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(Part test - 6)

Q.1
(a)
Q.2
(a)
(b)
(c)
(d)
Q.3

Instructions:Solve all the questions.

This Test hass 3 sections. Each section has 330 questions each.
Each objective question carries 4 marks. Wrong answer will have -1 mark.
mark
Time limit is 3:00 Hours..
CHEMISTRY
Which of the following compounds shows optical isomerism
[Cu ( NH 3 ) 4 ]2 + (b) [ZnCl
ZnCl4 ]2 (c) [Cr (C2O4 )3 ]3 (d) [Co(CN )6 ]3
Which kind of isomerism is exhibited by octahedral Co( NH 3 ) 4 Br2Cl ?
Geometrical and Ionization
Geometrical and Optical
Optical and Ionization
Geometrical only
Which one of the following has largest number of isomers ?
(a)
[ Ir ( PP3 ) 2 H (CO)]2 + (b)
[Co( NH 3 )5 Cl ]2 +
(c)

[ Ru ( NH 3 ) 4 Cl2 ]+

(d)

[Co(en) 2 Cl2 ]+

Q.4 Mixture X = 0.02 mol of [Co( NH 3 )5 SO4 ] Br and 0.02 mol of [Co( NH 3 )5 Br ]SO4 was
prepared in 2 litre of solution
1 litre of mixture X + excess AgNO3 Y .
1 litre of mixture X + excess BaCl 2 Z
Number of moles of Y and Z are
(a)
0.01, 0.01
(b)
0.02, 0.01
(c)
0.01, 0.02
(d)
0.02, 0.02
Q.5 The complex ion which has no d electrons in the central metal atom is
(a)
[ MnO4 ]
(b) [Co( NH 3 )6 ]3+ (c)
[ Fe(CN ) 6 ]3 (d)
[Cr ( H 2O) 6 ]3+
Q.6 The species havoing tetrahedral shape is
(a) [PdCl4 ]2 (b) [ Ni(CN ) 4 ]2
(c)
[ Pd (CN ) 4 ]2 (d)
[NiCl
NiCl4 ]2
Q.7
Which of the following factors may be regarded as the main cause of lanthanide
contraction
(a)
Poor shielding of one of 4 f electron by another in the subshell
(b)
Effective shielding of one of 4 f electrons by another in the subshell
(c)
Poorer shielding of 5d electrons by 4 f electrons
(d)
Greater shielding of 5d electron by 4 f electrons
Q.8 Of the following outer electronic configurations of atoms, the highest oxidation state is
achieved by which one of them
(a)
(n 1)d 3ns 2 (b)
(n 1)d 5ns1
(c)

(n 1)d 8 ns 2

(d)

(n 1) d 5 ns 2

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Q.9 A reduction in atomic size with increase in atomic number is a characteristic of
elements of
(a)
High atomic masses (b)
d-block
(c)
f block
(d)
Radioactive series
Q.10 Cerium ( Z = 58) is an important member of the lanthanoids
lanthanoids.. Which of the
following statements about cerium is incorrect
(a)
The +4 oxidation state of cerium is not known in solutions
(b)
The +3 oxidation state of cerium is more stable than the +4 oxidation state
(c)
The common oxidation states of cerium ar
are +3 and +4
(d)
Cerium (IV) acts as an oxidizing agent
Q.11 Which one of the following oxides is ionic
Mn2O7
CrO3 (d)
P2 O5
(a)
MnO (b)
(c)
Q.12 When ammonium dichromate is heated, the gas formed is
NH 3
(a)
(b)
(c)
(d)
N2
O2
H2
Q.13 The correct order of magnetic moments (spin only values in B.M.) among is
(a)
[ Fe(CN )6 ]4 > [ MnCl4 ]2 > [CoCl4 ]2
(b)

[ MnCl4 ]2 > [ Fe(CN )6 ]4 > [CoCl4 ]2

(c)

[ MnCl4 ]2 > [CoCl4 ]2 > [ Fe(CN )6 ]4

(d)
[ Fe(CN )6 ]4 > [CoCl4 ]2 > [ MnCl4 ]2
Q.14 The spin magnetic moment of cobalt in the compound

