Beruflich Dokumente
Kultur Dokumente
University of Zagreb, Faculty of Chemical Engineering and Technology, HR-10000 Zagreb, Croatia
Sintef ICT, Applied Cybernetics, 7465 Trondheim, Norway
c Norwegian University of Science and Technology (NTNU), Department of Chemical Engineering, 7491 Trondheim, Norway
d Julius Montz GmbH, PO Box 530, 40705 Hilden, Germany
e Delft University of Technology, Process & Energy Laboratory, 2628 CA Delft, The Netherlands
b
a b s t r a c t
Preliminary evaluations using a simple but reliable short-cut method indicated that a 15 component aromatics
mixture can be separated very efciently into four fractions according to the given product specications employing
either a single or a multiple partition wall dividing wall column (DWC). The obtained results have been used to initiate
rigorous simulations, to determine the number of stages required in different sections, as well as to obtain internal
ows of vapour and liquid necessary for dimensioning and adequate cost estimation for two design alternatives.
Based on the comparison of total annualised costs it appears that a multi-partition wall conguration that maximizes
energy efciency is a more attractive option for implementation in aromatics processing plants than more practical
single partition wall conguration.
2011 The Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
Keywords: Distillation; Energy saving; Dividing wall column; Thermal coupling
1.
Introduction
1156
Property
Platformate
Temperature ( C)
Pressure (bar)
Flow rate (kmol/h)
Flow rate (t/h)
Mass fraction
n-Butane
i-Pentane
n-Pentane
2-Methylpentane
n-Hexane
Benzene
3-Metylhexane
Toluene
Ethylbenzene
p-Xylene
m-Xylene
o-Xylene
m-Ethyltoluene
1-3-5-Trimethylbenzene
1-4-Diethylbenzene
C5-C6
37.0
3.01
343.0
31.73
0.019
0.064
0.045
0.080
0.043
0.086
0.020
0.247
0.035
0.042
0.122
0.055
0.047
0.077
0.017
2.
40.0
2.70
97.8
7.16
BRC
115.3
3.17
47.1
4.16
0.086
0.284
0.201
0.351
0.066
0.013
0.010
0.210
0.629
0.151
Toluene
Heavies
111.1
1.01
86.5
7.86
163.6
1.56
111.6
15.55
0.002
0.984
0.006
0.003
0.005
0.001
0.086
0.107
0.307
0.140
0.120
0.197
0.043
3.
3.1.
A, B, C, D
1157
Fig. 2 Schematic illustration of two alternative four-product DWCs: Kaibel column (2-4) and the fully extended Petlyuk
(2-3-4) congurations.
a signicant energy saving with respect to conventional conguration, which however is well below that achievable with
a fully extended counterpart.
However, the only known application so far of a 4-p DWC
is the simpler, Kaibel type column, with one partition wall,
with longitudinal sections in off-centre position (see Olujic
et al., 2009), which was adopted because of practical reasons,
i.e. its simpler design, construction and operation. The complexity, i.e. design, operation and control related uncertainties
seems to be the main reason that multiple partition wall congurations, which maximize energy saving, have not yet been
attempted in industrial practice.
An objective of this paper is to demonstrate that design
of internal conguration of a complex DWC is something that
can be done with certainty, and that column dimensioning can
be performed with some condence for applications utilising
columns equipped with structured packings, using the public domain knowledge. Namely, well established and highly
1158
Component
zi
Ki
n-Butane
i-Pentane
n-Pentane
2-Methylpentane
n-Hexane
Benzene
3-Metylhexane
Toluene
Ethylbenzene
p-Xylene
m-Xylene
o-Xylene
m-Ethyltoluene
1-3-5-Trimethylbenzene
1-4-Diethylbenzene
0.0308
0.0821
0.0581
0.0863
0.0456
0.1013
0.0187
0.2484
0.0306
0.0370
0.1062
0.0477
0.0363
0.0595
0.0114
6.2768
3.3869
2.8330
1.6298
1.3261
0.9417
0.7347
0.4154
0.2032
0.1888
0.1851
0.1637
0.0962
0.0841
0.0478
Product
D
D
D
D
D
S1
S1
S2
B
B
B
B
B
B
B
3.2.
practical non-welded partition wall technology, described in
greater detail elsewhere (Kaibel et al., 2007; Olujic et al., 2009;
Dejanovic et al., 2010a), allows assembling multiple partition
wall congurations without additional difculties.
