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WATER TREATMENT.
WASTE WATER TREATMENT.
Screening:
removal of
large floating
/suspended
debris, grit
and sand.
Flocculation - gentle
mixing of water with
chemicals to form
larger flocs.
Coagulation adding
chemicals and agitation to
promote suspended solids
to form/coagulate into
larger particles.
Filtration removal of
particles and floc by
gravity settlement
Disinfection
of effluent to
eliminate
harmful
pathogens.
1. Sedimentation
During this treatment step, the particles are simply allowed to settle due to gravity effect.
Particles may have very different, irregular shapes and when describing particles, an
equivalent to a sphere' diameter is used. It is hydrodynamic diameter (in water) and
aerodynamic diameter (in air).
The drag force is a function of the particles Reynolds number:
s d p
Re
1. Sedimentation
In most environmental engineering cases, only laminar flow is considered, therefore:
FD=3 vsdp
vs
g p d p2
18
1. Sedimentation
Figure shows the trajectory of a particle that is being carried by the horizontal flow of
water from one end to the other of a rectangular settling basin. The particle settles at
distance, hp:
v sVb
h p v s
Q
where =the hydraulic detention time of the basin; Vb=the basins volume; Q=the volumetric flow rate
of water through the basin.
In order to achieve higher efficiency of particles settling, the settling velocity (vs) should be
equal or greater than a critical settling velocity (vo):
h hQ hQ
Q
vo
Vb hAb Ab
where Ab=the surface area of the rectangular basin.
1. Sedimentation
The critical settling velocity is also known as surface loading rate or overflow rate.
If we want to design a clarifier to remove all particles of a size, d, from a water stream
with a flow rate, Q, the surface area, Ab, of the rectangular basin must be
Ab
18Q
g p d p2
The same formula is applicable for circular settling basin too. However, the influent enters
circular settling basins at the centre and the overflow rates are within
1.0-2.5 m3/m2 h.
Also the detention time influences the efficiency of the clarifier. The hydraulic detention
time in any tank is its volume divided by the influent flow rate (typically from 1 to 4
hours).
P
Vb
3. Filtration
va= Q / Af
The filter efficiency (production efficiency):
The effective filtration rate:
f = (Vf Vb Vr) / Vf
4. Disinfection
Disinfection is to kill any pathogens and prevent pathogens from growing
in the treated water.
Free chlorine is the most common disinfection procedure. It involves any
of the following compounds: gas Cl2, sodium hypochlorite (NaOCl),
calcium hypochlorite (Ca(OCl)2).
For Secondary disinfection, ammonia is added, which reacts with free
chlorine and forms chroloamines that have longer residence time in the
treated water.
Disinfectant byproducts (DBPs) include Trihalomethanes (THMs),
chloroform (CHCl3), and haloacetic acids (HAAs).
Presence of organic matter promotes formation of the DBPs, therefore the
disinfection is most efficient when carried out as the last treatment
process step.
Alternative disinfectants are chlorine dioxide (ClO2) and ozone (O3). Both
agents are effective against cysts and viruses but more costly compared
to chlorination. Additionally, ozone does not leave any protective residuals
in the water after the treatment.
EW = AW / n
6. Softening
The surface waters seldom have hardness exceeding 200 mg/L
and softening is not regular part of the water treatment.
For groundwater waters with hardness ~ 1000 mg/L the
treatment is required. It involves lime-soda ash and the ionexchange processes.
1. Lime-soda ash processing, Ca(OH)2 is added to water and pH
goes up to about 10.3. At this higher pH Mg++ and Ca++ ions
precipitate and are removed as solids.
2. In the ion-exchange process, the water flows through a
column packed with solid resin beads which are filled with
sodium ions that are exchanged for Mg++ and Ca++ ions as the
water passes through the resin. The resin must be
regenerated once the sodium is depleted from it.
6. Membrane Processes
All membranes can be considered semipermeable physical
barrier, they allow passage of water, while severely restricting
the permeation of contaminants in water (including pathogen,
hardness and dissolved solids, organic and disinfectant
byproduct precursors, metals, and suspended solids)
Classification of membrane: Particulate separation and solute
separation
1. Particulate separation (reject particles, including pathogens)
microfiltration and ultrafiltration
2. Solute separation (dissolved substance) nanofiltration and
reverse osmosis
Wastewater treatment
1. Primary treatment
Screening: to remove large objects, debris
Grit chamber allows the heavy stuff to settle,
a few min detention time
Primary settling tank or primary clarifier: the
flow is sufficiently reduced,
detention time is ~ 1.5 3 hours during which
about 50-65% of suspended solids and 25-40%
of BOD are removed.
Overflow rate and detention time are the key
parameters.
Microbial kinetics
Microorganisms consume organic matter (substrate) that is
measured in mg/L of BOD.
Mass of m/orgs fluctuates (depending on growth condition and
availability of substrate) and their biomass is measured in mg/L of
Volatile Suspended Solids (VSS or VS). See more details in Experiment #
2 of the lab. manual.
TS = total solid
TSS = total suspended solid
VSS = volatile suspended solid
TDS = total dissolved solid
During the exponential phase microbial growth, the increase in the microbial mass
growth rate, rg can be modeled by the first-order rate expression
If the microbes in the pond consume the inflowing biodegradable organic matter
according to typical kinetics, determine
a. The BOD5 leaving the pond
b. The biodegradable organic matter removal efficiency of the pond
c. The concentration of volatile suspended solids leaving the pond
Given Ks = 60 mg BOD5/L; kd = 0.06 d-1, k = 5 mg BOD5/(mg VSS.d)
Mixed liquor
Retention time:
Two conditions:
1. Supply of oxygen, i.e. aeration
2. Promoted growth of microbial biomass
Tall trickling filters filled with plastic media are called biotowers. The spaces
between the packing allow air to circulate easily so that aerobic conditions are
maintained. The media is covered by biological slime populated with
microorganisms, insects, fungus, protozoa, worms, snails, etc. that are
responsible for the w/water decomposition.
What is the principal difference b/w suspended and attached growth treatment?
Sludge treatment:
Sludge is a mixture of solids and water that
remains to be disposed of. The important objective of the sludge
treatment is to separate the water from the solids as much as
possible. The traditional method is anaerobic digestion. It is
slower than aerobic decomposition but has an advantage that a
small % of the waste is converted into new bacterial cells. Most of
the organics are converted into CO2 and CH4.
For the nitrification process the detention time of at least 15 days is required.
For the anaerobic part, denitrification, the reaction:
2NO3- + organic matter + bacteria N2 + CO2 + H2O
Because the denitrification takes place after waste treatment, there may be not enough
organic material for the bacteria and therefore additional nutrient is required, which is
typically methanol (CH3OH).
Phosphorus
Phosphorus in w/water exists as orthophosphate (H2PO4-; HPO42-, and PO43-), and it is
removed by reaction with added coagulant such as alum or lime.
The reaction:
Al2(SO4)3 + 2PO42- 2AlPO4 + 3SO42-