Physics&Chemistry Solutions Solutions of AIEEE 2004 Paper: Mathiit

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Solutions of AIEEE 2004 Paper

PHYSICS&CHEMISTRY SOLUTIONS
1. From Newton's formula
F
η=
A( ∆v x / ∆z)
∴ Dimensions of
dim ensions of force

η=
dim ensions of area × dim ensions of velocity − gradient
[MLT−2 ]
= 2 −1
= [ML−1T −1 ]
[L ] T ]
2. As given in question, retardation (negative acceleration) a ∝ x
om
⇒ a = kx
where k is a proportionality constant
⇒
dv
= kx
c
g.
dt
ng
dv dx
⇒ . = kx
dx dt
ye
dv  dx 
⇒ v = kx Q v = 
dx  dt 
.m
⇒ v dv = kx dx
Integrating, we get
w
∫ ∫
vf x
v dv = kx dx
w
vi 0
w
where vi and vf respectively are initial and final velocities of particle.

vf x
 v2   x2 
  =k 
 2   2 
  vi  0
v2f v 2i x2
⇒ − =k
2 2 2
1 2 1 2 1
⇒ mvf − mvi = mkx2
2 2 2
1
⇒ K.E.final − K.E.initial = mkx2
2
Hence, loss in kinetic energy ∝ x2
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3. Second law of motion gives
1
s = ut + gt 2
2
1
or h = 0 + gt 2 (Q u = 0)
2
 2h 
∴ T =  
 g 
T
At t = sec,
3
2
1 T
x = 0 + g 
2  3
1 T2
⇒ s = g.
om
2 9
g 2h  
s= × Q T = 2h 
⇒ 18 g
c 
 g 
g.
h
ng
∴ s= m
9
Hence, the position of ball from the ground
ye
h 8h
=h− = m
9 9
.m
r r r r
4. (A × B) = (B × A) (given)
r r r r r
w
⇒ (A × B) − (B × A) = 0
r r r r r
[Q (Br × Ar ) = − (Ar × Br )]
w
(A × B) + (A × B) = 0
w
r r r
⇒ 2(A × B) = 0
⇒ 2AB sin θ = 0
⇒ sin θ = 0 [Q | Ar | = A ≠ 0, | Br | = B ≠ 0]
∴ θ = 0 or π
5. We know in advance that range of projectile is same for complementary angles i.e. for θ and
(900 - θ ).
2u sin θ
∴ T1 =
g
2u sin(90 0 − θ) 2u cos θ
T2 = =
g g
u 2 sin 2θ
and R=
g
2u sin θ 2u cos θ
Therefore, T1 T2 = ×
g g
2u 2 (2 sin θ cos θ)
=
g2
2u 2 (sin 2θ)
=
g2
2R
=
g
∴ T1T2 ∝ R
6. For a particle moving in a circle with constant angular speed, velocity vector is always tangent to
om
the circle and the acceleration vector always points towards the centre of the circle or is always along
radius of the circle. Since, tangential vector is perpendicular to radial vector, therefore, velocity
vector will be perpendicular to the acceleration vector. But in no case acceleration vector is tangent
to the circle.
c
g.
7. Third equation of motion gives
v2 = u2 + 2as
ng
⇒ s ∝ u2 (since v = 0)
ye
where a = retardation of body in both the cases
s1 u12
∴ = ................. (i)
.m
s2 u 22
Here, s1 = 20 m, u1 = 60 km/h, u2 = 120 km/h. Putting the given values in eq. (i), we get
w
2
20  60 
w
= 
s2  120 
w
2
 120 
⇒ s2 = 20 ×  
 60 
= 20 × 4
= 80 m
8. The force exerted by machine gun on man's hand in firing a bullet = change in momentum per
second on a bullet or rate of change of momentum
 40 
=  ×1200 = 48 N
 1000 
The force exerted by man on machine gun = 144 N
144
Hence, number of bullets fired = =3
48
9. On releasing, the motion of the system will be according to the figure.
m1g - T = m1a ...... (i)
and T - m2g = m2a ...... (ii)
On solving;
 m − m2  a T T a
a =  1  g ........ (iii)
 m1 + m 2 
Here,
m1 = 5 kg, m2 = 4.8 kg, g = 9.8 m/s2 m 1g
m 2g
 5 − 4.8 
∴ a=  × 9.8
 5 + 4.8 
0.2
= × 9.8
9.8
=0.2 m/s2
10. Mass per unit length
om
M
=
L
=
4
= 2kg / m
c
g.
2
The mass of 0.6 m of chain = 0.6 × 2 = 1.2 kg
ng
0.6 + 0
The centre of mass of hanging part = = 0.3 m
ye
2
Hence, work done in pulling the chain on the table
.m
W = mgh
= 1.2 × 10 × 0.3
= 3.6 J
w
11. Let the mass of block be m.

w
R
Frictional force in rest position F
w
F = mg sin 300 m g sin 30 0 m g cos30 0

mg
1 30 0
10 = m × 10 ×
2
2 × 10
∴ m= = 2 kg
10
12. Work done in displacing the particle
rr
W = F. r
= (5î + 3 ĵ + 2 k̂) . (2 î − ĵ)

= 5 × 2+3 × (-1) + 2 × 0
= 10 - 3
=7J
13. Let the constant acceleration of body of mass m is a.
From equation of motion
v1 = 0 + at1
v1
⇒ a= ...... (i)
t1
At an instant t, the velocity v of the body
v = 0 + at
v1
v= t ...... (ii)
t1
Therefore, instantaneous power
P = Fv
= mav (Q F = ma)
v  v 
= m  1  ×  1 × t  [from equations (i) and (ii)]
 t1   t 1 
mv12 t
=
om
t12
14. When a force of constant magnitude acts on velocity of particle perpendicularly, then there is no
c
change in the kinetic energy of particle. Hence, kinetic energy remains constant.
g.
15. In free space, neither acceleration due to gravity for external torque act on the rotating solid sphere.
Therefore, taking the same mass of sphere if radius is increased then moment of inertia, rotational
ng
kinetic energy and angular velocity will change but according to law of conservation of momentum,
angular momentum will not change.
ye
16. Man will catch the ball if the horizontal component of velocity becomes equal to the constant speed
of man i.e.
.m
v0
v 0 cos θ =
2
w
1
⇒ cos θ =
w
2
⇒
w
cos θ = cos 60 0
∴ θ = 60 0
17. Let same mass and same outer radii of solid sphere and hollow sphere are M and R respectively.
The moment of inertia of solid sphere A about its diameter
2
I A = MR2 ..... (i)
5
Similarly the moment of inertia of hollow sphere (spherical shell) B about its diameter
2
IB = MR2 ....... (ii)
3
It is clear from eqs. (i) and (ii). IA < IB
18. The gravitational force exerted on satellite at a height x is
GMe m
FG =
(R + x)2
where Me = mass of earth
Since, gravitational force provides the necessary centripetal force, so,
GMe m mv20
=
( R + x) 2 ( R + x)
GMe m
⇒ = mv20
( R + x)
gR 2 m  GM 
⇒ = mv20 Q g = 2 e 
( R + x)  R 
 gR 2 
⇒ v0 =  
 ( R + x) 
1/ 2
 gR 2 
= 
 (R + x) 
om
19. Time period of satellite
( R + h) 3
T = 2π
GMe
c
g.
where R + h = orbital radius of satellite,
ng
Me = mass of earth
Thus, time period does not depend on mass of satellite.
ye
20. Gravitational potential energy of body on earth's surface