Split
Specied
Calculated
Recoveries
C1
C2.1
C2.2
PG/H
PE/F
PH/I
r(I,D) = 0.01
r(H,D) = 0.05
r(I,D) = 0.01
r(E,B) = 0.01
r(E,B) = 0.05
r(G,B) = 0.01
VT /F
D/F
0.76
1.28
1.28
0.4252
0.3057
0.6693
Nf
75
100
68
38
50
35
Nf
28
43
35
100
75
68
14
22
18
50
38
35
Split
Specied
Calculated
Recoveries
C1
C2.1
C2.2
C3.1
C3.2
C3.3
PE/I
PE/H
PG/I
PE/F
PG/H
PH/I
r(I,D) = 0.01
r(H,D) = 0.01
r(I,D) = 0.01
r(F,D) = 0.05
r(H,D) = 0.01
r(I,D) = 0.01
r(E,B) = 0.01
r(E,B) = 0.01
r(G,B) = 0.01
r(E,B) = 0.05
r(G,B) = 0.01
r(G,B) = 0.01
VT /F
D/F
0.51
0.56
0.65
1.06
0.76
1.13
0.4063
0.3545
0.4851
0.3057
0.4252
0.6693
1159
L/D = 3.267
336.2
102.9
439.1
RL=0.347
116.6
260.7
343.0
480.2
219.6
178.4
178.4
178.4
92.7
178.4
281.3
41.2
S1
85.7
S2
RV =0.624
572.8
Liquid
459.7
Vapour
V/B = 4.061
113.2
Fig. 6 Mass balance for 2-4 conguration, with all internal vapour and liquid ows and splits according to V-min
diagram.
tool that enables thorough and accurate assessment of potential for minimization of energy requirement of fully thermally
coupled distillation columns. This rather simple method is
based on assumptions of constant molar ows, innite number of stages, and constant relative volatilities, and therefore
holds for (near) ideal zeotropic mixtures. It relies on Underwoods equations utilised to estimate the value of theoretical
minimum boil-up ratio, outgoing from the thermodynamic
condition (q) and composition (z) of the feed and the K-values
or equilibrium constants of each component for given operating conditions.
The real power of the V-min diagram is that it contains
all necessary information to calculate the overall minimum
energy requirement and all the internal ow rates for an optimally operated extended Petlyuk arrangement for an arbitrary
multicomponent feed and any number of products (Halvorsen
and Skogestad, 2003c). Here, Halvorsen and Skogestad have
also shown that an optimally operated generalized Petlyuk
arrangement results in the lowest overall vapour ow requirement for any distillation conguration when we consider
constant pressure and no external heat integration.
We would generally anticipate that we would need to calculate the minimum energy for each succeeding column by
a new column computation, but Halvorsen and Skogestad
(2003b) showed that the properties determining minimum
energy in each sub-column can be found from the previous
column. This practically means that regardless the complexity of a situation, the V-min diagram containing all necessary
information can be constructed based on feed data only.
Importantly, this simple method that in original graphical
form provides direct insight into the optimal separations
behaviour in fully thermally coupled column arrangements
can be easily translated into analytical form and implemented
into a commercial process simulator, as it was done in present
paper to generate reliable initial guesses for rigorous simulations.
The composition of the feed considered in this study is
given in Table 2, with component K-values corresponding to
feed stage conditions, and component grouping according to
actual product specications. For convenience, each compo-
C3.1
C2.1
S1
F
C1
C 3.2
S2
C2.2
C3.3
B
Fig. 7 Partitioned part of a DWC according to 2-3-4
conguration, with three sections of main column
superimposed on that representing 2-4 conguration.
1160
3.2.1.
3.2.2.
Fig. 9 Mass balance of 2-3-4 conguration with all internal vapour and liquid ows according to V-min diagram.
1161
C3.2
= VTC2.2 VBC2.1
FV
(1)
2.1 LC2.2
FLC3.2 = LC
B
T
(2)
1162
Q C=-5055 kW
L/D = 5.628
99.1
w(benzene)=1.3%
656.5
557.4
N=20
2,1
651.9
552.9
324.3
174.1
N=19
1,1
279.3
2,2
133.3
324.3
N=17
371.3
316.7
363.7
315.6
318.0
44.6
2,3
343.0
287.1
N=18
w(benzene)=70.9%
289.5
86.5
311.5
1,2a
345.1
508.4
N=10
345.7
1,2b
346.4
633.9
2,5a
N=22
287.2
2,4b
277.1
N=22
546.0
615.0
w(toluene)=98.1%
203.1
203.1
193.0
746.7
N=15
618.3
2,5b
203.0
542.1
542.7
N=11
287.1
2,4a
287.2
734.9
731.1
N=15
716.9
604.1
V/B = 5.345
QR =5821 kW
112.8
w(toluene)=0.06%
Fig. 12 Mass balance of 2-4 conguration with all internal vapour and liquid ows according to rigorous model.
