Beruflich Dokumente
Kultur Dokumente
CORRDATA SYSTEM
REFERENCE MANUAL
CORRDATA Basic Software for use with RDC-CORROSOMETER,
RDC-CORROTEMP CORROSOMETER, RDC-CORRATER,
RDC-CORROTEMP CORRATER, CORROSOMETER, CORROTEMP
CORROSOMETER, and CORRATER probes
Contents
Contents
Chapter 1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Chapter 2 Specifications . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
RDC Units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
CORRDATA Mate I & II . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
PC Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Chapter 3 Installation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Unpacking . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Installing an RDC Unit on a Probe . . . . . . . . . . . . . . . . . . . . . . . 10
Intrinsic Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
CORRDATA Mate I & II . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
CORRDATA Basic PC Software . . . . . . . . . . . . . . . . . . . . . . . . 18
25
32
33
41
45
45
47
48
Contents
72
74
77
78
80
81
82
Chapter 8 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
RDC Units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
CORRDATA Mate I & II . . . . . . . . . . . . . . . . . . . . . . . . . . . .
PC CORRDATA Software . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Software Revisions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
ii
85
85
86
86
Contents
Chapter 9 Troubleshooting . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
RDC Unit Power Check . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Checking Functional Operation of RDC
with Mate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Mate I & II . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Checking Mate II Operation on Probes . . . . . . . . . . . . . . . . . . . .
Mate I & II Self Check System Reprogramming Utility . . . . . . . . .
PC. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
If Problems Still Occur . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
89
89
95
95
95
96
96
iii
Contents
Figures and Drawings
Figure
Page
1.1
1.2
3.1A
3.1B
3.2A
3.2B
3.2C
3.3
3.4
3.5
4.1
4.2
5.1
5.2
5.3
5.4
5.5
5.6
iv
Contents
5.7
6.1
6.2
Contents
Figures and Drawings (continued)
6.3
6.4
7.1
7.2
7.3
7.4
7.5
7.6
7.7
7.8
7.9
vi
Chapter 1
Introduction
Chapter 1 Introduction 3
CORROTEMP CORRATER units have a corresponding range of time intervals from 30 minutes
to 24 hours.
The Mate II also automates direct reading and logging of probes, without an RDC. This avoids
potential errors from incorrect recording of readings.
A basic CORRDATA software package is included free of charge with the Mate I & II for DOS
based PC's. This copyrighted software provides for system configuration, storage and
manipulation of the corrosion data.
Chapter 2
Specifications
RDC Units
Electronics
RDC - CORROSOMETER
CORROSOMETER probes
Battery Life:
unit
(RDC-CO)
compatible
with
Reading Storage:
RDC - CO: 2048 Readings
RDC - COT: 1024 Readings
RDC - CA: 1024 Readings
RDC - CAT: 512 Readings
all
Mechanical
Battery Powered:
6 x AA Alkaline cells - Typical life 10 hours continuous reading only
RDC's
6 hours continuous reading only probes (Mate II only)
Chapter 2 Specifications 7
Mechanical
Splash-proof enclosure
Environmental
Temperature range:
Operating - 0oF to 122oF ( -18oC to 50oC )
Storage
- 0oF to 150oF ( -18oC to 70oC )
PC Requirements
IBM PC or compatible
640k memory
MS DOS 3.3 or higher operating system ( MS DOS 4.01, 5.0, 6.0 or 6.2 preferred)
Serial port available (adapter cable provided for easy access to Mate I & II cable)
Chapter 3
Installation
NOTE: Your CORRDATA system components were carefully tested,
inspected and packaged prior to shipment. Before unpacking the
instruments, please inspect the packaged materials for shipping
damage and retain damaged packaged materials to support any claim
against your freight carrier should this become necessary.
Unpacking
Carefully remove the instruments from their packages. Included in the package you should
find:
RDC unit in NEMA 4 wall mounting enclosure with integral 10 foot probe to
instrument cable and probe connector.
Battery pack (mounted inside the RDC).
Chapter 3 Installation 11
Chapter 3 Installation 13
Chapter 3 Installation 15
WARNING! Care should be taken to see that any regulations
that exist in your area regarding the shipment and disposal of
lithium batteries are met. See Appendix D for further details and
Materials Safety Data Sheet (MSDS) for the battery pack.
Intrinsic Safety
The probes, RDC units, and Mate I & II systems have intrinsic safety ratings for use in
electrical hazardous area environments. Applicable certifications are identified on the
System components according to units ordered.
The intrinsically safe system has been certified with a rating of EEx ia IIC T4 at
temperatures of up to 500C. For temperatures from 500C to 700C the rating is EEx ia
IIC T3. This means that the system is safe for use in the severest of electrical hazardous
areas, where explosive gases are always present (Zones 0, 1, and 2; Divisions 1 and 2,
all groups) even with up to two fault conditions (designated by ia).
The gas classification IIC is the most stringent including gases such as acetylene and
hydrogen. This part of the rating relates to the spark energy that is required to create an
explosion.
Gases have a separate classification for explosive tendency based on hot surface
temperatures which are not necessarily the same as the spark ignition energy. The
temperature rating T4 indicates that no temperature of the equipment exceeds 1350C at
500C even under fault conditions. This rating includes all listed gases except carbon
disulfide (which requires T5 rating)
Care must be taken with intrinsically safe systems to maintain their carefully designed
integrity. The major features to note are as follows:
1. Mate I or II batteries must be replaced in a safe area.
2. Only the correct RDC batteries must be used, since they have integral
current limiting devices to permit their replacement in the hazardous area.
3. Only the intrinsically safe "Mate to PC" cable should be used between the
Mate I or II and the PC even though this is in the safe area. This prevents
any excess power from being passed onto the Mate II, which could then be
carried into the hazardous area.
4. Absolutely no substitution of parts or unauthorized repairs must be
undertaken or the certifications are rendered invalid.
Chapter 3 Installation 17
ROHRBACK COSASCO
SYSTEMS
Read
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
IBM PC or compatible.
640 K memory.
Hard disk.
MS-DOS 3.3 or higher operating system (MS-DOS 4.01, 5.0, 6.0 or 6.2
preferred).
The CORRDATA basic software package is included with the CORRDATA Mate unit
on 3 " diskettes.
To install the CORRDATA software, place the appropriate diskette in your floppy
drive. At the DOS prompt, change the drive to this floppy and type install. The
program gives the choice of the directory where the files are to be installed and the
serial port COM1 or COM2 to be used. Follow the on-screen instructions.
The default for the directory is CORRDATA installed in the root directory on the C
drive.
When the installation is complete, remove CORRDATA Software diskette and save as
a backup.
