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Introduction
3. Water treatment
3.1 Pre-treatment
3.3.1 Filtration.
3.3.2 Lagooning.
3.3.7 Disinfection.
4. Sewage treatment.
5. Parameters of agricultural significance.
5.6 pH.
Water pollution affects plants and organisms living in these bodies of water; and, in almost all
cases the effect is damaging either to individual species and populations, but also to the natural
biological communities.
Water pollution occurs when pollutants are discharged directly or indirectly into water bodies
without adequate treatment to remove harmful compounds.
Surface water and groundwater have often been studied and managed as separate
resources, although they are interrelated. Sources of surface water pollution are generally grouped
into two categories based on their origin.
Groundwater pollution
Most water pollution doesn't begin in the water itself. Take the oceans: around 80 percent of ocean
pollution enters our seas from the land. Virtually any human activity can have an effect on the quality of our
water environment. When farmers fertilize the fields, the chemicals they use are gradually washed by rain
into the groundwater or surface waters nearby. Sometimes the causes of water pollution are quite
surprising. Chemicals released by smokestacks (chimneys) can enter the atmosphere and then fall back to
earth as rain, entering seas, rivers, and lakes and causing water pollution. Water pollution has many
different causes and this is one of the reasons why it is such a difficult problem to solve.
Biological wastewater treatment processes are primarily designed for the removal of dissolved and
suspended organic matter from wastewaters. The environmental conditions are optimised to encourage
growth of the micro-organisms which use the organic compounds as substrate.
Biological wastewater treatment is also capable of removing other wastewater components, including
suspended solids, nitrogen, phosphorus, heavy metals and xenobiotics.
In general the biological wastewater treatment is the most efficient and economic way of removing organic
pollution from a wastewater.
Water treatment describes those processes used to make water more acceptable for a desired end-use.
These can include use as drinking water, industrial processes, medical and many other uses. The goal of
all water treatment process is to remove existing contaminants in the water, or reduce the concentration of
such contaminants so the water becomes fit for its desired end-use. One such use is returning water that
has been used back into the natural environment without adverse ecological impact.
The processes involved in treating water for drinking purpose may be solids separation using physical such
as settling and filtration, chemical such as disinfection and coagulation.
Biological processes are also employed in the treatment of wastewater and these processes may include,
for example, aerated lagoons, activated sludge or slow sand filters.
3.1 Pre-treatment
Screening
Grit removal
Primary treatment
In the primary sedimentation stage, sewage flows through large tanks, commonly called "primary
clarifiers" or "primary sedimentation tanks". The tanks are large enough that sludge can settle and floating
material such as grease and oils can rise to the surface and be skimmed off.
The purpose of tertiary treatment is to provide a final treatment stage to raise the effluent quality before it is
discharged to the receiving environment (sea, river, lake, ground, etc.). More than one tertiary treatment
process may be used at any treatment plant. If disinfection is practiced, it is always the final process. It is
also called "effluent polishing".
3.5.1 Filtration
Sand filtration removes much of the residual suspended matter. Filtration over activated carbon removes
residual toxins.
3.5.2 Lagooning
Lagooning provides settlement and further biological improvement through storage in large man-made
ponds or lagoons. These lagoons are highly aerobic and colonization by native macrophytes, especially
reeds, is often encouraged. Small filter feeding invertebrates such as Daphnia and species of Rotifera
greatly assist in treatment by removing fine particulates.
Construucted wetlands include engineered reedbeds and a range of similar methodologies, all of which
provide a high degree of aerobic biological improvement and can often be used instead of secondary
treatment for small communities, also see phytoremediation. One example is a small reedbed used to clean
the drainage from the elephants' enclosure at Chester Zoo in England.
Wastewater may contain high levels of the nutrients nitrogen and phosphorus. Excessive release to the
environment can lead to a build up of nutrients, called eutrophication, which can in turn encourage the
overgrowth of weeds, algae, and cyanobacteria (blue-green algae). This may cause an algal bloom, a rapid
growth in the population of algae. The algae numbers are unsustainable and eventually most of them die.
