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Chemical calculations:
Chemical reactions:
Important:
Review problems:
Calculations involving moles, Avogadro's number, density, mass percent.
I
II.
The density of ice is 0.917 g mL1 at 0 C and 101.3 kPa of pressure. Calculate
the volume occupied by 1.000 kg of ice under these conditions.
III.
An aqueous solution is 15.0% NaCl by mass and has a density of 1.15 g mL1.
(a)
Calculate the mass in grams of 300.0 mL of this solution.
(b)
Calculate the mass of NaCl present in 300.0 mL of this solution.
Calculations involving solutions, solution preparation and dilution.
1.
2.
3.
Calculate the volume (in mL) of 0.2002 mol L 1 KMnO4(aq) which contains
7.140 g of KMnO4.
4.
How many milliliters of 6.00 mol L1 HNO3 (aq) are required to make 500.0 mL of
0.255 mol L 1 HNO3(aq)?
5.
6.
(b) Be(NO3)2A4H2O
8.
9.
10.
When a 6.20 g sample of a compound containing only carbon, hydrogen and sulfur
reacted with an excess of Cl2, 16.7 g of HCl and 26.4 g of CCl4 were obtained.
Determine the empirical formula of the compound.
11.
Balancing equations.
12.
(b)
(c)
(d)
(e)
(f)
(g)
(h)
(i)
14.
Given the following equation for the combustion of ammonia with oxygen at high
temperatures: 4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g)
(a)
(b)
If 338 g of H2O are formed, calculate the maximum mass of NO formed and the
minimum masses of ammonia and oxygen which must be consumed.
15.
Determine the limiting reagent when 101.0 g of both reactants are mixed.
Justify your answer.
(b)
Assuming the limiting reagent is totally consumed, calculate the mass of the
excess reagent which remains unreacted.
(c)
17.
(a)
(b)
18.
Manganese can be isolated from MnO2 by the thermite reaction, in which the oxide
reacts with aluminum metal forming Mn and A12O3 and liberating a large amount of
heat. A mixture of 227g of MnO2 and 73.4g of Al is allowed to react to completion.
Calculate the actual yield of Mn if the % yield of the reaction is 75.0 %.
3 MnO2(s) + 4 Al(s) 3 Mn(s) + 2 Al2O3(s)
Gravimetric analysis.
19.
A 4.270 g sample of an unknown metal bromide XBr3 was dissolved in water and
treated with excess AgNO3. If 8.140 g of AgBr were recovered,
(a)
(b)
(c)
(d)
(e)
Identify element X.
20.
A 3.500 g sample of a compound of cobalt and iodine was dissolved in water and
treated with excess AgNO3 solution producing 5.255 g of Agl precipitate.
Determine the empirical formula of the compound.
21.
A 2.714 g sample of the hydrated salt, CuSO4AXH2O was dissolved in water and
treated with excess Ba(NO3)2 solution producing 2.537 g of BaSO4 precipitate.
Determine the value of X in the formula CuSO4AXH2O.
23.
Vitamin C, ascorbic acid, H2C6H6O6, (a weak diprotic acid), can be taken orally in
tablet form where it is the main ingredient. A vitamin C tablet with a mass of
0.4902 g is dissolved in sufficient deionized H2O and neutralized by 20.14 mL of
0.2742 mol L1 NaOH(aq). The neutralization reaction can be represented as
follows:
H2C6H6O6(aq) + 2 NaOH(aq) Na2C6H6O6(aq) + 2 H2O(l)
(a)
(b)
24.
25.
Calculate the volume in milliliters of 0.3450 mol L1 KOH(aq) required for the
complete neutralization of 38.55 mL of 0.1275 mol L1 H3PO4(aq). Hint: Write a
balanced equation for the reaction.
Strong electrolytes.
26.
27.
28.
Miscellaneous problems.
29.
30.
31.
32.
A compound of metal M and oxygen has the empirical formula M3O4 and is 72.36%
M by mass. Calculate the molar mass of metal M and hence determine its identity.
33.
34.
35.
36.
A crucible containing some limestone, CaCO3, has a total mass of 27.133 g. The
crucible is heated to decompose all the limestone according to the following
equation:
CaO(s) + CO2(g)
CaCO3(s)
heat
After the decomposition was complete, the crucible was cooled to room
temperature and reweighed giving a mass of the crucible and its contents of
26.847 g. Calculate the mass of the crucible.
37.
An element X forms an iodide XI3 and a chloride XCI3. The iodide is quantitatively
converted to the chloride when it is heated in a stream of chlorine:
2 XI3 + 3 Cl2 6 2 XCl3 + 3 I2
If 0.5000 g of XI3 is treated, 0.2360 g of XCl3 is obtained.
38.
(a)
(b)
Identify element X.
A mixture containing KClO3, KHCO3, K2CO3, and KCl was heated strongly,
producing CO2, O2, and H2O gases according to the following equations:
2 KClO3(s) 2 KCl(s) + 3 O2(g)
8
40.
A 1.9791 g sample of MnCl2AXH2O was heated to drive off the water of hydration,
leaving 1.2584 g of solid residue. Determine the value of X in the formula of the
hydrate.
41.
42.
A 25.00 mL sample of HCl(aq) was added to a 0.1000 g sample of CaCO3. All the
CaCO3 reacted, leaving some unreacted HCl(aq).
