Beruflich Dokumente
Kultur Dokumente
QuestionRevision
Question1.
Whatisthedecreasingstabilityorderofthefollowingcarbocationsasperinductiveeffectonly?
[A]
[B]
[C]
[D]
Question2.
Matchthefollowingelementswithcolourtheircomplexes/compoundsproduceforquantitative/qualitativedeterminationasper
Lassaigne'stest:
[A]
[B]
[C]
[D]
Question3.
Selecttheresponsethatcorrectlyidentifiesthenumberofcarbonatomsofeachhybridizationinthecompoundshown.
[A]
[B]
[C]
[D]
Question4.
Whichofthefollowingcompoundsisnotconstitutional/structuralisomerofthreeothers?
[A]
[B]
[C]
[D]
Methylcyclohexane
1,1,2Trimethylcyclobutane
Cyclopropylcyclobutane
1Heptene
Question5.
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QuestionRevision
Whichofthefollowingcompoundsis/arearomatic?
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
IandIII
OnlyI
OnlyIII
IIIandIV
Question6.
Whichofthefollowingresonatingstructureofdiazomethylene
,ismoststable?
[A]
[B]
[C]
[D]
Question7.
Howmanyopticallyactiveformsarepresentfortheformula:
[A]
[B]
[C]
[D]
2
3
1
4
Question8.
Whichofthefollowingshowgeometricalisomerism?
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyI
IandIII
I,IIIandIV
I,IIandIV
Question9.
InwhichofthefollowingcompoundsKJeldahl'smethodcan'tbeused:
Thecorrectchoiceis:
[A]
I&III
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[B]
[C]
[D]
QuestionRevision
II&III
IIIonly
Noneoftheabove
Question10.
Aracemicmixtureisan:
[A]
[B]
[C]
[D]
Equimolarmixtureoftautomers
Equimolarmixtureofenantiomers
Equimolarmixtureofdiastereomers
Equimolarmixtureofcisandtransisomers
Question11.
Whichoneofthefollowinghasthree
[A]
[B]
[C]
[D]
hybridizedcarbonatoms?
Toluene
Xylene
Mesitylene
Noneofthese
Question12.
Whichofthefollowingisnotcorrectfortartaricacid,HOOCCH(OH)CH(OH)COOH?
[A]
[B]
[C]
[D]
Itexistinfourstereoisomericforms
Itcontainstwochiralcarbonatoms
Ithastwoopticallyactiveisomers
Itsmesoformisopticallyinactive
Question13.
Planarcycliccompoundisaromaticifitcontains.
[A]
Acloseloopoflocalized
[B]
Acloseloopofdelocalized
[C]
Acloseloopofdelocalized
[D]
Acloseloopoflocalized
electronswhere
electronswhere
electronswhere
electronswhere
Question14.
Arrangefollowingspeciesindecreasingorderofstability?
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
Q>R>P
R>P>Q
R>Q>P
P>Q>R
Question15.
Fortheestimationofnitrogen,1.4gorganiccompoundwasdigestedbyKjeldahlmethodandtheevolvedammoniawasabsorbedin60
mLof
sulphuricacid.Theunreactedacidrequired20mLof
sodiumhydroxideforcompleteneutralization.Thepercentage
ofnitrogeninthecompoundis:
[A]
5%
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[B]
[C]
[D]
QuestionRevision
6%
10%
3%
Question16.
Whichofthefollowingstatementiscorrectforcyclooctatetraene?
[A]
[B]
[C]
Itisplanarcompound
Itisnonplanarcompound
Ithasdelocalized
electrons
[D]
Ithasdelocalized
electrons
Question17.
Whichofthefollowingiscorrectforintermediatespeciesgivenbelow.
[A]
Xisdestabilizedby
effectof
[B]
Xisstabilizedby+Meffectof
[C]
Xisdestabilizedby
[D]
XislessstablethanY.
effectof
groupwhileYisstabilizedby
effectof
groupwhileYisstabilizedby+Heffectof
groupwhileYisstabilizedby+Heffectof
group
group
group
Question18.