GMe m
U=−
.m
R
At a height h from earth's surface, its value is
w
GMe m
Uh = −
w
( R + h)
w
GMe m
=− (Q h = R)
2R
where Me = mass of earth
m = mass of body
R = radius of earth
∴ Gain in potential energy = Uh - U
GMe m  GMe m 
=− −− 
2R  R 
GMe m GMe m
=− +
2R R
GMe m
=
2R
gR 2 m  GM 
= Q g = 2 e 
2R  R 
1
= mgR
2
21. The necessary centripetal force required for a planet to move round the sun = gravitational force
exerted on it
mv2 GMe m
i.e. =
R Rn
1/ 2
 GM 
v =  n −1e 
R 
1/ 2
2πR  R n −1 
T= = 2πR ×  
Now, 
v  GMe 
om
1/ 2
 R 2 × R n −1 
= 2π  

 GMe 
c
g.
 R ( n +1) / 2 
= 2π  1/ 2


 (GMe ) 
ng
∴ T ∝ R ( n +1) / 2
ye
22. Work done in stretching the wire = potential energy stored

1
= × stress× strain × volume
.m
1 F l
w
= × × × AL
2 A L
w
1
= Fl
w
2
23. Retarding force acting on a ball falling into a viscous fluid
F = 6πηRv
where R = radius of ball
v = velocity of ball
and η = coefficient of viscosity
∴ F ∝ R and F ∝ v
Or in words, retarding force is proportional to both R and v.
24. The excess pressure inside the soap bubble is inversely proportional to radius of soap bubble i.e.
P ∝ 1 / r, r being the radius of bubble. It follows that pressure inside a smaller bubble is greater than
that inside a bigger bubble. Thus, if these two bubbles are connected by a tube, air will flow from
smaller bubble to bigger bubble and the bigger bubble grows at the expense of the smaller one.
25. The time period of simple pendulum in air
l
T = t 0 = 2π   ...... (i)
g
l, being the length of simple pendulum, In water, effective weight of bob

w' = weight of bob in air - upthrust
⇒ ρVg eff = mg − m' g = ρVg − ρ' Vg = (ρ − ρ' )Vg
where ρ = density of bob, ρ′ = density of water
 ρ − ρ' 
∴ g eff =   g
 ρ 
 ρ' 
=  1 −  g
 ρ
 
 
 l 
om
∴ t = 2π ...... (ii)
  ρ'  
  1 −  g 
 ρ 
c
g.
 
 1 
ng
t
Thus, =  
t0 1 − ρ' 
 ρ 
ye
.m
 
 
=  1  =  4 
   4 − 3
w
1000
 1 − (4 / 3) × 1000 
 
w
= 2 ⇒ t = 2 t0
w
26. Time period of spring
m
T = 2π  
k
k, being the force constant of spring.

For first spring
m
t1 = 2π   ...................... (i)
 k1 
For second spring
m
t 2 = 2π   ...................... (ii)
 k2 
The effective force constant in their series combination is
k1 k 2
k=
k1 + k 2
∴ Time period of combination
 m( k 1 + k 2 ) 
T = 2π  
 k1 k 2 
4π 2 m ( k 1 + k 2 )
⇒ T2 = ................ (iii)
k1 k 2
From equations (i) and (ii), we obtain
m m
t12 + t 22 = 4π2  + 
 k1 k 2 
 1 1 
⇒ t12 + t 22 = 4π2 m  + 
om
 k1 k 2 
4π2 m ( k1 + k 2 )
⇒ t12 + t 22 =
k1 k 2
c
g.
∴ t12 + t 22 = T 2 [from equation (iii)]
ng
27. In simple harmonic motion when a particle is displaced to a position from its mean position, then
its kinetic energy gets converted into potential energy and vice-versa. Hence, total energy of a
ye
particle remains constant or the total energy in simple harmonic motion does not depend on displacement
x.
.m
28. As given
 π
w
y = 10 −6 sin  100t + 20x +  ............. (i)

 4
w
Comparing it with
w
y = a sin(ωt + kx + φ) ............. (ii)

we find ω = 100 rad/sec, k = 20 per metre
ω 100
∴ v= = = 5 m/s
k 20
29. Initial angular velocity of particle = ω0 and at any instant t, angular velocity = ω
Therefore, for a displacement x, the resultant acceleration
f = (ω20 − ω2 ) x .............. (i)
External force F = m (ω20 − ω2 ) x .............. (ii)

Since, F ∝ cos ωt (given)
∴ From eq. (ii) m(ω20 − ω2 ) x ∝ cos ωt .............. (iii)

Now, equation of simple harmonic motion
x = A sin (ωt + φ) .......... (iv)
at t = 0 ; x = A
∴ A = A sin( 0 + φ )
π
⇒ φ=
2
 π
∴ x = A sin  ωt +  = A cot ωt ........... (v)
 2
Hence, from equations (iii) and (v), we finally get
m(ω20 − ω2 ) A cos ωt ∝ cos ωt
1
⇒ A∝
m(ω20 − ω2 )
30. For amplitude of oscillation and energy to be maximum, frequency of force must be equal to the
initial frequency and this is only possible in case of resonance.
om
In resonance state ω1 = ω2
31. Mayer's formula is
CP - CV = R
c
CP
g.
and γ=
CV
ng
Therefore, using above two relations, we find

R
ye
CV =
γ −1
.m
5
For a mole of monoatomic gas; γ =
3
w
R 3
∴ CV = = R
(5 / 3) − 1 2
w
w
7
For a mole of diatomic gas; γ =
5
R 5
∴ CV = = R
(75) − 1 2
When these two moles are mixed, then heat required to raise the temperature to 10C is
3 5
CV = R + R = 4R
2 2
Hence, for one mole, heat required is
4R
= = 2R
2
∴ CV = 2R
R 3
⇒ = 2R ⇒ γ=
γ −1 2
32. From Stefan's law
E ∝ AT 4
⇒ E ∝ r 2T4 (Q A = πr 2 )
E1 r12 T14
∴ =
E 2 t 22 T24
E1 R2T 4
or =
E 2 (2 R ) 2 × ( 2 T ) 4
E1 R2T4
or =
E 2 4R 2 × 16T 4
E2
∴ = 64
E1
33. In thermodynamic system, entropy and internal energy are state functions.
om
34. There will be no change in number of moles if the vessels are joined by valve. Therefore, from gas
equation
PV = nRT
c
g.
P1 V1 P2 V2 P(V1 + V2 ) P1V1T2 + P2 V2 T1 P(V1 + V2 )
⇒ + = ⇒ =
RT1 RT2 RT T1T2 T
ng
P(V1 + V2 ) T1T2
⇒ T=
ye
(P1V1T2 + P2 V2 T1 )
Now, according to Boyle's law (pressure = constant)
.m
P1V1 + P2V2 = P(V1 + V2)

( P1V1 + P2 V2 ) T1T1
w
Hence, T=
( P1V1T2 + P2 V2 T1 )
w
35. Initial momentum of surface

w
E
pi =
c
where c = velocity of light (constant).
Since, the surface is perfectly reflecting so, the same momentum will be reflected completely
Final momentum
E
pf = (negative value)
c
∴ Change in momentum
E E 2E
∆p = p f − p i = − − =−
c c c
Thus, momentum transferred to the surface is
2E
∆p' = | ∆p | =
c
36. Let the temperature of common inner slab (surface) be T0C.
Rate of heat flow
Q KA ∆T
H= =
t l
Q 2KA ( T − T1 )
∴ H1 =   =
 1
t 4x
Q KA (T2 − T)
and H2 =   =
 t 2 x
In steady state, the rate of heat flow should be same in whole system i.e.
H1 = H2
2KA(T − T1 ) KA (T2 − T)
⇒ =
4x x
T − T1
⇒ = T2 − T
om
2
⇒ T - T1 = 2T2 - 2T
2T2 + T1
⇒ T=
3
c
g.
Hence, heat flow from composite slab is
ng
KA (T2 − T)
H= [from eq. (i)]
x
ye
KA  2T + T1  KA
=  T2 − 2 = (T2 − T1 ) .............. (ii)
x  3  3x
.m
Accordingly,
w
 A(T2 − T1 ) K 
H= f .............. (ii)
 
