Beruflich Dokumente
Kultur Dokumente
of ThyssenKrupp
Technologies
Uhde
ThyssenKrupp
Urea
Table of contents
Page
1.
Company profile
2.
Introduction
3.
3.1
Synthesis
3.2
12
3.3
13
3.4
14
3.5
16
3.6
17
4.
18
5.
22
6.
Recent references
23
A fruitful partnership
Fertilisers are used worldwide in agriculture to secure world food
supplies and to reclaim barren and uncultivated land.
Uhde provides the necessary prerequisites for this with its
ultra-modern large-scale plants and economical processes
for the production of fertilisers.
1. Company profile
With its highly specialised workforce of more than 4,900 employees and its
international network of subsidiaries and branch offices, Uhde, a Dortmund-based
engineering contractor, has, to date, successfully completed over 2,000 projects
throughout the world.
Uhdes international reputation has been built on the successful application of
its motto Engineering with ideas to yield cost-effective high-tech solutions for its
customers. The ever-increasing demands placed upon process and application
technology in the fields of chemical processing, energy and environmental protection
are met through a combination of specialist know-how, comprehensive service
packages, topquality engineering and impeccable punctuality.
2. Introduction
Uhde has been a renowned partner in the engineering and construction of urea plants for more
than four decades. Plants built by the company
are located all over the world, some in regions
with extreme climatic conditions.
In the last eleven years Uhde has boasted a
further landmark in its fertiliser plant business:
Twelve new fertiliser plants with a total annual
urea capacity of over nine million tonnes have
been constructed and commissioned.
A milestone for Uhde was the large QAFCO 4
fertiliser complex for Qatar Fertiliser Company
(QAFCO), Mesaieed. This complex was successfully started up in 2004, making QAFCO the
world's leading urea producer at a single location.
Now, the SAFCO IV fertiliser complex, commissioned for Saudi Arabian Fertilizer Company
in Al Jubail in 2006, has an even higher urea
capacity. It comprises one of the world's biggest
urea synthesis plants as well as the biggest ever
single-train urea granulation plant.
2 NH3
ammonia
++
NH44O
+
CO2
exothermic carbon dioxide
H22N
H22N
H22N
C O
ammonium carbamate
endothermic
C O
H22O
water
water
urea
Reaction sequences
in the urea process
NH3
Synthesis
Urea
reaction
CO2
Carbamate
condensation
Carbamate
recycling
CO2 stripping
Low-pressure
recirculation
Evaporation
Prilling or
granulation
Urea product
Desorption and
hydrolysis
Purified process
condensate
3.1 Synthesis
Recirculation
Evaporation
13
19
7
11
5a
15
14
18
20
10
Recycling
from
granulation
4
2
NH3
CO2
Air
12
1.
2.
3.
4.
5.
5.a
5.b
6.
7.
7.a
Gases
Liquids
Urea
Steam /cooling water
16
CO2 compressor
H2 removal reactor
HP ammonia pump
HP heat exchanger (stripper)
HP carbamate condenser (HPCC)
Pool condenser
Pool reactor
Reactor
HP scrubber
HP scrubber sphere
8.
9.
10.
11.
12.
13.
14.
15.
16.
LP absorber
Dissociation heater and separator
LP carbamate condenser
Level tank for LPCC
HP carbamate pump
Atmospheric absorber
Flash tank
Pre-evaporator
Urea solution tank
7a
NH3
3
5b
4
2
CO2
Air
4
NH3
CO2
Air
3
1
17 21
11
Purified
process
water
30
23
24
22
25
33
Recycling
to
evaporation
32
29
34
Urea
granules
UF
27
26
31
28
Air
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
Air
Air
12
13
14
Easy maintenance
The limited amount of equipment and the plants compact arrangement
greatly facilitate plant maintenance.
Furthermore our layout guarantees easy access for servicing and
maintenance with all rotating equipment located at ground level.
On-stream time
15
Process Efficiency
The process conditions in the CO2 stripping process result in an
optimum conversion of both reactants eliminating the need for an MP
recirculation section and a pure ammonia recycle.
Stripping with CO2, which is much less soluble in urea than NH3,
contributes substantially to the extremely low recycle rates.