Hg[Co (SCN ) 4 ]

is

3
8
15 (d)
(a)
(b)
(c)
24
Q.15 Which of the following is not oxidized by O3
(a)
KI
(b)
(d)
FeSO4 (c)
KMnO4
K 2 MnO4
Q.16 Excess of KI reacts with CuSO4 solution and then Na2 S 2O3 solution is added to it.
Which of the statements is incorrect for this reaction
Na2 S 2O3 is oxidised (b)
(a)
CuI 2 is formed
(c)
(d)
Evolved I 2 is reduced
Cu 2 I 2 is formed
Q.17 Solder is an alloy of
(a)
70% lead, 30% tin
(b)
30% lead, 70% tin
(c)
80% lead, 20% tin
(d)
90% Cu, 10% tin
+3
+3
+3
+3
Q.18 Arrange Ce , La , Pm and Yb in increasing order of their ionic radii
(a)
Yb+3 < Pm +3 < Ce+3 < La +3
(b)
Ce +3 < Yb+3 < Pm +3 < La +3
(c)
Yb+3 < Pm +3 < La +3 < Ce +3
(d)
Pm +3 < La +3 < Ce +3 < Yb+3
Q.19 Among the following, the compound that is both paramagnetic and coloured is
(NH
NH 4 ) 2 (TiCl6 )
K 3 [Cu (CN 4 )]
(a) K 2Cr2O7 (b)
(c)
(d)
VOSO4
Q.20 Based on lattice energy and other considerations which one of the following alkali
metal chlorides is expected to have the highest melting point
(a)
LiCl (b)
NaCl (c)
KCl (d)
RbCl

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Q.21 Plaster of Paris is
1
CaSO4 . H 2O
2
Q.22 Sodium sulphate is soluble in water whereas barium sulphate is sparingly soluble because
(a)
The hydration energy of Na2 SO4 is less than its lattice energy
(b)
The hydration energy of Na2 SO4 is more than its lattice energy
(c)
The lattice energy of BaSO4 is more than its hydration energy
(d)
The lattice energy has no role to play in solubility
Q.23 In the extraction of aluminium the electrolyte is
(a)
Fused cryolite with felspar
(b)
Fused cryolite with fluorspar
(c)
Pure alumina in molten cryolite
(d)
Pure alumina with bauxite and molten cryol
cryolite
Q.24 One mole of calcium phosphide on reaction with excess water gives
(a)
One mole of phosphene
(b)
Two moles of phosphoric acid
(c)
Two moles of phosphene
(d)
One mole of phosphorus pentaoxide
Q.25 Hydrogen is evolved by the action of cold dil. HNO 3 on
(a)
Fe
(b)
Mn
(c)
Cu
(d)
Al
Q.26 The critical temperature of water is higher than that of O2 because H 2O molecule
has
(a)
Fewer electrons than oxygen
(b)
Two covalent bonds
(c)
V-shape
(d)
Dipole moment
Q.27 Pb and Sn are extracted from their chief ore by
(a)
Carbon reduction and self reduction.
(b)
Self reduction and carbon reduction.
(c)
Electrolysis and self reduction.
(d)
Self reduction and electrolysis.
Q.28 Of the following, which cannot be obtained by electrolysis of the aqueous solution of
their salt
(a)
Ag
(b)
Mg and Al (c)
Cu
(d)
Cr
Q.29 The slag obtained during the extraction of copper from copper pyrites is composed
mainly of
CaSiO3
FeSiO3
CuSiO3
(a)
(b)
(c)
(d)
SiO2
Q.30 Among the following statements, the incorrect one is
(a)
Calamine and siderite are carbonates
(b)
Argentite and cuprite are oxides
(c)
Zinc blende and pyrites are sulphides
(d)
Malachite and azurite are ores of copper
(a)

CaSO4 .2 H 2O (b)

CaSO4 .3H 2O (c)

CaSO4 .H 2O

(d)