w
x
w
 A(T2 − T1 )  KA
Hence,  K f = (T2 − T1 )
 x  3x
1
⇒ f=
3
37. For total internal reflection from glass-air interface, critical angle C must be less than angle of
incidence.
i.e. C<i
or C < 450 (Q ∠i = 450 )
1 1
But n= ⇒ C = sin−1  
sin C n
1
∴ sin−1   < 450
n
1
⇒ < sin 450
n A C
1
⇒ n> 45 0
sin 450 45 0
1
⇒ n>
(1 / 2 )
B
⇒ n> 2
38. A plano-convex lens behaves as a concave mirror if its one surface (curved) is silvered. The rays
refracted from plane surface are reflected from curved surface and again refract from plane surface.
Therefore, in this lens two refractions and one reflection occur. Let the focal length of silvered lens
1 1 1 1
is f. = + +
F f f fm
2 1
= +
om
f fm
where, f = focal length of lens before silvering
fm = focal length of spherical mirror
1 2 2
c
g.
∴ = + ............. (i) (Q R = 2fm )
F f R
ng
1  1 1 
Now, = (µ − 1)  −  ............. (ii)
f  R1 R 2 
ye
Here, R 1 = ∞, R 2 = 30 cm
.m
1 1 1 
∴ = (1.5 − 1)  − 
f  ∞ 30 
w
1 0.5 1
w
⇒ =− =−
f 30 60
w
⇒ f = -60 cm
Hence, from equation (i)
1 2 2
= +
F 60 30
6
=
60
F = 10 cm
Again given that, size of object = size of image
⇒ O=l
v l
∴ m=− =
u O
v
⇒ = −1 ⇒ v = -u
u
Thus, from lens formula
1 1 1
= −
F v u
1 1 1
= −
10 − u u
1 2
=−
10 u
∴ u = -20 cm
Hence, to get a real image, object must be placed at a distance 20 cm on the left side of lens.
39. The particular angle of incidence for which reflected light is totally polarized for reflection from air
to glass, is called the angle of polarisation (ip) (Brewster's law).
Accordingly, n = tan ip
⇒ ip = tan-1 (n)
where n = refractive index of glass.
40. For possible interference maxima on the screen, the condition is
om
d sin θ = nλ ............... (i)
Given : d = slit - width = 2 λ
∴ 2λ sin θ = nλ
c
g.
⇒ 2 sin θ = n
The maximum value of sin θ is 1, hence, n = 2 × 1 = 2
ng
Thus, equation (i) must be satisfied by 5 integer values i.e. - 2, -1, 0, 1, 2. Hence, the maximum
number of possible interference maxima is 5.
ye
41. In vacuum, ε 0 = 1
In medium, ε = 4
.m
So, refractive index µ = ε / ε0

w
= 4 /1 = 2
w
λ λ
λ' = =
w
Wavelength
µ 2
c c
and wave velocity v= =
µ 2
Hence, it is clear that wavelength and velocity will become half but frequency remains unchanged
when the wave is passing through any medium.
42. Let the spherical conductors B and C have same charge as q. The electric force between them is
1 q2
F=
4πε 0 r 2
r, being the distance between them.

When third uncharged conductor A is brought in contact with B, the charge on each conductor.
qA + qB
qA = qB =
2
0+q q
= =
2 2
Again when uncharged conductor A is brought in contact with C, then charge on each conductor
q A + qC
qA = qC =
2
(q / 2) + q
=
2
3q
=
4
Hence, electric force acting between B and C is
1 q Bq C
F' =
4πε 0 r 2
1 (q / 2) (3q / 4)
=
4πε 0 r2
om
3  1 q2 
=  2 
 4πε 0 r 
c
8 g.
3F
=
ng
8
43. Let a particle of charge q having velocity v approaches Q upto a closest distance r and if the velocity
ye
becomes 2v, the closest distance will be r

The law of conservation of energy yields, kinetic energy of particle = electric potential energy
between them at closest distance of approach
.m
1 2 1 Qq 1 Qq  1 
or mv = or mv2 = k ...........(i)  k = cons tan t = 
4πε 0 
w
2 4πε 0 r 2 r 
w
1 Qq
and m(2v)2 = k ........... (ii)
w
2 r'
Dividing equation (i) by equation (ii),
1 2 kQq
mv
2 = r
1 kQq
m(2v)2
2 r'
1 r'
⇒ =
4 r
r
⇒ r' =
4
44. In steady state, equating the sum of x-components of force to zero i.e.
FCD + FCA cos 450 + FCO cos450 = 0
1 ( −Q ) ( −Q ) 1 ( −Q ) ( − Q) 1 1 (−Q)q 1 FCB FCA
FCO
⇒ . + × + × =0 D
4πε 0 4πε 0 ( 2a ) 2 4πε 0 ( 2a / 2) a C
2 2 2 45 0
a 2 -Q -Q FCD
1 Q2 1 Q 2 1 2Qq 1 q
⇒ + . − × =0 a a
4πε 0 a 2 4πε 0 2a 2 2 a 2 2 2a
O
A B
Q a
⇒ Q+ − 2q = 0 -Q -Q
2 2
⇒ 2 2 + Q + Q − 4q = 0
⇒ 4q = (2 2 + 1) Q
Q
⇒ q = (2 2 + 1)
4
45. The full cycle of alternating current consists of two half cycles. For one half, current is positive and
for second half, current is negative. Therefore, for an a.c. cycle, the net value of current average out
to zero. While for the half cycle, the value of current is different at different points. Hence, the
om
alternating current cannot be measured by D.C. ammeter
46. The equivalent of the given circuit can be found as
c
2Ω
g.
1.5Ω 1.5Ω 1.5Ω 3Ω 1.5Ω
ng
6Ω
3Ω 3Ω 3Ω
⇒ ⇒ ⇒
ye
- + - + - + - +
6V 6V 6V 6V
.m
Hence, current supplied by the battery is

V 6
w
i= = =4A
R 1.5
w
47. Let R1 and R2 be the two resistances.

w
So, S = R1 + R2 (in series)

1 1
and P= + (in parallel)
R1 R 2
R1 R 2
⇒ P=
R1 + R 2
Accordingly, S = nP
 RR 
∴ R1 + R 2 = n 1 2 
 R1 + R 2 
For n to be less, R1 = R 2 = R
nR 2
∴ 2R =
2R
⇒ 4R2 = nR2 ⇒ n=4
1
48. Since, voltage remains same in parallel, so, i ∝
R
i1 R 2
⇒ =
i 2 R1
i1 ρl 2 / A 2  ρl 
= Q R = 
i 2 ρl1 / A1  A
2
r 
(Q A = πr )
i1 l 2
⇒ = ×  1  2
i 2 l1  r2 
2
i1 3  2 
⇒ = × 
i2 4  3 
i1 1
Hence, =
i2 3
om
49. Metre bridge is an arrangement which works on Wheatstone's principle so, the balancing condition
is
R l1
=
c
S l2
g.
where l2 = 100 - l1
ng
1st case: R = X, S = Y, l1 = 20 cm,

l2 = 100 - 20 = 80 cm
ye
X 20
∴ = ................. (i)
Y 80
.m
IInd case: Let the position of null point is obtained at a distance l from same end.
∴ R = 4x, S = Y, l1 = l, l2 = 100 - l
w
4X l
=
w
Y 100 − l
w
X l
⇒ = .................... (ii)
Y 4(10 − l )
Therefore, from equations (i) and (ii)
l 20
=
4(100 − l ) 80
l 1
⇒ =
4(100 − l ) 4
⇒ l = 100 - l
⇒ l = 50 cm
50. They are the resistors made up of semiconductors whose resistance decreases with the increase in
temperature. This implies that they have negative and high temperature coefficient of resistivity.
They are usually made of metal oxides with high temperature coefficient of resistivity.
51. Let time taken in boiling the water by the heater is t sec. Then
Q = ms ∆ T
836
t = 1× 1000(400 − 100 )
4.2
836
t = 1000 × 30
4.2
1000 × 30 × 4.2
t= = 150 sec
836
52. E = aθ + bθ 2 (given)
dE
For neutral temperature (θ n ) . =0
dθ
⇒ a + 2b θ n = 0
a
⇒ θn = −
om
2b
700  a 
∴ θn = − Q = 7000 C 
2
c  b 
g.
= -3500C < 00C
But neutral temperature can never be negative (less than zero) i.e. θ n < 00C.
ng
Hence, no neutral temperature is possible for this thermocouple.

