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MATERIAL SAFETY DATA SHEET

CmG Active EAX33


Date Issued:August 2007
p. 1 of 5

Company Details
Name
POWAFIX CC
Address
PO BOX 1230
WANDSBECK
UNIT 12 RUNWAY PARK
1474 SOUTH COAST RD
MOBENI

Tel
Fax

031-4622 571
031-4622 665

1.Product Identification:
Trade / Commercial Name
Chemical Name
UN No
DOT Hazard
SA Standard (SABS 0228)

Lacquer Thinners
Oxygenate Solvent, Thinners
1263
CLASS 3 PACKAGING GROUP II
CLASS 3.2

2.Composition:
Hazardous Components
Ethanol
Ethyl Acetate
Normal Propyl Acetate
Toluene
Xylene
Light Aliphatic Petroleum
Solvent
1- Methoxy- 2- propanol

Composition (%)

CAS No.

15 - 40
30 60
<5
0-20
10-23
0-10

64-17-5
148-78-6
109-60-4
108-88-3
1330-20-7
64742-89-8

<5

000107- 98- 2

Exposure Limits (TWA)


(STEL)
1000ppm
400ppm
200ppm
150ppm
150ppm
100ppm
100ppm

3.Hazards Identification
Fire:

Flammable Liquid: Will be easily ignited by heat, sparks or flames.


Vapors may form explosive mixtures with air. Can react violently with
oxidizers. Vapours are heavier than air and could travel to a source of
ignition and flash back. They will spread along ground and collect in low
confined areas (sewers, basements, tanks). Vapor explosion hazard
indoors, outdoors or in sewers. Runoff to sewer may create fire or
explosion hazard. Containers may explode when heated. Gel is lighter
than water. Fire could produce irritating or poisonous gases. Runoff
from fire control or dilution water could cause pollution.

Inhalation:

Toxic. Could be toxic if inhaled. May cause toxic effects if absorbed


through the skin. Symptoms may be delayed. Inhalation or contact with
material may irritate or burn skin, throat and eyes. Fire will produce
irritating, corrosive and/or toxic gases. Symptoms: Vapors may cause
irritation of the mouth, nose and throat, coughing, leading to sleep and
stupor, dizziness or suffocation.

Skin contact:

Absorbed through skin. Symptoms may be delayed. Symptoms include


redness, itching, drying and pain.

Eye contact:

Symptoms: Severe irritation, even corneal burns.

Ingestion:

Toxic. Could be fatal if inhaled. Symptoms are similar to those for


inhalation and may be delayed. Symptoms: From redness of face and
neck, exaggerated feeling of well-being, stomach pain, depression,
dizziness, headache, vomiting, and unconsciousness TO loss of coordination, slurred speech, drowsiness, stupor, coma and possibly death.

MATERIAL SAFETY DATA SHEET

CmG Active EAX33


Date Issued:August 2007
p. 2 of 5

Chronic Exposure:

Prolonged or repeated skin exposure may cause severe irritation or


dermatitis.

Aggravation of
Pre-existing
Conditions:

Persons with pre-existing skin disorders or eye problems, or


impaired liver, kidney or respiratory function may be more
susceptible to the effects of the substance.

4.

First Aid Measures

Skin

Promptly remove contaminated clothing. Wash affected area with plenty


of water and soap for at least 15 minutes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes. Irrigate eyes
thoroughly whilst lifting eyelids and rolling eyeballs. SEEK IMMEDIATE
MEDICAL ATTENTION.

Ingestion

Do not induce vomiting. Observe for symptoms of centrl nervous system


depression or drowsiness. Lie person down, and keep calm, prevent
person from self-inflicted harm. Never give anything by mouth to an
unconscious person. Seek immediate medical attention.

Inhalation

Remove from contaminated area. Loosen all tight clothing. Sit patient up
if conscious. If breathing is difficult, oxygen should be given by a trained
person. Begin rescue breathing if breathing has stopped. Begin CPR if
heart action has stopped. Seek immediate medical attention

5.

Fire Fighting Measures

Small fires:

Dry chemical, CO2 or alcohol resistant foam.

Large fires:

Extinguish with water spray, fog or alcohol resistant foam. Move


container from fire area if it can be done without risk. Cool down
containers with water spray. For massive fire in cargo area, use
unmanned hose holder or monitor nozzles. Withdraw immediately when
containers start bulging or in case of rising sound from venting safety
device or any discolouration of container due to fire. Keep unnecessary
people away. Isolate hazard area and deny entry. Stay upwind. Keep
out of low areas. Self-contained breathing apparatus (SCBA) and full
firefighters' protective clothing will provide limited protection. Protect
personnel and public from exposure to toxic smoke from burning product.

6.

Accidental Release Measures


Shut off ignition sources. No smoking, flames or flares in hazard area.
Always wear suitable protective clothing. Demarcate danger area (block
roads if necessary) and put out warning signs. Keep public and nonemergency people away from danger area. Keep upwind. Stay away
from low areas (also ensure that other people are staying upwind). If
water pollution occurs, notify the appropriate authorities. Avoid spillage
from entering drains or water courses. Provide adequate protective
equipment and ventilation. Notify Fire Brigade, Occupational Health and
Environmental authorities.

Spill or leak:

Shut off ignition sources; no flares, smoking or flames in hazard area.