For users of Microsoft Windows it is possible to run the CORRDATA Software as a
DOS application under Windows. Set the Command line to CD2 as applicable and set
the working directory to CORRDATA. See the Windows manual for details.
To commence the program in DOS select the CORRDATA directory and then type
"CD2". If using Windows double click on the Icon for CORRDATA.
Fit the "Mate to RDC" cable to the Mate I or II and connect it via the "Mate to PC"
cable to the required serial port, COM 1 or COM2, of your PC. The "Mate to PC"
cable brings the Mate I or II to PC connection to the front of the PC for ease of use. On
intrinsically safe units this cable also includes special isolation components.
Chapter 3 Installation 19
The serial port on the PC has either a 9 pin or 25 pin connector. If it has a 9 pin serial
port, you will need to use the 25 pin to 9 pin adaptor supplied with the cable assembly.
21
Chapter 4
System Overview
RDC's-Remote Data Collectors
There are several versions of RDC's including a CORROTEMP temperature measurement
unit. The options and capabilities for CORROSOMETER and CORROTEMP
CORROSOMETER units are as follows:
PROBES
CORROSOMETER (CO)
RDC UNIT
Metal Loss
Temp
Metal Loss
Temp
RDC-CO
YES
NO
YES
NO
RDC-COT OR RDC4-COT
Configured as RDC-CO
YES
NO
YES
NO
RDC-COT or RDC4-COT
Configured as RDC-COT
YES
-200C 1
YES
YES
For CORRATER and CORROTEMP CORRATER systems the options and capabilities
are as follows:
PROBES
CORRATER (CA)
RDC UNIT
Corrosion
Rate
Imbalance
RDC-CA
YES
RDC-CAT
Configured as RDC-CA
RDC-CAT
Configured as RDC-CAT
1
Temp
Corrosion
Rate
Imbalance
Temp
YES
NO
YES
YES
NO
YES
YES
NO
YES
YES
NO
YES
YES1
-200C 1
YES
YES
YES
A typical RDC CORROSOMETER entry screen is shown below in Figure 4.1, and a
typical metal loss graph output is shown in Figure 4.2
25
Chapter 5
System Configuration Procedures
System Configuration from the PC
System configuration is easily accomplished on the PC with CORRDATA basic software.
This configuration is subsequently downloaded to your Mate I or II and then to any RDC's
being used. Additional probe location information may also be stored on the CORRDATA
software, but is not transferred to the Mate I or II.
To commence system configuration on the PC, select the CORRDATA directory in which
the CORRDATA program is located and type CD2. Press Enter to clear the RCS
CORRDATA introduction screen, and display the main menu. Help screen information
is available via the F1 key for the menu items.
For this first time configuration, or for new additions to the existing list, select NEW to
display the sub-menu of input selections.
ID Number
Type
Span
Reading Interval
(Range 1 to 50)
(See Probe or Figure 5.6)
(See Probe or Figure 5.6)
(See "Choosing Probe Reading Frequency"
in Chapter 5)
Use the 8 or 9 keys to move between the highlighted entry fields. Press the Enter key to
gain access to the data entry box. Type in the required data, using the backspace, 6 or 7
arrows, or delete keys as necessary. For fields with pre-selected values use the 6 or 7
arrows. When a field entry is correct, press Enter to complete.
The entry screens for each type of probe are similar except as noted below:
Probe Tag
ID No.
Location
Model
Number
Alloy
This is the field for identification of the probe element alloy for
CORROSOMETER and CORROTEMP CORROSOMETER probes or the
probe electrode alloy for CORRATER and CORROTEMP CORRATER
probes. Typically the UNS alloy code is used such as K03005 for pipe
grade carbon steel. Alternatively Carbon Steel, 304 SS, Monel 400, or
other appropriate alloy references may be used if within the 8 character
maximum.
Type
Multiplier
Alarm
Rate
Reading
Interval
This entry only applies to probes using an RDC, and sets the frequency
with which readings will be taken automatically by the RDC unit. For
information on the selection of the most suitable interval see "Choosing
Probe Reading Frequency" later in this chapter. For the CORRATER or
CORROTEMP CORRATER probe, the only minutes selection is 30
minutes. Shorter times are not permitted since under some operating
conditions cycle times of up to 30 minutes are required to obtain accurate
measurements. For RDC4-COT multiplexer units the minimum time that
MUST be set is 15 minutes. If set to a shorter time it will default to 15
minutes when configuring the RDC4-COT.
Once all the necessary information has been completed on this screen and is correct, press
F2 to save the information. This will then return to the configuration mode - input
selection Figure 5.3.
Repeat the procedure with the next probe or probe/RDC entry until all the necessary entries
have been completed. When the final entry has been saved, use the Esc key as necessary
to move back up the menu tree.
To edit any of the entries, select Configure from the main menu to display the existing
probe list summary. Use the arrow keys to move the highlight bar to the required probe.
Select Edit from the menu bar. The information entry screen will appear which may then
be edited as required and saved with the F2 key. If you wish to exit without making any
changes use the Esc key.
WARNING! Editing is primarily for use at initial configuration.
Changing probe type, span, multiplier, or time interval after data
ROHRBACK COSASCO
SYSTEMS
Read
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
RDC
Route
EXIT
>
>
>
>
F1
F2
F3
F4
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Press START (F1) to commence the configuration information transfer from the PC to the
Mate I or II. During this process the Mate I or II will display the following message:
>
>
>
>
F1
F2
F3
F4
On completion of the configuration the CORRDATA Mate will display the message:
Mate Configured
EXIT
>
>
>
>
F1
F2
F3
F4
Press the red OFF key on the Mate I or II to switch off the unit, and disconnect it from the
serial cable assembly to the PC. The Mate I or II is now configured ready to transfer the
configuration information to any probe/RDC units. Now for the Mate II only, the clock
must be set on the Mate II before it can gather readings directly from probes without
RDC's, as described in the next section. This is required so that the probe readings are
correctly date and time stamped. For probes with RDC units, the controlling clock is in
the RDC and is set by the Mate I or II as described in the section "Configuration of the
RDC" later in this chapter. Exit the CORRDATA PC software if required with the Esc key
and Quit from the main menu.
To configure the RDC units with the CORRDATA Mate see "Configuration of the RDC"
later in this chapter.
2.
After the self test screen clears, press: SetUp (F4); Mate (F1); MANUAL CONF
(F1); SET TIME (F2); SET (F2). Enter the date and time in the format indicated:
Read
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
Mate
Configuration
Options
Phone
RDC Timer
EXIT
>
>
>
>
F1
F2
F3
F4
Select Configure Mate (F1) to program the probe data into the Mate II which will be
used to configure any probes with RDC's. The following screen will be displayed:
Mate Configuration
AUTO MANUAL NEW
CONF CONF PROBE EXIT
>
>
>
>
F1
F2
F3
F4
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
The system has a capacity of up to 50 probes per route. Each probe or probe with RDC
is identified by its allocated ID number.