It should be noted that use of commercial process simulator for short-cut simulation of 2-4 conguration is not
so straightforward. This case cannot be modelled as a series
of binary distillation calculations of the same feed, because
prefractionator column is not operated at a preferred split,
causing higher energy use in subsequent sections. A way of
performing simulations is to use the base case conguration
in Fig. 1, but with liquid fractions of the feed into the nal
two columns set to the effective liquid fraction of the thermal coupling. This will give an articial superheated feed to
the upper column and an articial sub-cooled feed to the lower
column giving the same ow changes at the junctions as in the
fully thermally coupled 2-4 conguration in Fig. 3. However,
this may in some cases give convergence problems because
the articial temperatures may become close to critical
values.
3.3.
Table 5 Comparison of energy requirements of studied sequences, estimated using shortcut and detailed methods.
Base case
Shortcut method
Vmin /F
Relative savings in reboiler duty (%)
Rigorous method
Total QR, [MW]
Total QR/F [MW/t]
Relative savings in reboiler duty (%)
2-4
2-3-4
2.21
1.34
39.4
1.11
49.8
10.03
0.324
5.82
0.183
42.0
4.81
0.152
52.0
1163
Conventional
Column
Shell tangent to tangent height (m)
Shell diameter (m)
Top pressure (bar)
Pressure drop (bar)
Reboiler duty (MW)
Total reboiler duty (MW)
Number of stages/trays
Number of packed beds
Number of distributors
Number of liquid catchers
Number of support grids
C1
C2
C3
40.5
2.0
1.70
0.313
3.76
10.03
40/61
39.5
2.0
2.70
0.272
3.12
5.82
38/59
39.5
1.8
1.01
0.244
3.15
4.81
38/59
2-4
2-3-4
63.8
2.2
2.2
0.150
5.82
60.4
2.1
2.2
0.137
4.81
129/
10 (7)
10 (7)
8 (5)
10 (7)
130/
13 (10)
11 (8)
9 (6)
13 (10)
Note: Numbers in parentheses indicate devices placed in partitioned part of the column.
3.4.
Dimensioning
effectively means that liquid and vapour ows and properties are known for every column stage. In conventional
column design, the dimensioning has to ensure stable column performance with regards to liquid and vapour loads. In
DWCs, dimensioning has one additional purpose, and that is
to ensure desired vapour split below the partition wall. Unlike
liquid split, which can be set precisely by an external device,
vapour split ratio is self-adjusting and is set by the governing pressure drops across different column sections. In other
words, in order to be able to precisely tune the vapour split, the
designer needs to be able to accurately predict and manipulate
accordingly the pressure drop of column sections separated by
the partition wall. In conjunction with the xed liquid split, the
pressure drop depends on the type and size of internals used.
If a bed, sized to ensure given separation, does not generate
sufcient pressure drop to ensure required vapour split, additional pressure drop can be arranged for instance by adjusting
the free area of liquid distributors and/or catchers accordingly.
The 2-4 conguration appeared to be rather simple in
this respect. Additional challenges are associated with present
attempt to evaluate feasibility of a multiple-partition wall
column, which means going beyond the limits of practical
experience of J. Montz GmbH, the pioneer in this eld among
equipment manufacturers, which was involved with design
and delivery of more than 90 packed DWCs so far.
Fig. 10 shows schematically ow resistances as encountered in the partitioned part of a 2-3-4 conguration DWC. In
Table 7 Equipment and utilities cost, and total annualised cost (TAC) for 2-4 and 2-3-4 congurations.