Whichofthefollowingcompoundscanexistinthreestereoisomericforms,twoopticallyactiveandoneopticallyinactive?
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyII
OnlyI
IandII
I,IIandIII
Question19.
Whichofthefollowingstructuralfeaturesiscorrectforintermediatesmethylfreeradical,methylcarbocationandmethylcarbanion
respectively?
[A]
[B]
[C]
[D]
Question20.
Whichofthefollowingcompoundscanshowtautomerism(ketoenolisomerism)?
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[A]
[B]
[C]
[D]
QuestionRevision
OnlyII
IandII
IIandIII
I,IIandIII
Question21.
Forwhichofthefollowingcompounds,bothmetamersandtautomersarepossible?
I.
II.
III.
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
OnlyII
OnlyI
IandII
IIandIII
Question22.
Howmanyisomericstructuresarepossiblefororganiccompoundhavingmolecularformula
[A]
[B]
[C]
[D]
6
7
8
9
Question23.
Selecttheorderofstabilityofthefollowingcarbocations:
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
I>II>III>IV
III>II>I>IV
IV>III>II>I
II>III>I>IV
Question24.
Inthestructureof4,4diisopropyl2,6dimethylheptane,numberof3oHatomsare:
[A]
[B]
[C]
[D]
18
5
3
4
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Question25.
Outofthefollowing,thealkene(s)thatexhibitsbothopticalisomerismandgeometricalisomerismis/are:
I.4Methylhex2eneII.3Ethylpent1eneIII.3Methylpent1ene
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
IandIII
OnlyI
IIandIII
I,IIandIII
Question26.
Inwhichofthefollowingresonatingstructurepolarcontributingstructureismorestablethanthenonpolarcontributingstructure.
[A]
[B]
[C]
[D]
Noneofthese
Question27.
Totalnumberofstereoisomersoffollowingcompoundare:
[A]
[B]
[C]
[D]
3
2
4
6
Question28.
Whichofthefollowinghassamephysicalproperties(suchasboilingpoint)?
[A]
[B]
[C]
[D]
Constitutionalisomers
Enantiomers
Diastereomers
Noneofthese
Question29.
Arrangethefollowingcarbocationsinthedecreasingorderofnumberofhyperconjugativestructures:
I.
II.
III.
Thecorrectchoiceis:
[A]
[B]
[C]
[D]
I>II>III
II>I>III
III>II>I
I>III>II
Question30.
Whichoneofthefollowinghasthelargestdipolemoment?
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[A]
[B]
[C]
[D]
Question31.
Theelectricfieldinaregionisgivenbythevector
[A]
[B]
[C]
[D]
.Themaximumdropinpotentialwillbealong:
Xaxis
Yaxis
theline4y=x
theline3y=4x
Question32.
AnequilateraltrianglewireframeofsideLhaving3pointchargesatitsverticesiskeptinxyplaneasshown.Componentofelectricfield
duetotheconfigurationinxdirectionatoriginis:[Originiscentroidoftriangle]
[A]
[B]
Zero
[C]
[D]
Noneofthese
Question33.
Thevariationofelectricfieldbetweenthetwochargesq1andq2alongthelinejoiningthechargesisplottedagainstdistancefromq1}
(takingrightwardsdirectionoffieldaspositive)asshown,thenthecorrectstatementis:
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[A]
[B]
[C]
[D]
QuestionRevision
q1andq2arepositiveandq1<q2
q1andq2arepositiveandq1>q2
q1ispositiveandq2isnegativeandq1<q2
q1andq2arenegativeandq1<q2
Question34.
Inaregionofspace,theelectricfieldisinthexdirectionandisgivenas
.Consideranimaginarycubicalvolumeofedgea,
withaitsedgesparalleltotheaxesofcoordinates.Thenetchargeinsidethisvolumeis:
[A]
Zero
[B]
[C]
[D]
Question35.