The decomposition of the algae by bacteria uses up so much of oxygen in the water that most or all of the
animals die, which creates more organic matter for the bacteria to decompose. In addition to causing
deoxygenation, some algal species produce toxins that contaminate drinking water supplies. Different
treatment processes are required to remove nitrogen and phosphorus.
The removal of nitrogen is effected through the biological oxidation of nitrogen from ammonia (nitrification)
to nitrate, followed by denitrification, the reduction of nitrate to nitrogen gas. Nitrogen gas is released to the
atmosphere and thus removed from the water.
3.5.6 Phosphorus removal
Phosphorus removal is important as it is a limiting nutrient for algae growth in many fresh water systems
(for negative effects of algae see Nutrient removal). It is also particularly important for water reuse systems
where high phosphorus concentrations may lead to fouling of downstream equipment such as reverse
osmosis.
3.5.7 Disinfection
The purpose of disinfection in the treatment of wastewater is to substantially reduce the number of
microorganisms in the water to be discharged back into the environment. The effectiveness of disinfection
depends on the quality of the water being treated (e.g., cloudiness, pH, etc.), the type of disinfection being
used, the disinfectant dosage (concentration and time), and other environmental variables. Cloudy water
will be treated less successfully since solid matter can shield organisms, especially from ultraviolet light or if
contact times are low. Generally, short contact times, low doses and high flows all militate against effective
disinfection. Common methods of disinfection include ozone, chlorine, ultraviolet light, or sodium
hypochlorite. Chloramine, which is used for drinking water, is not used in wastewater treatment because of
its persistence.
Early stages of processing will tend to produce smelly gasses, hydrogen sulfide being most common in
generating complaints from nearby areas. Large process plants in urban areas will often contain a foul air
removal tower, composed of air circulators, a contact media with bio-slimes, and circulating fluids to
biologically capture and metabolize the obnoxious gasses previously contained by reactor enclosures.
In order to use less space, treat difficult waste, deal with intermittent flow or achieve higher environmental
standards, a number of designs of hybrid treatment plants have been produced. Such plants often combine
all or at least two stages of the three main treatment stages into one combined stage. In the UK, where a
large number of sewage treatment plants serve small populations, package plants are a viable alternative
to building discrete structures for each process stage.
4 Sewage
Sewage treatment, or domestic wastewater treatment, is
the process of removing contaminants from wastewater
and household sewage, both runoff (effluents) and
domestic. It includes physical, chemical, and biological
processes to remove physical, chemical and biological
contaminants. Its objective is to produce a waste stream
(or treated effluent) and a solid waste or sludge suitable
for discharge or reuse back into the environment. This
material is often inadvertently contaminated with many toxic organic and inorganic compounds.
With over 8 billion people on the planet, disposing of sewage waste is a major problem. In developing
countries, many people still lack clean water and basic sanitation (hygienic toilet facilities). Sewage
disposal affects people's immediate environments and leads to water-related illnesses such as diarrhea
that kills 3-4 million children each year. (According to the World Health Organization, water-related
diseases could kill 135 million people by 2020.) In developed countries, most people have flush toilets that
take sewage waste quickly and hygienically away from their homes.
Yet the problem of sewage disposal does not end there. When you flush the toilet, the waste has to go
somewhere and, even after it leaves the sewage treatment works, there is still waste to dispose of.
Sometimes sewage waste is pumped untreated into the sea. Until the early 1990s, around 5 million tons of
sewage was dumped by barge from New York City each year. The population of Britain produces around
300 million gallons of sewage every day, some of it still pumped untreated into the sea through long pipes.
The New River that crosses the border from Mexico into California carries with it 20-25 million gallons (76-
95 million litres) of raw sewage each day.
In theory, sewage is a completely natural substance that should be broken down harmlessly in the
environment: 90 percent of sewage is water. In practice, sewage contains all kinds of other chemicals, from
the pharmaceutical drugs people take to the paper, plastic, and other wastes they flush down their toilets.
When people are sick with viruses, the sewage they produce carries those viruses into the environment. It
is possible to catch illnesses such as hepatitis, typhoid, and cholera from river and sea water.
