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LABORATORY WORKBOOK
0 INTRODUCTION
Knowledge of petrophysical and hydrodynamic properties of reservoir
rocks and basic reservoir fluid properties are of fundamental importance
to a petroleum engineer. Lab analysis conducted on rock and fluid
samples and well logging are the two major sources of information when
it comes to reservoir rock and fluid properties. While lab analysis is a
direct way to measure such properties, well logging is generally
considered as an indirect technique to gather information on the reservoir
rock and fluid properties. Presented in this unit (Petroleum Engineering
Lab) are some details on a number of simple but effective methods used
to analysis rock and fluid properties and review the nature and quality of
the information that can be obtained from them.
The drill string must be pulled out of the hole to replace the
normal bit by core bit and core barrel.
permeabilities).
Measurements
of
electrical
and
acoustic
0.4 References
1 POROSITY
1.1 Definitions
From the viewpoint of petroleum engineers, the two most important
properties of a reservoir rock are porosity and permeability. Porosity is a
measure of storage capacity of a reservoir. It is defined as the ratio of the
pore volume to bulk volume, and is may be expressed as either
percentage or a fraction. In equation form:
Pore Volume
Total Bulk Volume Volume Occupied by Solids
1-
( fraction)
( fraction )
12
Figure 1-1 Cubic packing (a), rhombohedral (b), cubic packing with
two grain sizes
For a uniform rock grain size, porosity is independent of the size of the
grains. A maximum theoretical porosity of 48% is achieved with cubic
packing of spherical grains, as shown in Figure
1 -1a. Rhombohedral
2 1 e
C f ( P2 P1 )
13
Cf
1 dV
V dP
14
Core analysis
Well testing
Where:
PR: Reference cell pressure,
Pe: Equilibrium pressure,
VR: Reference cell volume,
Vp: Pore volume
15
The reason for using helium during the experiment over other gases is
that helium has tiny molecules and combined with its high diffusivity can
penetrate even the smallest pores of the sample easily and quickly.
Helium is also non-toxic and non-reactive with the sample, so it is
considered non-damaging to the sample during the measurements.
The second method to measure the samples pore volume is using a
saturation technique. The weight of a dry sample is measured first and
then it is immersed in brine solution with a known salinity value in a
container which could be effectively vacuumed. The salinity of the brine
needs to be known as it is required to calculate its density. After every 24
hours the sample needs to be removed from the vacuum container and
weighed. The weight of the sample would keep increasing until it
becomes constant and does not change anymore by keeping it immersed
in brine. The difference between the weight of the dry and the fully brinesaturated sample is equal to the weight of the water which has gone into
the sample occupying the interconnected pores. Knowing the density of
the brine the volume of the brine present inside the sample can be
calculated which would be equal to the sample pore volume. The porosity
measurement
using
the
saturation
technique
is
extremely
time-
1.7 Experiments
1.7.1
Porosimeter Method
I.
Description
The helium porosimeter uses the principle of gas expansion, as
described by Boyles law. A known volume (reference cell volume) of
helium gas, at a predetermined pressure, is isothermally expanded into a
sample chamber. After expansion, the resulted equilibrium pressure is
measured. This pressure depends on the volume of the sample chamber
minus the rock grain volume, and then the porosity can be calculated.
II.
Procedure
The core plug should have already been dried out in the oven.
Using the instruments air gun clean the outside of the sample.
Then, first slightly unscrew and lift the top end plug of the core-holder
by pulling back the locking feature and then while being careful not to
drop the sample which may be already inside core-holder, unscrew
and open the bottom end plug and remove the sample.
Put the new sample inside the core holder and finger tight the bottom
part. Then pull back the locking feature and lower the top part and
again finger tight.
Add your core sample data into the apparatus software. This is done
by clicking on the small yellow button on top-left of the main window.
Petroleum Engineering laboratory
Petroleum Engineering Department, Curtin University
Then
close
the
sample
data
window
and
click
on
Porosity-
Choose your sample from the list which appears and enter the number
of confining pressure tests you want to have. Start with 500 psi then
1000 psi and two measurements under the final pressure (i.e. 2000
psi). In this window you have the option of measuring the permeability
as well but for this experiment remove the ticks next to permeability
and choose the porosity only.
