Beruflich Dokumente
Kultur Dokumente
285-293, 1996
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ELSEVIER
from
initially
II,
supercritical
carbon dioxide
Blowdown phenomena
Blowdown of pressure vessels and gas pipelines are of
great importance to the chemical and oil/gas industries
as pressure release can occur during a hazard, for maintenance reasons, or even as a part of the process cycle.
Haque et al. investigated experimentally the temperature distribution within large pressure vessels of various
geometry during pressure release using nitrogen and
285
286
Blowdown
of carbon
dioxide:
mixtures of nitrogen and carbon dioxide. Initial conditions were varied to be subcritical as well as supercritical (PO= 15 MPa), the fluid conditions during the blowdown were gaseous and two-phase due to condensing.
Full scale depressurization of a section of a riser platform using natural gas was conducted by Evanger et al.*
in order to measure the outer surface temperature of the
pipeline. Experiments of initial fluid pressures up to
pa = 8.8 MPa were carried out. Two-phase phenomena
during the pressure release were not reported. Theoretical work in this area was carried out by Chen et ~1.~.
A hyperbolic finite difference method using separated
momentum equations was proposed to calculate the twophase blowdown of single- and multi-component mixtures from pipelines.
In the nuclear power industries the hypothetical loss
of coolant accident (LOCA) is one of the most significant aspects of the design and test of the emergency
cooling system of a reactor. Hence blowdown of the
cooling circuit of pressurized water reactors has been
extensively investigated4. Extremely rapid depressurization of long horizontal pipes containing initially subcooled water was investigated by Edwards and OBrien,
and later by Alamgir et ~1.~. New theories have been
proposed to explain the pressure disturbances and the
violent phase change effects. Theoretical investigations
on blowdown processes of long pipes have been
accomplished by Krause. A one-dimensional mixture
model was proposed to be solved using the method of
characteristics. Applying the pipe problem of Edwards
and OBrien the model was verified.
Further investigations were carried out for blowdown processes from initially saturated conditions. This
kind of initial condition is indicated by State A in
Figure 1. The vessel contains saturated liquid with saturated vapour on top. After the top vented blowdown is
started only vapour is being blown off so that the pressure inside the vessel decreases. Subsequently, the boiling
process within the saturated liquid starts to develop. The
liquid-vapour interface rises due to the growth of vapour
bubbles. Two-phase flow venting occurs when the
liquid-vapour interface reaches the top of the vessel.
B. Gebbeken
and R. Eggers
is=Coj +V,,,
(2)
-*
=
vdrift
*
[-I*
U&P
P:
T = TCn
-73
I
A ,J p < kit
,
I
S'
EC
vapor
Specific entropy
Figure 1 Temperature-specific
entropy diagram, various initial
fluid conditions for pressure release
(1)
i&i,
1.18 - 1.53.
(3)
From this equation it becomes evident that the drift velocity strongly depends on the difference of the phase densities and on the surface tension. The surface tension in
turn strongly affects the size of the bubbles.
Considering depressurization of initially supercritical fluids various process characteristics can be observed
depending on the initial conditions. Possible initial conditions are indicated by State B and State C in Figure 1.
Considering State B the pressure release is started from
the supercritical condition on the left-hand-side of the
critical point (sB<S,,i~), whereas for State C the process
is started from the right-hand-side of the critical point
(S&S,&. Assuming an isentropic change of state until
saturation conditions are reached, condensation occurs if
the initial state is located on the right-hand-side whereas
flashing will occur if the process is initiated from the
left-hand-side of the critical point. The latter case
denoted by State B in Figure 1 was investigated by the
Blowdown
of carbon
dioxide:
Experimental
The experimental investigations consisted of pressure
release experiments
from initially subcooled and
supercritical conditions using pure carbon dioxide (CO,).
The critical data of carbon dioxide are pcrit = 7.38 MPa
and Tcrit= 304.2 K17.