5 Parameters of agricultural
significance
The quality of irrigation water is of particular importance in arid zones where extremes of temperature and
low relative humidity result in high rates of evaporation, with consequent deposition of salt which tends to
accumulate in the soil profile. The physical and mechanical properties of the soil, such as dispersion of
particles, stability of aggregates, soil structure and permeability, are very sensitive to the type of
exchangeable ions present in irrigation water. Thus, when effluent use is being planned, several factors
related to soil properties must be taken into consideration. A thorough treatise on the subject prepared by
Ayers and Westcot is contained in the FAO Irrigation and Drainage Paper No 29 Rev. 1 (FAO 1985).
Another aspect of agricultural concern is the effect of dissolved solids (TDS) in the irrigation water on the
growth of plants. Dissolved salts increase the osmotic potential of soil water and an increase in osmotic
pressure of the soil solution increases the amount of energy which plants must expend to take up water
from the soil. As a result, respiration is increased and the growth and yield of most plants decline
progressively as osmotic pressure increases. Although most plants respond to salinity as a function of the
total osmotic potential of soil water, some plants are susceptible to specific ion toxicity.
Many of the ions which are harmless or even beneficial at relatively low concentrations may become toxic
to plants at high concentration, either through direct interference with metabolic processes or through
indirect effects on other nutrients, which might be rendered inaccessible. Morishita (1985) has reported that
irrigation with nitrogen-enriched polluted water can supply a considerable excess of nutrient nitrogen to
growing rice plants and can result in a significant yield loss of rice through lodging, failure to ripen and
increased susceptibility to pests and diseases as a result of over-luxuriant growth. He further reported that
non-polluted soil, having around 0.4 and 0.5 ppm cadmium, may produce about 0.08 ppm Cd in brown rice,
while only a little increase up to 0.82, 1.25 or 2.1 ppm of soil Cd has the potential to produce heavily
polluted brown rice with 1.0 ppm Cd.
Important agricultural water quality parameters include a number of specific properties of water that are
relevant in relation to the yield and quality crops, maintenance of soil productivity and protection of the
environment. These parameters mainly consist of certain physical and chemical characteristics of the
water. Table 7 presents a list of some of the important physical and chemical characteristics that are used
in the evaluation of agricultural water quality. The primary wastewater quality parameters of importance
from an agricultural viewpoint are:
The most reliable index of the sodium hazard of irrigation water is the sodium adsorption ration, SAR. The
sodium adsorption ratio is defined by the formula:
(1)
A nomogram for determining the SAR value of irrigation water is presented in Figure 3 (US Salinity
Laboratory 1954). An exchangeable sodium percentage (ESP) scale is included in the nomogram to
estimate the ESP value of the soil that is at equilibrium with the irrigation water. Using the nomogram, it is
possible to estimate the ESP value of a soil that is at equilibrium with irrigation water of a known SAR
value. Under field conditions, the actual ESP may be slightly higher than the estimated equilibrium value
because the total salt concentration of the soil solution is increased by evaporation and plant trans-piration,
which results in a higher SAR and a corres-pondingly higher ESP value.
It should also be noted that the SAR from Eq 1 does not take into account changes in calcium ion
concentration in the soil water due to changes in solubility of calcium resulting from precipitation or
dissolution during or following an irrigation. However, the SAR calculated according to Eq 1 is considered
an acceptable evaluation procedure for most of the irrigation waters encountered in agriculture. If significant
precipitation or dissolution of calcium due to the effect of carbon dioxide (CO2), bicarbonate (HCO3-) and
total salinity (ECw) is suspected, an alternative procedure for calculating an Adjusted Sodium Adsorption
Ratio, SARadj. can be used. The details of this procedure are reported by Ayers and Westcot (FAO (1985).
The most common phytotoxic ions that may be present in municipal sewage and treated effluents in
concentrations such as to cause toxicity are: boron (B), chloride (Cl) and sodium (Na). Hence, the
concentration of these ions will have to be determined to assess the suitability of waste-water quality for
use in agriculture.