At the start and very 2-3 measurements one test should be run using a
1.5 standard steel sample to verify that the apparatus is calibrated. If
you find the instrument inaccurate please talk to one of your lab
instructors.
III.
1.7.2
Method
I.
Description:
The determination of the effective liquid porosity of a porous plug is the
initial part of the measurement of capillary pressure using porous plate
method in core laboratories. Before the capillary pressure is determined
the volume of the saturating liquid (brine or oil) in the core must be
known. Thus, the effective liquid porosity of the core can be calculated in
the beginning of capillary pressure measurement.
II.
Procedure
Weigh a dry core plug, Wdry, measure its diameter D, and length L
using a calliper.
Put the core in the beaker filled with brine and then transfer the
beaker into a desiccator connected to a vacuum pump and run
vacuum pump for about 30 minutes.
Repeat steps 3 and 4 for the 3rd time but this time leave the sample
under vacuum for 24 hours, Wsat-final.
Remove the sample from the beaker and leave it inside the oven to
dry out.
III.
Calculate the portion of the pore volume saturated with brine for each
weight measurement step, V= Wsat / brine.
1.8 References
Torster,
O.
and
Abtahi,
M.,
2003.
Experimental
reservoir
2.2.2
Centrifuge Flushing
A centrifuge which has been fitted with a special head sprays warm
solvent onto the sample. The centrifugal force then moves the solvent
through the sample. The used solvent can be collected and recycled.
2.2.3
2.2.4
Soxhlet Extraction
emptied by a siphon effect and flow into the boiling flask. The toluene is
then ready to start another cycle.
A complete extraction may take several days to several weeks in the
case of low API gravity crude or presence of heavy residual hydrocarbon
deposit within the core. Low permeability rock may also require a long
extraction time.
Trap
Core
Figure 2-2 Schematic diagram of Soxhlet (a) and Dean- Stark (b)
apparatus
2.2.5
Vacuum Distillation
The oil and water content of cores may be determined by this method.
As shown in Figure 2 -3, a sample is placed within a leak-proof vacuum
system and heated to a maximum temperature of 230 C. Liquids within
the sample are vaporized and passed through a condensing column that
is cooled by liquid nitrogen.
Acetone
Benzene
Benzen-methol Alcohol
Carbon-tetrachloride
Chloroform
Methylene Dichloride
Mexane
Naphtha
Tetra Chloroethylene
Toluene
Trichloro Ethylene
Xylene
Toluene and benzene are most frequently used to remove oil and
performed
in
regular
oven
or
vacuum
oven
at
2.4 Experiments
2.4.1
Saturation
Determination,
Dean-Stark
Distillation Method
I.
Description:
The objective of the experiment is to determine the oil, water and gas
II.
Procedure:
Fill 2/3 of the extraction flask with toluene. Also put a small volume of
water at bottom of the trap to increase the water level just reaching the
graduated part of the trap so the volume of any additional fluid entering
the trap later can be read.
Take about 30 cm of Teflon tape. Remove the sample from the beaker and
quickly weigh it and tie the Teflon tape around the sample.
Put the wrapped sample inside the flasks long neck using the long hook
provided. Tighten the ground joint fittings, but do not apply any lubricant
for creating tighter joints. Start circulating cold water in the condenser.
Turn on the heating jacket and adjust the rate of boiling so that the reflux
from the condenser is a few drops of solvent per second.
Continue the extraction for 10-15 hours.
Read the volume of collected water in the graduated tube. Turn off the
heater and cooling water and remove the sample from the apparatus and
transfer it into the oven (100 C) and set time to 12 hours.
Once the sample is dry and cooled down obtain the weight of the core.
Calculate the loss in weight WL, of the core sample due to the removal of
oil and water.
Measure the density of a separate sample of the oil.
Calculate the oil, water and gas saturations after the pore volume V p of
the sample is determined.
III.
Porosity:
Where:
Worg: Initial weight of saturated sample
IV.
Equations
2.5 References
Torster,
O.
and
Abtahi,
M.,
2003.
