Beruflich Dokumente
Kultur Dokumente
Translated from Fizika Tverdogo Tela, Vol. 46, No. 1, 2004, pp. 185188.
Original Russian Text Copyright 2004 by Malyshev, Peshev, Pritulov.
MAGNETISM
AND FERROELECTRICITY
AbstractTemperature dependences of the real ' and imaginary '' parts of the complex permittivity of lithiumtitanium ferrite ceramics are measured in the frequency range 102106 Hz at different test-signal amplitudes and dc bias voltages. It is found that the dielectric characteristics of the ceramic samples drastically
change in narrow temperature ranges. The assumption is made that relaxators whose reorientation is due to tunneling transitions of electrons inside bivalent iron iontrivalent metal ion pairs are involved in polarization
processes. Under certain conditions, the reorientation of relaxators can have collective character. 2004 MAIK
Nauka/Interperiodica.
1. INTRODUCTION
It is known that the conductivity and complex permittivity * substantially affect the propagation of electromagnetic waves in ferrite materials and, hence, can
be responsible for the functional properties of ferritebased devices. At present, there are many works concerned with the electrical properties of ferrites [110].
As a rule, dependences of the conductivity and complex permittivity * on the frequency f and temperature
T for polycrystalline ferrites are interpreted within
either the model of interlayer polarization [1] or the
model of interlayer polarization involving surface
states of grain boundaries [2]. Since interlayer polarization is caused primarily by charge transfer, the charge
transfer mechanism affects the characteristics of the
interlayer polarization. It is believed that charge transfer proceeds either through migration of charge carriers
over the impurity band [3, 4] or through hoppings of
carriers over localized energy levels due to electron
phonon interactions [5]. The hopping mechanism of
charge transfer in ferrites is associated with the presence of bivalent iron ions and electron transitions
between variable-valence ions, for example, Fe2+ +
Me3+
Fe3+ + Me2+ [6]. It has been established that
the higher the Fe2+ concentration, the higher the conductivity and the larger the real part ' of the permittivity. On this basis, it has been assumed that these transitions are responsible for charge transfer and polarization [79]. In this case, there is no need to invoke the
Koops model, because the recharging of ion pairs
Fe3+ + Me2+ can be considered as the
Fe2+ + Me3+
reorientation of dipoles in an ac electric field. Since the
components of ion pairs are crystal-forming ions, the
large value of ' can be explained by the high concentration of ion pairs. When electron transitions in these
pairs occur through phonon-assisted tunneling, it can
1
2
102
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2004
3
4
TC
101
300
106
1'
103
189
400
104
5
6
7
102
(b)
500
600
500
600
100
102
300
400
T, K
Fig. 1. Temperature dependences of (a) real ' and (b) imaginary '' parts of the complex permittivity measured at the
test-signal amplitude Utest = 56 mV in the course of (18)
heating and (1') cooling. Frequency: (1, 1', 5) 102, (2, 6) 103,
(3, 7) 104, and (4, 8) 106 Hz.
MALYSHEV et al.
190
103
(a)
(a)
1'
1
104
2'
103
102
1
2
3
1', 2', 3'
4, 4'
102
4
400
TC
101
300
400
500
(b)
'', rel. units
5
6
7
(b)
104
104
102
103
5
6
7
8, 5'8'
400
100
102
300
400
500
600
600
105
106
500
600
T, K
Fig. 2. Temperature dependences of (a) real ' and (b) imaginary '' parts of the complex permittivity measured at the
test-signal amplitude Utest = 2800 mV in the course of (1
8) heating and (1', 2') cooling. Frequency: (1, 1', 5) 102, (2,
2', 6) 103, (3, 7) 104, and (4, 8) 106 Hz.
500
T, K
600
Fig. 3. Temperature dependences of (a) real ' and (b) imaginary '' parts of the complex permittivity measured at the
test-signal amplitude Utest = 56 mV and frequency f =
103 Hz in the course of (18) heating and (1'8') cooling at
dc polarizing voltages Up: (1, 1', 5, 5') 0.2, (2, 2', 6, 6') 0.25,
(3, 3', 7, 7') 0.3, and (4, 4', 8, 8') 0 V.
and a low frequency is applied to the sample, the concentration of dipoles oriented along the same direction
can reach large values in certain time intervals. The
interaction between dipoles within these intervals can
lead to specific features in the behavior of polarization
(due to the collective reorientation of the dipoles) and,
possibly, to the formation of electric domains. Thus, we
believe that the features revealed in the temperature
dependences of the permittivity ' are associated with
the collective character of the dipole reorientation during part of the half-cycle of the ac electric field. To put
it differently, the electric field at regular intervals
induces a ferroelectric-like state in the dipole system.
In this respect, it is of interest to investigate the temperature dependences of the dielectric properties under
conditions where the dc polarizing voltage Up and the
ac test-signal voltage Utest = 56 mV < Up are applied to
the sample. In this case, the test signal does not change
the state of the dipole system and serves only for testing, whereas the concentration of dipoles oriented by
the dc electric field does not depend on the test-signal
frequency. It can be expected that, at a dc polarizing
voltage Up, the specific features in the temperature
dependences of the dielectric characteristics should be
observed at frequencies f > 100 Hz (unlike the depenPHYSICS OF THE SOLID STATE
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No. 1
2004
100
2'
3'
103
1'
460
1
2
3
4, 1'4'
480
102
400
'', rel. units
voltage Up. Similar features are observed in the temperature dependences of the dielectric characteristics measured at a frequency of 10 kHz (Fig. 4). As was
expected, the temperatures Tstart and Tend at f = 10 kHz
are equal to those at f = 1 kHz; i.e., these temperatures
depend on the dc polarizing voltage Up and are independent of the frequency f at low test-signal voltages
Utest. The inset shows the specific features in the dependences '(T) measured during cooling.
(a)
200
500
4. CONCLUSIONS
Thus, it was established that the activation energy of
relaxation polarization differs from the activation
energy of charge transfer and that the conductivity does
not depend on the frequency. This means that the interlayer polarization makes an insignificant contribution
to the high permittivity ' in the frequency and temperature ranges covered. It is found that the dielectric characteristics of the ceramic samples drastically change in
narrow temperature ranges. The features observed in
the temperature dependences of the dielectric characteristics can be associated with the collective reorientation of dipoles; in turn, the collective polarization is
most likely induced by the electric field.
600
(b)
105
5
6
7
8, 5'8'
104
103
102
400
500
T, K
600
Fig. 4. Temperature dependences of (a) real ' and (b) imaginary '' parts of the complex permittivity measured at the
test-signal amplitude Utest = 56 mV and frequency f =
104 Hz in the course of (18) heating and (1'8') cooling at
dc polarizing voltages Up: (1, 1', 5, 5') 0.2, (2, 2', 6, 6') 0.25,
(3, 3', 7, 7') 0.3, and (4, 4', 8, 8') 0 V. The inset shows the specific features in the dependences '(T) measured during (1'
3') cooling. Curve 3 in the inset is depicted for comparison.
REFERENCES
Vol. 46
No. 1
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2004
Translated by O. Borovik-Romanova