO RT0
(4)
2R
where EO is the value of E obtained by Ozawas method and R
is the gas constant.
Tb =
Fig.4
3.6
Adiabatic Time-to-explosion(tTlad)
S
k T
A = B exp
h
R
E
A exp
RT
S
H
kBT
exp
exp
=
h
R
RT
(5)
(6)
G = H TS
(7)
where kB is the Boltzman constant and h is the Plank constant.
3.5
dT
E
= QA exp
f ( )
dt
RT
t
Tbp0 C p exp ( E RT )
dT
= dt =
0
Te 0
QAf ( )
Cp
tTlad
Tbp0
Cp
Te 0
dT
(9)
(10)
(11)
Conclusions
No.3
XU Si-yu et al.
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