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
There is a provision for 12 alpha numeric probe identification or tag number characters.
Enter the required designation and press ENTER (F1).
NOTE: Different cursors indicate either alpha or numeric
entries (See Figure 3.5). Use the alpha/numeric keyboard
button to toggle between the modes as required.
NOTE: Additional descriptive probe information such as
company name, location, etc., may only be added on the PC
program, but not on the Mate II.
The next screen involves setting the frequency with which readings are taken if an RDC
is used.
On the RDC CORROSOMETER unit or RDC CORROTEMP
CORROSOMETER unit the options are intervals of 5, 10, 15, and 30 minutes, or 1, 2,
3, 4, 6, 8, 12 or 24 hours. For the RDC4-COT multiplexer unit this MUST NOT be set
less than 15 minutes. For the RDC CORRATER unit or the RDC-CORROTEMP
CORRATER unit the hourly settings are the same but the minute setting is limited to
30 minutes due to the automatic cycle time of the unit required for the measurement.
For choice of the most appropriate interval see "Choosing probe reading frequency",
later in this chapter. For the Mate II, if the probe to be read does not have an RDC
enter 0 and press ENTER (F1).
WARNING! Do not select a Mate I unit to read probes
since the unit does not have this capability.
The first of the two selection screens shows the hourly selections.
>
>
>
>
F1
F2
F3
F4
Either enter the number of hours required from the keyboard, using the CLR (F2) if
required and then press ENTER (F1), or press mins (F3) for selection of a minutes
range in which case the display will show the following for an RDC
CORROSOMETER unit or an RDC CORROTEMP CORROSOMETER unit:
RDC Time Interval
Enter ZERO if Probe
(5-30) > . . < minutes
ENTER CLR
hours
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
For a minute selection, only the preset values will be used. Enter the required value and
press ENTER (F1).
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
Up to 8 alpha numeric characters may be used for the alloy description. This may be
an abbreviated verbal description such as "C.Steel", "304 S.S.", or the 6 digit UNS
material code designation on the probe model or electrode set such as "K03005" or
"S30400". Type in the description and press ENTER (F1). This will display a
selection screen for the probe type.
>
>
>
>
F1
F2
F3
F4
>
>
>
F1
F2
F3
Press EXIT (F4) to return to the selection screen.
>
F4
YES
>
>
>
>
F1
F2
F3
F4
TYPE
SPAN
mils
mm
Strip Loop S4
1.0
0.025
25
2.0
0.051
51
4.0
0.102
102
C
B
B
D
5.0
0.127
127
B
D
A
10.0
0.254
254
11.25
0.285
286
B
A
20.0
0.508
508
25.0
0.635
635
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
The CORROSOMETER probe span is specified on the probe or may be obtained from
Table 5.5.
For the RDC CORRATER the corresponding screen requests input of the Alloy
Multiplier, as the following screen depicts.
Enter Alloy Mult.
>. . . . <
ENTER CLR
>
>
BkSp
>
EXIT
>
F2
F3
F4
Enter the appropriate span or multiplier and press ENTER (F1). The screen will
confirm the configuration information for this RDC is complete, and display the ID
number and Tag.
WARNING! The span is always entered in mils even if the
PC display is selected for millimeters or micrometers. The
probe span is designated on the probe in mils.
>
>
>
>
F1
F2
F3
F4
Press EXIT (F4) to complete the entry for this RDC unit and return to the second
configuration options screen.
At this point, the information for this particular RDC has been completely loaded into
the Mate and is now ready for the next entry, or for loading directly to the RDC unit.
WARNING! Reconfiguring a probe ID number will cause
loss of existing data on the Mate I or II. To avoid this, the
probe should be designated with a new ID. Editing of probe
configuration may be done on the PC, but this may distort
the existing stored data.
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
RDC
Route
EXIT
>
>
>
>
F1
F2
F3
F4
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
Enter the number of the RDC unit to be configured using CLR (F2) or BkSp (F3) if
required.
>
>
>
>
F1
F2
F3
F4
When configuring an RDC for the first time, it is necessary to set its internal clock that
is used for date stamping the recorded probe values. The clock on the RDC unit itself
has a battery backup so that it is unaffected by changing the main RDC batteries. Once
set the clock should not normally require resetting. In fact, resetting the clock will
cause loss of existing data in the RDC.
It is recommended that clock times are NOT
NOTE:
corrected for daylight savings times or summer time as this
complicates date and time stamping of corrosion data.
Attach the "Mate to RDC" cable to the Mate I or II, if not already connected, and
remove the protective cover from the connector on the front of the RDC. Plug in the
cable from the Mate I or II.
Before configuring the RDC, check that the unit has been set up and the batteries
connected as described in the "Installation of RDC unit" in Chapter 3. Press
DATE/TIME (F1) to display the following screen.
RDC Clock Set To
mm dd, yy hh:mm:ss
READ
SET
EXIT
>
>
>
>
F1
F2
F3
F4
To check the existing time, if previously set, on the RDC, press READ (F1). To set or
reset the time press SET (F2) to display the screen.
>
F1
>
>
>
F2
F3
F4
Type in the current year, month, date, hour (24 hour), minutes, and seconds, using the
CLR key (F2) and BkSp key (F3) as necessary. Once the entry is correct and the
selected time is reached, press ENTER (F1) to set in the selected time. The previous
screen reappears to confirm the entry.
RDC Clock Set To
mm dd, yy hh:mm:ss
READ
SET
EXIT
>
>
>
>
F1
F2
F3
F4
This completes the clock entry and the RDC unit may now be configured for the probe
parameters.
To exit the clock setting screen, press EXIT (F4) and return to the screen.
RDC Configuration
DATE CONF
TIME RDC
TEST
MODE
EXIT
>
>
>
>
F1
F2
F3
F4
To prepare the Mate I or II for loading the configuration information into the RDC
press CONF RDC (F2). If the RDC to be configured is a CORROSOMETER unit the
display will be:
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Followed by:
RDC # . .
Configured
EXIT
>
>
>
>
F1
F2
F3
F4
Pressing EXIT (F4) will return the screen to the RDC configuration screen ready for
the next RDC unit.
If there should be any problems with the RDC unit, the probe, or its connections, one
of the following messages will appear:
CORRECTIVE ACTION
C h e c k t h a t R D C
CORROSOMETER unit is being
used, not a CORRATER unit.
