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QuestionRevision

Question1.
Whatisthedecreasingstabilityorderofthefollowingcarbocationsasperinductiveeffectonly?

[A]
[B]
[C]
[D]

Question2.
Matchthefollowingelementswithcolourtheircomplexes/compoundsproduceforquantitative/qualitativedeterminationasper
Lassaigne'stest:

[A]
[B]
[C]
[D]

Question3.
Selecttheresponsethatcorrectlyidentifiesthenumberofcarbonatomsofeachhybridizationinthecompoundshown.

[A]
[B]
[C]
[D]

Question4.
Whichofthefollowingcompoundsisnotconstitutional/structuralisomerofthreeothers?
[A]
[B]
[C]
[D]

Methylcyclohexane
1,1,2Trimethylcyclobutane
Cyclopropylcyclobutane
1Heptene

Question5.
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Whichofthefollowingcompoundsis/arearomatic?

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

IandIII
OnlyI
OnlyIII
IIIandIV

Question6.
Whichofthefollowingresonatingstructureofdiazomethylene

,ismoststable?

[A]
[B]
[C]
[D]

Question7.
Howmanyopticallyactiveformsarepresentfortheformula:
[A]
[B]
[C]
[D]

2
3
1
4

Question8.
Whichofthefollowingshowgeometricalisomerism?

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

OnlyI
IandIII
I,IIIandIV
I,IIandIV

Question9.
InwhichofthefollowingcompoundsKJeldahl'smethodcan'tbeused:

Thecorrectchoiceis:
[A]

I&III

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[B]
[C]
[D]

QuestionRevision

II&III
IIIonly
Noneoftheabove

Question10.
Aracemicmixtureisan:
[A]
[B]
[C]
[D]

Equimolarmixtureoftautomers
Equimolarmixtureofenantiomers
Equimolarmixtureofdiastereomers
Equimolarmixtureofcisandtransisomers

Question11.
Whichoneofthefollowinghasthree
[A]
[B]
[C]
[D]

hybridizedcarbonatoms?

Toluene
Xylene
Mesitylene
Noneofthese

Question12.
Whichofthefollowingisnotcorrectfortartaricacid,HOOCCH(OH)CH(OH)COOH?
[A]
[B]
[C]
[D]

Itexistinfourstereoisomericforms
Itcontainstwochiralcarbonatoms
Ithastwoopticallyactiveisomers
Itsmesoformisopticallyinactive

Question13.
Planarcycliccompoundisaromaticifitcontains.
[A]

Acloseloopoflocalized

[B]

Acloseloopofdelocalized

[C]

Acloseloopofdelocalized

[D]

Acloseloopoflocalized

electronswhere
electronswhere
electronswhere
electronswhere

Question14.
Arrangefollowingspeciesindecreasingorderofstability?

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

Q>R>P
R>P>Q
R>Q>P
P>Q>R

Question15.
Fortheestimationofnitrogen,1.4gorganiccompoundwasdigestedbyKjeldahlmethodandtheevolvedammoniawasabsorbedin60
mLof

sulphuricacid.Theunreactedacidrequired20mLof

sodiumhydroxideforcompleteneutralization.Thepercentage

ofnitrogeninthecompoundis:
[A]

5%

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[B]
[C]
[D]

QuestionRevision

6%
10%
3%

Question16.
Whichofthefollowingstatementiscorrectforcyclooctatetraene?
[A]
[B]
[C]

Itisplanarcompound
Itisnonplanarcompound
Ithasdelocalized
electrons

[D]

Ithasdelocalized

electrons

Question17.
Whichofthefollowingiscorrectforintermediatespeciesgivenbelow.

[A]

Xisdestabilizedby

effectof

[B]

Xisstabilizedby+Meffectof

[C]

Xisdestabilizedby

[D]

XislessstablethanY.

effectof

groupwhileYisstabilizedby

effectof

groupwhileYisstabilizedby+Heffectof
groupwhileYisstabilizedby+Heffectof

group
group
group

Question18.
Whichofthefollowingcompoundscanexistinthreestereoisomericforms,twoopticallyactiveandoneopticallyinactive?

