Beruflich Dokumente
Kultur Dokumente
CINTICA
Profesora: Dra. Mara Guadalupe Crdenas Galindo.
Equipo:
Arriaga Olvera Paola.
Daz Arriaga Brenda del Carmen.
Gallegos Rodrguez Claudia.
Gutirrez Martnez Diego.
Palos Gmez Jorge.
Hora clase: 10:00 11:00
Fecha de Entrega: 21 / 09 / 15
1
=
1 ,
=
Tarea No. 3
1. Dat, Butt y Bliss (1989) estudiaron la hidrocloracin de 1-octanol (A) con HCl (B)
Concentracin HCl
(kmoles/m3)
1.3
1.042
0.686
0.562
0.381
0.262
0.182
Respuestas:
Mtodo Diferencial
Tiempo
(t)
[min]
0
25
75
100
150
200
250
Concentracin
(CHCl)
CHCl (nueva)
[mol/L]
1.3
1.2953
1.042
1.0493625
0.686
0.6849875
0.562
0.5553
0.381
0.3728
0.262
0.2553
0.182
0.1578
/ =
Ln CHCl (nueva)
Ln
0.0108
0.0089125
0.0058125
0.0046
0.00285
0.002
0.00205
0.25874233
0.04818284
-0.37835469
-0.58824677
-0.9867132
-1.36531596
-1.84642687
-4.52820915
-4.72030049
-5.14774451
-5.38169898
-5.86043629
-6.2146081
-6.18991549
1.2
1
0.8
0.6
0.4
0.2
0
0
50
100
150
tiempo (min)
200
250
300
Regresin polinomial
Ln CHCl (nueva)
0.25874233
0.04818284
-0.3783547
-0.5882468
-0.9867132
-1.365316
Estimacin
Lineal:
ln
-4.5282091
-4.7203005
-5.1477445
-5.381699
-5.8604363
-6.2146081
1.05772491 4.77790694
+- (error) 0.02137803 0.01608367
r
0.99836867 0.0293465
m
b
+- (error)
+- (error)
Ln r vs. Ln Concentracin
-4
-1.6
-1.4
-1.2
-1
-0.8
-0.6
-0.4
-0.2
-4.5
y = 1.0577x - 4.7779
R = 0.9984
Ln r
-5
-5.5
-6
Ln Concentracion
-6.5
0.2
0.4
Diferencias finitas
Tiempo (t)
[min]
0
25
75
100
150
200
250
Concentracin
(CHCl)
[mol/L]
1.3
1.042
0.686
0.562
0.381
0.262
0.182
Vel. Rxn. ()
CHCl (Prom)
[mol/L*min]
0.01032
0.00712
0.00496
0.00362
0.00238
0.0016
-0.000728
1.171
0.864
0.624
0.4715
0.3215
0.222
0.182
Ln CHCl (Prom)
Ln
0.262364264
0.041141943
-0.376877651
-0.576253429
-0.964955904
-1.339410775
-1.703748592
-4.573671519
-4.944847554
-5.306349538
-5.621281253
-6.040654791
-6.43775165
#NUM!
Estimacin Lineal:
0.039734216
4.923983036
0.029332508
+- (error)
0.995201381
0.053537329
+- (error)
1.14443729
+- (error)
r
-1.4
-1.2
-1
-0.8
-0.6
-0.4
-0.2
0
-4.5
-5
Ln r
y = 1.1444x - 4.924
R = 0.9952
-5.5
-6
-6.5
Ln Concentracion Promedio
-7
0.2
0.4
Mtodo Integral
t (min)
0
25
75
100
150
200
250
Ca
1.3
1.042
0.686
0.562
0.381
0.262
0.182
Ln Ca
0.262364264
0.041141943
-0.376877651
-0.576253429
-0.964955904
-1.339410775
-1.703748592
Ln Ca vs. Tiempo
0.5
0
0
50
100
150
Ln Ca
-0.5
-1
-1.5
y = -0.0079x + 0.2318
R = 0.999
-2
tiempo (min)
200
250
300
t (min)
0
25
75
100
150
200
250
Cb
1.3
1.042
0.686
0.562
0.381
0.262
0.182
1/Cb
0.769230769
0.959692898
1.457725948
1.779359431
2.624671916
3.816793893
5.494505495
1/Cb
2
y = 0.0183x + 0.3265
R = 0.9429
1
0
0
50
100
150
Tiempo (min)
200
250
300