Single Channel
RDC4
5 mins
39.5
---
10 mins
68.6
---
15 mins
90.9
30.8
30 mins
134.6
55.1
1 hour
177.2
90.9
2 hours
210.5
134.6
3 hours
224.6
160.3
4 hours
232.4
177.2
6 hours
240.7
198.1
8 hours
245.1
210.5
12 hours
249.6
224.6
24 hours
254.4
240.7
Reading Interval
CORRATER
Reading
Interval
Typical
Maximum
20 minute cycle
time
5 minute cycle
time
2 minute cycle
time
30 mins
16.4
55.1
104.5
1 hour
30.8
90.9
148.9
2 hour
55.1
134.6
189.2
3 hour
74.7
160.3
207.9
4 hour
90.9
177.2
218.8
6 hour
116.0
198.1
230.8
8 hour
134.6
210.5
237.3
12 hour
160.3
224.6
244.2
24 hour
198.1
240.7
251.5
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
For the Mate I press SetUp (F4) and CLRMEM (F3). For the Mate II press SetUp
(F4), Mate (F1), MANUAL CONF (F2), and CLR MEM (F3). On either Mate I
or II the following screen will appear:
CLEARING MEMORY
Please Wait
>
>
>
>
F1
F2
F3
F4
This will take approximately 30 seconds to clear, indicating that the memory is now
cleared.
49
Chapter 6
Normal Operating Procedures
Once the system has been configured as described in Section 5, data may be collected from probes
and RDC's at any time for transfer to the PC. Probes with RDC's normally will be left to
automatically collect data, and later at some convenient time, the data may be gathered. The
advantage of probes with RDC's is the improved resolution of corrosion dynamics due to the
increased reading frequency.
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
The following screen will appear. Press Read (F1) which displays the screen:
What to Read?
PROBE
RDC
EXIT
>
>
>
>
F1
F2
F3
F4
EXIT
>
>
>
>
F1
F2
F3
F4
Remove the protective cover on the connector of the front of the RDC unit and connect the
cable from the Mate I or II.
Press Start (F1).
The following screen will show during initial interrogation and data collection by the Mate
I or II.
Interrogating RDC
Please Wait
ABORT
>
>
>
>
F1
F2
F3
F4
If the following message appears check the connection between the Mate and RDC and try
the reading again. If the same message appears, check the RDC batteries as described later
in this chapter.
WARNING!
No Response from RDC
Try again in 30 sec.
EXIT
>
>
>
>
F1
F2
F3
F4
Once data collection commences the following screen will appear briefly.
>
>
>
>
F1
F2
F3
F4
This latter process takes only a second or two depending on the amount of data to transfer
so that they may barely be visible unless there is a problem with either process.
On completion of the data collection, the screen will display the identification of the RDC
from which data has been collected as follows:
Data Collected from
RDC # . .
Tag . . . . . . . . . . . .
EXIT
>
>
>
>
F1
F2
F3
F4
If for any reason there is a problem with data collection, one of several messages may
appear.
CORRECTIVE ACTION
Data collection is complete and pressing EXIT (F4) returns to the initial screen shown at
the start of this section ready for the next RDC unit.
Remove the "Mate to RDC" cable from the RDC, replace the protective cover on the RDC
unit connector and switch off the Mate I or II.
Disp
Dump
>
>
>
>
F1
F2
F3
F4
SetUp
RDC EXIT
>
>
>
>
F1
F2
F3
F4
Read CA or CO Probe
by
ID
TAG
EXIT
>
>
>
>
F1
F2
F3
F4
To select the probe by ID number, select ID (F1); to select the probe by TAG number,
select TAG (F2)
NOTE: Search by ID is more rapid than search by TAG.
Enter the appropriate ID or TAG for the selected probe, and press ENTER (F1). For a
CORROSOMETER or CORROTEMP CORROSOMETER probe the screen will display:
Connect Mate to
CORROSOMETER PROBE
ID: . . . . . . . . . . . .
START
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Check carefully that the correct probe to be monitored has been selected and press START
(F1). The screen will indicate that the probe is being read as it occurs. This time will vary
in length according to the probe being monitored. When complete, the probe reading will
be displayed as follows for a CORROSOMETER probe:
CO PROBE READINGS
Div: . . . Check: . . .
EXIT
>
>
>
>
F1
F2
F3
F4
CO PROBE READINGS
Div: . . . Check: . . .
Temp: . . . degs C
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
The readings with their time and date are automatically recorded by the Mate II, each time the
probe is read. When readings are complete, switch OFF the Mate II and proceed to the next probe
to be monitored.
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
To display the last recorded reading from the most recently read probe, press CURR
PROBE (F1). To select the reading from a different probe, press ID (F2) and the display
will request the ID number.
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
Type in the tag number including trailing spaces to fill the field and press ENTER (F1).
This search is not as fast as for the ID number. During the search the following screen is
displayed:
SEARCHING FOR PROBE
Please Wait
EXIT
>
>
>
>
F1
F2
F3
F4
After completing the probe search, data is displayed in the following manner:
Two screens are used to display data which vary slightly between standard and
CORROTEMP units. For example, reading a RDC CORROSOMETER the first screen
will display:
>
>
>
>
F1
F2
F3
F4
"Div" is the probe reading, where 0 to 1,000 is the useful probe life or span. "Check" tests
the integrity of the reference element, and should be within 25 of its initial value given
in the parentheses.
The second screen, viewed by pressing MORE (F1) will display:
. . . . Readings @ . . hrs
Alloy: . . . . . . . .
EXIT
>
>
>
>
F1
F2
F3
F4
For CORROTEMP versions the temperature is added to the second screen as follows:
. . . . Readings @ . . time
Alloy: . . . . . . . .
Temp:. . . . Deg C
EXIT
>
>
>
>
F1
F2
F3
F4
On probes with RDC's, the number and frequency of readings is indicated. On probes
without RDC's (Mate II only), the reading frequency is set to 0. The number of readings
is indicated to a maximum number of 2048 for CORROSOMETER RDC's, 1024 for
CORROTEMP CORROSOMETER RDC's, CORRATER RDC's, and 512 for
CORROTEMP CORRATER RDC's. For the Mate II reading probes directly the maximum
number of stored readings is 256. At the maximum number of readings the oldest reading
will be discarded whenever a new reading is added.
NOTE: During the RECEIVE operation the new data and the old
data will be merged in the current file and the old data will be
converted to a backup file automatically with a .BAK extension.
Mate
>
Configuration
Options
Phone
RDC Timer
>
>
EXIT
>
F2
F3
F4
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
CONF
RDC
TEST
MODE
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Select NEW PROBE (F3), and EXIT (F4) twice to return to the main menu. Data
collection of the new probe will commence, taking account of the new initial check
reading.
NOTE:
When changing out the CORROSOMETER or
CORROTEMP CORROSOMETER probe with the same type, it is only
necessary to reconfigure the RDC for the new check reading. No
reconfiguration is required of the PC or the Mate I or II since the same
probe type is used. If a different probe type is installed follow the
procedure in the next section of this chapter.