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MATHEMATICS
Q.1 Two fair dice are tossed. Let A be the event that the first die shows an even number
and B be the event that second die shows an odd number. The two events A and B are
(a)
Mutually exclusive
(b)
Independent and mutually exclusive
(c)
Dependent
(d)
None of these
Q.2 Three of the six vertices of a regular hexagon are chosen at random. The probability
that the triangle with these three vertices is equilateral, is equal to
1
1
1
1
(a)
(c)
(b)
(d)
5
2
10
20
Q.3 Three distinct numbers are selected from 100 natural number. The probability that
all the three numbers are divisible by 2 and 3 is
4
4
4
4
(a)
(b)
(c)
(d)
25
35
55
1155
Q.4 Out of 21 tickets marked with numbers from 1 to 21, three are drawn at random.
The chance that the numbers on them are in A.P., is
10
9
9
(a)
(b)
(c)
(d)
None of these
133
133
1330
Q.5 The letters of the word ASSASSIN are written down at random in a row. The
probability that no two S occur together is
1
1
1
(b)
(d)
None of these
(a)
(c)
35
14
15
Q.6 Let A and B be two events such that P ( A) = 0.3 and P ( A B ) = 0.8 . If A and B are
independent events, then P(B) =
5
5
2
3
(b)
(a)
(c)
(d)
5
6
7
5
Q.7
If A and B are events such that P( A B) = 3 / 4, P( A B) = 1 / 4, P( A ) = 2 / 3 , then

P( A B) is
(a)
5/12 (b)
3/8
(c)
5/8
(d)
1/4
3
1
1
Q.8 If P ( B ) = , P ( A B C ) = and P ( A B C ) = , then
4
3
3
(a)
1/12 (b)
1/6
(c)
1/15 (d)
1/9

P(B C)

is

Q.9 A pack of playing cards was found to contain only 51 cards. If the first 13 cards
which are examined are all red, then the probability that the missing cards is black, is
25
C13
1
2
1
(a)
(b)
(c)
(d)
51
3
3
2
C13
Q.10 The mean and the variance of a binomial distribution are 4 and 2 respectively. Then
the probability of 2 successes is
28
219
128
37
(a)
(b)
(c)
(d)
256
256
256
256

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Q.11
is

If three dice are thrown simultaneously, then the probability of getting a score of 7
(a)
5/216 (b)
1/6
(c)
5/72 (d)
None of these

Q.12 How many numbers can be made with the help of the digits 0, 1, 2, 3, 4, 5 which are
greater than 3000 (repetition is not allowed)
(a)
180
(b)
360
(c)
1380 (d)
1500
Q.13 The number of words which can be made out of the letters of the word MOBILE
when consonants always occupy odd places is
(a)
20
(b)
36
(c)
30
(d)
720
Q.14 We are to form different words with the letters of the word INTEGER. Let m1 be
the number of words in which I and N are never together, and m2 be the number of words
which begin with I and end with R. Then m1 / m2 is equal to
(a)
30
(b)
60
(c)
90
(d)
180
Q.15 The number of ways in which 5 male and 2 female members of a committee can be
seated around a round table so that the two female are not seated together is
(a)
480
(b)
600
(c)
720
(d)
840
Q.16 Numbers greater than 1000 but not greater than 4000 which can be formed with the
digits 0, 1, 2, 3, 4 (repetition of digits is allowed), are
(a)
350
(b)
375
(c)
450
(d)
576
Q.17 How many different nine
nine-digit
digit numbers can be formed from the digits of the
number 223355888 by rearrangement of the digits so that the odd digits occupy even places
(a)
16
(b)
36
(c)
60
(d)
180
Q.18 Total number of four digit odd numbers that can be formed using 0, 1, 2, 3, 5, 7 are
(a)
216
(b)
375
(c)
400
(d)
720
Q.19 The number of arrangements of the letters of the word BANANA in which two N's
do not appear adjacently is
(c)
80
(d)
100
(a)
40
(b)
60
Q.20

If a1 , a2 , a3 , ......., an , ...... are in G.P. then the value of the determinant

log an
log an + 3

log an +1
log an + 4

log an + 6

log an + 7

Q.21

log an + 2
log an + 5 is (a) 2
log an + 8

(b)

(c)

(d)

sin x cos x cos x

The number of distinct real roots of cos x sin x cos x = 0 in the interval
cos x cos x sin x

is

(a)

(b)

(c)

(d)

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2 + 3 1 + 3
Q.22 If p4 + q3 + r2 + s + t = + 1 2 4 , then value of t is
3 + 4 3
(a)

16

Q.23 If f ( x) =
(a)

Q.24

Q.25

(b)
1

2x

18

(c)

17

x
x( x 1)

(d)
( x + 1)