CaCO3(s) + 2 HCl(aq) CaCl2(aq) + H2O + CO2(g)
The unreacted HCl(aq) required 43.82 mL of 0.01185 M Ba(OH)2(aq) to complete
the following reaction.
2 HCl(aq) + Ba(OH)2(aq) BaCl2(aq) + 2 H2O(l)
Calculate the molar concentration of the original HCl(aq).
43.
44.
neutralized with an excess of HCl(aq). Then, the unreacted HCl can be titrated
with NaOH. In this way a quantitative determination of NO3 can be achieved. A
25.00 mL sample of nitrate solution was treated with zinc in basic solution. The
NH3(g) was passed into 50.00 mL of 0.1500 M HCl(aq). The unreacted HCl
required 32.10 mL of 0.1000 M NaOH for its titration. What was the [NO3] in the
original sample? Hint: Write balanced equations for the reaction of NH3(aq) with
HCl(aq) and HCl(aq) with NaOH(aq).
45.
(a)
(b)
46.
(b)
A 10.00 milliliter sample of the concentrated nitric acid was diluted with
water to a total volume of 500.0 milliliters. Then 25.00 milliliters of the
diluted acid solution was titrated with the standardized NaOH solution
prepared in part (a). The equivalence point was reached after 28.35
milliliters of the base had been added. Calculate the molarity of the
concentrated nitric acid.
47.
A hydrated nickel salt is 23.8% Ni, 13.0% S, 58.3% O and 4.9% H by mass. If its
molar mass is 246.9 g mol1, determine the formula of the hydrated salt.
48.
49.
50.
51.
52.
Predict whether or not a precipitate will form when the following aqueous solutions
are mixed using your knowledge of the solubility rules. Write balanced molecular
(whole formula) equations for all reactions which yield a precipitate.
(a)
AgNO3(aq) + CaCl2(aq)
(b)
(c)
CuSO4(aq) + Fe(NO3)3(aq)
(d)
Na2SO4(aq) + BaBr2(aq)
(e)
Pb(NO3)2(aq) + HI(aq)
(f)
CrCl3(aq) + NaOH(aq)
(g)
NH4NO3(aq) + Na 3PO4(aq)
(h)
Hg2(NO3)2(aq) + NaCl(aq)
(i)
K2S(aq) + NiCl2(aq)
(j)
Ca(NO3)2(aq) + K 2CO3(aq)
(k)
(l)
CaI2(aq) + (NH4)3PO4(aq)
Given the following word equations, write molecular (whole-formula form), total
ionic (ionic form) and net ionic equations for each:
(a)
(b)
(c)
(d)
(e)
(f)
(g)
(h)
Answers:
I
II
III
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
(a)
177 g O2, 133 g NO, 120 g H2O
91.5% yield
0.868 g Ag2S
12
(b)
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
(a)
HNO3 is LR (b)
11.4g KCl
(c)
121.5 g KNO3
(a)
2.25 g NO
(b)
90.6% yield
84.1 g Mn
(a)
n(AgBr) 0.04335 mol
(b) n(XBr3) 0.01445 mol
1
(c)
molar mass of XBr3 295.4 g mol (d)
molar mass of X = 55.8 g mol1
(e)
X is iron
Empirical formula is Col2
X = 5, compound is CuSO4A5H2O
0.1225 mol L 1 H2SO4(aq)
(a)
0.4863 g
(b)
99.20% purity
94.71%
42.74 mL
[Na+] = 0.0656 mol L 1, [SO42] = 0.0328 mol L 1
[Cl] = 0.425 mol L 1
[Al3+(aq)] = 0.128 M [Na +(aq)] = 0.384 M [SO42G(aq)] = 0.384 M
4.75% HC 2H3O2
x = 12
x = 2, potassium bromite
M is iron
15.0 g Ca3(PO4)2
62.7% yield of K 2Cr2O7
C5H9N3
mass of crucible = 26.483 g
(a) molar mass of X = 138.9 g mol1 (b) X is La (atomic # = 57)
56.0 % KCl
[H2SO4(aq)] = 0.04563 M
X=4
[Na+] = 0320 mol L 1
[HCl] = 0.1215 mol L 1
87.3% yield
[NO3] = 0.1716 mol L 1
EF = MF = C 3H6O2
(a) [NaOH] = 0.2764 mol L 1 (b) [HNO3] = 15.67 mol L 1
NiSO3A6 H2O
LiClO3
Iridium
74.3 g P 4
2 AgNO3(aq) + CaCl2(aq) 2 AgCl(s) + Ca(NO3)2(aq)
Na2SO4(aq) + BaBr2(aq) BaSO4(s) + 2 NaBr(aq)
Pb(NO3)2(aq) + 2 HI(aq) PbI2(s) + 2 HNO3(aq)
CrCl3(aq) + 3 NaOH(aq) Cr(OH)3(s) + 3 NaCl(aq)
Hg2(NO3)2(aq) + 2 NaCl(aq) Hg2Cl2(aq) + 2 NaNO3(aq)
K2S(aq) + NiCl2(aq) NiS(s) + 2 KCl(aq)
Ca(NO3)2(aq) + K 2CO3(aq) CaCO3(s) + 2 KNO3(aq)
3 CaI2(aq) + 2 (NH4)3 PO4(aq) Ca3(PO4)2 (s) + 6 NH4I(aq)
13
52.
14