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abstract
Article history:
The effect of waste paper on biogas yield produced by co-digesting fixed amount of cow
dung and water hyacinth in five digesters AeE was studied at room temperature. Waste
paper was observed to improve biogas yield in digesters BeE with digester A acting as the
6 December 2010
control. However, as the amount of waste paper increased the biogas yield was observed to
decrease. Kinetic model based on first order kinetic was derived to estimate the maximum,
ultimate, biogas yield and also the ultimate methane yield from these biomass mixtures.
The maximum biogas yield estimated using this model for digesters BeE were 0.282, 0.262,
Keywords:
0.233, and 0.217 lg1 VS fed with goodness of fit (R2) of 0.995, 0.99, 0.889, and 0.925
Anaerobic
respectively, which were obtained by fitting the experimental biogas yield ( yt) against (exp
Biogas yield
(kt)1)/exp(kt). The ultimate biogas and methane yield at very low batch solid load were
extrapolated to be 0.34 and 0.204 lg1 VS fed respectively. In essence, the addition of waste
paper in the co-digestion of cow dung and water hyacinth can be a feasible means of
Waste paper
improving biogas yield and also alternative means of recycling waste paper. Furthermore,
the kinetic model developed can compliment other models used in anaerobic digestion of
agricultural and solid waste.
2010 Elsevier Ltd. All rights reserved.
1.
Introduction
b i o m a s s a n d b i o e n e r g y 3 5 ( 2 0 1 1 ) 1 3 4 5 e1 3 5 1
2.
The materials used for this experiment were cow dung, waste
paper, and water hyacinth. Pre-treatment operations involved
weighing about 500 g of freshly harvested water hyacinth and
allowing it to sun-dry for a period of 30 days, after which they
were oven-dried. This oven-dried water hyacinth was then
ground to fine particles using a grinding mill. Similar operation
was applied to the waste paper. Standard methods were used
for waste paper and water hyacinth measurements [11] with
respect to the total and volatile solids. The cow dung was sun
dried for a period of 20 days to preserve its microbial population
and then crushed mechanically using a mortar and pestle.
2.1.
Preparation of digesters
3.
3.1.
b i o m a s s a n d b i o e n e r g y 3 5 ( 2 0 1 1 ) 1 3 4 5 e1 3 5 1
Total
solids (%)
pHb
pHa
Cumulative
biogas (L)
k (day1)
3.846
5.303
6.716
8.088
10.70
7.49
10.91
14.53
17.79
24.67
7.18
6.81
6.71
6.69
6.41
7.96
7.57
7.35
7.40
7.35
0.320
0.720
0.842
1.052
1.110
0.00795
0.00434
0.00401
0.00390
0.00336
A
B
C
D
E
a After experiment.
b Before experiment.
dC
Qo Co Qo C VR rC
dt
(1)
VR
dC
VR rC
dt
(2)
(3)
(4)
This equation generally relates to substrate (biomass) biodegradability with no information about the biogas yield. However,
a correlation between substrate biodegradability and biogas
yield at any time ( yt) can be developed assuming all substrate
(biomass) are converted into biogas as shown in Fig. 3 [8],
although, in reality all substrate may not be converted to biogas.
From the correlation it can be deduced that,
Co Ct
yt
Co
ym
(5)
and
Co
ym
Ct ym yt
(6)
(8)
b i o m a s s a n d b i o e n e r g y 3 5 ( 2 0 1 1 ) 1 3 4 5 e1 3 5 1
Co
ym - yt
Biogas yield
ym
Substrate
C o - Ct
yt
C(t)
t
time (t)
(9)
3.2.
Application of kinetic model in the estimation of
maximum biogas yield
(10)
So that
p 1 ekt
(11)
1349
3.3.
Application of kinetic model in the estimation of
ultimate biogas ( yL) yield
The ultimate biogas yield which is the maximum biogas yield
obtainable at solid loading very close to zero was determined
by plotting the total solids (%) and/or waste paper addition
(% of total solids) against their corresponding maximum
biogas yield observed in the various digesters (Fig. 9).
The relationship between the percent of total solids fed
into the reactor and the maximum biogas yield for reactor B,
(12)
(13)
b i o m a s s a n d b i o e n e r g y 3 5 ( 2 0 1 1 ) 1 3 4 5 e1 3 5 1
3.4.
1
Vdigester
3
(14)
Rearranging,
3Vgc Vdigester
(15)
But
Vgc yt $m
and
(16)
yt
kt
e 1
ym
kt
e
(17)
(18)
rThus,
kt
e 1
ym $m
Vdigester 3
kt
e
(19)
Hence, for a given value for k and ym, the volume of the
batch reactor can be estimated for any retention time
required. For example the plot of Vdigester against various
retention times for digesters B, C, D and E (Fig. 10) showed that
2.2, 2.4, 2.7 and 3 L reactors would be required to contain the
reaction process and biogas produced for retention period of
62 days respectively. Similar, capacity in cubic meter is
possible depending on the solid loading.
This means, that 0.73, 0.8, 0.9 and 1.0 L of biogas was
produced by digester B, C, D and E respectively. These estimated
values approximate reasonably with the volume of biogas
obtained experimentally (Table 1). A safety factor between 1.05
and 1.2 may be used for final correction when designing batch
reactor for these biomass types at room temperature.
4.
Conclusion
references
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