19

( x + 1) x

, then f (100) is equal to

3x( x 1) x( x 1)( x 2) ( x + 1) x( x 1)
0
(b)
1
(c)
100
(d)
100

If A =
1
(a)
1

0
1 0
, B=
, then the value of for which A2 = B is

1
5 1
(b)
1
(c)
4
(d)
No real values

2 2
1 1 1
4
Let A = 2 1 3 and 10.B = 5 0 . If B is the inverse of matrix A, then
1 1
1 2 3
1

is
(a)

Q.26

Q.27

5
(b)
1
(c)
2
2

If A =
and | A3 | = 125 then =

2
(a)
3
(b)
2
(c)
5

(d)

(d)

If A is a matrix of order 3 and | A | = 8, then | adj A | =

(a)
1
(b)
2
(c)
23
(d)
26

Q.28 The negation of the statement

If I become a teacher, then I will open a school, is :
(1) I will become a teacher and I will not open a school.
(2) Either I will not become a teacher or I will not open a school.
(3) Neither I will become a teacher nor I will open a school.
(4) I will not become a teacher or I will open a school.
Q.29 The inverse of the statement "If the husband is unhappy, then the wife is happy" is :
(a) If the wife is unhappy then the husband is happy
(b) If the husband is happy, then the wife is unhappy
(c) If the wife is happy, then the husband is unhappy
(d) Iff the husband is unhappy then the wife is unhappy
Q.30 If p = ABC is equilateral and q = each angle is 60. Then symbolic form of
statement. ABC is equilateral, if each of its angle is of 60.
(a) p p
(b) p q
(c) p q
(d) pq

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PHYSICS
Q.1 Two rods (one semi-circular
circular and other straight) of
same material and of same cross--sectional area are joined
as shown in the figure. The points A and B are maintained
at different temperature. The ratio of the heat transferred
Straight rod
B
A
through a cross-section
section of a semi
semi-circular rod to the heat
transferred through a cross-section
section of the straight rod in
a given time is
(a)
2:
(b)
1:2
(c) : 2
(d)
3:2
Q.2 Three rods made of the same material and having the same cross
B
section have been joined as shown in the figure. Each rod is of the same
0oC
o
o
length. The left and right ends are kept at 0 C and 90 respectively. The
A
temperature of the junction of the three rods will be
C
(a)
45o C
o
(b)
60 C
(c)
30o C
(d)
20o C
Q.3 The coefficient of thermal conductivity of copper is nine times that
of steel. In the composite cylindrical bar shown in the figure. What will be
100oC
the temperature at the junction of copper and steel
Copper
(a)
75oC
18 cm
(b)
67oC
o
(c)
33 C
(d)
25oC
Q.4 Six identical conducting rods are joined as shown in figure.
Points A and D are maintained at temperatures 200oC and 20oC
respectively. The temperature of junction B will be
(a)
(b)
(c)
(d)

120oC
100oC
140oC
80oC

90oC

90oC

0oC
Steel
6 cm

20oC

200oC
A

Q.5 An ice box used for keeping eatables cool has a total wall area of 1 metre2 and a wall
thickness of 5.0 cm. The thermal conductivity of the ice box is K= 0.01 J/moC.. It is filled with ice
at 0oC along with eatables on a day when the temperature is 30oC. The latent heat of fusion of ice
is 334103 J/kg. The amount of ice melted in one day is (1 day = 86,400 seconds)
seconds
(a)
776 g (b)
7760 g (c)
11520 g
(d)
1552 g
T

Q.6
The graph. Shown in the adjacent diagram, represents the
variation of temperature (T)) of two bodies, x and y having same surface
area, with time (t)) due to the emission of radiation. Find the correct relation
between the emissivity (e)) and absorptivity ((a) of the two bodies

y
x

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(a)

ex > e y & a x < a y

(b)

ex < e y & a x > a y

(c)

ex > e y & a x > a y

ex < e y & a x < a y

(d)
Q.7
The plots of intensity versus wavelength for three black
bodies at temperatures T1, T2 and T3 respectively are as shown.
Their temperature are such that
(a)
T1 >T2 > T3
(b)
T1 >T3 > T2
(c)
T2 >T3 > T1
(d)
T3 >T2 > T1
Q.8 The adjoining diagram shows the spectral energy density
distribution E of a black body at two different temperatures. If
the areas under the curves are in the ratio 16 : 1, the value of
temperature T is
(a)
32,000 K
(b)
16,000 K
(c)
8,000 K
(d)
4,000 K