>
>
>
>
F1
F2
F3
F4
Press NEW PROBE (F3) and Select the ID of the probe being changed and press Enter
(F1) to zero the initial check reading and adjust the installed date. Replace the old probe
if not already done so. Press EXIT (F4) twice to get to opening menu screen. Then read
the new probe in the normal way. This will then generate a new initial check (which will
display in the parentheses) and will change the installed date. The probe list on the PC will
indicate the new installation date.
Action
1)
1)
2)
2a)
2b)
CORRATER or CORROTEMP CORRATER probes require that the electrodes are always
fully submerged in a sufficiently conductive electrolyte. Consequently, the probes should
NOT be positioned in an environment where:
1)
2)
2)
3)
Replace the battery connector and push the test button (2) to check the new
battery is operating correctly, by illumination of the red indicator (3).
4)
Do not switch off the back up battery during this main battery replacement.
ROHRBACK COSASCO
SYSTEMS
Read
Disp
Dump SetUp
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Connect the Mate II to the serial port of the PC with the cable assembly supplied, using the
25 pin connector or the 25 to 9 pin adapter as necessary.
WARNING! Check that the cable is connected to the correct
COM1 or COM2 port corresponding to the version of the
CORRDATA software installed (See Chapter 3 "CORRDATA PC
Software").
To commence data transfer press START (F1). Warnings will show on the Mate II screen
if no communication occurs, or if any bad communication is detected.
WARNING
ACTION
No response from PC
Check connections.
Bad communication.
Repeat the transfer
operation.
During copying of the data to the PC, the following screen will appear on the Mate II,
showing the data copying by ID number.
Dumping Data to PC
Please Wait
RDC # . .
ABORT
>
>
>
>
F1
F2
F3
F4
The PC will show the file copying as it occurs, and the subsequent merging of the new data
into the existing data files. If any configuration mismatches are detected between the Mate
71
Chapter 7
Corrosion Data Analysis
In the basic software package the corrosion data may be viewed one probe at a time in a graphical
format which is generally the most useful to interpret corrosion events and trends.
Once data has been collected by the Mate I or II and transferred to the PC, the CORRDATA software
program is ready to display that data.
It should be made clear here the fundamental difference between CORROSOMETER or and
CORRATER probes. CORROSOMETER probes directly measure metal loss whereas CORRATER
probes directly measure corrosion rate. A single reading from a CORRATER prove gives the corrosion
rate at that time. For a CORROSOMETER probe the metal loss over some finite period of time must
be used to calculate corrosion rate.
NOTE:
CORROTEMP CORROSOMETER probes are
CORROSOMETER probes with a temperature measurement sensor
added, and CORROTEMP CORRATER probes are CORRATER probes
with a temperature sensor added.
In a sense the CORROSOMETER measurement can be likened to an automobile odometer or
mileometer, where the CORRATER measurement can be likened to the speedometer.
For a CORROSOMETER probe, the "current corrosion rate" must actually be calculated on the metal
loss occurring over some finite period of time, normally ranging from a few hours to a few days. Hence
for the CORROSOMETER probe corrosion rate is always a calculated number.
The Mate II collects corrosion data both from probes with RDC's, and directly from probes without
RDC's. The advantage of RDC's is to provide much higher frequency of measurements and a much
improved resolution of corrosion dynamics. The graphical display of RDC generated data is similar
to data generated by individual probe readings, in that straight lines are drawn between the individual
readings. The only difference between the two types of data is that data points from direct probe
measurements are identified with small circles around each point.
CORROTEMP
Figure 7.3 CORROSOMETER Metal Loss Graph from an RDC with Rate and Date Display
To zoom in on the corrosion data graph press Esc to return to the display sub-menu and select
Ranges. Choose either the X-Select or Y-Select as required. If the Y-Select is chosen the
graph will reappear with two horizontal cursors lines at the top and bottom of the graph.
Use the 8 or 9 keys to move the cursor lines, and the Space bar to toggle between the two
cursors as shown in Figure 7.4. When you are satisfied with the selection press Esc.
If you also wish to zoom in on the X-axis choose the X-Select. The graph will reappear with
the X range zoomed in. Use the 7 or 6 keys to move the cursor lines and the Space bar to
toggle between cursors, and to select the required range. Press Esc twice and View to display
the zoomed in graph.
With an imbalance graph, a similar average imbalance value may be automatically read off the
graph.
85
Chapter 8
Maintenance
RDC Units
There is little requirement for maintenance on the RDC unit other than battery change-out and
ensuring that the probe connections remain clean.
Battery check and replacement is described in "RDC Battery Check and Replacement" in
Chapter 6. For guidance on the selection of probe reading intervals, see "Choosing Probe
Reading Frequency" in Chapter 5.
The RDC unit also includes a small rechargeable battery for memory backup on one circuit
board, which is charged by the main battery. This rechargeable battery is set into operation at
start up of the RDC (see Figure 3.2). Its storage capacity with a dead main battery is
approximately three months.
WARNING! If the RDC is to be left inoperative for some time
disconnect the main battery and switch off the back up battery. At
start up the back up battery MUST be switched on BEFORE the
main battery.
CORRDATA Mate I or II
The only requirements for maintenance on these units are battery change-out, general care and
cleanliness of the unit, and occasional inspection of the connectors for damage.
The Mate I or II operates with six AA battery cells. The use of alkaline batteries is
recommended which will give an average operating time of 40 hours when continuously used
with RDC's only, or as few as 8 hours if used with probes only. ( Mate II only)
Low batteries are indicated by the screen cursor which changes from:
~ to LB
The Mate I & II have a small lithium battery back up on an internal circuit board with an
anticipated life of 7 - 10 years. The unit must be returned to Rohrback Cosasco or its
authorized representative for replacement of this battery.
Software Revisions
The revision level of the PC software can be checked from the part number revision on the
system diskettes.
The revision levels of the RDC unit and the Mate I or II may be checked with the Mate I or II
as follows:
Press the ON switch on the Mate I or II. Select Read (F1) from the start up screen to display:
What to Read?
PROBE MODE
RDC
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Chapter 8 Maintenance 87
Press REV (F1) to display:
SOFTWARE REVISION
MATE = 7.4
RDC = 6.8
EXIT
>
>
>
>
F1
F2
F3
F4
If the Mate I or II is not connected to an RDC, the following screen will be displayed:
WARNING!
No Response from RDC
Try again in 30 sec.
EXIT
>
>
>
>
F1
F2
F3
F4
Press EXIT (F4). This will display the revision of the Mate I or II without that of the RDC.