Inthefigurebelow,apointcharge+Q 1isatthecentreofanimaginarysphericalGaussiansurfaceandanotherpointcharge+Q 2is
outsideoftheGaussiansurface.PointPisonthesurfaceofthesphere.Whichoneofthefollowingstatementsistrue?
[A]
[B]
[C]
[D]
Bothchargescontributetothenetelectricfluxthroughthespherebutonlycharge+Q 1contributestotheelectricfieldatpointP
onthesphere.
Bothchargescontributetothenetelectricfluxthroughthespherebutonlycharge+Q 2contributestotheelectricfieldatpointP
onthesphere.
Onlythecharges+Q 1contributestothenetelectricfluxthroughthespherebutbothcharges+Q 1and+Q 2contributetothe
electricfieldatpointP.
Onlythecharges+Q 2contributestothenetelectricfluxthroughthespherebutbothchargecontributetotheelectricfieldat
pointP.
Question36.
Achargeqisplacedatthecentroidofanequilateraltriangle.ThreechargesequalQareplacedattheverticesofthetriangle.The
systemoffourchargeswillbeinequilibriumifqisequalto:
[A]
[B]
[C]
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[D]
Question37.
Figureshowsacircularsurfaceandaparaboloidalsurface.ItisplacedinauniformelectricfieldofmagnitudeEsuchthatthecircular
surfaceisorientedatrightanglestothedirectionoffield.Electricfluxthroughtheparaboloidalsurfaceis:
[A]
zero
[B]
[C]
[D]
Question38.
ThelinearchargedensityonadielectricringofradiusRisvaryingwith
Thepotentialatthecentreoftheringis:
[A]
Zero
[B]
[C]
[D]
Question39.
AninfiniteplanesheetofaluminiumofareaAhastotalchargeQuniformlydistributedoveritssurfaces.Theelectricfieldhearitssurface
is
.Thesamechargeisspreaduniformlyononesurfaceofglassslabhavingsamefacearea.Theelectricfieldintensitynearits
surfaceis
[A]
[B]
[C]
[D]
Cannotsayanything
Question40.
Twoinfinitesheetshavingchargedensities
areplacedintwoperpendicularplaneswhosetwodimensionalviewisshown
inthefigure.Thechargesaredistributeduniformlyonsheets.FourpointsaremarkedI,II,IIIandIVtheelectricfieldintensitiesatthese
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pointsare
,respectively.Choosethecorrectoption.
[A]
[B]
[C]
[D]
Noneoftheabove
Question41.
ThreeconcentricsphericalconductorsA,BandCarearrangedasshowninthefigure.IftheyaregivenchargesQ 1,Q 2,Q 3
respectively,thepotentialatpointPwillbe:
[A]
[B]
[C]
[D]
Question42.
Twosmallsphereswithmassm1andm2hangfrommassless,insulatingthreadsoflengthl1andl2.Thetwospherescarrychargesq1
andq2respectively.Thesphereshangsuchthattheyareonsamehorizontallevelandthethreadsareinclinedtotheverticalatangle
.Whichoftheconditionisrequiredif
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[A]
[B]
[C]
QuestionRevision
m1=m2
|q1|=|q2|
l1=l2
[D]
Question43.
TwoconcentricconductingthinshellsofradiusRand2Rcarrycharges+Q,+3Qrespectively.
Themagnitudeofelectricfieldatadistancexoutsideandinsidefromthesurfaceofoutersphereissame.Thenthevalueofxis:
[A]
[B]
[C]
[D]
Question44.
Athin,metallicsphericalshellcontainspointchargeqplacedatthecentreandanotherpointchargeq1isplacedoutsideitasshownin
figure.Boththechargesarepositive.Theforceonthecentralchargeduetotheshellis:
[A]
[B]
[C]
[D]
Towardsleft
Towardsright
Upward
Zero
Question45.