Conguration
Equipped with
Total equipment costs ($)
Shell
Internals
Reboiler
Condenser
Total
Savings
Operating costs ($/year)
Cooling
Heating
Total
Savings
TAC ($/year)
Savings
Conventional
Sieve trays
2-4
Structured packings
2-3-4
Structured packings
1,819,996
768,276
561,294
637,547
3,787,113
1,015,543
1,358,112
393,578
264,245
3,031,478
20.0%
924,883
1,441,898
336,353
272,759
2,975,893
21.4%
577,257
986,355
1,563,612
1,942,323
108,103
752,127
860,230
45.0%
1,163,378
40.1%
86,632
620,980
707,612
54.7%
1,005,201
48.2%
1164
Q C =-4038 kW
L/D = 4.170
99.5
w(benzene)=1.3%
514.4
3,1
516.4
414.9
N=18
416.8
178.3
2,1
173.4
83.3
N=7
78.4
337.8
333.2
3,2
N=15
325.5
320.0
44.6
160.6
1,1
N=10
145.6
55.7
40.7
10.7
2,2
N=15
10.5
20.6
82.9
2,3
N=9
77.7
36.5
20.5
274.9
324.6
3,3
N=20
267.7
316.9
w(benzene)=70.9%
343.0
162.2
400.2
1,2
N=12
186.5
424.6
31.3
241.3
248.4
3,4
N=28
232.5
225.4
86.5
265.7
2,4
276.5
457.4
N=19
468.2
494.0
3,6a
493.6
N=21
492.7
3,6b
472.3
N=21
225.3
146.0
N=27
3,5
216.0
136.6
w(toluene)=98.4%
606.4
605.1
603.9
584.7
V/B = 4.202
Q R =4806 kW
112.4
w(toluene)=0.06%
Fig. 13 Mass balance of 2-3-4 conguration with all internal vapour and liquid ows according to rigorous model.
(3)
(4)
(5)
In present case, with pronounced differences in the number of stages and ow rates of phases in parallel sections
of the column, different types and sizes of J. Montz corrugated metal sheet structured packings of series B1 have
been considered to provide enough exibility in this respect.
Two basic structured packing area sizes were considered as
appropriate for this case, 250 and 350 m2 /m3 , respectively, in
conjunction with different corrugation inclination angles as
well as designs, i.e. M and MN. For the same specic geometric area, using a packing with 60 instead of common
45 means a nearly factor three drop in the pressure drop,
and a 30% higher capacity, at the expense of some 20% loss
of efciency (Olujic et al., 2002). Packings of series M have
a long smooth bend at the end of the corrugations, which
reduces the pressure drop and increases the capacity accordingly.
If this packing is used at vapour loads below the loading
point then some 10% loss of efciency should be accounted
3.5.
Cost estimation
4.
1165
1166
5.
Conclusions
An energy efcient alternative has been proposed for recovery of essential fractions in a renery aromatics complex.
Three columns conguration has been replaced by one DWC
for obtaining four products. Two options, one with a single longitudinal partition wall, with some sections off-centre, and a
multiple-partition wall column containing three sections in
parallel have been worked out using rigorous simulations initiated using the values of governing variables estimated using
an established short-cut method.
V-min diagram proved to be a simple and effective tool
for identication and conceptual design of internal, minimum
energy requirement conguration of a multi-product DWC, as
well as for reliable initialization of detailed (rigorous) calculations.
Detailed calculation method adopted, in conjunction with
a simple empirical objective function for design optimality indication, allows easy determination of the stage and
reux requirement of a complex DWC. The dimensioning method developed for standard, three-product columns
appeared to be an effective tool for design and assessment
of cost-effectiveness of alternative internal congurations
of four-product multiple partition wall DWC equipped with
structured packings.
The simulation studies indicated a strikingly large energy
saving potential compared to conventional conguration,
resulting in a 40.1% and 48.2% lower TAC for single- and multiple partition wall DWC, respectively. This means that more
complex, multiple-partition wall column is a more attractive
option for industrial implementation, but due to its constructional complexity it may appear impractical.
Regarding the scale of this and similar applications, additional 17.7% saving in operating costs translates into large
nancial benets. Therefore in present and similar cases there
may be a strong incentive to put more effort and resources into
overcoming potential barriers and making multiple-partition
wall DWC congurations industrially viable.
Thanks to the availability of proven non-welded, self-xing
partition wall structured packing technology, multiple partition wall congurations could be realized in practice. If it
appears that control of the complex DWCs (subject of an
ongoing research effort at NTNU) will not be too demanding
(impractical), than the barriers other than technical need to
be overcome to enable practical implementation of this highly
sustainable distillation column technology.
Acknowledgement
The authors would like to thank INA Renery Sisak, Croatia,
member of MOL Group for providing actual plant data for the
purposes of this study.
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