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Inter (Part-l) Lahore Board 2010

Chemistry
Time Allowed: 20 Minutes

Paper I (Objective Type)

Max. Marks: I7

Note: Write answers to the questions on the objective answer sheet provided. Four possible answers A, B,
C and D to each, question are given. Which answer you consider correct, fill the circle in front of A, B, C or
D with Marker or Pen ink to each question on the answer sheet provided.
1. The volume occupied by 1.4g N2 at STP is:
(A) 2.4 dm3
(B) 11.2 dm3
(C) 2.24 dm3
2. Silver has isotopes:
(A) 9
(B) 16
(C) 17
3. Solvent extraction is an equilibrium process and is controlled by:
(A) Distribution law
(B) amount of solvent
(C) Law of mass action
(D) The amount of solute
4. The molar volume of CO2 is maximum as:
(A) STP
(B) 0oC and 2atm
(C) 127oC and Iatm
(D) 273oC and 2atm
5. Ice occupied space than liquid water :
(A) 9%
(B) 10%
(C) 11%
26. Structure of CrO4 is :
(A) Tetrahedral
(B) Octahedral
(C) Cubic
(D) Tricinic
7. Total number of spectral regions in a spectrum is:
(A) 4
(B) 6
(C) 7
8. The value of Planks constant is:
(A) 6.6210-34 J.S
(B) 6.6210-27 J.S
(C) 6.6210-21 J.S
(D) 6.6210-31 J.S
9. Bond angle between two H S H bond is:
(A) 104.5 oC
(B) 107.5 oC
(C) 92 oC
10. S.I unit of dipole moment is:
(A) Pm
(B) Debye
(C) mC

(D) 1.12 dm3

(D) 18

(D) 12%

(D) 8

(D) 95oC
(D) all

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11. The total heat content of a system is called:

(A) Entropy
(B) Enthalpy
(C) Temperature
(D) Internal energy
12. Law of mass action derived by Guldberg and Waage in:
(A) 1909
(B) 1906
(C) 1846
13. Ionization of hydrogen sulphide gas is suppressed by:
(A) KCl
(B) NaCl
(C) HCl
3
14. 10g NaOH dissolved per 250 cm of solution has molarity:
(A) 0.5 M
(B) 1.0 M
(C) 1.5 M
15. Oxidation number of chromium in K2Cr2O7 is:
(A) 2
(B) 4
(C) 6
16. Emf of zn Cu cell is:
(A) 0.0 v
(B) 0.5 v
(C) 1.0 v
17. A substance which makes the catalyst more effective is called:
(A) Inhibitor
(B) Retarder
(C) promoter
(D) Auto catalyst

(D) 1864
(D) NH4Cl
(D) 2.0 M
(D) 12
(D) 1.1 v

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Inter (Part-l) Lahore Board 2010

(SECTION l)

Chemistry
Time Allowed: 2.40 Hours

Paper I (Essay Type)

Max. Marks: 68

Note: Out of Q. No. I, 2, 3 and 4 write any Twenty-Two (22) short answers. While writing answer write
question No and its part carefully. Each part carries two marks. 44
1.

(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)

2.

(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)

3.

(i)
(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)

Define actual yield, write formula for the calculation of percentage yield.
One mg of K2CrO4 has thrice the number of ions than the number of formula units
when ionized in water.
Why oxygen cannot be determined directly in combustion analysis?
Define distribution law and how it is helpful in solvent extraction.
Define chromatography. Give its two uses.
State Joule Thomson effect. Write its application?
Why regular air cannot be used in divers tank?
Calculate the density of methane at STP.
Explain electron gas theory.
Define transition temperature with two examples.
Evaporation causes cooling effect, why?
Boiling needs a constant supply of heat, why?
State Auf bau principle and Pauli's exclusion principle.
Explain orbital.
Why e/m value of positive rays for different gases are different but those of cathode rays
the e/m value are same? Justify it.
Why atomic spectrum 1s line spectrum.
Why ionic compounds do not show the phenomenon of isomerism?
Write down two postulates of VSEPR theory.
The ionic radius of cation is smaller than atomic radius but that of an anion is greater than
atomic radius. Explain with reason.
What factors influence the ionization energy?
Define state function and give examples.
Justify that heat of formation of compound is sum of all the other enthalpies.
Explain the term buffer capacity.
Solubility of glucose in water is increased by increasing the temperature. Explain with
reason.

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4.

(i)

(ii)
(iii)
(iv)
(v)
(vi)
(vii)
(viii)
(ix)

What will be the effect on the position of equilibrium on following system if:
(1) Temperature is increased
(2) Chlorine is added
PCl5
PCl3 + Cl2 H = 90 kj/mol
The sum of mole fraction of all the components is always equal to unity for any solution.
Explain with reason.
What are azeotropic mixtures?
What is water of crystallization? Give two examples.
Calculate the oxidation number of chromium inCrCl 3 and Cr2O7-2.
Salt bridge is not required in lead storage cell. Why?
What is standard hydrogen electrode?
What are enzymes? Give two examples in which enzymes act as catalyst.
What is half life method for determination of order of a reaction?

(SECTION ll)

Note: Attempt any THREE questions

5.

(a)

(b)

6.

(a)
(b)

7.

(a)
(b)

8.

(a)
(b)

9.

(a)
(b)

Mg metal reacts with HCl to give hydrogen gas. What is the minimum volume of HCl solution
(27% by weight) required to produce 12.1g of H2? The density of HCl solution is 1.14g/dm3 .
Mg + 2HCl
MgCl2 + H2
4
Define hydrogen bonding? How does it explain the indicated properties of following
substances:
4
(1) Solubility of hydrogen bonded molecules.
(2) Structure of ice.
Define bond energy? Discuss two factor effecting the bond energy.
Explain enthalpy and prove that H = qp

4
4

Define orbital. Discuss shape of its two types.

Describe Daltons law of partial pressure. Write its three applications

4
4

What is electrochemical series? Give its any three applications.

Ca(OH)2 is sparingly soluble compound. Its solubility product is 6.510 -6. Calculate the
solubility of Ca(OH)2.

4
4

Explain elevation of boiling points with the help of figure.

4
Distinguish between homogeneous and heterogeneous catalysis with suitable example. 4