ye
53. Mass of substance liberated at cathode

m = zit
.m
where, z = electro-chemical equivalent

= 3.3 × 10-7 kg/C
w
i = current flowing = 3A.

t = 2 sec
w
∴ m = 3.3 × 10-7 × 3 × 2
w
= 19.8 × 10-7 kg
54. Let R be the radius of a long thin cylindrical shell.
To calculate the magnetic induction at a distance r (r < R) from the axis of
cylinder, a circular shell of radius r is shown:
Since no current is enclosed in the circle so, from Ampere's circuital law,
r
magnetic induction is zero at every point of circle. Hence, the magnetic induction
at any point inside the infinitely long straight thin walled tube (cylindrical) is
R
zero.
55. The magnetic field at the centre of circular coil is
µ0i
B=
2r
l
where r = radius of circle = (Q l = 2πr )
2π
µ 0 i 2π
∴ B= ×
2 l
µ 0 iπ
= ................. (i)
l
When wire of length i bents into a circular loops of n turns, then
l = n × 2 π r'
l
⇒ r' =
n × 2π
Thus, new magnetic field
µ 0 ni µ 0 ni n × 2π
B' = = ×
2r ' 2 l
µ 0 iπ 2
= ×n
l
= n2B [ from eq (i)]
om
56. The magnetic field at a point on the axis of a circular loop at a distance x from the centre is
µ 0 iR 2
B= ............... (i)
2( R 2 + x 2 )3 / 2
c
g.
Given : B = 54 µ T, x = 4 cm, R = 3 cm
Putting the given values in eq (i), we get
ng
µ 0 i × (3) 2
∴ 54 =
2(32 + 4 2 ) 3 / 2
ye
9µ 0 i 9µ 0 i
54 = =
.m
⇒
2(25) 3/ 2
2 × (5)3
54 × 2 × 125
w
∴ µ0 i =
9
w
µ 0 i = 1500 ............... (ii)

w
Now, putting x = 0 in equation (i), magnetic field at the centre of loop is
µ 0 iR 2 µ 0 i
B= =
2R 3 2R
1500
= = 250 µT [from equation (ii)]
2×3
57. Force acting between two current carrying conductors
µ 0 I1 I 2
F= l ................. (i)
2π d
where d = distance between the conductors,
l = length of each conductor
µ 0 ( −2 I 1 ) ( I 2 )
Again F' = .l
2π (3d)
µ 0 2I1 I 2
=− .l ................. (ii)
2π 3d
Thus, from equations (i) and (ii)
F' 2
=−
F 3
2
⇒ F' = − F
3
58. The time period of oscillations of magnet
 I 
T = 2π   ................... (i)
 MH 
mL2
where I = moment of inertia of magnet = (m, being the mass of magnet)
12
M = pole strength × L
om
When the three equal parts of magnet are placed on one another with their like poles together, then
2
1 m L
I' =     × 3
12  3   3 
c
g.
1 mL2
=
ng
12 9
I
ye
=
9
.m
L
and M' = pole strength × × 3
3
w
=M
w
 I/9 
Hence, T' = 2 π  
 MH 
w
1
⇒ T' = × T
3
2
T' = sec
3
59. Electromagnets are made of soft iron. The soft iron has high retentivity and low coercivity.
60. In an LCR series a.c. circuit, the voltage across inductor L leads the V L
current by 900 and the voltage across capacitor C lags behind the 900
current by 900. i
900 V R
Hence, the voltage across LC combination will be zero.
V C
61. The rate of change of flux or emf induced in the coil is
dφ
e = −n
dt
∴ Induced current
e n dφ
i= =−
R' R' dt
Given : R' = R + 4R = 5R, dφ = W2 - W1, dt = t, (Here W1 and W2 are flux associated with one
turn).
Putting the given values in eq. (i), we get

n (W2 − W1 )
∴ i=−
5R t
62. The flux associated with coil of area A and magnetic induction B is
φ = BA cos θ
om
1  1 2
= Bπr 2 cos ωt Q A = 2 πr 
2  
c
dφ
g.
∴ e induced = −
et
ng
d 1 
=−  Bπr 2 cos ωt 
dt  2 
ye
1
= Bπr 2 ω sin ωt
.m
e 2induced
w
∴ Power P=
R
w
B2 π 2 r 4 ω2 sin 2 ωt
=
w
4R
Hence, Pmean = < P >
B2 π 2 r 4 ω2 1  1
= . Q< sin ωt >= 2 
4R 2  
( Bπr 2 ω)2
=
8R
63. In the condition of resonance
XL = XC
1
or ωL = .................. (i)
ωC
Since, resonant frequency remains unchanged,
so, LC = cons tan t
or LC = constant
∴ L1C1 = L2C2
⇒ L × C = L2 × 2C
L
⇒ L2 =
2
64. The emf induced between ends of conductor
1
e= BωL2
2
1
= × 0.2 × 10−4 × 5 × (1) 2
2
= 0.5 × 10 −4 V
= 5 × 10 −5 V = 50µV
65. Einstein's photoelectric equation is
K .E .
K.E.max = hv − φ
om
............... (i)
The equation of line is v
y = mx + c .............. (ii) c =φ
Comparing above two equations

c
g.
m = h, c = - φ
ng
Hence, slope of graph is equal to Planck's constant (non-variable) and does not depend on intensity
of radiation.
ye
hc
66. =φ
λ
.m
hc 6.6 × 10 −34 × 3 × 108

⇒ λ max = =
φ 4 × 1.6 × 10 −19
w
= 310 nm
w
F = qE
67. In steady state, electric force on drop = weight of drop
∴ qE = mg
w
mg
⇒ q=
E
9.9 × 10 −15 × 10 mg
= = 3.3 × 10 −18 C
3 × 10 4
68. Law of conservation of momentum gives
m1v1 = m2v2
m1 v 2
⇒ =
m 2 v1
4 3
But m= πr ρ
3
or m ∝ r3
m1 r13 v 2
∴ = =
m 2 r23 v1
1/ 3
r1  1 
⇒ = 
r2  2 
∴ r1 : r2 = 1 : 21/3
69. As given H2 + 1H2 
1
4
→ 2He + energy
The binding energy per nucleon of a deuteron (1H2)
= 1.1 MeV
∴ Total binding energy = 2 × 1.1 = 2.2 MeV
The binding energy per nucleon of helium (2He4) = 7 MeV
∴ Total binding energy = 4 × 7 = 28 MeV
Hence, energy released in the above process
= 28 - 2 × 2.2 = 28 - 4.4 = 23.6 MeV
70. According to law of conservation of energy, kinetic energy of α -particle = the potential energy of
om
α - particle at distance of closest approach.
1 2 1 q1q 2
mv =
i.e. 2 4πε 0 r
c
g.
9 × 10 9 × (2e) × (92e)  1 2 
Q mv = 5 MeV 
ng
∴ 5 MeV =
r  2 
ye
9 × 10 9 × 2 × 92 × (1.6 × 10 −19 ) 2
⇒ r=
5 × 10 6 × 1.6 × 10 −19
.m
∴ r = 5.3 × 10 −14 m = 10 −12 cm