Athinsemicircularringofradiusrhasapositivecharge'q'distributeduniformlyoverit.Thenetfield
atthecentreOis:
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[A]
[B]
[C]
[D]
Question46.
Lettherebeasphericallysymmetricchargedistributionwithchargedensityvaryingas
uptor=Rand
forr>R,whereristhedistancefromtheorigin.Theelectricfieldatadistancer(r<R)fromtheoriginisgivenby:
[A]
[B]
[C]
[D]
Question47.
AchargeQisplacedateachoftheoppositecornersofasquare.Achargeqisplacedateachoftheothertwocorners.Ifthenet
electricalforceonQiszero,theQ/qequals:
[A]
[B]
[C]
[D]
Question48.
Electricfluxthroughasurfaceofarea100m2lyinginthexyplaneis
[A]
[B]
[C]
[D]
if
100
141.4
173.2
200
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Question49.
ThemaximummagnitudeofelectricfieldduetoaringofRadius5mandchargeperunitlengthof
atapointontheaxisof
theringis:
[A]
[B]
[C]
[D]
Question50.
ThevariationofelectricfieldthroughasolidsphereofradiusRandhavingnetchargeQisshownis:
[A]
[B]
[C]
[D]
Question51.
AveQchargeisplacedat
anda+veQchargeisplacedat
.AseparatechargeQisfirstbroughtat
wheretheforceexperiencedbyitisF1andthenbroughtatR(y=a)wheretheforceexperiencedbyitisF2.Then
F1/F2is:
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[A]
[B]
[C]
[D]
Question52.
Apointchargeqisplacedinsideaconductingsphericalshellofinnerradius2Randouterradius3RatadistanceofRfromthecentreof
theshell.Theelectricpotentialatthecentreofshellwillbe:
[A]
[B]
[C]
[D]
Question53.
TheelectricfieldduetoapointchargeatdistanceRisE1andtheelectricfieldduetoaringcarryingsamechargeatadistanceRonthe
axisofringisE2.Then,
is:
[A]
[B]
[C]
[D]
Question54.
Thepotentialatthecentreofthesolidspherehavingtotalcharge
uniformlydistributedoverthesphereofradius2unitsis:
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[A]
[B]
[C]
[D]
Question55.
Twosolidspheresofradius2mand4mhavecharges6Cand3Crespectively.Theyareplacedatinfinitedistanceandjoinedbya
conductingwire.Finally,theyattaintheequalpotentialwhichis:
[A]
[B]
[C]
[D]
Question56.
Sixchargesareplacedatthecornerofaregularhexagonasshown.IfanelectronisplacedatitscentreO,forceonitwillbe:
[A]
[B]
[C]
[D]
Zero
AlongOF
AlongOC
Noneofthese
Question57.
Aninfinitenonconductingsheetofchargehasasurfacechargedensityof
.Theseparationbetweentwoequipotential
surfacesnearthesheetwhosepotentialdifferby5Vis:
[A]
[B]
[C]
0.88cm
0.88mm
0.88m
[D]
Question58.
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Potentialdifferencebetweencentre&thesurfaceofsphereofradiusRanduniformvolumechargedensity
withinitwillbe:
[A]
[B]
[C]
[D]
Question59.
Acharge3coulombexperiencesaforce3000Nwhenplacedinauniformelectricfield.Thepotentialdifferencebetweentwopoints
separatedbyadistanceof1cmalongthefieldlinesis:
[A]
[B]
[C]
[D]
10V
90V
1000V
9000V
Question60.
TwoconcentricconductingshellsofradiiRand3RcarryingchargesQand2Qrespectively.Ifthechargeoninnershellisdoubled.How
manytimeswillthepotentialdifferencebetweeninnerandoutershellsbecome?
[A]
[B]
[C]
[D]
2
4
1/2
1/4
Question61.
If
,then:
[A]
[B]
[C]
[D]
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Question62.
Giventhefunction
(wherea>2).Thenf(x+y)+f(xy)=
[A]
[B]
[C]
[D]
Noneofthese
Question63.