CO2 and NH3 consumption is reduced to almost
stoichiometric values by continually improving the process with
respect to emissions.
Low corrosion
The aggresive nature of the process media means that the
process with the lowest temperature will ultimately create the least
corrosive conditions.
Unique preventive process conditions and application of the best
available construction materials minimise corrosion and achieve
outstanding on-stream factors. No need for elaborate zirconium or
titanium materials.
Low emissions
The low NH3/CO2 ratio reduces the content of free ammonia in the urea
solution, thereby minimising ammonia emission in the finishing section.
The application of state-of-the-art technology for treating
gaseous and liquid effluents ensures minimal environmental impact.
The result: a purified process condensate that can be reintroduced
as make-up water for cooling water or as boiler feedwater.
Simple operation
The process involves far less equipment and fewer process steps
than competitive processes and, with its unique measurement of the N/C ratio
using an advanced density meter, operational comfort is always ensured.
We take full advantage of the advances in computer control technology
and supply advanced process control systems to suit the needs of your
operators.
To facilitate process handling even further, we also provide operator
training on process simulators.
Blocking-in the synthesis loop during plant shutdown (up to 72 hours)
greatly facilitates restart and enables a rapid return to production.
Uhdes newly-introduced high-pressure centrifugal pumps in ammonia
and carbamate service, developed together with Flowserve (Irving, USA),
have more than lived up to expectations: In operation at the QAFCO 4 plant
since late December 2004, they have proved themselves to be highly reliable
and to require minimal maintenance.
16
Stamicarbons granulation
technology
In 1995 Stamicarbon introduced its patented granulation
technology, which was developed in the 1970's and 1980s.
This technology, first applied
by Uhde for three grass-roots
plants in Egypt, can be offered
as an alternative.
17
Flexibility
Its outstanding flexibility permits
virtually all requested product
size distributions, from an average diameter of 2 - 7 mm, to
be produced in the same plant
without interrupting operation
for size change. The granulation unit provides simple startup and shutdown procedures
and a turndown ratio which is
40 % of the nominal capacity.
On-stream time
The inherent reliability of the
process is largely due to the fact
that the granulators have no
moving parts, the blowers and
fans are only used for the treatment of ambient or scrubbed
air and no belt conveyors are
required to transport solids
within the granulation unit.
Emissions
Efficient, cost-effective scrubbing technology is used to
recover the valuable product
and to meet the most stringent
environmental requirements.
Large single-train capacities
With its compact granulation
unit the process is the ideal
choice for large single-train
urea production plants. The
granulation units for SAFCO IV
in Saudi Arabia and QAFCO 4
in Qatar are excellent examples with their capacities of
3,600 mtpd and 3,500 mtpd
of urea granules, respectively.
Product quality
High-quality granules with a
well-rounded shape, which are
very hard and particularly
resistant to crushing and abrasion, making them dust-free,
non-caking and completely
free-flowing.
High efficiency
With its sophisticated product
size selectivity, the granulator
minimises both the urea recycle
and the load for the evaporation
section.
18
NH3 (100 %)
CO2 (100 %)
kg
kg
kg
m3
kWh
kg
Product quality
N content
Biuret content
Moisture content
Formaldehyde content
Crushing strength
Particle size (typical):
wt.%
wt.%
wt.%
wt.%
kg
%
ppm by wt.
ppm by wt.
mg/Nm3
mg/Nm3
564
730
860
88
58
4.5
46.2
0.8
0.2
0.45
3.0 (3.0 mm )
90 (2.0 - 4.0 mm )
1
1
30
30/140
(1)
(2)
With/without acidic scrubbing, which generates a small quantity of ammonium sulphate or ammonium nitrate solution.
All consumption figures are per metric ton of final product and serve as general information only.
Local conditions may have a considerable influence on the performance figures.