71. When forward bias is applied on npn-transistor, then it works as an amplifier. In forward biased npn-
w
transistor, electrons move from emitter to base and holes move from base to emitter.
w
72. For a transistor amplifier in common emitter configuration, current again

w
h fe
Ai = −
1 + h oe R L
where h fe and h oe are hybrid parameters of a transistor.
50
∴ Ai = = −48.78
1 + 25 × 10 −6 × 1 × 103
73. We know that resistance of conductor is directly proportional to temperature (i.e. R ∝ ∆t ) , while
 1
resistance of semiconductor is inversely proportional to temperature  ie. R ∝ .
 ∆t 
Therefore, it is clear that resistance of conductor decreases with decrease in temperature or vice-
versa, while in case of semiconductor, resistance increases with decrease in temperature or vice-
versa.
Since, copper is pure conductor and germanium is a semiconductor hence, due to decrease in
temperature, resistance of conductor decreases while that of semiconductor increases.
74. According to Pauli's exclusion principle, the electronic configuration of number of subshells existing
in a shell and number of electrons entering each subshell is found. Hence, on the basis of Pauli's
exclusion principle, the manifestation of band structure in solids can be explained.
75. When p-end of p-n junction is connected to positive terminal of battery and n-end to negative
terminal of battery, then p-n junction is said to be forward bias. In forward bias, the more numbers
of electrons go from n-region to p-region and more numbers of holes go from p-region to n-region.
Therefore, major current due to both types of carriers takes place through the junction causing a
reduction in height of depletion region and barrier potential.
76. Any suborbit is represented as nl such that n is the principle quantum number (in the from of values)
and l is the azimuthal quantum number(its name)
Value of l < n, l 0 1 2 3 4
s p d f g
Value of m: -l, -l + 1 .... 0, .... + l
1 1
Value of s : + or -
2 2
Thus for 4f : n = 4, l = 3, m = any value between -3 to +3
om
77. E.C. of Cr (Z = 24) is
n l
2
1s 1 0
2s 2
2
c 0
g.
6
2p 2 1
ng
2
3s 3 0
6
3p 3 1
5
3d 3 2
ye
1
4s 4 0
Thus electrons with l = 1, = 12
.m
with l = 2, = 5
+ 3+
78. Li and B each has one orbit.
w
O2- and F- each has two orbits.

w
Thus ionic radius of O2-, F- > Li+, B3+

w
1
O2- and F- are isoelectronic and rn ∝
Z
Thus ionic radius of
O2- (Z = 8) > F- (Z = 9)
1 1 1
79. = vH = R H  2 − 2 
λ  n1 n 2 
1 1 
=1.097 × 107  − 2
1 ∞ 
2
1
∴λ= m = 9.11× 10 −8 m = 91.1 × 10 −9 m
1.097 × 10 7
= 91.1 nm (1nm = 10-9 m)
80. Species Structure Ip bp VSEPR Bond angle
S
H2S H H
2 2 Ip-Ip 900
Ip-bp
bp-bp
N
NH3 H H 1 3 Ip-bp 1070
H
bp-bp
F 0 3 b p - bp 120 0
BF3 F -B
F 0 4 b p - bp 109 0 8 0
H
Si H
H H
Thus bond angle H2S < NH3 < SiH4 < BF3
om
81. Species Z Electron gained or Electrons
lost in the formation
+
K 19 -1 18
Ca 2+
20 -2
c 18
g.
3+
Sc 21 -3 18
ng
-
Cl 17 +1 18
In this set all have 18 electrons, thus isoelectronic.
82. While moving along a group from top to bottom, acidic, nature of oxides decreases and along a
ye
period left to right, acidic nature increases.

Al Si P S
.m
Z 13 14 15 16
Al2O3 SiO2 P 2O 3 SO 2
w

 →
amphoteric acidic max.acidic
w
Thus, Al2O3 < SiO2 < P2O3 < SO2

w
83. Bond length is inversely proportional to bond-order. Bond-order in NO + = 3

NO = 2.5
+
Thus bond length in NO > NO
84. O- (g) + e- 
→ O2- (g),
∆H 0 = 844 kJ mol−1
This process is unfavourable in the gas phase because the resulting increase in electron-electron
repulsion overweighs the stability gained by achieving the noble gas configuration.
85. H3BO3 has structure
sp 3 sp 2
H -O -B -O -H
O -H
Boron has three bonds thus sp2 hybridised. Each oxygen has two bonds and two lone pair hence
sp3 hybridised.
86. Tetrahedral structure is associated with sp3 hybridised central atom without any lone pair.
F
d isto rted
X eF 4 Xe
o ctah ed ral
F F F
[N i (C N )4 ]2- squ are planar
d isto rted
SF4 F -S - F trigo n al
F F b ip yram id al
F-
↓
B F 4- B tetrahed ral
F F F
87. (n - 1 )d 8 n s2 ↑↓ ↑↓ ↑↓ ↑ ↑ ↑↓ 4 (as in N i)
om
(n - 1 )d 8 n s2
(n - 1 )d 5 n s1 ↑ ↑ ↑ ↑ ↑ ↑ 6 (as in C r)
(n - 1 )d 5 n s1
c
g.
ng
(n - 1 )d 3 n s2 ↑ ↑ ↑ ↑↓ 5 (as in V )
(n - 1 )d 3 n s2
ye
(n - 1 )d 5 n s2 ↑ ↑ ↑ ↑ ↑ ↑↓ 7 (as in M n )
.m
(n - 1 )d 5 n s2
3
88. Average K.E. = RT / N 0
w
2
w
(K.E.) ∝ T
∴ (K.E.) 313 (K.E.) 293 = 313 293
w
89. sp d has octahedral structure such that four hybrid orbitals are at 900 w.r.t. each
3 2
O
other and others two at 900 with first four.
90. Boiling point = T0(Solvent) + ∆Tb (Elevation in b.p.)
∆Tb = miK b
where, m is the molality ( ≈ Molarity M)
i, the van't Hoff factor = [1 + (y - 1)x]
Kb, molal elevation constant.
Thus ∆Tb ∝ i
Assume 100% ionisation
(a) mi (Na2SO4) = 0.01[1 + (y - 1)x] = 0.03
(b) mi (KNO3) = 0.01 × 2 = 0.02
(c) mi (urea) = 0.015
(d) mi (glucose) = 0.015
91. F2 has the most negative ∆G 0 value which is dependent on hydration enthalpy
92. Van der Waals equation for one mol of a gas is
 a 
P + V2  [V − b] = RT
 
where b is volume correction. It arises due to finite size of molecules.
93. H3PO4 is a tribasic acid, thus ionising in three steps:
I. H3PO4 H+ + H2PO-4
II. H2PO-4 H+ + HPO2-4
III. HPO2-4 H+ + PO3-4
Conjugate base is formed when an acid loses its proton. Thus HPO2-4 is the conjugate base of H2PO-4
(which is an acid in step II, but is the conjugate base of H3PO4 in step I).
94. Avogadro's number
NA = 6.02 × 1023 = 1 mol
∴ 6.02 × 10 molecules = 0.001 mol in 100 mL (0.1 L) solution
20
mol 0.001
∴ Molar concentration = = = 0.01M
om
volume in L 0.1
95. H3PO3 is a dibasic acid (containing two ionisable protons attached to O directly).
H3PO3 2H+ + HPO2-4
∴
c
0.1 M H3PO3 = 0.2 N H3PO3 and 0.1 M KOH = 0.1 N KOH
g.
N1V1 = N2V2
ng
(KOH (H3PO3)
0.1 V1 = 0.2 × 20
V1 = 40 mL
ye
96. In CH3CH2OH, there is intermolecular H-bonding while it is absent in isomeric ether CH 3OCH3
Larger heat is required to vapourise CH3CH2OH as compared to CH3OCH3, thus (a) is incorrect.
.m
CH3CH2OH is less volatile than CH3OCH3, thus vapour pressures are different, thus (b) is incorrect.
b.p. of CH3CH2OH > CH3OCH3, thus (c) is correct.
w
mass
Density = , due to ideal behaviour at a given temperature and pressure volume and molar
w
volume
w
mass are same. Hence, they have same vapour density. Thus (d) is correct.
97. Water and hydrochloric acid ; and water and nitric acid form miscible solutions, thus they form ideal
solutions. - no deviation.
In case of CH3COCH3 and CHCl3, there is interaction between them thus force of attraction between
CH3COCH3 ....... CHCl3 is larger than between CHCl3 ....... CHCl3 or CH3COCH3 ... CH3COCH3
and thus V.P. is less than expected. -a negative deviation.
In case of CH3OH, there is association by intermolecular H-bonding breaks and thus force of
attraction between CH3OH and benzene molecules is smaller than between CH3OH or benzene
molecules (in pure state). Vapour pressure of mixture is greater than expected -a positive deviation.
CH3 CH3 CH3

| δ+ | δ+ |
O - H ......... O - H ............ O - H .......
δ− δ− δ−δ+
98. (a) pA = XA p0A true

