Beruflich Dokumente
Kultur Dokumente
Version number:
Supersedes date:
6.00
26/07/2013
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Automotive.
1.3. Details of the supplier of the substance or mixture
3M United Kingdom PLC, 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT.
Address:
Telephone: +44 (0)1344 858 000
tox.uk@mmm.com
E Mail:
www.3M.com/uk
Website:
1.4. Emergency telephone number
+44 (0)1344 858 000
Ingredient
Naphtha (petroleum), hydrotreated light
Toluene
HAZARD STATEMENTS:
H225
H315
H336
H373
CAS Nbr
64742-49-0
108-88-3
% by Wt
15 - 40
<3
nervous system
PRECAUTIONARY STATEMENTS
Prevention:
P210A
P260
P262
Response:
P331
P301 + P310
P370 + P378G
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
Do not breathe dust/fume/gas/mist/vapours/spray.
Do not get in eyes, on skin, or on clothing.
Do NOT induce vomiting.
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.
In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or
carbon dioxide to extinguish.
Symbol(s)
Highly
Flammable
Irritant
Contains:
No ingredients are assigned to the label.
Risk phrases
R11
R38
R67
Safety phrases
S16
S23C
S51
S24
S62
Highly flammable.
Irritating to skin.
Vapours may cause drowsiness and dizziness.
Keep away from sources of ignition - No Smoking.
Do not breathe vapour or spray.
Use only in well ventilated areas.
Avoid contact with skin.
If swallowed, do not induce vomiting: Seek medical advice immediately and show this container or
label.
CAS Nbr
1317-65-3
64742-49-0
EU Inventory % by Wt
EINECS 215- 15 - 40
279-6
EINECS 265- 15 - 40
151-9
Classification
Xn:R65 - Nota 4,P (EU)
F:R11 (Vendor)
Xi:R38; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P
(CLP)
Flam. Liq. 2, H225; Skin Irrit. 2,
H315; STOT SE 3, H336 (Self
Classified)
Asphalt, oxidized
64742-93-4
EINECS 265196-4
EINECS 265-
15 - 40
3- 7
__________________________________________________________________________________________
Page: 3 of 19
199-0
R10 (Vendor)
Xi:R38; R67 (Self Classified)
Asp. Tox. 1, H304 - Nota P
(CLP)
Flam. Liq. 3, H226 (Vendor)
Skin Irrit. 2, H315; STOT SE 3,
H336 (Self Classified)
Methanol
68953-58-2
EINECS 273219-4
25038-32-8
108-88-3
<3
EINECS 203- < 3
625-9
67-56-1
1- 5
Repr.Cat.3:R63; F:R11;
Xn:R48/20; Xn:R65; Xi:R38;
R67 - Nota 4 (EU)
Flam. Liq. 2, H225; Asp. Tox. 1,
H304; Skin Irrit. 2, H315; Repr.
2, H361d; STOT SE 3, H336;
STOT RE 1, H372 (CLP)
F:R11; T:R23-24-25-39/23;
T:R39/24; T:R39/25 (EU)
Flam. Liq. 2, H225; Acute Tox.
3, H331; Acute Tox. 3, H311;
Acute Tox. 3, H301; STOT SE
1, H370 (CLP)
Lecithins
8002-43-5
__________________________________________________________________________________________
Page: 4 of 19
4.3. Indication of any immediate medical attention and special treatment required
This product contains methanol. Methanol poisoning can cause metabolic acidosis, blindness, and death. Onset of signs or
symptoms may be delayed for 18 to 24 hours. If methanol poisoning is confirmed, intravenous (IV) administration of ethanol
should be considered. Additional pharmacologic and supportive care should be based on the treating physicians judgement.
CAS Nbr
108-88-3
Limestone
1317-65-3
Methanol
67-56-1
Agency
Health and
Safety Comm.
(UK)
Health and
Safety Comm.
(UK)
Health and
Safety Comm.
(UK)
Limit type
TWA: 191 mg/m (50 ppm);
STEL: 384 mg/m (100 ppm)
TWA(as inhalable dust):10
mg/m3;TWA(as respirable
dust):4
mg/m3;TWA(Inhalable):10
mg/m3;TWA(respirable):4
mg/m3
TWA:266 mg/m3(200
ppm);STEL:333 mg/m3(250
ppm)
Additional comments
Skin Notation
Skin Notation
Gloves made from the following material(s) are recommended: Polymer laminate
Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective
clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of
a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator
type(s) to reduce inhalation exposure:
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
Half facepiece or full facepiece supplied-air respirator
For questions about suitability for a specific application, consult with your respirator manufacturer.
