PART-I

CHEMISTRY
SECTION I
Straight Objective Type
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This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE is correct.
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1.

2.

3.

Which of the following is arranged order of increasing boiling point.

a) H2 0 < CCl4 < CS2 < CO2

b) CO2 < CS2 < CCl4 < H2O

c) CS2 < H2O < CO2 < CCl4

d) CCl4 < CS2 < CO2 < H2O

The O - O bond length in O2 , O2
AsF4 and K O2 is

a) O2 ( AsF4 ) < O2 < K

O2

b) O2 ( AsF4 ) < K
O2 < O2

c) O2 < O2 ( AsF4 ) < K

O2

d) K
O2 < O2 < O2 ( AsF4 )

The species having diamagnetic nature and bond order 1 is

2a) O2

4.

5.

+
b) O2

2+
c) O2

d) O2

The increasing order of bond dissociation energy is :

a) F2 < Cl2 < O2 < N2

b) F2 < Cl2 < N2 < O2

c) Cl2 < F2 < O2 < N2

d) N2 < O2 < F2 < Cl2

According to MO theory:
+
a) O2 is paramagnetic and bond order is greater then O2
+
b) O2 is paramagnetic and bond order is less than O2
+
c) O2 is diamagnetic and bond order is more than O2
+
d) O2 is diamagnetic and bond order is less than O2

6.

Which compound has electrovalent, covalent, co-ordinate as well as hydrogen bond?

a) CuSO4 ,5H2O

7.

b) ZnSO4 ,7 H2O

c) FeSO4 ,7 H2O

+
Among KO2 , KAIO2 ,CaO2 and NO2 unpaired electron is present in:

d) FeCl3 ,6H2O

+
a) NO2 and CaO2

8.

b) KO2 and KAIO2

c) KO2 only

d) CaO2 only

Lattice energy of BeCO3 ( I) , MgCO3 ( II) and CaCO3 ( III) is in order:

a) I < II < III

b) I > II > III

c) I < III < II

d) II < I < III

SECTION II
Multiple Correct Answer Type
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This section contains 4 multiple correct answer(s) type questions. Each question has 4
choices (A), (B), (C) and (D), out of which ONE OR MORE is/are correct.
___________________________________________________________________________
9.
Which of the following statement is incorrect.
a) O2 is paramagnetic, O3 is also paramagnetic
b) O2 is paramagnetic, O3 is diamagnetic
c) O2 is paramagnetic, C2 is paramagnetic
d) Different observation is found in their bond order when NO NO and CO CO
10.

11.

Correct order of decreasing boiling points is

a) HF Hl HBr HCl

b) H 2O H 2Te H 2 Se H 2 S

c) NH 3 SbH 3 AsH 3 PH 3

d) CH 4 GeH 4 SiH 4

Which of the following molecules, are paramagnetic

a) O2

12.

b) He2

c) N 2

d) B2

Which of the following molecules involve intramolecular H bond

a) Ortho nitrophenol

b) Chloral hydrate

c) Para nitro phenol

d) Benzoic acid

SECTION III
Linked Comprehension Type
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This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice
questions have to be answered. Each question has 4 choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
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Passage 1:

According to MOT, two atomic orbitals overlap resulting in the formation of molecular
orbitals. Number of atomic orbitals overlapping together is equal to the molecular orbital
formed. The two atomic orbital thus formed by LCAO (linear combination of atomic
orbital) in the same phase or in the different phase are known as bonding and antibonding
molecular orbitals respectively. The energy of bonding molecular orbital is lower than that
of the pure atomic orbital by an amount V . This known as the stabilization energy. The
energy of antibonding molecular orbital is increased by V (destabilization energy).

13) The bond order of N 2 is equal to that of :

2

a) O2
b) O2
c) O2
d) none
14). Which among the following pairs contain both paramagnetic species.
2

a) O2 and N 2
b) O2 and N 2
c) O2 and N 2
d) O2 and N 2
15) Which of the following combination of orbitals is correct?
a)

b)

c)
d)

Passage 2:
In general boiling point of covalent compounds is affected due to increasing molecular
weight and
hydrogen bonding. Thus it is observed that the boiling point of
octanol is greater that water while
that of methanol is lesser than water. The
other properties which are considerably affected due to
hydrogen bond formation are
acidic nature, melting point, anomalous behaviour of water below
It is
40 C .,
therefore concluded that hydrogen bonding plays a vital role in explaning many observable
facts.
16) Which among the following has maxim boiling point?
a) CH 2 CH 2 CH 2 2 CH 2OH
b)

CH 3 CH 2 CH 2 CH CH 3
|
OH

CH 3
CH 3 CH 2 CH CH 2 CH 3
c)

17)

|
OH

|
CH 3 C CH 2 CH 3

d)

|
OH

Ka2 of Maleic acid is lesser than Ka2 of fumaric acid due to:
a) intramoleculalr hydrogen bonding in the formed after one proto0n removal in fumaric

acid
b) intermolecular hydrogen bonding in the ion formed after one proton removal in maleic
acid
c) intramolecular hydrogen bonding in the ion formed after one proton removal in malecic
acid
d) intermolecular hydrogen bonding in the ion formed after one proton removal in fumaric
acid.
18) For which of the following the value of Ka is minimum?
a)

b)

c)

d)

SECTION IV
Matrix Match Type
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This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column I are labeled A, B, C
and D, while the statements in Column II are labelled p, q, r, s and t. Any given
statement in Column I can have correct matching with ONE OR MORE statement(s)
in Column II. The appropriate bubbles corresponding to the answers to these questions
have to be darkened as illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s and t; then
the correct
darkening of bubbles will look like the following:

.
19. Match the Column I (molecules) with Column II (bond order) and select the correct
answer:
Column I
a)
b)
c)
d)

20.

Li2
N2
Be2
O2

Column II
p) 3
q) 2
r) 1.0
s) 0

Match the Column I with Column-II:

Column I
NH
a)
4 Cl
b) HNC
c) Liquid H2O2
d) CuSO4 ,5H2O

Column II
p) Covalent bond
q) Ionic bond
r) Hydrogen bond
s) Co-ordinate bond
CHEMISTRY

Q. No.

Answer

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20

B
A
A
A
A
A
C
B
A,C,D
A,B
A,D
A,B
C
D
C
A
C
B
a-r;b-p;c-s;d-q
a-p,q,s;b-p,s;c-p,r;d-p,q,rs

Hints and Solutions

1.
2)

CHEMISTRY
b) As increase of M.w t, B.P increase but H2O contain Intermolecular H-bond
+

A) o2
AsO4 O2

O2 O2

K
O2 O2
O - O, B.L of O2+ < O2 < O2- ( since B.Oa
3)
4)
5)

a) Conceptual
a) Conceptual
a) Conceptual

6)

.SO .H O
a) CuSO4 .5H2O =
Cu ( H2O) 4
4 2

+2
2
Electrovalent between Cu SO4

Four H2O molecules are Coordinated

- 2
one H2O molecule is H bond with SO4

7)

( )

c) KO2 has super oxide ion O2

This ion has one unpaired e-

1
Ionic size

8)

Lattice energy a

9)

(a, c, d) Conceptual

10)

(a, b)

1
)
B.C

Due to inter molecular H-bond b.p of HF is more in a and b.p of H2O is more in b. But
b.p of
11) (a, d) conceptual
12) (a, b) conceptual
19)

conceptual

20) conceptual

NH3 is less than SbH3