Beruflich Dokumente
Kultur Dokumente
YNNO C. IGUT
June 6, 2015
I.
: 245
Area of Assignment
Direct Supervisor
Bienvenido Tanaman
1
Distillery Department
btanaman@scbiph.com
(+63) 917 543 8101
Jocelyn S. Sorrilla
Quality Control and Assurance Department
jsorrilla@scbiph.com
(+63) 917 300 5842
Jaymar J. Relota
Environmental Management Department
jrelota@scbiph.com
(+63) 922 454 1464
II.
sales agreement with Petron Corporation, the country's leading oil company and
gasoline retailer, for the supply of bioethanol. In addition to that, the company
also produces semi refined liquid sugar which is sold to sugar centrals in Negros
Occidental. The company also produces power (electricity), and contributes to the
Negros Occidental power grid using the bagasse of the sugarcane extracted from
the milling department. On a daily basis, SCBI processes a maximum of 1,500
tons of sugarcane to produce 125,000 liters of Bioethanol and generate a rated
capacity of around 7.4MW where at least 2.4 MWh is to be supplied to the power
grid. The production of both alternative and renewable energy is governed by
separate contracts, apart from those executed with other government agencies
under the Executive Branch.
SCBI uses sugarcane as their raw material during the first few years of
operation. Negros Occidental, being the sugarcane capital of the Philippines, is
strategically the best location to put up this plant. Situated at the San Carlos AgroIndustrial Economic Zone on the Eastern coast of Negros Occidental, SCBI takes
advantage of both favorable weather patterns and the best quality and yield in
sugarcane to supply the country's fuel and energy demands, in compliance with
the mandates of the Biofuels Act of 2006, otherwise known as RA 9367 and the
Renewable Energy Act (REA) of 2008, otherwise known as RA 9513. The
company has a fifteen (15) year agreement with three (3) local plantations for the
supply of the bulk of its sugarcane requirements and works with smaller
sugarcane planters and cooperatives for the balance of its feedstock requirements.
There came a time when the price of sugarcane rose up to the point where the
same amount of sugarcane can be bought for the same amount of bioethanol. The
company called this event as the perfect storm. The effects of this event is drastic
to the point where the company is almost at ground zero.
The company decided to modify the production of the company by using
another type of raw material which is molasses. Molasses is a viscous liquid
containing fermentable sugars which is the by-product of refined sugar
production. The company succeeded to restore profits and the Milling Department
which produces cane syrup intended mainly for fermentation is also gaining
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money by selling semi refined liquid sugar to sugar centrals around Negros
Occidental.
Majority of the shares of the company is owned by the Roxas Holdings
Incorporated. The new management just took over last May 2015.
III.
the different parameters of the process for all of which are carefully monitored in
the control room.
The supervisor also showed us the material balance for the multiple effect
evaporator (Figure 11).
Distillery Department
discussed.
A manual for the fermentation section was also handed so as to
study the different materials involved in the fermentation process
and its corresponding uses.
process.
The whole process was also toured together with the supervisor.
Other equipment present such as the plate heat exchangers (Figure
16) and the cooling towers (Figure 17) were also toured and the
uses of such were explained.
Weighing House
o A weighing bridge (Figure 21) is used to measure the weight of the
sugarcanes being delivered to SCBI. The weighing bridge is also used to
measure the incoming molasses and other materials (bagasse, salt, coconut
shells, etc.). We are tasked to weigh these materials and also placing the
results in the computer system.
measure the apparent purity and brix of the sample. Moisture content is
demand (COD).
Incoming Process Materials Section
o The IPM section involves the analysis of the molasses (sugar content, pH,
etc). Analysis of the sugar content was mainly done by Total Sugar as
Inverts analysis. The unfermentable sugar concentration was also analyzed
using the Unfermentable Reducing Sugar (UFRS) analysis procedure.
o It also involves the analysis of the moisture content of the wood fuels
being bought.
Fermentation and Distillation Section
o This section involves the analysis of the alcohol content, density and
moisture content of the samples from the different sections of the
distillation column. This also involves the total cell count of the
microorganism present in the fermenters.
o Analyzed in this section is also the amount of residual sugar (unfermented
sugars) in the fermenters in a specific time of the day.
Quality Assurance
o The QA lab involves the analysis of the denatured alcohol (pH, alcohol
content, acidity etc.)
inside the AD tank and the overflow were analyzed every hour.
