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Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION - I
Straight Objective Type
This section contains 8 multiple choice questions. Each question has choices (A), (B), (C) and (D), out
of which ONLY ONE is correct.
1.
How much volume of 63% w/w aq. HNO3 solution (d = 1.5 g/ml) is diluted with sufficient water to prepare
1 L of 3 M HNO3 solution
(A) 200 ml
(B) 300 ml
(C) 1200 ml
(D) 1300 ml
2.
3.
A chemist decided to determine the Emprical formula of an unknown compound. He collects following
informations :
(I) Compound contains 2 : 1 ratio of 'H' and 'O' atoms(number of atoms).
(II) Compound has 40% C by mass
(III) Compound contains C, H and O only.
What is the empirical formula of the compound :
(A) CH3O
(B) CH2O
(C) C2H2O
(D) CH3O2
(SPACE FOR ROUGH WORK)
RESONANCE
P1R180710C0-1
4.
A 25 ml volume of 0.3 M H3PO3 is completely titrated with 45 ml of Ba(OH)2. The molarity of Ba(OH)2
solution is :
5.
(A) 0.348 M
(B) 0.500 M
(C) 0.167 M
(D) 0.250 M
6.
(D) 8 and 87
The correct decreasing order of preferance of functional group during the IUPAC nomenclature of polyfunctional
groups compound is :
(A) CONH2, COCl, CN, CHO
||
O
||
O
||
O
||
O
RESONANCE
P1R180710C0-2
7.
Select the structure with correct numbering for IUPAC name of the compound :
(A)
(B)
(C)
(D)
RESONANCE
P1R180710C0-3
8.
Number of isomers represented by molecular formula C5H10O2 which have most prior functional group in
IUPAC system.
(A) 2
(B) 3
(C) 4
(D) 5
SECTION - II
Multiple Correct Answers Type
This section contains 4 multiple correct answer(s) type questions. Each question has 4 choices (A),
(B), (C) and (D), out of which ONE OR MORE is/are correct.
9.
Which of the following molarity values of ions are correct for a aqueous solution which contain 5.85 % w/v
NaCl, 5.55% w/v CaCl2 and 6% w/v NaOH. [Na = 23, Cl = 35.5 , Ca = 40, O = 16 ]
(A) [Cl1] = 2M
(B) [Na+] = 1M
(C) [Ca2+] = 0.5 M
(D) [OH] = 1.5 M
10.
11.
Lithium metal reacts with nitrogen gas to produce a white solid Lithium nitride (Li3N) according to the reaction:
6 Li (s) + N2 (g) 2Li3N(s)
If 8.4 g of Li is taken initially with excess of N2 (g) then :
(A) Volume of nitrogen gas consumed at STP is 4.48 L
(B) Total mass of the product obtained is 14g
(C) Total number of atoms obtained in the product is 1.6 NA
(D) Lithium and nitrogen combine in ratio 3 : 2 by mass.
(SPACE FOR ROUGH WORK)
RESONANCE
P1R180710C0-4
12.
SECTION - III
Comprehension Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions have to
be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
The average oxidation states of sulphur in Na2S2O3 and Na2S4O6 are respectively.
(A) + 5 & + 2
(B) + 2 & + 2.5
(C) + 5 & 2.5
(D) + 2 & + 4
14.
Moles of sodium thiosulphate reacted and unreacted after the reaction are respecticvely.
(A) 3 & 2
(B) 2 & 3
(C) 2.2 & 1.8
(D) 1.8 & 2.2
(SPACE FOR ROUGH WORK)
RESONANCE
P1R180710C0-5
15.
If instead of given amount of sodium thiosulphate, 8 moles of sodium thiosulphate along with 3 moles of
CuSO4 were taken initially. Then moles of sodium cuprothiosulphate formed and remaining mole of Na2S2O3
are respectively :
(A) 0.5, 5.5
(B) 0.5, 2.5
(C) 1.5, 4
(D) 2, 2.5
(A) 3-(Prop-2-ynl)hexe-1,3,5-triene
(C) 4-Ethenylhexa-4, 6-dien-1-yne
17.
(A) 4Fluoro1methoxypent1yn4ene
(C) 4Fluoro1methoxypent3en1yne
(B) 1Fluoro1methyl4methoxybut1en3yne
(D) 2Fluro5methoxypent2en4yne
RESONANCE
P1R180710C0-6
18.
SECTION - IV
Vapour density of mixture of NO2 and N2O4 decreases with temp because N2O4 decompose into NO2 on
heating.
20.
The valency factor of H3PO4 against reaction with NaOH, where it form monohydrogenphosphate salt, is
equal to '2'.
21.
If all the oxygen from 40g SO3, 22 g CO2 and 9 g H2O is made to combine to form oxygen gas, then the
volume of oxygen gas produced at NTP is 67.2 L.
22.
All structural isomers have same general formula and different physical properties.
RESONANCE
P1R180710C0-7
SECTION - V
23.
5.6 g of an oxide of a hypothetical metal required 2.4 g coke for its complete reduction to metal along with the
production of CO gas. Find the equivalent weight of metal in case of given metal oxide.
24.
In the reaction, xHI + yHNO3 NO + 2 + H2O. Calculate the sum of (x + y) value for per mole of nitric
oxide in balanced reaction.
25.
How many moles of cuprous sulphide could be oxidised by 4 moles of acidified K2Cr2O7 solution to produce
a bent-shaped gas (SO2) and Cu2+ ?
26.
The total number of metamers possible for a compound with the molecular formula C5H12O.
RESONANCE
P1R180710C0-8