445 g/l
44.46 %
__________________________________________________________________________________________
Page: 7 of 19
Condition
Not specified.
Not specified.
Not specified.
Not specified.
Not specified.
Not specified.
Not specified.
Route
Dermal
InhalationVapor(4 hr)
Ingestion
Dermal
InhalationVapor (4
hours)
Ingestion
Dermal
Ingestion
Dermal
InhalationDust/Mist
(4 hours)
Ingestion
Dermal
InhalationVapor (4
hours)
Ingestion
Dermal
Species
Value
No data available; calculated ATE >5,000 mg/kg
No data available; calculated ATE >50 mg/l
Rabbit
Rat
Rat
Rabbit
Rat
Rat
Rat
Rat
Rabbit
Rat
Rat
InhalationDust/Mist
(4 hours)
Ingestion
Rat
Rat
Rat
Rat
Toluene
Styrene-isoprene copolymer
Dermal
InhalationVapor (4
hours)
Ingestion
Dermal
Styrene-isoprene copolymer
Ingestion
Rat
Not
available
Not
available
Methanol
Methanol
Dermal
InhalationVapor
Ingestion
Methanol
Species
Rabbit
Human
Value
Irritant
Minimal irritation
__________________________________________________________________________________________
Page: 9 of 19
Limestone
Solvent naphtha (petroleum), light aromatic
Quaternary ammonium compounds, bis(hydrogenated tallow alkyl)dimethyl, salts
with bentonite
Toluene
Styrene-isoprene copolymer
Methanol
Rabbit
Rabbit
Rat
No significant irritation
Irritant
No significant irritation
Rabbit
Rabbit
Irritant
No significant irritation
Mild irritant
Species
Rabbit
Human
Rabbit
Rabbit
Rabbit
Value
Mild irritant
Mild irritant
No significant irritation
Mild irritant
No significant irritation
Rabbit
Moderate irritant
No significant irritation
Moderate irritant
Rabbit
Skin Sensitisation
Name
Naphtha (petroleum), hydrotreated light
Species
Guinea
pig
Guinea
pig
Guinea
pig
Guinea
pig
Value
Not sensitizing
Not sensitizing
Not sensitizing
Not sensitizing
Not sensitizing
Photosensitisation
Name
Asphalt, oxidized
Species
Human
Value
Some positive data exist, but the data are not
sufficient for classification
Species
Value
Name
Naphtha (petroleum), hydrotreated light
Asphalt, oxidized
Asphalt, oxidized
Route
In Vitro
In vivo
In Vitro
Toluene
Toluene
Methanol
In Vitro
In vivo
In Vitro
Methanol
In vivo
Value
Not mutagenic
Not mutagenic
Some positive data exist, but the data are not
sufficient for classification
Not mutagenic
Not mutagenic
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Respiratory Sensitisation
Name
Carcinogenicity
Name
Naphtha (petroleum), hydrotreated light
Route
Inhalation
Species
Mouse
Asphalt, oxidized
Not
specified.