In Figure 2 a sketch of the experimental plant is
shown. The volume of the cylindrical high pressure test
vessel is V= 0.05 m3. A system pressure up to
= 30 MPa can be achieved. The inner diameter of
P
thmeapressurevessel is d = 0.242 m, the height to diameter
ratio is h/d = 4.5. A venting pipe of cross-sectional area
A = 50 mm* is connected to the top. An exchangeable
orifice for varying the cross-sectional area of the venting
line is installed. A quick-opening ball valve is used to
assure the controlled initiation of the blowdown. Ambient pressure of approximately pa = 0.1 MPa can be
assumed at the end of the venting line. The test fluid
was filled into the vessel from the top by using a diaphragm pump.
Various measuring sensors are used to obtain information about the transient process parameters. A piezoresistive pressure transducer is attached to the bottom of
the vessel. It proved to be important to use a sensor with
low signal deviation due to temperature change since
CCD-Comer0
LrzFF-1
I
T
storage
tonk
1h
3
G
T
-&)P
(4)
(5)
P(P)
p = p(p).
(6)
The liquid to vapor phase density ratio during the experiments performed varied from p,Ipv = 3 to p,/pv = 20.
Approximately 70% of the cross-sectional area of
the pressure vessel was irradiated by a broad beam as
can be seen in Figure 3. Thus an accurate cross-sectional
averaged magnitude for the density can be assured.
However, the dynamic error due to a changing void fraction during a time interval was proved to be negligible
due to the large cross-sectional area irradiated and the
low phase velocities. The error due to void orientation
effects is negligible due to the fact that 7Cs is a hard
source for which the absorption is weak and can be
approximated by a linear relationship. This was proved
r--
pressure
vessel50 I
670
DR
PR
Experimental
mm
c?
00
Figure 2
287
and R. Eggers
I-----M
B. Gebbeken
set up
counter,
photomultiplier
WR
Figure 3
Gamma
densitometer
288
Blowdown
i&t) =
&l(t)
The weight sensors are operated by strain gauge technique. The measuring signal is low-pass filtered using a
limiting frequency off= 10 s-l.
All measuring signals are processed by an A/D converter and a personal computer. The pneumatic ball
valve which is used to open the venting line is also controlled by the PC. A measuring frequency off= 20 s-l
per sensor proved to be convenient for the experiments
performed such that no information was lost and the
amount of data could still be managed.
Besides measuring the process parameters an
important issue for describing the thermohydraulic
phenomena is a visual observation. In high pressure
technology, observation windows of various designs are
used. The visible diameter of these windows is small
because of thermal and mechanical stress. Strict safety
requirements must be met when designing windows
exposed to dynamic stress.
To observe the transient thermohydraulics in the
vessel during the depressurization of initially supercritical carbon dioxide a pressure capsulated borescope combined with a CCD camera is used. Usually borescopes
are designed for low pressure ranges. Therefore, a pressure capsule for the borescope had to be designed for this
application. The capsulated borescope is put through the
cover of the vessel. Thus a view from the top into the
vessel is achieved. The CCD camera is connected to the
borescope outside of the vessel.
The pressure capsule is mounted on the cover of
the pressure vessel. The borescope is capsulated by a
pressure pipe. The pressure pipe is supported and sealed
in a bore of the cover of the vessel. Using an electrical
drive the borescope can be moved vertically from the
lower end of the cover to a depth of 500 mm inside the
vessel. At the tip of the pressure pipe a sapphire glass
is located. The window is sealed such that mechanical
stress within the window cannot develop even for high
temperature gradient conditions. The thickness of the
window is 8 mm. An anti-reflex coating is provided for
both sides of the window to avoid reflections of the light
which is transported through the borescope into the vessel to illuminate the object.
During the pressure release the pictures obtained by
the CCD camera are taped. The video pictures are provided with a time code. The timing of the video pictures
and the measuring signals are synchronised. Thus the
height of the flashing liquid layer can be obtained.
transients
20 MPa
T,=313K
15
Amin = 17 mm2
I---+
/
;ii
%
; 0
3
8
h
5
0
0
Time
Figure 4 Phase distribution
supercritical conditions
150
100
50
during
(s)
blowdown
from
initially
Blowdown
of carbon
dioxide:
B. Gebbeken
289
and R. Eggers
Initial conditions:
T,=313K
Amin = 50 mm2
0
0
25
50
Time
Figure 6
pressure
Pressure transients
75
(s)
during
blowdown,
varied initial
Initial conditions:
Initial conditions:
p0 = 15 MPa
PO=15MPa,T,=313K
A,i,
--
A,i,
= 17 mm2
A,i,
= 50 mm2
= 50 mm2
----T,=298K
--
T,=313K
10
I
I
\
..