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

OnlyII
OnlyI
IandII
I,IIandIII

Question19.
Whichofthefollowingstructuralfeaturesiscorrectforintermediatesmethylfreeradical,methylcarbocationandmethylcarbanion
respectively?
[A]
[B]
[C]
[D]

Question20.
Whichofthefollowingcompoundscanshowtautomerism(ketoenolisomerism)?

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[A]
[B]
[C]
[D]

QuestionRevision

OnlyII
IandII
IIandIII
I,IIandIII

Question21.
Forwhichofthefollowingcompounds,bothmetamersandtautomersarepossible?

I.

II.

III.

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

OnlyII
OnlyI
IandII
IIandIII

Question22.
Howmanyisomericstructuresarepossiblefororganiccompoundhavingmolecularformula
[A]
[B]
[C]
[D]

6
7
8
9

Question23.
Selecttheorderofstabilityofthefollowingcarbocations:

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

I>II>III>IV
III>II>I>IV
IV>III>II>I
II>III>I>IV

Question24.
Inthestructureof4,4diisopropyl2,6dimethylheptane,numberof3oHatomsare:
[A]
[B]
[C]
[D]

18
5
3
4

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Question25.
Outofthefollowing,thealkene(s)thatexhibitsbothopticalisomerismandgeometricalisomerismis/are:
I.4Methylhex2eneII.3Ethylpent1eneIII.3Methylpent1ene
Thecorrectchoiceis:
[A]
[B]
[C]
[D]

IandIII
OnlyI
IIandIII
I,IIandIII

Question26.
Inwhichofthefollowingresonatingstructurepolarcontributingstructureismorestablethanthenonpolarcontributingstructure.
[A]
[B]

[C]
[D]

Noneofthese

Question27.
Totalnumberofstereoisomersoffollowingcompoundare:

[A]
[B]
[C]
[D]

3
2
4
6

Question28.
Whichofthefollowinghassamephysicalproperties(suchasboilingpoint)?
[A]
[B]
[C]
[D]

Constitutionalisomers
Enantiomers
Diastereomers
Noneofthese

Question29.
Arrangethefollowingcarbocationsinthedecreasingorderofnumberofhyperconjugativestructures:
I.

II.

III.

Thecorrectchoiceis:
[A]
[B]
[C]
[D]

I>II>III
II>I>III
III>II>I
I>III>II

Question30.
Whichoneofthefollowinghasthelargestdipolemoment?

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[A]

[B]

[C]

[D]

Question31.
Theelectricfieldinaregionisgivenbythevector
[A]
[B]
[C]
[D]

.Themaximumdropinpotentialwillbealong:

Xaxis
Yaxis
theline4y=x
theline3y=4x

Question32.
AnequilateraltrianglewireframeofsideLhaving3pointchargesatitsverticesiskeptinxyplaneasshown.Componentofelectricfield
duetotheconfigurationinxdirectionatoriginis:[Originiscentroidoftriangle]

[A]
[B]

Zero

[C]
[D]

Noneofthese

Question33.
Thevariationofelectricfieldbetweenthetwochargesq1andq2alongthelinejoiningthechargesisplottedagainstdistancefromq1}
(takingrightwardsdirectionoffieldaspositive)asshown,thenthecorrectstatementis:

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[A]
[B]
[C]
[D]

QuestionRevision

q1andq2arepositiveandq1<q2
q1andq2arepositiveandq1>q2
q1ispositiveandq2isnegativeandq1<q2
q1andq2arenegativeandq1<q2

Question34.
Inaregionofspace,theelectricfieldisinthexdirectionandisgivenas

.Consideranimaginarycubicalvolumeofedgea,

withaitsedgesparalleltotheaxesofcoordinates.Thenetchargeinsidethisvolumeis:
[A]

Zero

[B]
[C]

[D]

Question35.
Inthefigurebelow,apointcharge+Q 1isatthecentreofanimaginarysphericalGaussiansurfaceandanotherpointcharge+Q 2is
outsideoftheGaussiansurface.PointPisonthesurfaceofthesphere.Whichoneofthefollowingstatementsistrue?

