Beruflich Dokumente
Kultur Dokumente
w
ap
eP
e
tr
.X
5070/01
CHEMISTRY
Paper 1 Multiple Choice
May/June 2004
1 hour
Additional Materials:
[Turn over
om
.c
s
er
2
1
Aqueous hydrogen peroxide undergoes catalytic decomposition as shown in the equation below.
2H2O2(aq) 2H2O(l) + O2(g)
The diagram shows part of the apparatus used to measure the rate of decomposition.
X
aqueous
hydrogen
peroxide
catalyst
burette
gas syringe
measuring cylinder
pipette
chromatography paper
beaker
spot of mixture
liquid
be placed so that the spot is just below the level of the liquid.
UCLES 2004
5070/01/M/J/04
3
3
In a sample of air at 25 oC, the molecules of oxygen, nitrogen and carbon dioxide all move with
different average speeds.
Which of the following lists the molecules in order of decreasing average speed?
fastest
slowest
carbon dioxide
oxygen
nitrogen
nitrogen
oxygen
carbon dioxide
oxygen
carbon dioxide
nitrogen
oxygen
nitrogen
carbon dioxide
Which of the following is the best method of obtaining pure water from ink?
A
chromatography
distillation
filtration
freezing
18 x 100
160
UCLES 2004
5 x 18 x 100
160 + 1 8
18 x 100
160 + 18
5070/01/M/J/04
5 x 18 x 100
160 + (5 x 18)
[Turn over
4
6
fertiliser
solution
dirty green
precipitate
forms
warm the
mixture
UCLES 2004
5070/01/M/J/04
5
8
Li+
Mg2+
B
key
Silicon atom
Oxygen atom
UCLES 2004
5070/01/M/J/04
[Turn over
6
11 In the circuit below, the lamp lights up.
lamp
electrodes
substance X
liquid ethanol
12 The formula of china clay (aluminium silicate) was shown in an old book as Al2O3.2SiO2.2H2O.
This formula is shown in a modern book as Al2(OH)x Si2Oy.
What are the values of x and y in the modern formula?
x
13 What is the concentration of iodine, I2, molecules in a solution containing 2.54 g of iodine in
250 cm3 of solution?
A
U4Cl
UCl2
UCLES 2004
UCl4
U2Cl
5070/01/M/J/04
7
15 The equation for the burning of hydrogen in oxygen is shown below.
2H2(g) + O2(g) 2H2O(g)
Which information does this equation give about the reaction?
A
16 A current was passed through concentrated aqueous potassium chloride, KCl, as shown.
+
concentrated aqueous
potassium chloride
K+ only
Cl and OH
K+ only
Cl only
K+ and H+
Cl only
K+ and H+
Cl and OH
UCLES 2004
5070/01/M/J/04
[Turn over
8
17 When the experiment shown was set up, the bulb lit, but there were no decomposition products at
the electrodes.
lamp
+ve
_ve
electrodes
X
What is X?
A
bromine
mercury
H2O(l) H2O(s)
UCLES 2004
5070/01/M/J/04
9
19 The diagram shows apparatus for measuring the volume of hydrogen given off when an excess of
dilute hydrochloric acid is added to powdered metal. The volume of gas is measured at room
temperature and pressure.
dilute
hydrochloric
acid
tap
graduated
tube
water
metallic
powder
The experiment is carried out three times, using the same mass of powder each time but with
different powders:
pure magnesium
pure zinc
Which powder gives the greatest volume of hydrogen and which the least volume?
greatest volume of H2
least volume of H2
magnesium
zinc
magnesium
the mixture
zinc
magnesium
zinc
the mixture
20 Which change will increase the speed of the reaction between 1 mol of each of the gases, X and
Y?
A
a decrease in temperature
UCLES 2004
5070/01/M/J/04
[Turn over
10
21 Dilute hydrochloric acid was reacted with magnesium ribbon and the volume of hydrogen gas
evolved was measured for the first 80 s.
40
30
total
volume of
20
hydrogen
produced / cm3
10
0
10
20
30
40
60
50
70
80
0.4 cm3 / s
2.5 cm3 / s
4 cm3 / s
40 cm3 / s
22 Small portions of aqueous potassium iodide and of acidified, aqueous potassium manganate(VII)
were added to four solutions. The colour changes seen are shown in the table.
solution number
potassium iodide
potassium manganate(VII)
colourless to red
purple to colourless
colourless to red
no change
no change
purple to colourless
no change
no change
1 only
UCLES 2004
1 and 2 only
1 and 3 only
5070/01/M/J/04
2 and 4 only
11
23 The table gives information about three indicators.
colour change
indicator
low pH
methyl orange
bromothymol blue
phenolphthalein
pH at which colour
change takes place
high pH
red
yellow
4.0
yellow
blue
6.5
colourless
pink
9.0
If equal volumes of these three indicators were mixed, which colour would be observed at pH 5?