Experimental
reservoir
3 LIQUID DENSITY
3.1 Definitions
Density () is defined as the mass of the fluid per unit volume. In
general, it varies with pressure and temperature. The dimension of
density is kg/m3 in SI or lb/ft3 in the Filed units system.
Specific gravity () of a liquid is defined as the ratio of the density of a liquid
to the density of water both measured at standard conditions. The
specific gravity of liquid in the oil industry is often measured by some
form of hydrometer that has its special scale. The American Petroleum
Institute (API) has adopted a hydrometer for oil lighter than water for
which the scale, referred to as the API scale, is:
310
Note: When reporting the density, the units of mass and volume used
at the measured temperature must be explicitly stated, e.g. grams per
millilitre
(cm3)
at
T(C).
The
standard
reference
temperature
for
Westphal balance
API hydrometer
Pycnometer
Bicapillary pycnometer.
The first two methods are based on the principle of Archimedes: A body
The API hydrometer is usually used for determining oil gravity in the oil
field. When a hydrometer is placed in oil, it will float with its axis vertical
after it has displaced a mass of oil equal to the mass of hydrometer
(Figure 3 -4a). The hydrometer can be used at atmospheric pressure or at
any other pressure in a pressure cylinder.
The pycnometer (Figure 3 -4b) is an accurately made flask, which can
be filled with a known volume of liquid. The specific gravity of liquid is
defined as the ratio of the weight of a volume of the liquid to the weight
of an equal volume of water at the same temperature.
3.3 Experiments
3.3.1
I.
Description:
This method covers the determination of the density or relative density
II.
Procedure
Thoroughly clean the pycnometer and stopper with a cleaning agent,
rinse well with distilled water. Finally rinse with acetone and dry.
III.
Fluid
Pycnometer+li
quid
(gr)
Pycnome
ter Vol.
(cm3)
Densit
y
(g/cm3
)
Specifi
c
Gravit
y
Standar
d
Deviati
on
IV.
Equations
3.4 References
4 VISCOSITY
4.1 Definitions
Viscosity is defined as the internal resistance of fluid to flow. The basic
equation of deformation is given by
411
where
required to keep the upper plate moving at constant velocity v in the xdirection and A is area of the plate in contact with the fluid (Figure 4 -5).
By fluid viscosity, the force is transmitted through the fluid to the lower
plate in such a way that the x-component of the fluid velocity linearly
depends on the distance from the lower plate.
It is assumed that the fluid does not slip at the plate surface.
Newtonian fluids, such as water and gases, have shear-independent
viscosity and the shear stress is proportional to the shear rate (Figure 4
-6).
In the oil industry viscosity generally is expressed in centipoise, cp (1
cp =10-3 Pa.s).
Figure 4-6 Shear stress vs. shear rate for a Newtonian fluid
viscosity
of
liquids
usually
rises
with
pressure
at
constant
comparison of the times required for a given volume of the tested liquids
and of a reference liquid to flow through a given capillary tube under
specified
initial
head
conditions.
During
the
measurement
the
In this method the Poiseuilles law for a capillary tube with a laminar flow regime
is used.
412
where t is time required for a given volume of liquid V with density of
and viscosity of to flow through the capillary tube of length l and radius
r by means of pressure gradient P.
The driving force P at this instrument is gl. Then:
413
or:
414
The capillary constant is determined from a liquid with known viscosity.
4.3.2
4 -8), which is
based on Stokes law for a sphere falling in a fluid under effect of gravity.
A polished steel ball is dropped into a glass tube of a somewhat larger
diameter containing the liquid, and the time required for the ball to fall at constant
velocity through a specified distance between reference marks is recorded.
The following equation is used
415
where:
= absolute viscosity, cp
t = falling time, sec
b = density of the ball, g/cm3
f = density of fluid at measuring temperature, g/cm3
K = ball constant.
The rolling ball viscometer will give good results as long as the fluid
flow in the tube remains in the laminar range. In some instruments of this
type both pressure and temperature may be controlled.
4.3.3
Rotational Viscometer
Inner
cylinder
When the distance between the cylinders d, is small, we can define the
viscosity gradient for laminar flow regime as:
416
where R is radius of the inner cylinder and
torque from the torsion spring on the inner cylinder must be equal but
opposite in direction to the torque on the rotor applied from the motor.