[A]
[B]
[C]
[D]

Bothchargescontributetothenetelectricfluxthroughthespherebutonlycharge+Q 1contributestotheelectricfieldatpointP
onthesphere.
Bothchargescontributetothenetelectricfluxthroughthespherebutonlycharge+Q 2contributestotheelectricfieldatpointP
onthesphere.
Onlythecharges+Q 1contributestothenetelectricfluxthroughthespherebutbothcharges+Q 1and+Q 2contributetothe
electricfieldatpointP.
Onlythecharges+Q 2contributestothenetelectricfluxthroughthespherebutbothchargecontributetotheelectricfieldat
pointP.

Question36.
Achargeqisplacedatthecentroidofanequilateraltriangle.ThreechargesequalQareplacedattheverticesofthetriangle.The
systemoffourchargeswillbeinequilibriumifqisequalto:
[A]
[B]
[C]

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[D]

Question37.
Figureshowsacircularsurfaceandaparaboloidalsurface.ItisplacedinauniformelectricfieldofmagnitudeEsuchthatthecircular
surfaceisorientedatrightanglestothedirectionoffield.Electricfluxthroughtheparaboloidalsurfaceis:

[A]

zero

[B]
[C]
[D]

Question38.
ThelinearchargedensityonadielectricringofradiusRisvaryingwith

Thepotentialatthecentreoftheringis:

[A]

Zero

[B]

[C]

[D]

Question39.
AninfiniteplanesheetofaluminiumofareaAhastotalchargeQuniformlydistributedoveritssurfaces.Theelectricfieldhearitssurface
is
.Thesamechargeisspreaduniformlyononesurfaceofglassslabhavingsamefacearea.Theelectricfieldintensitynearits
surfaceis

[A]
[B]
[C]
[D]

Cannotsayanything

Question40.
Twoinfinitesheetshavingchargedensities

areplacedintwoperpendicularplaneswhosetwodimensionalviewisshown

inthefigure.Thechargesaredistributeduniformlyonsheets.FourpointsaremarkedI,II,IIIandIVtheelectricfieldintensitiesatthese
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pointsare

,respectively.Choosethecorrectoption.

[A]

[B]

[C]
[D]

Noneoftheabove

Question41.
ThreeconcentricsphericalconductorsA,BandCarearrangedasshowninthefigure.IftheyaregivenchargesQ 1,Q 2,Q 3
respectively,thepotentialatpointPwillbe:

[A]

[B]

[C]

[D]

Question42.
Twosmallsphereswithmassm1andm2hangfrommassless,insulatingthreadsoflengthl1andl2.Thetwospherescarrychargesq1
andq2respectively.Thesphereshangsuchthattheyareonsamehorizontallevelandthethreadsareinclinedtotheverticalatangle
.Whichoftheconditionisrequiredif

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[A]
[B]
[C]

QuestionRevision

m1=m2
|q1|=|q2|
l1=l2

[D]

Question43.
TwoconcentricconductingthinshellsofradiusRand2Rcarrycharges+Q,+3Qrespectively.
Themagnitudeofelectricfieldatadistancexoutsideandinsidefromthesurfaceofoutersphereissame.Thenthevalueofxis:

[A]
[B]
[C]
[D]

Question44.
Athin,metallicsphericalshellcontainspointchargeqplacedatthecentreandanotherpointchargeq1isplacedoutsideitasshownin
figure.Boththechargesarepositive.Theforceonthecentralchargeduetotheshellis:

[A]
[B]
[C]
[D]

Towardsleft
Towardsright
Upward
Zero

Question45.
Athinsemicircularringofradiusrhasapositivecharge'q'distributeduniformlyoverit.Thenetfield

atthecentreOis:

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[A]

[B]

[C]

[D]

Question46.
Lettherebeasphericallysymmetricchargedistributionwithchargedensityvaryingas

uptor=Rand

forr>R,whereristhedistancefromtheorigin.Theelectricfieldatadistancer(r<R)fromtheoriginisgivenby:

[A]

[B]

[C]

[D]

Question47.
AchargeQisplacedateachoftheoppositecornersofasquare.Achargeqisplacedateachoftheothertwocorners.Ifthenet
electricalforceonQiszero,theQ/qequals:
[A]

[B]
[C]
[D]

Question48.
Electricfluxthroughasurfaceofarea100m2lyinginthexyplaneis
[A]
[B]
[C]
[D]

if

100
141.4
173.2
200

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Question49.
ThemaximummagnitudeofelectricfieldduetoaringofRadius5mandchargeperunitlengthof

atapointontheaxisof

theringis:
[A]

[B]

[C]

[D]

Question50.
ThevariationofelectricfieldthroughasolidsphereofradiusRandhavingnetchargeQisshownis:

[A]

[B]

[C]

[D]

Question51.
AveQchargeisplacedat

anda+veQchargeisplacedat

.AseparatechargeQisfirstbroughtat

wheretheforceexperiencedbyitisF1andthenbroughtatR(y=a)wheretheforceexperiencedbyitisF2.Then
F1/F2is:

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[A]

[B]

[C]

[D]

Question52.
Apointchargeqisplacedinsideaconductingsphericalshellofinnerradius2Randouterradius3RatadistanceofRfromthecentreof
theshell.Theelectricpotentialatthecentreofshellwillbe:

[A]

[B]

[C]

[D]

Question53.
TheelectricfieldduetoapointchargeatdistanceRisE1andtheelectricfieldduetoaringcarryingsamechargeatadistanceRonthe
axisofringisE2.Then,

is:

[A]
[B]
[C]

[D]

Question54.
Thepotentialatthecentreofthesolidspherehavingtotalcharge

uniformlydistributedoverthesphereofradius2unitsis:

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[A]

[B]

[C]

[D]

Question55.
Twosolidspheresofradius2mand4mhavecharges6Cand3Crespectively.Theyareplacedatinfinitedistanceandjoinedbya
conductingwire.Finally,theyattaintheequalpotentialwhichis:
[A]

[B]

[C]

[D]

Question56.
Sixchargesareplacedatthecornerofaregularhexagonasshown.IfanelectronisplacedatitscentreO,forceonitwillbe:

[A]
[B]
[C]
[D]

Zero
AlongOF
AlongOC
Noneofthese

Question57.
Aninfinitenonconductingsheetofchargehasasurfacechargedensityof

.Theseparationbetweentwoequipotential

surfacesnearthesheetwhosepotentialdifferby5Vis:
[A]
[B]
[C]

0.88cm
0.88mm
0.88m

[D]

Question58.
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Potentialdifferencebetweencentre&thesurfaceofsphereofradiusRanduniformvolumechargedensity

withinitwillbe:

[A]

[B]
[C]

[D]

Question59.
Acharge3coulombexperiencesaforce3000Nwhenplacedinauniformelectricfield.Thepotentialdifferencebetweentwopoints
separatedbyadistanceof1cmalongthefieldlinesis:
[A]
[B]
[C]
[D]

10V
90V
1000V
9000V

Question60.
TwoconcentricconductingshellsofradiiRand3RcarryingchargesQand2Qrespectively.Ifthechargeoninnershellisdoubled.How
manytimeswillthepotentialdifferencebetweeninnerandoutershellsbecome?
[A]
[B]
[C]
[D]

2
4
1/2
1/4

Question61.
If

,then:

[A]

[B]

[C]

[D]

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Question62.
Giventhefunction

(wherea>2).Thenf(x+y)+f(xy)=

[A]
[B]
[C]
[D]

Noneofthese

Question63.
Therangeofthefunction
[A]
[B]
[C]
[D]

,is:

[1,3]
[1,5]
[3,5]
Noneofthese

Question64.
Theperiodofthefunction
[A]
[B]
[C]
[D]

,where[.]denotesthegreatestintegerfunction,is:

1
2
Noneofthese

Question65.