19
20
21
22
Project management
www.uhde.biz
6. Recent references
23
E
P
C
Com- Customer
pletion
Plant Site
Plant
Process
Capacity
2010
Arzew,
Algeria
Urea plant
Granulation
Urea solution
Urea granules
Damietta,
Egypt
Urea plant
Granulation
Stamicarbon Turnkey
Stamicarbon
Damietta,
Urea plant
Egypt
Granulation
Helwan,
Urea plant
Egypt
Granulation
Ain Sukhna/Suez,Urea plant
Egypt
Granulation
Alexandria,
Urea plant
Egypt
Granulation
Al Jubail,
Urea plant
Saudi Arabia
Granulation
Urea solution
Urea granules
Urea solution
Urea granules
Urea solution
Urea granules
Urea solution
Urea granules
Urea solution
Urea granules
1,925 t/d
2,000 t/d
1,925 t/d
2,000 t/d
1,925 t/d
2,000 t/d
1,925 t/d
2,000 t/d
3,250 t/d
3,600 t/d
Stamicarbon
UFT
Stamicarbon
Stamicarbon
Stamicarbon
Stamicarbon
Stamicarbon
Stamicarbon
Stamicarbon
UFT
Tecen,
Turkmenistan
Mesaieed,
Qatar
Bintulu,
Malaysia
Urea solution
Urea granules
Urea solution
Urea granules
Urea solution
Expansion by
Urea granules
Expansion by
Urea solution
Expansion by
Urea granules
Expansion by
Urea solution
Urea granules
Urea solution
1,050 t/d
1,050 t/d
3,200 t/d
3,500 t/d
2,250 t/d
446 t/d
2,400 t/d
550 t/d
3,000 t/d
1,000 t/d
3,000 t/d
800 t/d
1,925 t/d
2,000 t/d
740 t/d
Stamicarbon
UFT
Stamicarbon
UFT
Stamicarbon
Urea granules
950 t/d
Urea plant
Granulation
Urea plant
Granulation
Urea solution
Urea granules
Urea solution
Urea granules
2,000 t/d
2,000 t/d
1,925 t/d
2,000 t/d
Geleen,
Urea plant
The Netherlands
Belle Plaine,
Urea plant
Canada
Granulation
Urea solution
for UAN
Urea solution
Urea granules
Expansion by
Urea solution
Urea granules
Urea prills
Expansion by
1,150 t/d
2010
2008
2007
2006
2006
2006
2004
2004
2004
Orascom Construction
Industries for Sonatrach
Orascom Fertiliser
Company (Sorfert)
Egyptian Agrium
Nitrogen Products Co.
SAE (EAgrium)
Misr Oil Processing Co.
Helwan
Fertilizer Co.
Egyptian Fertilizer
Co. (EFC II)
Alexandria Fertilizer Co.
(AlexFert)
Saudi Arabian
Fertilizer Company
(SAFCO IV)
Turkmendokunhimiya
via Gap Insaat
Qatar Fertilizer
Company (QAFCO 4)
ASEAN Bintulu Fertilizer
Sdn Bhd (ABF)
Urea plant
Granulation
Urea plant
Granulation
Urea plant
Granulation
2003
Urea plant
Granulation
2000
1999
Egyptian Fertilizer
Co. (EFC I)
Incitec Ltd.
1998
1998
1998
1997
1997
Qatar Fertilizer
Company (QAFCO 3)
Ultrafertil
1996
Ain Shukna/
Suez, Egypt
Gipson Island,
Australia
Donaldsonville,
USA
Alexandria,
Egypt
Mesaieed,
Qatar
Araucaria,
Brazil
Urea plant
Granulation
Urea plant,
evaporation
Granulation
Urea plant
Granulation
Urea plant
Prilling
Licensor or
Know-how
Engineering
Procurement
Construction
3,450 t/d
3,450 t/d
2,850 t/d
2,850 t/d
850 t/d
2,000 t/d
2,200 t/d
1,975 t/d
475 t/d
Contract
Project Notes
Stamicarbon E, P
UFT
Turnkey
Turnkey
Turnkey
Turnkey
Turnkey
Pool condenser
E, P
Pool reactor
Turnkey
Pool condenser
E
2. Expansion
UFT
Stamicarbon E
Expansion
UFT
Stamicarbon Turnkey
UFT
Stamicarbon Turnkey
In cooperation
UFT
with Shedden
Uhde
Stamicarbon E, P
UFT
Stamicarbon Turnkey
UFT
Stamicarbon E, P
Pool reactor
Stamicarbon E
UFT
Expansion
Stamicarbon Turnkey
UFT
Stamicarbon E, P, C
Expansion
PDF 22.1.2009