The effective area of the applied torque is 2.R.h where h is length of the
cylinder. The viscous drag on the inner cylinder is k..R, where k is the torsion
constant of the spring and is angular displacement of the instrument in
degrees. Then:
417
which gives:
418
4.4 Experiments
4.4.1
Type Viscometer
I.
Description
The main objective of the measurement is to determine the kinematic
II.
Definitions
Dynamic viscosity () is the ratio between the applied shear stress and the
III.
Where:
cSt = centistokes, cp = centipoise
1cp = 10-3 Pa.s, 1cSt = 10-6 [m2/s]
IV.
Procedure
IMPORTANT: make sure you use the right viscometer for the right
fluid as directed by your lab instructor. If not sure about anything
ask the lab instructors for advice.
Select a clean, dry calibrated viscometer (Figure 4 -10) having a range
covering the estimated viscosity (i.e. a wide capillary for a very viscous
liquid and a narrower capillary for a less viscous liquid).
Charge the viscometer: To fill, turn viscometer upside down. Dip tube (2)
into the liquid to be measured while applying suction to tube (1) until
liquid reaches mark (8). After inverting to normal measuring position,
close tube (2) with the rubber stopper before liquid reach mark (3).
Allow the charged viscometer to remain long enough to reach the room
temperature. Read the calibration constants-directly from the viscometer
or its documentations.
Measuring operation: Open tube (1) and measure the time it takes the
liquid to rise from mark (3) to mark (5). Measuring the time for rising from
mark (5) to mark (7) allows viscosity measurement to be repeated to
check the first measurement.
If two measurements agree within required error (generally 0.2-0.35%),
use the average for calculating the reported kinematic viscosity.
4.5 References
5 Resistivity
5.1 Definitions
Porous rocks are comprised of solid grains and void space. The solids,
with the exception of certain clay minerals, are non-conductors.
Therefore, the electrical properties of a rock sample depend on the
geometry of the voids and the fluid with which those voids are filled. The
fluids of interest in petroleum reservoirs are oil, gas, and water. Oil and
gas do not conduct electricity. However, water is a conductor when it
contains dissolved salts, such as NaCl, MgCl 2, KCl which are normally
found in formation reservoir water. Current is conducted in water by the
movement of ions and can therefore be termed electrolytic conduction.
The resistivity of a porous material is defined by:
519
where
r = resistance,
A = cross-sectional area, m2
L = length, m
Index:
The
second
fundamental
notion
of
electrical
the
formation
factor
and
porosity
by
introducing
the
cementation factor:
523
where
= porosity of the rock
m = Archies cementation factor.
Archie reported that the cementation factor probably ranged from 1.8
to 2.0 for consolidated sandstones and for clean unconsolidated sands
was about 1.3.
Saturation Exponent: The well-known Archies equation establishes a
relationship between resistivity index and water saturation of rocks as
follows:
524
where
Sw = water saturation
Petroleum Engineering laboratory
Petroleum Engineering Department, Curtin University
Roa/Rw). Wyllie (3) proposed that the observed effect of clay minerals was
similar to having two electrical circuits in parallel, the conducting clay
minerals and the water-filled pores. Thus:
525
where Roa is the resistivity of a shaly sand when 100% saturated with
water of resistivity Rw. Rc is the resistivity due to the clay minerals. FRw is
the resistivity due to the saturating water, and F is the true formation
factor of the rock (the constant value when the rock contains lowresistivity water).
As
Rw 0, lim Fa
Rw 0
Rc
F
. Therefore Fa approaches F as a limit, as Rw
Rc
F
5.5 Experiments
5.5.1
Rocks
I.
Description
The objective of this experiment is to measure as many as possible of
the main electrical properties of porous rock like water resistivity,
formation factor, tortuosity, cementation factor, resistivity index and
saturation exponent.
II.
Procedure
Resistance measurements are performed using a LCR meter. The
resistivity of the sample can then be developed when the size of the
sample is known.
III.