Therangeofthefunction
[A]
[B]
[C]
[D]
,is:
[1,3]
[1,5]
[3,5]
Noneofthese
Question64.
Theperiodofthefunction
[A]
[B]
[C]
[D]
,where[.]denotesthegreatestintegerfunction,is:
1
2
Noneofthese
Question65.
Evaluate
[A]
[B]
[C]
[D]
1
2
0
Noneofthese
Question66.
Evaluate
[A]
[B]
[C]
[D]
1
2
3
0
Question67.
Findtheintegervalueofnforwhich
[A]
[B]
[C]
[D]
isafinitenonzeronumber.
4
5
3
Noneofthese
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Question68.
Thevalueof
[A]
isequalto:
[B]
[C]
[D]
1
Noneofthese
Question69.
Thevalueof
,equals:
[A]
[B]
[C]
[D]
Question70.
If
[A]
[B]
[C]
[D]
existsandisequalto0,then:
a=3andb=9/2
a=3andb=9/2
a=3andb=9/2
Question71.
If
[A]
[B]
[C]
[D]
,whereaisafinitenumber,thenthevalueofa+bis:
1
2
3
Noneofthese
Question72.
.Then:
[A]
[B]
[C]
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[D]
Question73.
WhichofthefollowingfunctionshavefinitenumberofpointsofdiscontinuityinR([.]representsthegreatestintegerfunction):
[A]
[B]
[C]
[D]
Question74.
Thefunction
[A]
[B]
[C]
[D]
is:
Discontinuousatonlyonepoint
Discontinuousexactlyattwopoints
xdiscontinuousexactlyatthreepoints
Discontinuousexactlyatfourpoints
Question75.
If
,iscontinuousatx=0,then:
(Where[.]representsthegreatestintegerfunctionand{.}representsfractionalpartofx)
[A]
f(0)=5/2
[B]
[C]
[D]
Question76.
If
[A]
[B]
[C]
[D]
iscontinuousatx=0,thenthevalueof
is:
4loge2
2loge2
loge2
Noneofthese
Question77.
If
iscontinuousatx=0,thentheorderedpair(a,b)is:
[A]
[B]
[C]
[D]
(1,3)
(1,1)
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Question78.
If
,then:
[A]
fisderivableat
[B]
fiscontinuousbutnotderivableat
[C]
LHDat
is1
[D]
RHDat
is1
Question79.
Whichofthefollowingfunctionsisnotdifferentiableatx=1?
[A]
[B]
[C]
[D]
Noneofthese
Question80.
If
[A]
[B]
[C]
[D]
,then
is:
Differentiableatx=0
Continuousbutnotdifferentiableatx=0
Discontinuousatx=0
Noneofthese
Question81.
If
,then:
[A]
isdiscontinuousatx=0
[B]
isdifferentiableatx=0
[C]
isnondifferentiableatx=0,2
[D]
iscontinuousatx=0
Question82.
Consider
If
iscontinuousatx=1,then:
[A]
[B]
[C]
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[D]
QuestionRevision
Noneofthese
Question83.
Consider
If
iscontinuousat
,then:
[A]
[B]
[C]
[D]
Noneofthese
Question84.
Consider
If
[A]
[B]
[C]
[D]
iscontinuousat
,then
has:
Imaginaryroots
Boththerootspositive
Boththerootsnegative
Rootsofoppositesigns
Question85.
.Then
at
is:
[A]
[B]
[C]
[D]
2
Noneofthese
Question86.
If
[A]
[B]
[C]
[D]
,then
at
is:
4
2
6
0
Question87.
If
,then
is:
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[A]
[B]
[C]
[D]
Question88.
If
[A]
[B]
[C]
[D]
andgiventhatF(5)=5,thenF(10)is:
5
10
0
15
Question89.
If
,then
is:
[A]
[B]
[C]
[D]
Noneofthese
Question90.
If
[A]
[B]
[C]
[D]
,thenfindthevalueof
4
2
0
1
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