COTTON . POLYESTER.

COTTON &BLENDS

SATEESH GORE,
DIRECTOR
 PRE-TREATMENT 　 DYEING
PRINTING FINISHING

　　　　　　　　　　　　ELECTRON GROUP

CONTENT
　　　　FOLW OF PROCESS CHEMICAL TYPE RECOMMENDED ITEM　　　　　　　　　　

MERCERIZATION PENETRATING AGENT Laserol QW (Odorless TYPE)

SCOURING & SCOURING AGENT Laser PCM ECO (Hyper Scouring)

BLEACHING LASER LF-ECO (Non Foaming)
FABRIWET ECO (Conc TYPE)
STABILIZER for SCOUR LG (One-Pack Assistant)
H2O2 BLEACHING STABIL AWN (Organic TYPE)
STABIL SIFA (ECO Friendly)
CHELATING AGENT SEQUEL UD (Good for IRON)
SEQUEL AD (Chelating/Dispersing/ Sequestering)
SEQUEL 200 NT (Silicate Scale Remove ability )
DE-H2O2 AGENT BURST DEAIR
POLYESTER
ALKALI BATCH PROCESS ( No-Yellowing )
REDUCTION ACCELERATOR ( Hyper TYPE )

DYEING LEVELING AGENT for REACTIVE/DIRECT DYES

Dye Developer RDL ( Leveling/Retarding/Brightning)
for DISPERSE DYES Dye Developer DX (Dispersing/ Leveling /Bufering)
Dye Leveler SDBL ( Multi TYPE )
Dispro Bright PDR ( Dispersing )
Dye Leveler DAN( Leveling/Buffering )

SOAPING 　　　 for REACTIVE Bright Wash 200 (Weakly Cationic TYPE )
for REACTIVE/DISPERSE Sequel 200

FIXING For-REACTIVE DYES Reacto Fix 30 (Easy De-Fixing )

Reaccto Fix 50 (Hyper TYPE )
　　 Eco Friendly DIRECT/REACTIVE DYES San Fix 30 (Poly-Amine TYPE )
San Fix Conc (Copper TYPE )
FINISHING SOFTENER Microsoft OC Flex Cata Flex
Microsoft OC Liquid Cata Dilution
Microsoft NA Flex
Microsoft RA Flex
Microsoft NYS Non Yellowing
AMINO-SILICONE Microsoft 5000
Microsoft 250

FLUOROCARBON
Laser Guard EC 100)
EXCELLENT 400 (Cross linking Agent)
POLYURETHANE Laser Bond 1000 (Water dispersion)
Laser Bond 2000 (Water dispersion)
POLYETHYLENE EMULSION Shonex 100 (Sewing Ability Improver )
THEORY & APPLICATION
1. MERCERIZATION

PURPOSE 1. GIVE LUSTER

2. IMPROVE DYEING QUALITY
3. IMPROVE FORM STABILITY
4. IMPROVE STRENGTH
5. IMPROVE HANDLE

CONDITION 1. CONCENTRATION OF NAOH(F)....... 15-30°Be

2. ALKALI PENETRATING AGENT.....… 5-10g/l
LASEROL QW
3. TEMPERATURE ..................……….…1 5-30℃ LOW TEMP: GOOD LUSTER
HIGH TEMP: GOOD HANDLE
4. TIME.........................…... 30-60sec (TOTAL)
5. TENSION........................ TENSION OF WARP & FILLING
(INFLUENCE ON LUSTER)
REQUEST ABILITIES TO PENETRATING AGENT
1. ALKALI RESISTANCE............. .STABILITY IN 20-30°Be
2. PENETRATION..................…… FIRST PENETRATION & INTERNAL PENETRATION
3. FOAMING......................……… .LOW FOAMING
2 ALKALINE BOILING / SCOURING
GENERAL PROCESS
1st BATH ................... NAOH (F) 26° Be
Fabriwet ECO 10 to 30 g/l 10 sec / ONE-BATH
Sequel UD Conc 02 g/l

2ed BATH ................... NAOH (F) 26°Be

Fabriwet ECO 10 g/l 10 sec / ONE-BATH
Sequel UD Conc 02 g/l
TIMING ................................. TENSION FOR WARP (25-30sec)

3rd BATH ...................NAOH(F) 26°Be

Fabriwet ECO 10 g/l 10sec/ONE-BATH
Sequel UD Conc 02 g/l
4th BATH ................................. WATER RINSING
5th BATH ................................. HOT WATER RINSING 80℃
6th BATH ................................. HOT WATER RINSING 60℃
7th BATH ................................. NEUTRALIZATION 60℃ CH3COOH(80%) 5cc/l
8th BATH ................................. NEUTRALIZATION 60℃ CH3COOH(80%) 5cc/l
9th BATH ................................. WATER RINSING
10th BATH .............................….. WATER RINSING