This part of the training also involves the analysis of the Chemical
Oxygen Demand (COD) of the incoming spent wash and also the
exit wash from the AD tank and the Total Volatile Fatty Acids (T-
IV.
crushers first extract juice from the sugarcane without any additives. The
extracted juice from this part is called the absolute juice and is stored in the juice
tank. The bagasse (leftover fibers of sugarcanes) from the first extraction are
passed to the next set of fork crushers (second stage) in which they are mixed
with water so as to dissolve the remaining sugars. The principle of solid liquid
extraction can be applied in this part. The bagasse after the second stage is passed
again to another set of fork crushers (third stage) where pure water is further
added to increase the concentration gradient and extract more sugar from the
bagasse. Finally it is passed on to the fourth stage (Figure 6) where the exiting
bagasse is now fed to the boiler house so that it can be used as fuel for power
generation. It is really evident in the plant, that they make the most out of their
raw material.
The Milling department also includes the boiling house. The boiling house
also involves several processes. First, the extracted juice from the different stages
of extraction are placed in a heater for clarification purposes. Then the heated
juice is passed on to the liming tank where Calcium Oxide (CaO) is added also for
clarification purposes and so as to regulate the pH of the solution. The optimum
pH should be around 6.8-7.2. Then the solution is further heated to 100 oC and is
placed on an isothermal clarifier tank. At 100oC, the juice from the solution is
separated from the heavy solid particles also termed as mud. The juice from the
clarifier is termed as clear juice with sugar concentration of approximately 15
brix. Brix is a measure of the sugar content of the solution. The clarified juice is
now passed to the multiple effect evaporators with 5 effects (Figure 7). On the
other hand, the settled mud is passed through a rotary drum filter (Figure 9) in
which the filtrate is also fed to the evaporators. Using the concepts learned from
the academe, the filtrate has the same concentration as the clarified juice for they
are in equilibrium. This part of the process caught my interest for we have studied
theories and design parameters for rotary drum filters in ChE 425, Introduction to
Particle Technology and design for multiple effect evaporators in ChE 424, Heat
and Mass Transfer Processes. The type of evaporators used is a vertical tube
evaporator. It was not hard understanding the flow of process at this part because
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of the fact that this was discussed in my ChE 424 class. The aim of the evaporator
is to reach a syrup concentration of 65 brix by removing water from the clarified
juice. A brix spindle is used at the 5th effect to measure the brix of the overflow.
We also got the chance to look at the theoretical material and energy
balances prepared by the Design Engineer himself (Figure 11). The concept of
conservation is truly the governing principle for such design. It was not a simple
in and out process but there are many recycle streams placed to conserve energy. I
tried also to connect the diagram in the actual setting but it was definitely hard
especially because the piping systems are too hard to follow.
Distillery Department
The next department that I have been into is the distillery department
where I spent 77 hours. At first, I was introduced to the supervisor and the
operators of the section. The distillery department involves the fermentation and
the distillation section where each section is manned by a single operator and
guided by the supervisor. I was very excited since we have been designing
theoretical fermenters in ChE423, Engineering of Homogenous Chemical
Reactions and in ChE426, Introduction to Biotechnology. Also we have been
introduced to the basics of design for continuous distillation columns in ChE421N
Separation Processes.
The fermentation process involves the use of three culture vessels (CVs)
namely the CV-1, CV-2 and CV-3 (Figure 12). The higher the number the bigger
is the size of the culture vessel. The purpose of these vessels is for growth and
multiplication of the yeast used for fermentation, the Saccharomyces pombe. The
culture started from a 6 L Florence Flask in which the yeast activity is analyzed
through the microscope. It is then transferred to CV-1 containing diluted molasses
(~12-16 brix) with a retention time of approximately 10-12 hrs. CV-1 is also
fortified with nutrients for the yeast to thrive namely the Biocide, Urea (Nitrogen
source) and MgSO4 (Magnesium source). I have tried pouring the culture in CV-1
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and preparing the nutrient mix. After the retention time, it is expected that the
yeasts consumed the nutrients inside, have grown and multiplied so that they
should now be transferred to CV-2 for further multiplication and growth and then
to the CV-3. Each of the vessels before the growth and multiplication period must
be sterilized using steam. I have tried operating the sterilization part of the CV-3
and CV-2 and monitoring these operation through the computers in the control
room. It is actually good that each vessels are now automated for any changes in
the operating conditions (e.g. temperature, mixture level, etc.) can be closely
analyzed. The operators are very critical in the working conditions of the process.
Any deviations from the normal working conditions are immediately attended to.
After the sterilization, the culture media is prepared by filling the tank with
diluted molasses (~12-16 brix). Concentrated molasses is fed to the tanks (~85
brix) which is simultaneously added with water to obtain the desired
concentration. I have also tried preparing the molasses solution in the culture
vessels and sadly, the process is trial and error. Water is fed with the molasses and
then measuring its brix in a specified volume. We have suggested to make mass
balance around the culture vessels so as to know the theoretical amount of water
and molasses needed and they said that they will take it into consideration.