T3
I

T2

T1

TK
E

2000 K

Q.9 A cup of tea cools from 80oC to 60oC in one minute. The ambient temperature is 30oC. In
cooling from 60oC to 50oC it will take
(a)
30 Seconds (b)
60 Seconds (c)
90 Seconds (d)
50 Seconds
Q.10 The freezing point on a thermometer is marked as 20 and the boiling point at as 150. A
temperature of 60C on this thermometer will be read as
(a)
40
(b)
65
(c)
98
(d)
110
Q.11 The design of a physical instrument requires that there be a constant difference in length
of 10 cm between an iron rod and a copper cylinder laid side by side at all temperatures. If
Fe = 11 10 6 C 1 and cu = 17 10 6 C 1 , their lengths are
(a)
28.3 cm, 18.3 cm
(b)23.8 cm, 13.8 cm (c)23.9 cm, 13.9 cm (d)27.5 cm, 17.5 cm
Q.12 A brass rod and lead rod each 80 cm long at 0C are clamped together at one end with
their free ends coinciding. The separation of free ends of the rods if the system is placed in a
steam bath is ( brass = 18 10 6 / C and lead = 28 10 6 / C )
(a)
0.2 mm (b)
0.8 mm (c)
1.4 mm (d)
1.6 mm
Q.13 A uniform solid brass sphere is rotating with angular speed 0 about a diameter. If its
temperature is now increased by 100
100C.. What will be its new angular speed. (Given
5
B = 2.0 10 perC )
1.1 0 (b)
1.01 0 (c)
0.996 0
0.824 0
(a)
(d)

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Q.14 Two holes of unequal diameters d1 and d 2 (d1 > d 2 ) are
cut in a metal sheet. If the sheet is heated
(a)
Both d1 and d 2 will decrease
(b)
Both d1 and d 2 will increase
d1 will increase, d 2 will decrease
(c)
d1 will decrease, d 2 will increase
(d)

d2
d1

Q.15 The specific heat of a substance varies with temperature t(C) as

c = 0.20 + 0.14 t + 0.023 t 2 (cal / gm C )
The heat required to raise the temperature of 2 gm of substance from 5C to 15C
C will be
(a)
24 calorie
(b)
56 calorie
(c)
82 calorie
(d)
100 calorie
Q.16 2 kg of ice at 20C is mixed with 5 kg of water at 20C in an insulating vessel having a
negligible heat capacity. Calculate the final mass of water remaining in the container. It is given
that the specific heats of water and ice are 1 kcal/kg per C and 0.5 kcal/kg/C while the latent
heat of fusion of ice is 80 kcal/kg
kg
(a)
7 kg (b)
6 kg (c)
4 kg (d)
2 kg
Q.17 A cyclic process ABCA is shown in the V-T diagram. Process on the P-V diagram is
V
C

B
A

(a)
A
B

(b)
A

(c)

P
A

(d)

C
V

Q.18 An ideal gas is taken through the cycle A B C A, V(m3)

as shown in the figure. If the net heat supplied to the gas in the
C
B
2
cycle is 5 J,, the work done by the gas in the process C A is
(a)
5J
1
A
(b)
10 J
P(N/m2)
10
(c)
15 J
(d)
20 J
Q.19 A monoatomic ideal gas, initially at temperature T1 , is enclosed in a cylinder fitted with a
frictionless piston. The gas is allowed to expand adiabatically to a temperature T2 by releasing
the piston suddenly. If L1 and L2 are the lengths of the gas column before and after expansion
respectively, then T1 / T2 is given by
(a)

L1

L2

2/3

(b)

L1
L2

(c)

L2
L1

(d)

L2

L1

2/3

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B
V

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Q.20 During an adiabatic process, the pressure of a gas is found to be proportional to the cube
of its absolute temperature. The ratio C p / Cv for the gas is
3
2

(a)

4
3

(b)

(c)

5
3

(d)