Core D,
Core L,
rx,
Ro,
Cementation
Formation
ID
fraction
factor, m
factor, F
Core D,
Core L,
rx,
R t,
Ro,
Swfract
Resistivity
Saturation
ID
ion
Index, I
exponent, n
5.6 References
6 PERMEABILITY
6.1 Definition
Permeability is a property of the porous medium and it is a measure of
capacity of the medium to transmit fluids. Permeability is a tensor that in
general is a function of pressure. Usually, the pressure dependence is
neglected in reservoir calculations, but the variation with position can be
pronounced. Very often the permeability varies by several magnitudes,
and such heterogeneity will of course influence oil recovery.
6.1.1
Darcys Law
6-3
3
where u is superficial velocity, k is permeability tensor, is fluid
viscosity, P is pressure gradient, is fluid density and g is gravitational
vector. Writing flow velocity as the ratio of volumetric rate to crosssectional area perpendicular to flow q/A in distance L, Darcys law can be
expressed:
6-3
4
The dimensions of permeability can be established by substituting the
units of the other parameters in the equation. The unit Darcy results from
the choice of cgs system units:
6.1.2
6-3
r 4 p
8 L
where
= tube radius
= length of tube
= flow rate
p
r
Comparing Equation
6-3
6
so that:
6-3
7
6-3
n A r 2
6-3
r 4 p
8 L
6-4
r2
8
, of the real
pore network, such that the actual length of each capillary is L , to give:
k
r2
8
6-4
1
S n 2rL
6-4
2
6-4
3
so that:
n 2r A
6-4
4
6-4
5
6 -41
6-4
3
2 2
k ck
6-4
3
2
6-4
r 2 3
where r is the hard sphere radius and csc is the Kozeny constant for the
simple cubic structure.
Attempts have been made to use the Kozeny equation for more
complex geometries, for example fractured systems. Permeability in
fractured
reservoirs
is
dominated
by
the
small
amount
of
high
width.
In this model the bulk volume will be of the order of a3 and the surface
area exposed to flow will be of the order of a2, hence the specific surface
will scale as a-1. If it is assumed that the matrix is impermeable then the
fracture porosity of the model will be (a2w/a3 =) w/a.
Substituting these values into the Kozeny equation gives:
kf cf
w
a
1
a
cf
6-4
w3
a
a
Figure 6-17 Simplified Fracture Model
Obviously this is a gross simplification and assumes not only that the
simple approach of Kozeny applies but also that a representative average
of a and w can be determined.
6.1.3
Klinkenberg Effect
All the lines when extrapolated to infinite mean pressure (1/P m=0)
intercept the permeability axis at a common point. This point is
designated KL, or the equivalent liquid permeability.
drop.
Various
techniques
are
used
for
permeability
Unsteady-state permeameter
Steady-state permeameter
6.2.1
Steady-state Permeameter
equation applicable to gas flow. In this equation the gas flow is measured
at atmospheric conditions, thus Patm = 1 atm.
6-5
2
Hassler core holder may be used with this instrument. The Hassler
system is an improvement of the rubber plug system whose tightness is
limited at certain pressures.
The core is placed in a flexible rubber tube (Fig. 3). The Hassler cell has
these advantages:
a. Excellent tightness.
6.2.2
Unsteady-state Permeameter
confined sample, and the pressure vs. time behaviour is observed as the
pore fluid moves through the sample from the samples upstream
reservoir to a 2nd reservoir located downstream of the sample. When a
pressure pulse P0 is applied, the differential pressure P(t) decays
exponentially as a function of time, t:
6-5
3
6.3 Experiment
6.3.1
I.
Description
The same equipment used to measure porosity utilising Boyles law is
used here to measure permeability through the pulse decay method. As
part of your prelab report you are required to do some research on
permeability measurement using pulse decay method and reflect your
findings in your report.
II.
Procedure
Before you start make sure that the core plug is clean and dry.
At the start and very 4-5 measurements one test should be run using
1.5 standard samples to verify that the apparatus is calibrated.
III.
Make a plot of the pressure pulse decay vs. time. And discuss
the apparent trend in the data.
6.4 References
7 CAPILLARY PRESSURE
7.1 Definitions
Capillary pressure is the force that causes a fluid to rise up a fine tube
when one end of the tube is immersed in a wetting fluid. Evaluating the
capillary pressure of reservoir rocks is important because capillarity
controls the static distribution of fluids in the reservoir prior to production
and the distribution of the remaining hydrocarbons after primary
production.
