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10) Inoculation.
With a good inoculation, less residual magnesium is required to give good nodularity. This
again means less alloy addition and better magnesium recovery.
11) Ladle design.
The ratio of internal Height: Diameter should be at least 2:1 and the pocket should have
space enough to carry the alloy addition and covering material (see TI sheet No.10). The
ladle should also be properly insulated to minimise heat losses and consequently the
required treatment temperature (see TI sheet No. 21). A tundish cover lid is also highly
recommended for alloy and temperature recovery reasons.
12) Chemical composition of nodulariser.
High magnesium content in the alloy will give a violent reaction and reduced recovery.
High Ca will reduce the reactivity and increase the recovery, but also increase the
tendency to slag formation. Rare earth’s (cerium) will assist in giving better recovery
because it allows for working at lower magnesium in the alloy and lower residual
magnesium in the iron (see TI sheet No. 20).
13) Alloy sizing.
A wide alloy sizing gives dense bulk packing in the pocket. The alloy will then fuse and
react (dissolve) slowly in a controlled manner with a minimum of pieces floating. Lumps
floating and burning on the surface are a waste (see TI sheet No. 20).
14) Storage of foundry alloys.
All foundry alloys will oxidise if exposed to moisture. Oxidised alloys will give a lower
recovery than fresh materials. Containers of alloy should be stored in a dry place and not
opened until required at the treatment station (see TI sheet No. 1).
R e q u ir e d M g F e S i
a d d it io n w t %
1 .9
O x id is e d
M g - a llo y .
1 .8 T a p p in g
te m p . T im e b e tw e e n L a d le d e s ig n
M gFeSi add. d ia m e t e r : h e ig h t C a = 0 ,5 , heavy
1 .7 1 5 2 0 °C R e = 0 ,5
a n d t a p p in g
S = 0 .0 1 6
5 m in 1 :1
1 .6 none C a = 0 ,5
lo t o f
S = 0 .0 1 1 4 8 0 °C 2 m in som e 1 :1 ,5 som e
som e C a = 1 ,0
1 .5
good
c le a n
1 .4 fu rn a c e 30 s C a = 2 ,5
1 4 6 0 °C A llo y
C over 1 :3
S = 0 .0 0 6 S la g in C a = 2 ,5 fre s h
1 .3 fu r n a c e .
S u lp h u r - R e = 1 ,5
c o n t.
1 .2 C h e m ic a l
c o m p o s it io n
of M gFeSi
Factors that can influence the MgFeSi addition to a ductile iron ladle treatment process.
Appendix:
Checklist Recovery and Addition of Mg in Ductile Iron Ladle Treatment Processes.
Technical Information 23 - Appendix
Checklist - Recovery and Addition of Mg
in Ductile Iron Ladle Treatment Processes
For process improvements fill in information in the white fields.
To help you detect possible causes for sudden changes in Mg-recovery and needed Mg-
addition, fill in both white and grey fields.
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