Q.21 Work done by a system under isothermal change from a volume

V1

to

V2

for a gas which

n 2
= nRT
obeys Vander Waal's equation (V n) P +
V

V n
V V
V
V V
+ n2 1 2 (b)
+ n2 1 2
nRT loge 2
nRT log10 2
(a)
V1 n
V1V2
V1
V1V2
V n
V V
V n
VV
+ n 2 1 2 (d)
+ n 2 1 2
nRT loge 2
nRT loge 1
(c)
V1V2
V2 n
V1 V2
V1 n
Q.22 Which of the following graphs correctly represents the variation of = (dV / dP ) / V with
P for an ideal gas at constant temperature
(a)

(b)

(c)

(d)

Q.23 When an ideal diatomic gas is heated at constant pressure, the fraction of the heat energy
supplied which increases the internal energy of the gas, is
(a)

2
5

3
5

(b)

(c)

3
7

(d)

5
7

Q.24 A gas mixture consists of 2 mole of oxygen and 4 mole of argon at temperature T.
Neglecting all vibrational modes, the total internal energy of the system is
(a)
4 RT (b)
15 RT (c)
9 RT (d)
11 RT
Q.25An ideal gas is initially at a temperature T and volume V.. Its volume is increased by V due
to an increase in temperature T,, pressure remaining constant. The quantity =

V
VT

varies with

temperature as

(a)

(b)

T + T
T
(Temp. K
K)

(c)

T + T
(Temp. K)

(d)

T + T
T
(Temp. K)
K

Q.26 Two block of masses 1 kg and 4 kg are connected

by a metal wire going over a smooth pulley as shown in the

10

1kg
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4 kg

T + T
(Temp. K)

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figure. The breaking stress of the metal is 3.18 10 10 N / m 2 .
The minimum radius of the wire so it will not break is
(a)
1 10 5 m
(b)
2 10 5 m
(c)
3 10 5 m
(d)
4 10 5 m
Q.27 Three blocks, each of same mass m, are connected with
wires W1 and W2 of same cross-sectional
sectional area a and Youngs
modulus Y.. Neglecting friction the strain developed in wire W2 is
(a)

2 mg
3 aY

(b)

3 mg
2 aY

(c)

1 mg
3 aY

(d)

W1

W2

3 mg
aY

Q.28 Water rises in a vertical capillary tube upto a height of 2.0 cm.. If the tube is inclined at an
angle of 60 o with the vertical, then upto what length the water will rise in the tube
(a)

2.0 cm (b)

4.0 cm (c)

4
3

cm (d)

2 2 cm

Q.29 An inverted bell lying at the bottom of a lake 47.6 m deep has 50 cm3 of air trapped in it.
The bell is brought to the surface of the lake. The volume of the trapped air will be (atmospheric
pressure = 70 cm of Hg and density of Hg = 13.6 g/cm3)
(a)
350 cm3
(b)
300 cm3
(c)
250 cm3
(d)
22 cm3
Q.30 A homogeneous solid cylinder of length L (L < H / 2) . Cross-sectional
area A / 5 is immersed such that it floats with its axis vertical at the
d
H/2
H/
liquid-liquid
liquid interface with length L / 4 in the denser liquid as shown in
L
the fig. The lower density liquid is open to atmosphere having pressure P0 .
2d
H/2
H/
Then density D of solid is given by
(a)

5
d
4

4
d
5

(b)

(c)

Ad

d
5

(d)

Q.30 A hemispherical bowl just floats without sinking in a liquid of density 1.2 103kg/m3. If
outer diameter and the density of the bowl are 1 m and 2 104 kg/m3 respectively, then the inner
diameter of the bowl will be
(a)
0.94 m (b)
0.97 m (c)
0.98 m (d)
0.99 m
Q.30 A large open tank has two holes in the wall. One is a square hole of side L at a depth y
from the top and the other is a circular hole of radius R at a depth 4y from the top. When the tank
is completely filled with water the quantities of water flowing out per second from both the holes
are the same. Then R is equal to
(a)

(b)

2 L

L
2

(c)

(d)

L
2

Q.30 A ball of radius r and density falls freely under gravity through
a distance h before entering water. Velocity of ball does not change even
on entering water. If viscosity of water is , the value of h is given by
(a)

2 21
g
r
9

(c)

2 4 1
g
r
81

(b)

2 2 1
g
r
81

(d)

2 4 1
g
r
9

11

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