2. SCOURING & BLEACHING

 PURPOSE 1.Removal impurity
2. Removal color material
3. Gives Re-wetting ability
IMPURITIES OF COTTON AND COTTON/POLYESTER
Primary impurity (Natural impurity)....…….. .Pectin , Cotton wax , fat , Protein , Inorganic compound etc... 8-12%
Secondary impurity (Unnatural impurity)..... Size , any kind of oil , surfactant , Interweaving dirt etc..… 10-15%
…..TOTAL 18-27%
INORGANIC AGENT ALKALI AGENT …………CAUSTIC SODA
AMMONIA WATER
SODIUM SALT ……….. CARBONATE
PHOSPHATE
SILICATE

SURFACE ACTIVE ) ………………………………………….. ANIONIC SURFACTANT

AGENT ) NONIONIC SURFACTANT
SCOURING
AGENT ORGANIC SOLVENT …………………………………………. PER-CHLORO ETHYLENE
TRI-CHLORO ETHYLENE
1,1,1- TRICHLOROETHANE
HYDROCARBONS
ENZYME TYPE AGENT …………………………………………. PROTEO LYTIC ENZYME
OXIDATION AGENT ………………………………………… HYDROGEN PEROXIDE
* SURFACE ACTIVE AGENT gives emulsify effect, dispersing effect and wetting effect in scouring process.
The scouring effect is getting better to use inorganic agent together.

BLEACH POWDER
CHLORINE TYPE SODIUM CHLORITE

OXIDATION TYPE HYDROGEN PEROXIDE

PERACID TYPE SODIUM PERBORIC ACID

BLEACHING AGENT POTASSIUM PERMANGANATE

SODIUM PEROXIDE
PERACETIC ACID
SULFUROUS ACID

REDUCTION TYPE SODIUM ACIDIC SULFITE

HYDROSULFITE

HYDROGEN PEROXIDE BLEACH

FOR EFFECTIVE DECOMPOSITION OF HYDROGENPEROXIDE

HYDROGEN PEROXIDE
ACTIVATION
 ☆Alkali condition ☆Temperature condition
☆Heavy Metal ionic condition
Fe++, Cu++

ACCELERATION FACTORES

　CONTROL FACTOR
　　STABILIZER

Mechanism 　 Acid side Alkali side

stable Hydrogen peroxide accelerate decomposition
①　H2O + 1/2O2
H2O2 add NaOH
②　HO2 + 1/2H2 (Perhydroxi ion)
++ ++
1 This reaction is accelerated by Fe , Cu … that remain in treatment water or gray cotton.
This reaction make strong oxygen in initial, and it works to make Oxi-Cellulose .
Oxi-cellulose cause some troubles, like a low tear strength or pinhole
2 This reaction is accelerated by Ca++,Mg++…in high Alkali condition.
 Perhydroxi ion gives high oxidation power to decompose color materials, however, it does not make oxi-cellulose, and it also gives high scouring
effect.
Point ( In order to make effective perhydroxi ion in Hydrogen peroxide bleach )
1 Suitable Temperature condition
The decomposition speed increases with the square of the Temperature from 70℃.
2 Suitable Alkali condition
The Reaction is accelerated in high Alkali condition. ( pH=11 )
The Reaction is accelerated in low Alkali condition.
3 Penetrating agent which give high penetrating effect to fabric inside.
4 Stabilizer which control decomposition of Hydrogen peroxide.
It is necessary to control fast decomposition and to get leveling whiteness in high Alkali condition.
it can be control fast decomposition in low Alkali condition, but it cause low whiteness and oxi-cellulose problems.
5 Sequestering agent which Chelate heavy metal ions
Some kind of Sequestering agents Chelate not only Fe++ , Cu++ but also Ca++,Mg++.
Ca++,Mg++ gives good effect to make Perhydroxi ion. Dispersing type Sequestering agent is better than strong type chelating agent.

STABILIZER

SILICATE TYPE for exhaust / continuous.

Generally Not Made Because of Load on Water Purification Problems like COD /BOD
1 Gives high whiteness
2 Gives high stabilizer effect in high concentrated Alkali condition.
3 Cheap
4 Gives Harsh handling
5 Cause silicate scale troubles in the steamer or on the roll bar.

Non- SILICATE TYPE for exhaust

1 Stabilizer effect is poor than SILICATE TYPE in high concentrated Alkali.
2 Whiteness is poor than SILICATE TYPE.
3 Gives Soft handling
4 Gives high re-wetting ability for later processes.

CBR – series for exhaust / continuous

1 No silicate scale troubles, due to Non-SILICATE TYPE.
2 Gives high sequestering / dispersing effect.
3 Stabilizer effect is better than SILICATE TYPE.
4 Prevent degraded cellulose and pin-hole troubles, due to high sequestering / dispersing effect.
5 Gives high Whiteness
6 Gives Soft handling.

STABILIZER EFFECT
TEST CONDITION STABILIZER
TEMP×TIME　95℃ ×　Xmins IMPROVE SCOURING ABILITY
Bath Recipe EXHAUST METHOD
H2O2(35%) 15cc/l NON-SILICATE TYPE ENZYME BASED
NaOH(F) 1.5g/l STABIL AWN ENZOSTAB 15
Stabil AWN /SIFA 1.5g/l CONTINUOUS / EXHAUST
ENZOSTAB-15
Fabriwet ECO-LF 5.0g/l
 NON-SILICATE TYPE ENZYME BASED
STABIL AWN
STABIL SIFA/ STABIL AWN

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