Inhalation
Human
and
animal
Mouse
Toluene
Dermal
Mouse
Value
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
sufficient for classification
Some positive data exist, but the data are not
__________________________________________________________________________________________
Page: 10 of 19
Toluene
Ingestion
Rat
Toluene
Inhalation
Mouse
Methanol
Inhalation
Multiple
animal
species
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Species
Test result
Limestone
Ingestion
Rat
NOAEL 625
mg/kg/day
Inhalation
Rat
Inhalation
Rat
Inhalation
Rat
Toluene
Inhalation
Toluene
Inhalation
Toluene
Ingestion
NOAEL
1,500 ppm
NOAEL
1,500 ppm
NOAEL 500
ppm
Toluene
Inhalation
Toxic to development
Human
Methanol
Ingestion
Rat
Methanol
Ingestion
Methanol
Inhalation
Toxic to development
Mouse
Exposure
Duration
premating &
during
gestation
2 generation
2 generation
2 generation
Human
NOAEL Not
available
occupational
exposure
Rat
NOAEL 2.3
mg/l
1 generation
Rat
LOAEL 520
mg/kg/day
NOAEL Not
available
NOAEL
1,600
mg/kg/day
LOAEL
4,000
mg/kg/day
NOAEL 1.3
mg/l
during
gestation
poisoning
and/or abuse
21 days
Test result
Exposure
Duration
Mouse
during
organogenesis
during
organogenesis
Target Organ(s)
Specific Target Organ Toxicity - single exposure
Name
Route
Target Organ(s)
Value
Naphtha (petroleum),
hydrotreated light
Naphtha (petroleum),
hydrotreated light
Inhalation
Inhalation
central nervous
system depression
respiratory irritation
Limestone
Inhalation
respiratory system
Solvent naphtha
(petroleum), light aromatic
Solvent naphtha
(petroleum), light aromatic
Inhalation
central nervous
system depression
respiratory irritation
Solvent naphtha
(petroleum), light aromatic
Toluene
Ingestion
Toluene
Inhalation
Inhalation
Inhalation
central nervous
system depression
central nervous
system depression
respiratory irritation
Species
NOAEL Not
available
NOAEL Not
available
Rat
Human
Human
NOAEL
0.812 mg/l
NOAEL Not
available
NOAEL Not
available
90 minutes
NOAEL Not
available
NOAEL Not
available
NOAEL Not
available
__________________________________________________________________________________________
Page: 11 of 19
Toluene
Inhalation
immune system
Toluene
Ingestion
Methanol
Inhalation
central nervous
system depression
blindness
Methanol
Inhalation
Methanol
Inhalation
central nervous
system depression
respiratory irritation
Methanol
Ingestion
Methanol
Ingestion
classification
Some positive data exist, but the
data are not sufficient for
classification
May cause drowsiness or
dizziness
Causes damage to organs
Mouse
NOAEL
0.004 mg/l
3 hours
Human
NOAEL Not
available
NOAEL Not
available
NOAEL Not
available
NOAEL Not
available
poisoning
and/or abuse
occupational
exposure
not available
NOAEL Not
available
NOAEL Not
available
poisoning
and/or abuse
poisoning
and/or abuse
Human
Human
blindness
central nervous
system depression
Human
Rat
Human
6 hours
Route
Target Organ(s)
Value
Species
Test result
Asphalt, oxidized
Inhalation
respiratory system
Human
NOAEL Not
available
Limestone
Inhalation
respiratory system
Human
NOAEL Not
available
occupational
exposure
Toluene
Inhalation
Human
NOAEL Not
available
poisoning
and/or abuse
Toluene
Inhalation
auditory system |
nervous system |
eyes | olfactory
system
respiratory system
Exposure
Duration
occupational
exposure
Rat
LOAEL 2.3
mg/l
15 months
Toluene
Inhalation
Rat
NOAEL 11.3
mg/l
15 weeks
Toluene
Inhalation
endocrine system
Rat
NOAEL 1.1
mg/l
4 weeks
Toluene
Inhalation
immune system
Mouse
NOAEL Not
available
20 days
Toluene
Inhalation
Mouse
NOAEL 1.1
mg/l
8 weeks
Toluene
Inhalation
Human
NOAEL Not
available
occupational
exposure
Toluene
Ingestion
hematopoietic
system | vascular
system
nervous system
Rat
NOAEL 625
mg/kg/day
13 weeks
Toluene
Ingestion
heart
Rat
Ingestion
Toluene
Ingestion
hematopoietic
system
NOAEL
2,500
mg/kg/day
NOAEL
2,500
mg/kg/day
NOAEL 600
mg/kg/day
13 weeks
Toluene
Toluene
Ingestion
endocrine system
Mouse
NOAEL 105
mg/kg/day
28 days
Toluene
Ingestion
immune system
Mouse
NOAEL 105
mg/kg/day
4 weeks
Methanol
Inhalation
liver
Rat
NOAEL 6.55
4 weeks
Multiple
animal
species
Mouse
13 weeks
14 days
__________________________________________________________________________________________
Page: 12 of 19
Methanol
Inhalation
respiratory system
Rat
Methanol