The yeasts from the CV-3 are then transferred to two pre-fermenters (PFs)
working in parallel. Then after the specified retention time, the contents from PF1
and PF2 (Figure 14) are transferred to the Fermenter 1. There are actually two
fermenters coined as F1 and F2 (Figure 15) both having a capacity of 1,250 m 3
(1,250,000 L). The method of introducing the solution in F2 is by cascading
motion, meaning the solution in F1 will enter a pipe connecting F1 and F2 once
the contents in F1 reaches a certain level. A syrup tank was constructed initially
for storage of syrup but since the raw material for fermentation is now molasses,
the syrup tank is converted into another fermenter namely F3. The solution from
F1 and F2 will also cascade to F3. All fermenters have a retention time of
approximately 36-48 hours. The solution from these fermenters is then transferred
to the buffer tank and is passed to the yeast separators and then to the storage tank
for distillation.
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The distillation process for me is one the processes that I look forward to
seeing in the actual scale. The distillation process in SCBI is continuous.
Honestly, I expected that the stripping and rectification part is connected in a
single column yet in SCBI, it is separated. In the academe also we are used to
designing distillation columns with 20 stages at maximum yet the number of
stages in the stripping section alone is 72. The distillation process also kept true in
its schematic diagram in the sense the condensers are located at the top and the
reboilers at the bottom except for the reflux tank which is located at the bottom. It
was interesting exploring the distillation columns and tracing the entry and exit of
materials involved in the process. The actual setting is really harder but the
principles governing the process is still the Vapor-Liquid equilibria of ethanol and
water mixture. This was also emphasized in the explanation of our supervisor. The
distillation section has 4 columns in order namely the primary column,
dealdehyde column, the rectification column and the recovery column (Figure
14). One smart thing in the distillation section for me is that the process ends in a
molecular sieve which uses ceramic zeolites with pores small enough to trap
water moisture and recover ~99.8% of absolute ethanol. I have also seen the
material and energy balances around the column and what amazed me is the
actual conservation of energy specifically the heat energy. For example, the heat
from the vapor output of another column is used to heat the incoming solution in
the reboiler. This in return condenses the vapor product. The true sense of
conservation and economics is observed in the distillery.
The experience was also amazing because the manager treated us like
regular analysts. She reprimands us whenever we missed out on important points
during the analysis which in a way is very helpful so that we will never make the
same mistakes again. Not all analysts in the QC/QA department are Chemistry
majors but they are very critical on their analysis.
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The Manager discussed to us the design for the Anaerobic Digester tank
(Figure 25). The design as I quote from him is the first and last because it is not
the usual AD design. Instead of a single room tank, the inside is divided into five
compartments. The AD however does not function the way it should have as it
was originally designed. Some modifications were done so that the AD can
function like an Upflow Anaerobic Digester Tank (UASB). This goes to show that
equipment designs can change from time to time depending on the significance
and efficiency of operation.
During a specific time, we get samples from the AD tank to analyze its
volatile fatty acids (VFA) content, chemical oxygen demand (COD) and
alkalinity. These factors are important for the flow rate of waste into the AD is not
constant and will depend on these factors. For example, if the VFA content is
high, the flowrate should be decreased for the acidogens will produce more acids
that the methanogens cannot accommodate. This can also lead to a decrease in pH
which the methanogens are sensitive to.
I have also learned in EMD the importance of teamwork in accomplishing
tasks. The manager itself is very hands on in the actual operation.
V.
Recommendations
SCBI includes a boiler house which generates power from the dried bagasse in
the mill. Sadly, we havent got the chance to explore this part of the plant. I would
strongly recommend that the boiler house can also be toured by ChE students for
energy generation is also a field in which Chemical Engineers can be an expert of.
Also, I would like to recommend handing out OJT manuals where the different
processes and equipment of the plant are there for reference.
SCBIs OJT program is really good. The fact that I was exposed in almost all
of the processes in the industry further strengthened my knowledge in Chemical
Engineering. I strongly recommend this company to the future practicums.
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Lastly, I believe that my training from the University of San Carlos has been
an enormous help in understanding the different processes in SCBI. The things
going on in the different equipment and analysis are not that hard to understand
because of the theories learned in the academe.
VI.
Annexes
17
18
Figure
Figure
9. Rotary
7. Multiple
Drumeffect
Filter evaporators (5 effects)
Figure
Figure10.
8. Evaporator
Mill and Boiling
window.
house control room
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Figure 11. Theoretical Mass Balance along the multiple effect evaporators.
Distillery Department
Fermentation Section
1
2
20
Distillation Section
21
22
QC/QA Department
Figure 19. Bioethanol storage tanks.
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24
25
26
27
Figure 32. Storage lagoons for the clarified wastewater from the
boiler house. Organic matters left in the wastewater undergo
natural decomposition. Once treated, it is recycled back to the
cooling towers.