A nomogram for determining sodium adsorption ratio (US Salinity Laboratory 1954)
Federal and state definitions of low-level radioactive waste differ. In Texas, low-level radioactive waste
includes radioactive waste that has a half-life of 35 years or less and fewer than 10 nanocuries per gram of
transuranics, as well as wastes with half-lives of more than 35 years if special criteria for the disposal of the
waste are established by the TCEQ.* The federal definition, on the other hand, considers any radioactive
waste that has less than 100 nanocuries per gram of transuranics low-level.
Texas's nuclear plants—as well as many of the state's universities and industries—sent their radioactive
wastes to a low-level radioactive facility in Barnwell, South Carolina, until July 1994, when the facility
temporarily closed. Since then, the facility has reopened and both the Barnwell and a similar facility in Clive
Utah -- accept low-level radioactive waste from Texas generator. However, the Barnwell facility will stop
accepting waste from Texas beginning in 2008 and the Utah site only accepts certain kinds of low-level
radioactive waste. The two nuclear plants in Texas currently store their nuclear wastes on-site in above-
ground facilities, while hospitals and universities either store such waste on-site or send it to a centralized
storage facility in Fort Stockton, Texas.There are an estimated 60 sites throughout Texas which store low-
level radioactive waste.
Low-level radioactive waste regulation falls under the jurisdiction of both the TCEQ and the Texas
Department of Health's Bureau of Radiation Control. While TCEQ regulates disposal of low-level waste and
has the authority to issue a license for a disposal facility, the TDH regulates and licenses the use, transport,
and storage of radioactive materials.
Under the federal Low-Level Radioactive Waste Policy Act of 1980 and 1985 amendments, states are
expected to arrange for disposal of low-level waste generated within their borders -- other than those
wastes generated by federal weapon facilities -- or form a compact with other states to create a single
disposal site, which may refuse to accept waste from other states not in the compact. In 1981 the Texas
legislature created the Low Level Radioactive Waste Disposal Authority to develop a state site to manage
these wastes. In 1991 the legislature ordered the Waste Disposal Authority to locate the site in Hudspeth
County, and in 1992 a site was preliminary approved in Hudspeth County, about seven miles from Sierra
Blanca. In 1993, Texas formed a compact with the States of Vermont, and Maine to dispose of low-level
radioactive waste from these two states and from Texas in Texas, which was later approved by the U.S.
Congress.In 1996 the then-TNRCC proposed a draft permit for the site. However, several individuals, cities,
counties, and organizations from both sides of the border opposed the permit, and in 1997 the State Office
of Administrative Hearings ordered a hearing to decide whether to recommend denying or granting the
permit. In July 1998 the hearings examiners in the case recommended that the TNRCC deny the permit
because the applicant failed to characterize the fault directly beneath the site and failed to address potential
negative socioeconomic impacts from the proposed facility.* In October 1998 the TNRCC commissioners
denied the permit. In 1999, the Texas legislature eliminated the TRLLWDA, transferring all of its functions
to the TNRCC. Finally, in 2003, the Texas Legislature approved and the governor approved HB 1567,
which created a process for a private entity to hold a license to dispose of low-level radioactive waste, and
also allow another similar facility -- which could be owned by the same company although the wastes would
have to be disposed of separately -- to accept low-level federal radioactive waste from Department of
Energy (DOE) weapon or other facilities.
Under the legislation, the TCEQ has written rules for how it will accept applications to dispose of the
radioactive waste, and applications would need to be received by January of 2004. Applicants would need
to submit an application fee of $500,000. The disposal site would be run and managed by the private
company, but after a time period would revert to state ownership. Because of the way both the legislation
and the subsequent rules are written, it is most likely the waste site would be located in Andrews County in
West Texas. Waste Control Specialist, a private waste management company, currently manages a mixed
hazardous waste landfill and radioactive storage facility in Andrews County and has proposed disposing
and managing low-level radioactive waste there. Another company – Envirocare – has in the past proposed
building a facility to accept low-level radioactive waste in several counties in West Texas. It is expected that
one or more of these companies would apply for a permit to manage low-level state and federal radioactive
waste. Nonetheless, the application is certain to generate some opposition, and a decision will not be
reached on approving such a site for several years.
