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Molecular Symmetry Be Group Theory.

Generation of rt from Motional Vector Basis Set.

(1) An atom whose nucleus (vector origin) Is shifted from its original position
by an operation of the group contributes zero to the character of that
operation's matrix in the total representation.

(2) An atom which is not shifted by an operation. and of whose motional


vectors. none is rotated about their local nuclear origin by the operation,
contributes +3 to the character of that operation's matrix in the total
representation.

(3) If an atom is unshifted by an operation, but rotated about its own nucleus
(vector origin), then it contributes to the character of that operation's matrix
in accord with:
Operation Contribution to rt
Cn 1+ 2cos(21t/n)
~ -1
C3 o
C4 1
Q, 2
8n -1 + 2cos(-21t/n) = (Cn's-value)-2
81 =a 1
82 =i -3
83 -2
84 -1
86 o

MSGT,RepnGen'n: AWA 26 VII 90.


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