Ingestion
liver | nervous
system
Rat
mg/l
NOAEL 13.1
mg/l
NOAEL
2,500
mg/kg/day
6 weeks
90 days
Aspiration Hazard
Name
Naphtha (petroleum), hydrotreated light
Solvent naphtha (petroleum), light aromatic
Toluene
Value
Aspiration hazard
Aspiration hazard
Aspiration hazard
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
CAS Nbr
8002-43-5
Styreneisoprene
copolymer
25038-32-8
Solvent
naphtha
(petroleum),
light aromatic
Limestone
64742-95-6
Limestone
Naphtha
(petroleum),
hydrotreated
light
Toluene
Toluene
Toluene
Toluene
1317-65-3
64742-49-0
1317-65-3
108-88-3
108-88-3
108-88-3
108-88-3
Quaternary
68953-58-2
ammonium
compounds,
bis(hydrogenat
Organism
Type
Exposure
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Experimental 96 hours
Western
Mosquitofish
Rainbow trout Experimental
Data not
available or
insufficient for
classification
Coho Salmon Experimental
Water flea
Experimental
Green Algae
Experimental
Sheepshead
Experimental
Minnow
Zebra Fish
Analogous
Compound
LC50
>100 mg/l
21 days
NOEC
>100 mg/l
96 hours
48 hours
72 hours
28 days
LC50
EC50
EC50
NOEC
5.5 mg/l
3.78 mg/l
12.5 mg/l
3.2 mg/l
96 hours
LC50
>100 mg/l
__________________________________________________________________________________________
Page: 13 of 19
ed tallow
alkyl)dimethyl,
salts with
bentonite
Quaternary
68953-58-2
ammonium
compounds,
bis(hydrogenat
ed tallow
alkyl)dimethyl,
salts with
bentonite
Quaternary
68953-58-2
ammonium
compounds,
bis(hydrogenat
ed tallow
alkyl)dimethyl,
salts with
bentonite
Asphalt,
64742-93-4
oxidized
Methanol
67-56-1
Methanol
Methanol
67-56-1
67-56-1
Methanol
67-56-1
Water flea
Analogous
Compound
48 hours
EC50
>100 mg/l
Green algae
Analogous
Compound
72 hours
EC50
>100 mg/l
EC50
16.9 mg/l
EC50
LC50
22,200 mg/l
22,300 mg/l
NOEC
9.96 mg/l
Data not
available or
insufficient for
classification
Algae or other Experimental 96 hours
aquatic plants
Water flea
Experimental 48 hours
Fathead
Experimental 96 hours
minnow
Algae or other Experimental 96 hours
aquatic plants
CAS Nbr
8002-43-5
Styreneisoprene
copolymer
25038-32-8
Solvent
naphtha
(petroleum),
light aromatic
Limestone
64742-95-6
Naphtha
(petroleum),
hydrotreated
light
64742-49-0
1317-65-3
Test type
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Duration
N/A
Study Type
N/A
Test result
N/A
Protocol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
__________________________________________________________________________________________
Page: 14 of 19
Toluene
108-88-3
Toluene
108-88-3
Quaternary
68953-58-2
ammonium
compounds,
bis(hydrogenat
ed tallow
alkyl)dimethyl,
salts with
bentonite
Asphalt,
64742-93-4
oxidized
Methanol
67-56-1
Experimental
Photolysis
Experimental 14 days
Biodegradation
Data not
N/A
available or
insufficient for
classification
Other methods
N/A
N/A
Data not
N/A
available or
insufficient for
classification
Experimental 14 days
Biodegradation
N/A
N/A
N/A
BOD
92 % weight
CAS Nbr
8002-43-5
Styreneisoprene
copolymer
25038-32-8
Solvent
naphtha
(petroleum),
light aromatic
Limestone
64742-95-6
Naphtha
(petroleum),
hydrotreated
light
Toluene
64742-49-0
1317-65-3
108-88-3
Quaternary
68953-58-2
ammonium
compounds,
bis(hydrogenat
ed tallow
alkyl)dimethyl,
salts with
bentonite
Asphalt,
64742-93-4
oxidized
Test type
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Data not
available or
insufficient for
classification
Experimental
Bioconcentrati
on
Data not
available or
insufficient for
classification
Duration
N/A
Study Type
N/A
Test result
N/A
Protocol
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
Log Kow
2.73
Other methods
N/A
N/A
N/A
N/A
Data not
available or
N/A
N/A
N/A
N/A
__________________________________________________________________________________________
Page: 15 of 19
Methanol
67-56-1
insufficient for
classification
Experimental 3 days
BCF-Carp
Bioaccumulati 1
on factor
Other methods
CAS Nbr
64742-93-4
108-88-3
Classification
Grp. 2A: Probable
human carc.
Gr. 3: Not classifiable
Regulation
International Agency
for Research on Cancer
International Agency
for Research on Cancer
__________________________________________________________________________________________
Page: 16 of 19
__________________________________________________________________________________________
Page: 19 of 19