(b) π = i MRT = MRT true (if van't Hoff factor i = 1)
(c) i = [1 + (y - 1)x]
y = number of ions
x = degree of ionisation
i = 3 for BaCl2 x = 1 (strong electrolyte)
i = 2 for KCl x = 1(strong electrolyte)
i = (1 + x) for CH3COOH x << 1 (weak)
i = 1 for sucrose (non-electrolyte)
i (for BaCl2) > KCl > CH3COOH > sucrose
Thus (c) is also true.
(d) ∆Tf = K f m
Kf is dependent on solvent.
Thus freezing points [=T (solvent) - ∆Tf ) are different.
Thus (d) is false.
99. When equal number of cations and anions (such that charges are equal) are missing (1 Na +,
1 Cl-/l Fe2+, 2Cl-)
It is a case of Schottky defect.
om
100. Work done due to change in volume against constant pressure
W = - P(V2 - V1) = -1 × 105 Nm-2 (1 × 10-2 - 1 × 10-3)m3
= -900 Nm = -900 J
c
(1 Nm = 1 J)
101.
g.
Any cell (like fuel cell), works when potential difference is developed.
102. Order = 1
ng
Concentration changes from 0.8 M to 0.4 M in (50%) 15 minutes thus half-life is = 15 minutes
= T50
ye
A change from 0.1 M to 0.025 M is 75% and for first order reaction
T75 = 2 × T50 = 2 × 15 = 30 minutes (OR)
.m
T50 = 15 minutes
2.303log 2 2.303 log 2
k= =
w
T50 15
w
a = 0.1 M
(a - x) = 0.025 M
w
2.303  a 
For first order: k= log  
t a−x
2.303 log 2 2.303 0.1 2.303

= log = log 4
15 t 0.025 t
2.303 log 2 2 × 2.303 log 2

∴ =
15 t
∴ t = 30 minutes
103. In the expression for equilibrium constant (Kp or Kc) species in solid state are not written (i.e. their
molar concentrations are taken as 1)
P4(s) + 5O2(g) P4O10(s)
1
Thus, Kc =
[O2 ]5
104. K p = K c (RT) ∆n
∆n = Sum of coefficients of gaseous products - that of gaseous reactants.
CO(g) + Cl2(g) → COCl2 (g)
∴ ∆n = 1 - 2 = -1
∴ Kp = Kc (RT)-1
Kp 1
∴ = ( RT) −1 =
Kc ( RT)
105. N2(g) + O2(g) 2NO(g)
[NO]2
Kc = = 4 × 10 − 4
[N 2 ][O 2 ]
1 1
NO N 2 (g) + O2 (g)
2 2
[N 2 ]1 / 2 [O2 ]1/ 2
K 'c =
om
[NO]
1 1
= = 50
Kc 4 × 10 − 4
c
g.
106. 2A + B → C
ng
Rate = k[A][B]
It represents second-order reaction.
ye
Thus unit of k is M-1 s-1

∴ (a) is false
T50 is dependent of concentration but not constant
.m
∴ (b) is false
w
1 d[A] d[C]
− = , thus (c) is also false
2 dt dt
w
107. Sn(s) + 2Fe3+ (aq) → 2Fe2+ (aq) + Sn2+ (aq)

w
E 0cell = E OX
0
+ E 0red
= ESn
0
/ Sn2+
+ E 0Fe3+ / Fe2+
Given 0
E Sn 2+
/ Sn
= −0.14 V
∴
0
E Sn / Sn2+
= +0.14 V
E 0Fe3+ / Fe2+ = 0.77 V
∴ E 0cell = 0.14 + 0.77 = 0.91 V

108. For the solute Ax By xA + yB
Ksp = xxyy (s)x + y
MX4 M4+ + 4X-
x = 1, y = 4
∴ Ksp = (4)4 (1)1 (s)5 = 256 s5
1/ 5
 K sp 
∴ s =  

 256 
109. Relation between Keq and Ecell is
2.303 RT
E 0cell = log K eq
nF
0.0591
E 0cell = log K eq (at 298 K)
n
0.0591
0.591 = log K eq
1
∴ log Keq = 10
∴ Keq = 1 × 1010
110. I : C(s) + O2(g) → CO2(g) ∆H = −393.5 kJ
1
II : CO(g) + O (g) → CO2(g), ∆H = -283.0 kJ
om
2 2
I - II gives
c
1
III : C(s) + O (g) → CO(g), ∆H = -110.5 kJ
2 2
g.
This equation III also represents formation of one mol of CO and thus enthalpy change is the heat
ng
of formation of CO (g).
111. By Kohlarusch's law
ye
^0NaBr = ^0NaCl + ^0KBr - ^0KCl

= 126 + 152 - 150
.m
= 128 S cm2 mol-1

112. Zn(s) + 2H+ → Zn2+ (aq) + H2(g)
w
[Zn 2+ ]
Reaction quotient Q =
[H + ]2
w
Corresponding cell is
w
Zn | Zn2+ (C1) || H+ (aq) | Pt (H2)

- +
anode cathode
0.0591
and E 0cell = E 0cell − log K
2
0.0591 [Zn 2 + ]
= E cell −
0
log + 2
2 [H ]
0.0591 [H + ]2
= E cell +
0
log
2 [Zn 2+ ]
If H2SO4 is added to cathodic compartment, (towards reactant side), then Q decreases (due to
increase in H+). Hence equilibrium is displaced towards right and Ecell increases.
113. Helium is not used to produce and sustain powerful superconducting magnets. All others are the uses
of helium.
114. Normal optimum temperature of enzymes is between 250C to 400C hence (a) is false. Similarly (b)
and (c) are also false. Enzymes have well defined active sites and their actions are specific in nature.
115. Mg3N2(s) + 6H2O (l) → 3Mg(OH)2 + 2NH3 (g)
1mol 2mol
116. Froth-floatation is used to concentrate sulphide ores [Galena (PbS)]
117. Be (Z = 4) has maximum covalency of 4 while Al (Z = 13) has maximum covalency of 6.
118. AlCl3 is covalent but in water, it become ionic due to large hydration energy of Al3+
AlCl3 + 6H2O [Al (H2O)6]3+ + 3Cl-
119. Atmospheric N2 has no reaction with tin thus (a) is not true.
As temperature decreases, white tin ( β -form) changes to grey tin( α -form).
1 3 .2 0 C
α − Sn β − Sn
α − Sn has a much lower density.

120. E0Cr3+/Cr2+ = -0.41 V
om
E0Mn3+/Mn2+ = +1.57 V
E0Fe3+/Fe2+ = +0.77 V
E0Co3+/Co2+ = +1.97 V
c
More negative value of E0red indicates better reducing agent thus easily oxidised. Thus oxidation of
g.
Cr2+ to Cr3+ is the easiest.
ng
121. CuSO4 + 2KI → CuI2 + K2SO4
unstable
2CuI2 → Cu2I2 + I2
ye
Thus CuI2 is not formed.