Evaluate

[A]
[B]
[C]
[D]

1
2
0
Noneofthese

Question66.
Evaluate
[A]
[B]
[C]
[D]

1
2
3
0

Question67.
Findtheintegervalueofnforwhich

[A]
[B]
[C]
[D]

isafinitenonzeronumber.

4
5
3
Noneofthese

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Question68.
Thevalueof
[A]

isequalto:

[B]
[C]
[D]

1
Noneofthese

Question69.
Thevalueof

,equals:

[A]
[B]
[C]

[D]

Question70.
If
[A]
[B]
[C]
[D]

existsandisequalto0,then:
a=3andb=9/2
a=3andb=9/2
a=3andb=9/2

Question71.
If
[A]
[B]
[C]
[D]

,whereaisafinitenumber,thenthevalueofa+bis:
1
2
3
Noneofthese

Question72.
.Then:

[A]
[B]
[C]
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[D]

Question73.
WhichofthefollowingfunctionshavefinitenumberofpointsofdiscontinuityinR([.]representsthegreatestintegerfunction):
[A]
[B]
[C]
[D]

Question74.
Thefunction
[A]
[B]
[C]
[D]

is:

Discontinuousatonlyonepoint
Discontinuousexactlyattwopoints
xdiscontinuousexactlyatthreepoints
Discontinuousexactlyatfourpoints

Question75.
If

,iscontinuousatx=0,then:

(Where[.]representsthegreatestintegerfunctionand{.}representsfractionalpartofx)
[A]

f(0)=5/2

[B]
[C]
[D]

Question76.

If

[A]
[B]
[C]
[D]

iscontinuousatx=0,thenthevalueof

is:

4loge2
2loge2
loge2
Noneofthese

Question77.
If

iscontinuousatx=0,thentheorderedpair(a,b)is:

[A]
[B]
[C]
[D]

(1,3)
(1,1)

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Question78.
If

,then:

[A]

fisderivableat

[B]

fiscontinuousbutnotderivableat

[C]

LHDat

is1

[D]

RHDat

is1

Question79.
Whichofthefollowingfunctionsisnotdifferentiableatx=1?
[A]
[B]
[C]
[D]

Noneofthese

Question80.
If

[A]
[B]
[C]
[D]

,then

is:

Differentiableatx=0
Continuousbutnotdifferentiableatx=0
Discontinuousatx=0
Noneofthese

Question81.
If

,then:

[A]

isdiscontinuousatx=0

[B]

isdifferentiableatx=0

[C]

isnondifferentiableatx=0,2

[D]

iscontinuousatx=0

Question82.
Consider

If

iscontinuousatx=1,then:

[A]
[B]
[C]
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[D]

QuestionRevision

Noneofthese

Question83.
Consider

If

iscontinuousat

,then:

[A]
[B]
[C]
[D]

Noneofthese

Question84.
Consider

If
[A]
[B]
[C]
[D]

iscontinuousat

,then

has:

Imaginaryroots
Boththerootspositive
Boththerootsnegative
Rootsofoppositesigns

Question85.
.Then

at

is:

[A]
[B]
[C]
[D]

2
Noneofthese

Question86.
If
[A]
[B]
[C]
[D]

,then

at

is:

4
2
6
0

Question87.

If

,then

is:

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[A]

[B]

[C]

[D]

Question88.
If
[A]
[B]
[C]
[D]

andgiventhatF(5)=5,thenF(10)is:
5
10
0
15

Question89.
If

,then

is:

[A]

[B]

[C]
[D]

Noneofthese

Question90.
If

[A]
[B]
[C]
[D]

,thenfindthevalueof

4
2
0
1

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