SOFTWARE REVISION
MATE = 7.4
RDC = 0.
EXIT
>
>
>
>
F1
F2
F3
F4
89
Chapter 9
Troubleshooting
Troubleshooting any CORRDATA system problem will generally be done by treating the electronic
sections as black boxes. By cross checking the basic components of the system i.e. batteries, probe,
RDC, Mate I & II and PC it is possible to narrow down the problem unit. Any faulty electronic units
must be returned to the factory for repair.
Test RDC unit batteries with test switch adjacent to the battery connector
inside the RDC unit. Illumination of the red indicator shows a good battery.
No illumination indicates a new battery is required.
2)
A number of warning messages are displayed by the RDC unit which are self
explanatory.
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
Mate
Configuration
Options
Phone
RDC Timer
EXIT
>
>
>
>
F1
F2
F3
F4
BkSp
EXIT
>
>
>
>
F1
F2
F3
F4
Enter the ID number of the RDC unit or alternatively "0" if the RDC number is not known.
Press ENTER (F1).
Chapter 9 Troubleshooting 91
RDC Configuration
Connect Mate to RDC
DATE CONF TEST
TIME RDC MODE
EXIT
>
>
>
>
F1
F2
F3
F4
With the "Mate to RDC" cable attached to the Mate I or II, connect the Mate I or II cable to
the RDC and press TEST MODE (F3). Any problem of communication with the RDC will
be indicated by warning messages.
WARNING MESSAGE
CORRECTIVE ACTION
>
>
>
>
F1
F2
F3
F4
READ
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
Press EXIT (F4) to return to the previous screen. Allow at least 3 minutes for completion
of the reading and press READ (F3).
If the RDC is a CORROSOMETER or CORROTEMP CORROSOMETER unit the display
should display the divisions value and check value printed on the test probe.
TEST PROBE READINGS
DIV: . . .
CHK: . . .
EXIT
>
>
>
>
F1
F2
F3
F4
For a CORRATER or CORROTEMP CORRATER RDC unit, the display will display a rate
value and imbalance value corresponding to that printed on the test probe thus:
TEST PROBE READINGS
Rate: . . . . MPY
Imbal: . . . .
EXIT
>
>
>
>
F1
F2
F3
F4
If the displayed values are beyond the limits shown on the test probe, the RDC unit may need
repair.
Chapter 9 Troubleshooting 93
Press EXIT (F4) to return to the TEST PROBE MENU.
READ
EXIT
>
>
>
>
F1
F2
F3
F4
Remove the test probe and reconnect the cable to the working probe. Press EXIT (F4) to
return to RDC Test Modes.
RDC TEST MODES
READ
TEST READ READ
PROBE CONF TIME
EXIT
>
>
>
>
F1
F2
F3
F4
Press READ CONF (F2) if you wish to verify the configuration information for the RDC
unit. For an RDC CORROSOMETER the display will be as follows:
RDC . . CORROSOMETER
Tag . . . . . . . . . . . .
Type . . . . . Span . . . .
Alloy . . . . . . . .
MORE
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
In either case to read the rest of the configuration data press MORE (F4). The screen will
display the readings information. For readings set in hours the display will be:
Interval . . hours
Num. Readings . . . . .
Next. Reading . . . . .
EXIT
>
>
>
>
F1
F2
F3
F4
>
>
>
>
F1
F2
F3
F4
The Num. Readings shows how many readings have been collected (the maximum number
of readings for a CORROSOMETER RDC is 2048 readings for a CORRATER RDC or
CORROTEMP CORROSOMETER RDC is 1024, and for a CORROTEMP CORRATER
RDC is 512 readings).
If all information is correct press EXIT (F4).
Chapter 9 Troubleshooting 95
Mate I or II
If the problems are common to all the RDC units, then the problem is probably with the
Mate I or II or the PC. It is possible to distinguish the difference between Mate I or II and
PC problems, since RDC information can be displayed on the Mate I or II and at the PC.
To verify if the Mate I or II is operational, check the batteries and collect data from an RDC
or probe which is known to be "good" (as much as this is possible) and use the display
routine described in "Displaying Probe Data", in Chapter 6 of the manual. If the reading
displayed is correct the Mate I or II is functioning and the problem may be with the PC or
communication to the PC.
>
>
>
>
F1
F2
F3
F4
Pressing EXIT (F4) will clear the screen and allow operation of the unit. However, it is
recommended the Mate be reprogrammed as the effect of corrupted software may be difficult
to predict.
PC
If the CORRDATA program does not start up on your computer, check to see if the
specification of your system meets the requirements listed in Chapter 2 of the manual.
If the program starts up but does not communicate with the Mate I or II, check the interface
connectors and ensure that the correct serial port is being used, and that the appropriate
COM1 or COM2 version of the software has been installed. If another device is using the
selected serial port, either change the serial port being used by CORRDATA or use a switch
box.
Installing the alternate version of CORRDATA software for the other serial port is described
under Installation in Chapter 3.
The CORRDATA program may be run under Windows 3.1 as a DOS application as
described in the Windows operating manual. Care must be taken with Windows set up,
particularly with regard to other devices, such as a mouse, modem, or a network, that may
use the same interrupt as the COM port used for communications with the Mate I or II. If
difficulties are experienced contact RCS for assistance.
97
Chapter 10
ASCII Transfer Utility
When the CORRDATA Software is installed to the hard disk of the PC, a spreadsheet utility file
MAKE_ASC.EXE is also included. This utility may be used to convert the CORRDATA data
files (with extension.DAT) to ASCII files which may be imported directly to spreadsheets such
as Lotus 1-2-3. The file names are automatically created by the utility with the general form
ID_X.PRN, where X is the probe ID number, and saved in the CORRDATA directory.
To operate this utility, change to the CORRDATA directory and type MAKE_ASC.EXE. If
running under Windows, double click on the MAKE_ASC.EXE file in the CORRDATA directory
in File Manager. This will immediately generate converted .PRN files for each .DAT file.
To import the file into Lotus 1-2-3, start the Lotus 1-2-3 program. Select the menu, and enter
File; Import; Numbers. Modify the directory to the location of the saved .PRN files and press
Enter. In Lotus version 4 or 5 for Windows, select File; Open; select the File Type to text (txt,
prn); change the Directory to CORRDATA; click on the required file ONCE; select the
COMBINE button and select formatted and OK. For Excel or other spreadsheets make sure that
the field delimiter is set to comma. Select the file or files as required. The ASCII format for a
CORROTEMP probe, for example, is as follows:
"Rohrback Cosasco Systems, Inc.