2r
Air
h
Water
7-5
2 cos
r
geometry.
1
1
rc1 rc 2
Pc
7-5
5
In this equation rc1 and rc2 refer to the principal radii of curvature of the
interface and is sometimes referred to as the specific free energy of the
interface, more commonly the surface tension.
For the case of a capillary tube, rc1 and rc2 are equal, and by simple
geometrical considerations they are related to the radius of the capillary
as follows:
rc1 rc 2
r
cos( )
7-5
6
Pc 0.434 h
7-5
Non-wetting Phase
Free Surface
Free Surface
Wetting Phase
Non-wetting Phase
Pressure
Depth
Pnw nw gz
Pnw
Pc
Pc Pnw Pw
Pw
Free
Surface
height
Pc 0
Free
Surface
Pw w gz
Wetting Phase
4.6 cos
r
7-5
8
Pc1
2 1 cos1
r
Pc 2
2 2 cos 2
r
Pc1 Pc 2
1 cos 1
2 cos 2
7-5
9
The values of interfacial tension, , and contact angle, , are known for
a range of pairs of fluids under different conditions, and typical values are
given in Table 7 -3.
Wetting
Phase
Non-
Conditions
wetting
Phase
Contact
Interfacial
Angle
Tension
(Degrees)
(dynes/cm)
Brine
Oil
Reservoir
30
30
Brine
Oil
Laborator
30
48
y
Brine
Gas
Reservoir
(50)
Brine
Gas
Laborator
72
y
Oil
Gas
Reservoir
Gas
Mercury
Laborator
140
480
Table 7-3 Typical values for contacty angle and IFT for different fluid pairs
under different conditions
Centrifugal Method
In the centrifugal method a sample that has been saturated with the
wetting fluid is placed in a container of the non-wetting fluid. The
container is then rotated and the centrifugal force produces a pressure
gradient throughout the sample, directed outward from the axis of
rotation. It is normally the case that the wetting fluid is denser than the
non-wetting fluid so that a higher pressure is developed in the fluid within
the sample. The excess pressure in the wetting fluid is the capillary
pressure, and it is this pressure that causes the wetting fluid to be
expelled out of the end of the sample furthest from the axis of rotation. At
the same time non-wetting fluid enters at the nearest end.
At a constant rate of rotation an equilibrium saturation distribution will
develop
according
to
the
relationship
between
capillary
7.4.2
Displacement Method
P1
P2
P3
P4
P3
P2
P1
100%
50%
0%
P4
yS
ed
ort
orl
Po
Un
so
rte
d
Bimodal
Well Sorted
100%
0%
A
100
7.4.3
7.5 Hysteresis
A set of consecutive drainage and imbibition capillary pressure curves
are schematically shown in Figure 7 -28, from which it can be seen that
different results are obtained depending on which fluid is displacing
Capillary Pressure
Pc
Drainage
Imbibition
0%
S wr
1 S or 100%
% of Pore Volume
heterogeneities
and/or
surface
roughness
and
7.6 Experiments
7.6.1
Plate Method
I.
Description:
The porous plate method is the most accurate measurement of
capillary pressure in homogeneous and heterogeneous cores. Several
plugs can be measured at a time. The limitation is that the capillary
discontinuity may distort the results.
II.
Procedure:
1
Weigh the brine saturated core and take note of the core ID.
Remove the cells lid by loosening its bolts. Then put the saturated
core on top of the porous plate in the cell.
Close the cells lid and tighten the bolts to make sure there will be no
leaks. Then adjust the pressure regulator to an output pressure of 3
psi.
Petroleum Engineering laboratory
Petroleum Engineering Department, Curtin University
After 1 week, isolate the air supply to the cell and after releasing the
pressure inside the cell take out the core from the cell.
Repeat steps 2-4 every week for pressures of 10, 25, 50 and 80.
III.