While it is difficult to estimate how much waste would be buried at such a site, estimates of "compact"
waste -- low-level radioactive waste in Texas, Vermont and Maine -- are between two and three million
cubic feet, while the DOE expects to generate hundreds of millions of cubic meters of low-level radioactive
waste by 2007. Under the bill, up to 162 million cubic feet of DOE waste could be disposed of in Texas.
Contains higher amounts of radioactivity and may require special shielding. It typically comprises resins,
chemical sludges and reactor components, as well as contaminated materials from reactor
decommissioning. Worldwide it makes up 7% of the volume and has 4% of the radioactivity of all radwaste.
It may be solidified in concrete or bitumen for disposal. Generally short-lived waste (mainly from reactors) is
buried, but long-lived waste (from reprocessing nuclear fuel) will be disposed of deep underground.
In addition, coal power production, oil and gas exploration and production, fertilizer production, and water
treatment can all produce wastes classified as naturally occurring. For example, the insides of oil extraction
pipes may be coated with radium, or radium may be brought up to the surface while drilling for oil. Naturally
occurring radioactive wastes are managed apart from other radioactive and toxic wastes.
Naturally occurring radioactive material waste is regulated in Texas by three different agencies. The Texas
Department of Health's Bureau of Radiation Control regulates the receipt, possession, strorage, use and
treatment of NORM, while the Railroad Commission of Texas regulates the disposal of oil and gas NORM
waste. Finally, the Texas Commission on Environmental Quality regulates disposal of all other NORM
waste that does not result from oil and gas production.
In oil and gas exploration, development and production, NORM originates in underground formations and
can be brought to the surface in the formation water that is produced along with oil and gas, usually in the
form of radium 226 and 228 and radon gas. Concentrations of these NORM wastes can occur in sludge
that accumulates in oil pits, or become present in well tubulars or other equipment. Under RCT regulations,
oil and gas waste containing NORM can no be injected back underground or discharged into surface
waters without a permit. Oil and gas producers that are removing pipes from the ground which might
contain traces of uranium or other radioactive materials must first get a license from the Department of
Health. If they intend to export the waste to another site in Texas, that disposal site must be licensed by the
Railroad Commission. As of January 1998, only two off-site disposal sites—Newpark Environmental
Services in Winnie, Texas, and Lotus, L.L.C. in Andrews County—were authorized by the Railroad
Commission to receive naturally occurring radioactive material waste. Both use pits and injection wells to
dispose of the waste.
6.5 Transuranic Waste
Transuranic waste, or TRU, includes waste containing plutonium and other elements heavier than uranium
which contain more than 100 nanocuries of alpha-emitting isotopes. Transuranic waste is produced mainly
from the reprocessing of spent nuclear fuel rods, nuclear weapons production, and reactor fuel assembly.
The main producer of transuranic waste is the Department of Energy's nuclear weapons production
facilities. In 1999 the department began sending transuranic waste for disposal at natural underground salt
formations near Carlsbad, New Mexico. This locale is known as the Waste Isolation Pilot Plant, or WIPP.
While the site was certified by the EPA in 1998, it still must receive an operating permit from the New
Mexico Environment Department before it can receive other types of radioactive and hazardous waste.
In Texas, tons of plutonium from the nation's nuclear arsenal are being stored at the Pantex nuclear
weapons plant some seventeen miles northeast of Amarillo in Carson County. About 2,000 nuclear
weapons are being dismantled there each year and stored at the plant site. The Pantex plant is owned by
the Department of Energy and operated under contract by Mason and Hangar-Siles Mason Co. In 1994 the
plant was declared a Superfund site and is currently
Radioactive wastes occur at all stages of the nuclear fuel cycle - the process of producing electricity from
nuclear materials. The fuel cycle comprises the mining and milling of the uranium ore, its processing and
fabrication into nuclear fuel, its use in the reactor, the treatment of the used fuel taken from the reactor after
use and finally, disposal of the wastes.
The fuel cycle is often considered as two parts - the "front end" which stretches from mining through to the
use of uranium in the reactor - and the "back end" which covers the removal of used fuel from the reactor
and its subsequent treatment and disposal. This is where radioactive wastes are a major issue.