Stop leak if you can without risk. Water spray may reduce vapour, but it
may not prevent ignition in closed spaces. Ventilate area well. Restrict
persons not wearing PPE from entering area. Contain product and
reclaim if possible. Keep out of confined spaces. Absorb residues with
vermiculite, dry sand, earth or other similar product. Collect and deposit

MATERIAL SAFETY DATA SHEET

CmG Active EAX33


Date Issued:August 2007
p. 3 of 5

in sealed containers for disposal. Contaminated soil to be excavated and


transported to a hazardous materials waste disposal site. Dispose by
incineration.
Small spills:

Take up with sand or other noncombustible absorbent material and place


into containers for later disposal.

Large spills:

Dike far ahead of liquid spill for later disposal.

7.

Handling And Storage


Separation of at least 3 metres from corrosives is recommended.
Storage in the same storage space is prohibited with the following
classes: These storage spaces should be at least 10 metres apart:
Explosives
Poisonous Gases
Oxidizing Agents
Organic Peroxides
Radioactive materials
Corrosives
Avoid contact with strong oxidizers. Store in tightly closed containers in a
cool, well-ventilated area. Smoking and open flames are prohibited in
storage area. Metal containers should be bonded before
decanting/transferring the product. Use only non-sparking tools and
equipment.

8.

Exposure Controls/Personal Protection

Occupational Exposure
Limits

Individual substances: See page 1

Controls

The control measures appropriate for a particular work site depend on


how this material is used and on the extent of exposure. The best
protection is to have enclosed operations or provide local exhaust
ventilation at the site of chemical release. Use a non-sparking, grounded
ventilation system separate from other exhaust ventilation systems.
Exhaust directly to the outside. Supply sufficient replacement air to make
up for air removed. Have a safety shower/eye wash fountain readily
available in the immediate work area.

Personal Protection

If engineering controls and work practices are not effective in controlling


this material then wear suitable personal protection equipment, including
chemical safety goggles, face shield, boots, impervious gloves, overalls,
& respiratory protection. Always have appropriate equipment available
for use in emergencies.
Fire: Use full personal protective clothing, including a self-contained
breathing apparatus.
Inhalation: Handle only in well-ventilated open area. In emergency or
non-routine tasks, use self-contained breathing apparatus.
Skin: Wear appropriate clothing to prevent repeated or prolonged skin
contact. Butyl rubber or PVC gloves may also be used. Provide safety
showers.
Eye: Wear safety chemical goggles or face shields where splashing may
occur. Provide eyewash stations.
Ingestion: Do not drink. Do not eat or drink in the area where product is
being handled or stored.

MATERIAL SAFETY DATA SHEET

CmG Active EAX33


Date Issued:August 2007
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9.

Physical & Chemical Properties


Appearance
Colour
Odour
Boiling Point
Flash Point
Relative density (water = 1 )

Liquid
Clear
Mild, alcohol, fruity
75 - 150C
<10C
0,8 0.9

10. Stability And Reactivity

Conditions to Avoid

Risk of violent reaction. Avoid contact with strong oxidizers.

Incompatible Materials

Strong oxidizers.

11. Toxicological Information

Routes of Entry

Absorbed through the skin, eye contact, inhalation and ingestion.

Toxicity to Animals

WARNING: The LC50 values hereunder are estimated on the basis of a


4 hour exposure.
Acute oral toxicity (LD50): 3450mg/kg (Mouse). (Ethanol).

Chronic Effects
on Humans

Carcinogenic effects:
Classified 3 (not classifiable for human),
by IARC (Ethanol).
Mutagenic effects:
Classified proven for human (Ethanol).
Teratogenic effects:
Classified proven for human (Ethanol).
Developmental toxicity: Classified Development toxin (proven),
(Ethanol).
The substance is toxic to blood, kidney, liver, heart and the reproductive
system.

Special Remarks on
Chronic Effects on
Humans

Detected in material milk in humans. Normal Propanol)

Special Remarks on
otherChronic Effects on
Humans

Exposure can cause nausea, headache and vomiting. (Normal Propanol)

Other Toxic Effects

Very hazardous in case of ingestion.


Hazardous in case of skin contact (irritant, sensitizer, permeator), of eye
contact (irritant), of inhalation.

12. Ecological Information

Ecotoxicity

Not available

Products of
biodegradation

Possibly hazardous short degradation products are not likely. However,


long term degradation products may arise.

Toxicity of the Products


of Biodegradation

The products of degradation are less toxic than the product itself.

MATERIAL SAFETY DATA SHEET

CmG Active EAX33


Date Issued:August 2007
p. 5 of 5

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent
to an approved incinerator or disposed in an approved waste facility. Processing, use or
contamination of this product may change the waste management options. Dispose of container and
unused contents in accordance with requirements.
14. Transport Information
UN No
IMDG-Shipping Name
IMDG Code
DOT No.
DOT HAZARD
Marine Pollutant

1263
Flammable liquids.
3.2
UN 1263
CLASS 3 PACKAGING GROUP II
Yes

15. Regulatory Information

R11 Highly flammable


S7
Keep container tightly closed
S9
Keep container in a well-ventilated place.
S14.8 Keep away from oxidizing and acidic substances.
S15 Keep away from heat
S16 Keep away from sources of ignition No Smoking
DISCLAIMER:

POWAFIX provides the information contained herein in good faith


but makes no representation as to its comprehensiveness or
accuracy. This document is intended only as a guide to the
appropriate precautionary handling of the material by a properly
trained person using this product. Individuals receiving the
information must exercise their independent judgement in
determining its appropriateness for a particular purpose.
POWAFIX MAKES NO REPRESENTATIONS OR WARRANTIES,
EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION
ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION
SET FORTH HEREIN OR THE PRODUCT TO WHICH THE
INFORMATION REFERS. ACCORDINGLY POWAFIX WILL NOT BE
RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR
RELIANCE UPON THIS INFORMATION.

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