.m
122. CN- is a better complexing agent (C) as well as a reducing agent (A)
Thus properties (A) and (C) are shown.
Property (C) : Ni2+ + 4CN- → [Ni(CN)4]2-
w
w
II I 1
Property (A): CuCl2 + 5KCN → K3[Cu(CN)4] + (CN)2 + 2KCl
w
2
- 2+ +
(CN reduces Cu to Cu )
123. Co-ordination number is the maximum covalency shown by a metal or metal ion. It is the maximum
number of ligands attached to metal by sigma bonds or coordinate bonds.
124. (a) Fe2+ [A r] ↑↓ ↑ ↑ ↑ ↑

3d6 4s 4p
Fe2+ in strong ligand CN- [A r] ↑↓ ↑↓ ↑↓

3d6 4s 4p
[Fe(CN)6]4- [A r] ↑↓ ↑↓ ↑↓ ×× × ×××
d 2 sp 3 in n er
d -orb ital co m plex
(b) Mn2+ [A r] ↑ ↑ ↑ ↑ ↑
3d5 4s 4p
Mn(CN)4-6 [A r] ↑↓ ↑↓ ↑ ×× × ×××
d 2 sp 3
in n er d-o rb ital co m plex
(c) Co3+ [A r] ↑↓ ↑ ↑ ↑ ↑
3d6 4s 4p
[Co(NH3)6]3+ [Ar] NH3 is a strong ligand [A r] ↑↓ ↑↓ ↑↓ ×× × × ××

d 2 sp 3
in n er d-o rbital com plex
om
(d) Ni2+ [A r] ↑↓ ↑↓ ↑↓ ↑ ↑
4p
c
g. 3d8 4s
In this case also NH3 is a strong ligand but electrons remain unpaired since only one orbital is left
vacant in 3d. Thus
ng
× ××× ××
ye
[Ni(NH3)6]2+ [A r] ↑↓ ↑↓ ↑↓ ↑ ↑
3d8 4s 4p 4d
.m
sp 3 d 2
o uter d-o rbital com plex
w
125. Chlorophyll contains Mg, hence (a) is incorrect statement.

w
126. +3 and +4 states are shown by Ce in aqueous solution. Thus statement (c) is incorrect.
127. [Co(en)2Cl2] forms optical and geometrical isomers.
w
128. Number of unpaired electrons in [Fe(CN)6]4- is zero.

Thus magnetic moment = N(N + 2) = 0 B.M. (N = unpaired electrons)
N in [MnCl4]2- = 5, 35 B.M.
N in [CoCl4]2- = 3, 15 B.M.
Thus (a) is the only correct alternate
92 M → Y N +
238 X
129. 2 24 He
X = 230
Y = 88
230
88 N → AB L + 2 0
1 e (β + )
∴ A = 230 =n+p
∴ B = 86 = p ∴ n = 144
130. If y = number of half-lives,
total time
∴ y=
half − time
24
=
6
=4
C = amount left after y half-life
C0 = initial amount
y
1
∴ C = C0  
2
6
1
= 200  
2
= 3.125 g
131. If nitrogen is present in organic compound then sodium extract contains Na4[Fe(CN)6].
om
Na + C + N fuse
→
 NaCN
FeSO4 + 6NaCN 
→ Na 4 [ Fe (CN)6 + Na 2SO4
c
( A)
g.
A changes to Prussian blue Fe4[Fe(CN)6]3 on reaction with FeCl3.
ng
4FeCl3 + 3Na4[Fe(CN)6] 
→ Fe4[Fe(CN)6]3 + 12NaCl
132. Let unreacted 0.1 M (= 0.2 N) H2SO4 = V' mL
∴ 20 mL of 0.5 M NaOH = V' mL of 0.2 N H2SO4
ye
∴ 20 × 0.5 = V' × 0.2

∴ V' = 50 mL
.m
Used H2SO4 = 100 - 50 = 50 mL

w
1.4 NV
% Nitrogen =
w
w
where N = normality of H2SO4

w
V = volume of H2SO4 used

1.4 × 0.2 × 50
∴ % Nitrogen = = 46.67%
0.30
% of nitrogen in
14 × 100
(a) CH3CONH2 = = 23.73%
59
14 × 100
(b) C6 H5CONH2 = = 11.48%
122
28 × 100
(c) NH2 CONH2 = = 46.67%
60
28 × 100
(d) NH2 CSNH2 = = 36.84%
76
CH 3
133. Isobutene C = CH 2 has minimum force of attraction (due to steric hindrance).
CH 3
Thus minimum boiling point.
6 4
134. Carbon with -OH group is given C1 thus it is 3, 3-dimethyl-1-cyclohexanol. 1 3
HO
O O
135. (a) C H 3 - C - O - C H 3 (b) C H 3 - C - H
sp 3 sp 2 sp 3 sp 3 sp
O
(c) CH 3 − C ≡ N (d) CH 3 − C _ N
sp 3 sp sp 3 sp 2
om
Acetonitrile does not contain sp2 hybridised carbon hence (c).
*
136. (a) C H 3 - C H - C H 2 C H 3
c
g.
Cl
ng
One chiral carbon atom, forms d-and l-optical isomers.
(b) Two chiral carbon atoms, forms, d-, l- and meso forms.
ye
CH 3
H - *C -C l
.m
p lan e o f
sym m etry H - *C - C l
CH
w
3
w
(c) C H 3 - * C H - * C H - C H 2 C H 3
w
Cl Cl
Two chiral carbon atom but does not have symmetry. Hence meso form is not formed.
(d) C H 3 - * C H - C O O H
OH
One chiral carbon atom, meso form is not formed.

137. Cl- is the best leaving group being the weakest nucleophile out of NH-2, Cl-,
O
−
O − C2 H5 and O − C − CH3
Note: If acid HX is weak, its conjugate base X- is strong and vice-versa.

NH < C H OH < CH COOH< HCl
3−  − 3  
2 5
−

−
→
NH2 > C2H5O > CH3COO > Cl
←    

conjugate base
138. C H 3 - * C H contains chiral carbon thus optically active.
C H 2C H 3
COOH COOH COOH COOH

NO 2
139. (a) (b) (c) (d)
NO 2
NO 2
-NO2 group at any position shows electron withdrawing effect thus acid strength is increased. But
o-nitro benzoate ion is stabilised by intramolecular H-bonding hence its acid strength is maximum,
Thus acid strength (II) > (III) > (IV) > (I)
140. CH3 - (an electron releasing (+I) group) increases electron density at N-atom hence basic nature is
increased.
om
I-
(a) NH 2 (b) NH CH 3
I+
I-
c
g.
I-
(c) NH 2 (d) CH 2 NH 2
ng
I+
CH 3
ye
C6H5 (an electron withdrawing group (-1) group) decreases electron density at N-atom thus basic
nature is decreased (Lone-pair on N in aniline compounds is used in delocalisation of π - electrons
.m
in benzene).
Thus (d) is the strongest base.
w
141. Uracil is present in RNA but not in DNA.

w
142. CCl3CHO + 2 Cl
w
Chloral Chlorobenzene
conc
 → DDT
. H 2SO4
143. Aqueous NaCl is neutral hence there is no reaction between ethyl acetate and aqueous NaCl.
O O O CH3
144. C H 3 - C - B r + C H 3 M g I 
 → CH 3 − C − CH 3 
 → C H 3 - C - C H 3 + C H 3 M g I 
 →C H 3 - C - O M gI
CH3
a q .N H 4 C l
CH3
C H 3 -C -O H
CH 3
2-m eth yl-2-p ro pano l
145. Carbonyl compounds are reduced to corresponding alkanes with (Zn + conc HCl). It is called
Clemmensen reduction.
O
CH3CH2 . C − CH3 Zn )+
( Hg →CH3CH2 CH2CH3
HCl
146. A + NaOH → alcohol + acid

Thus it is Cannizzaro reaction. A is thus aldehyde without H at α - carbon. (as C6H5CHO, HCHO)
2C6H5CHO + NaOH → C6H5CH2OH + C6H5COONa
147. Dehydration of alcohol is in order
1 0 < 20 < 30
Thus (c), a 30 alcohol is dehydrated very easily.
148. Chiral carbon has all the four different groups attached to it.
(a) CH3CH2CH2CH2Cl no chiral carbon atom
*
(b) CH3 C HCH2 CH2 CH3
Cl
om
one chiral carbon atom
*
(c) CH 3CH 2CH 2 C HCH 2 Cl
CH
c
3
g.
o ne ch iral carbo n ato m
ng
* *
(d) CH3 C H − C HCH2 CH3
ye
CH 3 Cl
tw o chiral carbon atom
.m
149. Insulin is a hormone built up of two polypeptide chains.