Core No.:
Pa
Date
, D:
cm, L:
cm, Wsat:
gr, Porosity:
Step
Pc(i),
Wwet(i),
Sw(i),
r(i),
W(i)/Ww
No.
psi
gr
fraction
ater
0
1
2
3
4
5
where
Pc(i) = capillary pressure of the ith step, psi
Wwet(i) = core weight of ith step, gr
Sw(i) = (Wwet(i)-Wdry)/Wwater, ith water saturation of Pc(i)
Wwater = Wsat-Wdry, gr
r(i) = 2g-w /Pc(i), radius corresponding to Pc(i)(in Pascals), microns(m)
g-w = 72.0 dynes/cm, interfacial tension of gas-water
Pc(i) = pressure reading, dynes/cm 2
W(i)/Wwater = (Wwet(i-1)-Wwet(i))/Wwater, fraction of the capillaries of r(i) in total pore
volume
7.7 References
Grain Density:
8.1 Introduction
Grain volume is usually used for measuring pore volume or porosity of
the rock samples in reservoir evaluation. Besides that knowing grain
volume can be helpful in identifying grain density of the rock sample.
However grain volume data itself is not in the interest of reservoir
engineers or geologists in determining reservoir characteristics.
Grain density is calculated by dividing the sample dry weight (in
grams) by the grain volume. It can be utilized in determination of the rock
type. Major rock types such as sandstone, limestone, and dolomite fall
into specific grain density range (Table 1).
Grain Density(cc/gr)
Sandstone
2.65
Limestone
2.71
Dolomite
2.85-2.87
Anhydrite
2.96
Coal
1.5
Gypsum
2.35
Read the digital pressure recorder on the front panel when there is
not any gas in the system as the zero pressure in table 2. You should
use this value to correct the later recorded values for the pressures
(Pcorrected=Precorded-Zero pressure).
Open the SUPPLY GAS valve and pressurize the reference section of
the porosimeter. Close the SUPPLY GAS valve and monitor the
pressure for 10 seconds. The pressure should equilibrate to a point
that the last digit fluctuates very slowly. Record the digital pressure
data under Preference in table 2.
Now remove billet A from the system and repeat the steps 2 to 4 and
record the appropriate data under after removing billet section in the
table 2. Repeat this procedure for other billets as well and record the
pressure data.
Now by having all the required data it is possible to calculate the
reference volume based on the recorded values in table 2 using the
following formula:
Where:
VREF: System Reference Volume, cm3
VBillets Removed: Volume of the removed billets, cm 3
PRef. Full: Reference cell pressure when all billets is in grain cell, psi
PGC Full: Grain cell pressure with all billets is in grain cell, psi
PRef.Rem.: Reference pressure for measurement with a billet removed, psi
PGC Rem: Grain cell pressure when the billet (or billets) removed, psi
You should re-calculate the reference volume each time that you
remove one billet from the grain cell and finally take an arithmetic
average to report the reference volume of the system and use this value
for grain volume measurement.
Set the sample on the table top. Create a stack of billets next to the
sample that is equal in height or slightly taller than the sample
height. You should mix and match the billets such that you create a
stack as close as possible to the height of the sample. Excess height
creates excess dead volume in the chamber, which can increase the
uncertainty of the measurement.
After creating a stack equal to or slightly taller than the sample, place
the others (remaining) billets inside the grain cell.
Petroleum Engineering laboratory
Petroleum Engineering Department, Curtin University
Carefully place your sample on top of the billets in the cup and
prepare to measure the sample grain volume.
Open the SUPPLY GAS valve and pressurize the reference section of
the porosimeter. Record the digital pressure data under P ref.
Sample
in
table 3.
10 Open the TO CORE valve. Allow the pressure to equilibrate in the
grain cell. When the pressure comes to equilibrium record the digital
pressure data under PGC Sample.
Now by having required parameters from tables 2 and 3, it is possible
to calculate grain volume of the sample using the following formula:
Where:
VGrain: Grain Volume, cm3
VBillets Removed: Volume of removed billets, cm3
PRef. Full: Reference Pressure when grain cell is full of billets, psi
PGC Full: Grain cell pressure when grain cell is full of billets, psi
VRef.: Reference volume of system, cm3
PRef. Sample: Reference cell pressure when sample is inside grain cell, psi
PGC Sample: Grain cell pressure when sample is inside grain cell, psi
III.
Report
8.5 References