\
.
0
0
25
50
Time
during
75
(s)
blowdown,
25
50
Time
varied initial
75
(s)
varied venting
290
Blowdown
of carbon
dioxide:
B. Gebbeken
and R. Eggers
pO =
T,=313K
288
Amin= 17mm2
238
I I
213
0
50
100
T4-T8
150
200
blowdown
from
Time (s)
Figure 8 Temperature
transients
initially supercritical conditions
during
Blowdown
of carbon
B. Gebbeken
dioxide:
1.0
1.0
0.8
0.8
291
and R. Eggers
Initial Condiiins
T,=313K,p0=15MPa
0.2
0.2
0.0
0.0
50
25
75
Void fraction
fluid conditions,
t=2os
t=4os
0.8
0.6
0.4
Time (s)
Figure 9
A
+
0.2
0.0
100
?? !=lOs
0 t=30s
1.0
time and the resulting lower evaporation rates. Accordingly, the liquid layer was observed to drop down at
later times.
The effect of varied cross-sectional area of the venting pipe on the void fraction profile is shown in
Figure 11. No orifice was installed in this case such that
the minimum cross-sectional area of the venting line was
A,i = 50 mm*. The initial fluid conditions
were
1.0
Initial Conditions:
0.8
To=313K,po=25MPa
*min = 17
mm*
?? t=1os
A
0.0
0.2
0.4
t=20s
0.6
Void fraction
0.8
1.0
Figure 10
Initial Conditions
- T,=313K,p0=15MPa
0.2
&,,, = 50 mm
W
0
0.0
t=1os
t=3os
t=20s
0.0
0.2
0.4
0.6
Void fraction
Figure 11
?? t=4Os
0.8
1.0
292
Blowdown
of carbon
dioxide:
B. Gebbeken
Conclusions
Experimental investigations of blowdown processes for
initially supercritical carbon dioxide are presented. The
pressure release was started from the left-hand-side of
the critical point (so < s,,it) such that flashing occurred
after saturation conditions were reached. Thermohydraulic phenomena were discussed, particularly the pressure transients, the axial temperature profile, and the axial
void fraction profiles.
After blowdown is initiated the fluid remains single-phased until saturation conditions have been reached.
A two-phase mixture is blown off after the onset of
flashing. A vapour dome develops on top of the liquid
layer. Subsequently,
the vapour phase including
entrained liquid drops is blown off.
For all experiments performed a sharp bend of the
pressure curve was observed at the onset of flashing. The
pressure at which flashing occurred first depends mainly
on the initial conditions due to the almost isentropic
change of state during the supercritical/subcooled blowdown.
The void fraction profile was measured using a
gamma densitometry. Significant gradients in void fraction can be observed during the blowdown process due
to phase separation effects. Phase separation effects
depend on the difference between the saturation densities
of both phases and the surface tension. Therefore, the
LJ7 k
h
Phase 2
Phase 1
&
&
Phase 4
Phase 3
Figure 12
Characteristic
and R. Eggers
Blowdown
of carbon
dioxide:
Acknowledgements
The authors thank the Deutsche Forschungsgemeinschaft
for financial support of this research under grant No.
Eg 7212.
References
1 Haque A., Richardson,
2
3
4
5
6
7
8
9
10
11
_I
12
B. Gebbeken
and R. Eggers
293
Nomenclature
A
C0
d
D
f
h
j
M
ni
P
.Y
t
T
I
vdrlft
V
Greek symbols
E
Void fraction
P
cT
Subscripts
a
crit
g
max
0
n
Ambient
Critical
Gas
Liquid
Maximum
Initial
Saturated liquid
Saturated vapor