"CORRDATA ASCII TRANSFER UTILITY
"(C)Copyright 1992
"
"","CORROTEMP PROBE"
"
"TAG","","AE 0023"
"ID","","23"
"TYPE","","D"
"SPAN","","10.00"
"INTERVAL",""," - "
"INSTALLED","","30 Sep 92"
"LAST READ","","15:34 30 Sep 92"
""
" TIME ","TEMP","METAL LOSS "
"(DAYS)","(DEG C)","(MILS) "
0.649,28.000000,0.980000
Column 2
Column 3
CORROSOMETER
Time
Metal Loss
CORROTEMP CORROSOMETER
Time
Temperature
Metal Loss
CORRATER
Time
Imbalance
Corrosion Rate
CORROTEMP CORRATER
Time
Imbalance
Corrosion Rate
Column 4
Temp
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
A
B
C
D
Rohrback Cosasco Systems, Inc.
CORRDATA ASCII TRANSFER UTILITY
(C)Copyright 1992
CORROTEMP PROBE
TAG
0023
ID
23
TYPE
D
SPAN
10.00
INTERVAL
INSTALLED 30 Sep 92
LAST READ 15:34 30 Sep 92
TIME
(DAYS)
0.649
The first column is the time base in days from midnight at the start of installation. The decimal
portion indicates the time of day, i.e. 0.25 is 6:00 a.m., 0.5 is mid-day, 0.75 is 6:00 p.m., etc.
This time is computed for every probe reading independent of whether an RDC is used or not. If
the readings are from probes with RDC's, the INTERVAL above will indicate the reading interval
in addition to the actual times computed for column 1.
For graphical displays, set graph type to XY, and select the data range to be displayed as required.
99
Chapter 11
Mate Operation with Downhole Corrosion
Monitor System (DCMS)
The operating of the CORRDATA System with the downhole corrosion monitor is almost identical
to that with an RDC. The main difference is that communication with the downhole tool is carried
out at a data transfer rate of 300 Baud instead of 9600 Baud used between the Mate and RDC, and
the Mate and PC.
This requires that the baud rate is set to 300 to communicate with the downhole corrosion monitor
and then reset to 9600 baud to communicate with its PC.
NOTE: A special interface unit supplied with the downhole tool is
required to connect to the downhole corrosion monitor.
To change the baud rate, switch ON the Mate. After the self test screen clears and the main menu
appears.
ROHRBACK COSASCO
SYSTEMS
Read
Disp
Dump
SetUp
>
>
>
>
F1
F2
F3
F4
BAUD
TEST
EXIT
>
>
>
>
F1
F2
F3
F4
9600
EXIT
>
>
>
>
F1
F2
F3
F4
Press 300 (F1) for downhole corrosion monitor tool. This Mate will automatically shut off and
restart with the Baud Rate Changed.
WARNING! Remember to repeat the procedure and set the Baud
rate to 9600 to communicate with the PC.
Appendix A 101
Appendix A
Theory of Operation of CORROSOMETER Systems
CORROSOMETER Systems are based on the electrical resistance method of corrosion monitoring
pioneered by Rohrback in the 1950's and 1960's. CORROSOMETER probes are basically
"electrical coupons." They determine the loss of metal from the probe by measuring the change
in its resistance. Because of the very low resistances involved, very sensitive monitoring circuits
are used in CORROSOMETER instruments to measure the change in probe resistance compared
to a protected reference element resistance series-connected to the corroding measurement element.
A "check" element is also included and is protected from the process along with the reference
element. The ratio of check to reference resistance should remain constant. If it doesn't, this
indicates that degradation of the reference element may be occurring and that metal loss readings
obtained from the probe are questionable. A simplified diagram of a typical electrical resistance
monitoring circuit is shown in Figure 1.
FIGURE 1
FIGURE 2
Appendix A 103
Corrosion
Rate
(mpy)
10
20
25
0.1
73 days
5 months
6 months
12 months
24 months
30 months
0.5
15 days
29 days
37 days
73 days
5 months
6 months
1.0
7 days
15 days
18 days
36 days
73 days
3 months
5.0
35 hours
3 days
4 days
7 days
15 days
18 days
10
18 hours
35 hours
2 days
4 days
7 days
9 days
25
7 hours
14 hours
18 hours
35 hours
3 days
4 days
50
4 hours
7 hours
9 hours
18 hours
35 hours
2 days
75
140 mins
5 hours
6 hours
12 hours
23 hours
29 hours
100
105 mins
4 hours
5 hours
9 hours
18 hours
22 hours
TABLE 1
Elapsed Time* To:
Corrosion
Rate*
with 10 mil
Span Probe
Early Trend
Indication
(4 Div.)
Meaningful
Rate Data
(10 Div.)
End of Useful
Probe Life
(1000 Div.)
1.6 hours
4.0 hours
17 days
220 mpy
(5.6 mm/y)
4.0 hours
10.0 hours
1.4 months
88 mpy
(2.2 mm/y)
9.6 hours
1 day
3.3 months
37 mpy
(0.94 mm/y)
18.0 hours
1.8 days
6.0 months
20 mpy
(0.51 mm/y)
1.1 days
2.7 days
9.0 months
13 mpy
(0.33 mm/y)
1.5 days
3.7 days
12.0 months
10 mpy
(0.25 mm/y)
1.8 days
4.6 days
15.0 months
8 mpy
(0.20 mm/y)
2.2 days
5.5 days
18.0 months
6.7 mpy
(0.17 mm/y)
2.9 days
7.3 days
24.0 months
5 mpy
(0.13 mm/y)
TABLE 2
From Table 1, it would appear desirable to always choose probes with the lowest span available
in order to get the greatest sensitivity. However, the more sensitive the probe, the faster the entire
probe span will corrode away and require a new probe to be installed.
FIGURE 3
CORROSOMETER monitoring systems can be applied to all processes. However, some types
of CORROSOMETER probes are better suited to the requirements of particular applications than
others.
Different styles of CORROSOMETER probes are affected to different degrees by pitting attack.
Figure 4 shows the results of pitting attack on a wire loop probe. Although the remaining wire
thickness shows that only 30% or so of the probe span has been consumed, the probe is obviously
out of service. Cylindrical elements on the other hand, are affected to a much lesser degree by
pitting because of the much larger circumference of the measuring element. Wire loop and tube
Appendix A 105
loop elements also have a tendency to be electrically shorted by a bridge of iron sulfide corrosion
product. This is especially prevalent in low-velocity streams over an extended period. The effect
of such bridging is to reduce the measured metal loss of the probe, creating a misleadingly low
corrosion rate. Cylindrical probes demonstrate more resistance to iron-sulfide bridging due to their
construction and lower inherent resistance per unit length, thus minimizing the effect of the shunt
resistance. Where pitting or substantial FexSy deposition are expected to be problems, cylindrical
probes should be chosen wherever possible over loop-style probes.