A
blue
green
orange
yellow
temperature / oC
10
20
30
40
50
HCl / cm3
50
40
30
20
10
NaOH / cm3
UCLES 2004
5070/01/M/J/04
[Turn over
12
25 Which method of preparation of a pure salt solution requires the use of a pipette and burette?
A
BaCl 2(aq) +
H2SO4(aq)
BaSO4(s)
2HCl (aq)
CuO(s)
2HCl (aq)
CuCl 2(aq)
H2O(l)
KOH(aq)
HCl (aq)
KCl (aq)
H2O(l)
MgCO3(s) +
H2SO4(aq)
MgSO4(aq) +
H2O(l) + CO2(g)
26 Which statement about the manufacture of ammonia by the Haber Process is correct?
A
element 2
element 3
1 and 2
1 and 3
2 and 4
3 and 4
UCLES 2004
5070/01/M/J/04
element 4
13
29 Sodium, aluminium and sulphur are in the same period of the Periodic Table.
What trend in types of oxide occurs across this period?
left
right
acidic
amphoteric
basic
amphoteric
basic
acidic
basic
acidic
amphoteric
basic
amphoteric
acidic
30 Use the Periodic Table to decide which element has all four of the properties shown.
caesium, Cs
cobalt, Co
iodine, I
strontium, Sr
painting it
The activation energy for the reaction of aluminium with other elements is too high.
UCLES 2004
5070/01/M/J/04
[Turn over
14
33 Which oxide can be reduced to the metal by hydrogen?
A
calcium oxide
copper(II) oxide
magnesium oxide
sodium oxide
34 The data gives the concentration, in parts of pollutant per billion parts of air, of polluting gases in
four different industrialised cities.
In which city are limestone buildings under greatest threat from pollution?
city
sulphur
dioxide
nitrogen
dioxide
ozone
17
46
23
32
33
30
38
40
11
45
14
21
mineral salts
nitrates
oxygen
phosphates
sewage
simple sugar
condensation.
hydrogenation.
hydrolysis.
polymerisation.
UCLES 2004
5070/01/M/J/04
15
37 Methane, CH4, the first member of the alkane homologous series, has a boiling point of 161 oC.
Which molecular formula and boiling point could be correct for another alkane?
molecular formula
boiling point / oC
C2H4
88
C2H6
185
C3H6
69
C3H8
42
results
stays red
aqueous bromine
stays brown
lighted splint
gas burns
ammonia
ethene
methane
oxygen
39 An organic compound, Y, reacts with sodium hydroxide to give a compound with formula
C3H5O2Na.
What is compound Y?
A
ethanol
propane
propanoic acid
propanol
C2H4
UCLES 2004
C2H6
C2H5OH
5070/01/M/J/04
CH3CO2H
Magnesium
Sodium
University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES) which is itself a department of
the University of Cambridge.
5070/01/M/J/04
Strontium
Rubidium
89
227
Actinium
Ac
Key
X = atomic symbol
72
Hafnium
Lanthanum
57
178
40
Hf
Zr
91
Zirconium
22
139
Yttrium
89
Titanium
Ti
48
La
39
21
Scandium
Sc
45
88
Radium
87
Francium
226
Ra
56
Barium
Caesium
Fr
55
137
Ba
133
Cs
38
Sr
Rb
37
88
85
20
Ca
Calcium
Potassium
19
40
12
24
Mg
23
Na
Beryllium
Lithium
39
11
Be
II
Li
Ta
181
Niobium
Nb
93
90
58
73
Mo
96
184
Protactinium
Thorium
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
55
27
59
28
59
29
64
30
65
Ru
101
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
Iron
Fe
56
Co
150
Sm
Pu
94
152
Eu
Am
95
Americium
63
Europium
78
Platinum
Pt
Iridium
195
46
Palladium
Pd
106
Ir
Plutonium
62
Ni
Nickel
192
Samarium
77
45
Rhodium
Rh
103
Cobalt
Gd
157
Gold
Au
197
Silver
Ag
108
96
64
Curium
Cm
Gadolinium
79
47
Cu
Copper
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
11
Dy
162
Thallium
Tl
204
Cf
98
Californium
66
Es
Holmium
Ho
165
Lead
Pb
207
Tin
99
Einsteinium
67
82
50
Sn
In
Indium
119
32
Germanium
Ge
73
Silicon
115
Dysprosium
81
49
31
Gallium
Ga
70
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
B
7
14
Sb
122
Arsenic
As
75
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
N
8
Se
79
Sulphur
32
Oxygen
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
16
O
9
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
Hydrogen
VII
VI
He
IV
III
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
52
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
16