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Introduction
The Model 108 Analyzers are reliable,
flexible and versatile instruments based on
electrochemical & infrared gas sensors
for the measurement of hydrogen sulfide
(H2S),carbon monoxide (CO), methane
(CH4) &carbon dioxide (CO2).These
products are available in a portabe
configuration with a rechargeable battery
operation.
Other Continuous Analyzers include the
Model 201-B PID or FID Analyzer for total
VOCs, a thermal conductivity detector
(TCD),Model 204 and a Model 210
Oxygen Analyzer. The addition of these
new Analyzers greatly improves the
capability and range of process analyzers
from PID.
Principle of Operation
Electrochemical (EC)
Amperometric techniques can use two or
three electrode systems for detection. A
membrane is used to separate the phase
being measured (air containing a toxic gas)
from the electrolyte where the measurement
takes place. The oxygen electrode was first
described by Clarke in 1956 and is perhaps
the best known of this type. Here, a fixed
potential is applied to one electrode and the
current generated by oxygen being
consumed according to:
O2 + 2H20 + 2e- [H202] + 2OHis measured.
Various organic and inorganic compounds
can be sensed at an electrode interface by
applying a voltage that is equivalent to the
oxidation or reduction potential. As the
appropriate compounds diffuse to the
electrode, they will be oxidized or reduced
and will produce a current (proportional to
concentration). This signal is amplified and
displayed on the digital meter. The calibration
value for each sensor is stored in the
processor memory for later retrieval.
The O2 sensor has a long lifetime acidic
electrolyte in the sensor.
Applications
Vent monitoring CH4 & CO2%
Combustion efficiency-Combustibles &
O2
Stack gas monitoring- CO,O2- Sampling
systems available
Scrubbler outlets- efficiency of
CO2, H2S removal
Specifications
Options
Sensors-Combination of sensors
from single IR for methane (VOCs) and/
or O2, plus CH4 or 1 or 2 EC sensors.
Multiple analytical modules can be used
with a single readout In short term
sampling cases, a coalescing filter that
removes liquid water and particulate is
for sampling.
7.5 pounds
RangeThe IR sensor for methane has a range of 0100%. A second IR sensor is availabel for
measuring CO2. Other sensors are designed
to be used for measuring stack gases. . A
special oxygen sensor with an acidic
electrolyte is available for measuring oxygen
in stack gases where the acid gases such
as CO2 would interfere with operation.
Sampling Systems
One of the most difficult challenges is
to deliver a sample stream saturated
with water at an elevated temperature
to the analyzer without any change in
the composition of the compounds to
be measured. A photo of one of our
sample conditioning system is shown
below. The system used for stack gases
involves dilution with ambient air to cool
the temperature of the as and to remove
the water from the gas and prevent
condensation. The dilution gas is
passed through a filter to remove any
interfering gases (SO 2 , NO....).
Calibration gas is introduced at the inlet
to correct for any losses and/or dilution
in the system.
For additional information, please
contact PID Analyzers.
Sensor Specs
Table I
Sensor Specifications
Sensor
Range ppm
Carbon Monoxide0-1,000
Carrbon Monoxide-SG 0-10,000
Hydrogen SulfideSG 0-1,000
Oxygen-SG**
0-30 %
Carbon Dioxide
0-100%
Methane
0-100%
Det. Limit
1
10
1
0.1%
1%
1%
Resp.Time (s)
15
15
15
8
30
30
Interferences
H2, C2H4
H2, C2H4
with filter
no CO2 interference
-----------------------------------------------------------------------------------------------------------------
Biogas Composition
Spotlight on Technology
Technology
The Model 108 's infrared sensors have two
interference filters and two temperature
sensors: one at the absorbance maximum
(3 microns for ClL), the other at the mini
mum. Each is in a leg of a Wheatstone Bridge
circuit. If the sample is irradiated by an TR
(infrared) source and CtL is present, it will
increase the temperature of the CH. IR sensor
44
CO2
2 : 41~ 1Q~5
(magnified 20 xl
'"
I
l.5 If
1~ t
H~
05 (magrifted 50 xl
Ii
.~JJ
--~-I
.J
:
.
/\
. /
f
o.o~\....:...J
Compound
Concentration %
co,
40-60
CH,
45-60
0,
0.1-1
H,S
0-3
H,
0-1
l~ 11
~\j
~
---~--~-~-i -'---'~I----.-.-j
Figure 1
Figure 2
Emerging Applications
On many closed landfills, municipalities are
installing solar cells to generate power for the
cities or towns. For sites like this it is impor
tant to monitor the sites more closely to pro
tect the investment in solar power. On Cape
Cod in Massachusetts, many of the 13 towns
have worked together with a private contrac
tor to install solar cells on landfills to gener
ate electlicilY for the towns at a considerably
lower cost than conventional power. Of the
50+ landfills in MA, 38 are cWTently generat
ing power by burning methane.
CryoGas International