FIGURE 4
Most cylindrical probes are of all-welded construction in order to eliminate the need for sealing
metal elements to non-metallic glass, epoxy or ceramic. This all-welded construction gives the
probe superior resistance to leaking. Probes with higher temperature ratings can also be
constructed in the all-welded style. A drawback to the all-welded style is that the element is
electrically connected to the pipe wall which can, in certain conditions, interfere with the corrosion
reaction on the probe. Also, because cylindrical probes are welded, in some conditions preferential
corrosion can occur in the heat-affected zones near the weld.
Flush probe elements are thin, flat metal sections embedded in epoxy or a hermetic glass seal
inside a metal probe body. Flush probes also experience certain characteristic problems, most
notably: lack of adhesion of the metal element to the epoxy, cracking of glass seals due to
differential expansion and erosion of the epoxy or glass due to high velocities, abrasive materials
in the flowstream or both. Flush CORROSOMETER probes mounted on the bottom of the line
have been shown to provide good results in a sour gas gathering system.
Because the measurement element is part of the primary pressure seal, and because it's designed
to corrode, CORROSOMETER probes have a reduced resistance to leaking after prolonged
exposure. Once the measurement element has corroded through, the internals of the probe body
are exposed to the process fluid. Although materials are chosen in part for their strength and lack
of permeability, it is our experience that process fluids will permeate throughout the probe packing
material. For this reason, quality probes are constructed of corrosion-resistant body materials and
include a secondary pressure seal, often consisting of a hermetic glass-sealed connector. Other
back-up seals are utilized in special cases, especially where process fluids will attack glass (e.g.
107
Appendix B
Theory of Operation of CORRATER Systems
CORRATER systems measure the instantaneous corrosion rate of a metal in a conductive fluid
using the linear polarization resistance ("LPR") measurement technique. Corrosion is an
electrochemical process in which electrons are transferred between anodic and cathodic areas on
the corroding metal resulting in oxidation (corrosion) of the metal at the anode and reduction of
cations in the fluid at the cathode.
Sterns and Geary originally demonstrated that the application of a small polarizing potential
difference ()E) from the corrosion potential (E ) of a corroding electrode resulted in a measured
current density (i ) which is related to the corrosion current density (i ) by equation (1):
corr
meas
)E =
i
meas
corr
b b
(2.303 i ) (b + b )
a
corr
where:
(1)
Since the Tafel coefficients are more or less constant for a given metal/fluid combination, i is
proportional to i which is proportional to the corrosion rate. Equation (1) and the entire LPR
technique are only valid when the polarizing potential difference is very low (typically up to 20
mV). In this region the curves are linear, hence the term LPR.
meas
corr
Inspection of Equation (1) shows that the result is a resistance, the Polarization Resistance, R .
While strictly speaking, there are both anodic and cathodic R values, which can differ, they are
usually assumed to be equal. The resistance to current flow between anode and cathode on the
LPR probe is the sum of both polarization resistance values and the resistance of the solution
between the electrodes (R ) as shown in Equation (2):
p
E = i
meas
(2R + R )
p
(2)
From Equations (1) and (2), obtaining results from the LPR technique would seem to require only
instantaneous readings of resistance. In practice, however, the determination of polarization
corr
Appendix B 109
A serious problem develops, however, when the solution resistance increases or the polarization
resistance decreases enough to make the solution resistance a significant portion of the total
resistance to current flow between the electrodes. In these cases, the accuracy of the LPR
measurement is affected. This situation tends to occur at high corrosion rates (low polarization
resistance) and in solutions with low conductivity (high solution resistance) and is manifested by
the indicated (measured) corrosion rate being lower than the actual corrosion rate. The graph in
Figure B-3 shows the effect of this limitation on the recommended operating range of LPR
instruments.
Appendix B 111
Several techniques have been used over the years to minimize the impact of solution resistance on
LPR measurements. The most common techniques involved the use of a three electrode probe.
The effectiveness of the reference electrode in reducing the effect of solution resistance has been
shown to be dependent upon the proximity of the reference electrode to the measurement electrode.
Rohrback Cosasco three-electrode probes (see Figure B-4) are unique compared to other major
LPR probes because they utilize a closely-spaced electrode.
The above points are clearly indicated in ASTM Standard Guide G96 which quotes:
"3.2.8
Two-electrode probes and three-electrode probes with the reference electrode equidistant from the test and
auxiliary electrode do not correct for effects of solution resistance without special electronic solution resistance
compensation. With high to moderate conductivity environments, this effect of solution resistance is not
normally significant.
3.2.9
Three-electrode probes compensate for the solution resistance R by varying degrees depending on the position
and proximity of the reference electrode to the test electrode. With a close-spaced reference electrode, the effects
S
3.2.10
A two-electrode probe with electrochemical impedance measurement technique at high frequency short circuits
the double-layer capacitance, C , so that a measurement of solution resistance R can be made for application
as a correction. This also extends the operating range over which adequate determination of polarization
resistance can be made."
dl
CORRATER Instruments
Rohrback Cosasco's current CORRATER product line includes the Model 9000 portable
CORRATER instrument which has a fixed time cycle and does not include the SRC feature; the
Model 9030 single-channel instrument with user-selectable cycle time which pioneered the use of
SRC in CORRATER instruments; and three instruments - the Model RDC - CORRATER, the
Model RCS-8 and the Model 9134 CORRATER Probe Interface Module, which incorporate
proprietary, fully-automatic cycle time selection and advanced SRC features.
Imbalance (or Pitting/Index)
In addition to general or uniform corrosion, localized corrosion (pitting) may occur in a system.
This can result in much more rapid failure of a structure than a simple measure of corrosion rate
would indicate. A pit on the metal surface is the result of a localized, high anodic current density.
Positive ions flow away from the pit into the solution and electrons flow away from the pit into
the surrounding metal.
If it were possible to place a zero-impedance ammeter between the pit and the nearby metal
surface, the current in the anode-cathode system of the pit could be measured. Individual
measurements are not practical because the areas are small. Instead, current flow between the two
metallurgically identical electrodes of a CORRATER probe under short-circuit conditions can be
used to indicate pitting tendency. All Rohrback Cosasco CORRATER instruments include a
imbalance/pitting reading. The user should note that this is a qualitative measurement (or index)
and utilize it accordingly. It has proven very useful in many applications (e.g. cooling water
treatment) and offers information not generally available about a system except by coupons which
lag behind actual events and offer no way of detecting upsets.
If the pitting reading is low compared to the corrosion reading, the pitting problem will probably
be minimal. On the other hand, a pitting reading which is high compared to the corrosion reading
can indicate that pitting or crevice corrosion will be the main form of corrosive attack. When the
readings are about equal, some pitting is indicated, but the pits will probably be broad and shallow.