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H. Moseley found that the atomic number of an element is a more fundamental property than its
atomic mass.
Accordingly, Mendelevs Periodic Law was modified and atomic number was adopted as the basis of
Modern Periodic Table.
So, the Modern Periodic Law can be stated as follows:
Properties of elements are a periodic function of their atomic number.
(Note - atomic number is the number of protons in the nucleus of an atom. It is represented with
sign Z).
Elements, when arranged in order of increasing atomic number Z, lead us to the classification
known as the Modern Periodic Table.
Prediction of properties of elements
The properties of elements which are changed gradually (in increasing or decreasing order) with the
increase in atomic number or according their placement in the periodic table are called periodic
properties.
Periodic properties directly depend upon the electronic configuration of the element.
The maximum number of electrons that can be placed in a shell, depends on the formula 2n2 where
n is the number of the given shell from the nucleus.
For example,
K Shell 2 (1)2 = 2, hence the first period has 2 elements.
L Shell 2 (2)2 = 8, hence the second period has 8 elements.
M Shell 2 (3)2 = 18, but the outermost shell can have only
8 electrons, so the third period also has only 8 elements.
The position of an element in the Periodic Table tells us about its chemical reactivity.
The valence electrons determine the kind and number of bonds formed by an element.
Trends in the Modern Periodic Table
1. Valency :
The number of electron which are either exchanged (given or taken) or shared by an element for
getting stability (during bond formation) is called its valency.
The valency of an element is determined by the number of valence electrons present in the
outermost shell of its atom.
In a period from left to right, positive valency increases, while negative valency decreases. In a group
the valency usually remains he same.
2. Atomic size:
The term atomic size refers to the radius of an atom. The atomic size may be visualised as the
distance between the centre of the nucleus and the outermost shell of an isolated atom.
The atomic radius of hydrogen atom is 37 pm (picometre, 1 pm = 1012m).
Atomic size increases from top to bottom in a group as the number of shell is added.
In a period however, the atomic size decreases on moving left to right. This is because, the number of
shell is not increased, but the amount of charge (electrons and protons) increase. This increases the
shielding effect. (Note- Shielding effect is the holding effect of nucleus on the electrons of outermost
shall).
3. Metallic and Non-metallic Properties
The metals like Na and Mg are towards the left-hand side of the Periodic Table while the non-metals
like sulphur and chlorine are found on the right-hand side. In the middle, we have silicon, which is
classified as a semi-metal or metalloid because it exhibits some properties of both metals and nonmetals.
Metallic property of an element is the tendency to loose or donate electron. The atom which looses its
electron quickly is said to be more metallic in nature. Metallic property is also called electropositive
character i.e., tendency to make a positive ion.
On the other hand non metallic property is the tendency of an element to gain or receive electrons.
More quick the gaining, more will be the non-metallic character. This character is also called
electronegativity i.e., tendency to make a negative ion. (Note fluorine is the most electronegative
element).
In a group metallic character increases and non metallic character decreases. This is because in a
group, the number of shell increases so, shielding effect decreases. As a result, electrons can be
easily donated.
In a period, due to increasing shielding effect, the tendency to loose electrons decreases. So, metallic
character in a period decreases, while non metallic character increases.
So, metals are electropositive, while non metals are electronegative.