150. NO, NO2, SO2 and SO3 are responsible for smoke (environmental pollution).
w
w
w
Today’s Mathiitians..... Tomorrow’s IITians.
Solutions of AIEEE 2004 Solved Paper
MATHEMATICS SOLUTIONS
1. Let R = {(1, 3), (4, 2), (2, 4), (2, 3), (3, 1)} is a relation on the set A = {1, 2, 3, 4}, then
(a) Since ∈ R and (2,3) ∈ R, so R is not a function.
(b) Since (1, 3) ∈ R and (3, 1) ∈ R but (1, 1) ∉ R. So R is not transitive.
(c) Since (2, 3) ∈ R but (3, 2) ∉ R, so R is not symmetric.
(d) Since (4, 4) ∉ R so R is not reflexive, Hence the option (c) is correct.
2. The given function f(x) = 7-x Px-3 would be defined if
(i) 7 - x > 0 ⇒ x < 7
(ii) x - 3 > 0 ⇒ x > 3
(iii) (x - 3) < (7 - x)
⇒ 2x < 10 ⇒ x < 5
⇒ x = 3, 4, 5
om
Hence Range of f(x) = {4P0, 3P1, 2P2}
Range of f(x) = {1, 3, 2}
3. Since z + iw = 0 ⇒ z = − iw
c
g.
⇒ z = iw
⇒ w = -iz
ng
Also arg(zw) = π
⇒ arg (-iz2) = π
ye
⇒ arg (-i) + 2 arg(z) = π

π
(Q arg(−i) = −π / 2 )
.m
⇒ − + 2 arg(z) = π
2
3π
w
⇒ 2 arg(z) =
2
w
3π
⇒ arg(z) =
w
4
4. z1/3 = p + iq
(x - iy)1/3 = (p + iq) (Q z = x − iy)
⇒ (x - iy) = (p + iq) 3
⇒ (x - iy) = p3 +(iq)3 + 3p2qi + 3pq2i2

⇒ (x - iy) = p3 - iq3 + 3p2qi - 3pq2
⇒ (x - iy) = (p3 - 3pq2) + i (3p2q - q3)
On comparing both sides, we get
⇒ x = (p3 - 3pq2) and - y = 3p2q - q3
⇒ x = p(p2 - 3q2) and y = q(q2 - 3p2)
x y
⇒ = (p 2 − 3q 2 ) and = (q 2 − 3p 2 )
p q
x y
Now, + = p − 3q 2 + q 2 − 3p 2
p q
x y
⇒ + = −2p 2 − 2q 2
p q
x y
⇒ + = −2(p 2 + q 2 )
p q
x/p + y/q
⇒ = −2
(p2 + q 2 )
5. Given that
|z2 - 1| = |z|2 + 2
|z2 + (-1)| = |z2| + |-1|
It shows that the origin, -1 and z2 lies on a line and z2 and -1 lies on one side of the origin, therefore
z2 is a negative number. Hence z will be purely imaginary. So we can say that z lies on y-axis.
om
0 0 − 1
6. The given matrix A =  0 − 1 0 

− 1 0 0 
c
g.
(a) It is clear that A is not a zero matrix.
ng
1 0 0 − 1 0 0
(b) (−1) l = −1 0 1 0  =  0 − 1 0  ≠ A
  
ye
0 0 1  0 0 − 1
i.e., (-1)l ≠ A
.m
−1 0 0 0 0 −1
(c) | A | = 0 −0 −1
−1 0 −1 0
w
0 0
= 0 - 0 - 1 (-1) = 1
w
Since |A| ≠ 0 . So A-1 exists.

w
0 0 − 1  0 0 − 1
(d) A = A.A =  0 − 1 0   0 − 1 0 
2   
 − 1 0 0  − 1 0 0 
1 0 0
⇒ A = 0 1 0 
2
0 0 1
⇒ A2 = I
7. Since B is inverse of A, i.e. B = A-1
4 2 2
So, 10A −1
= − 5 0 α 

 1 − 2 3 
4 2 2
−1 
10A A =  − 5 0 α  A
 1 − 2 3 
4 2 2  1 − 1 1 
10 I =  − 5 0 α  2 1 − 3

(Q A −1
A=I )
 1 − 2 3  1 1 1 
10 0 0   10 0 0 
   
⇒  0 10 0  = − 5 + α 5 + α − 5 + α 
 0 0 10  0 0 10 
⇒ −5+α = 0
⇒ α=5
8. Since a1, a2, .......... an are in G.P.
om
Then, an = a1rr-1
⇒ log an = log a1 + (n - 1) log r
an + 1 = a1rn
⇒ log an + 1 = log a1 + n log r
c
g.
an + 2 = a1rn + 1
⇒ log an + 2 = log a1 + (n + 1) log r
ng
............. an + 8 = a1rn + 7
⇒ log an + 8 = log a1 + (n + 7) log r
ye
log a n log a n +1 log a n + 2 log a 1 + ( n − 1) log r log a 1 + n log r log a 1 + ( n + 1) log r

.m
Now, log a n + 3 log a n + 4 log a n + 5 = log a 1 + ( n + 2) log r log a 1 + ( n + 3) log r log a 1 + ( n + 4) log r
log a n + 6 log a n + 7 log a n +8 log a 1 + ( n + 5) log r log a 1 + ( n + 6) log r log a 1 + ( n + 7) log r
w
Now R 2 → R 2 − R1 and R 3 → R 3 − R1
w
log a 1 + (n − 1) log r log a 1 + n log r log a 1 + ( n + 1) log r 

w
  = 0 (Since two rows are identical)

⇒  3 log r 3 log r 3 log r 
 3 log r 3 log r 3 log r 
9. Let α and β be two numbers whose arithmetic mean is 9 and geometric mean is 4.
∴ α + β = 18 ........... (i)
and αβ = 16 ........... (ii)
∴ Required equation is
x2 - (α + β)x + (αβ) = 0
⇒ x2 - 18x + 16 = 0 [using equation (i) and equation (ii)]
10. Since (1 - p) is the root of quadratic equation
x2 + px + (1 - p) = 0 ........ (i)
So, (1 - p) satisfied the above equation
∴ (1 - p)2 + p(1 - p) + (1 - p) = 0
(1 - p)[1 - p + p + 1] = 0
(1 - p)(2) = 0
⇒ p=1
On putting this value of p in equation (i)
x2 + x = 0
⇒ x(x + 1) = 0
⇒ x = 0, -1
11. S(K) = 1 + 3 + 5 + ...... + (2K - 1) = 3 + K2
Put K = 1 in both sides
∴ L.H.S = 1 and R.H.S. = 3 + 1 = 4
⇒ L.H.S. ≠ R.H.S.
Put (K + 1) on both sides in the place of K L.H.S. = 1 + 3 + 5 + .... + (2K - 1) + (2K + 1)
R.H.S. = 3 + (K + 1)2 = 3 + K2 + 2K + 1
Let L.H.S. = R.H.S.
1 + 3 + 5 + ....... + (2K - 1) + (2K + 1) = 3 + K2 + 2K + 1
⇒ 1 + 3 + 5 + ........ + (2K - 1) = 3 + K2
om
If S(K) is true, then S(K + 1) is also true.
Hence, S(K) ⇒ S(K + 1)
12. Total number of ways in which all letters can be arranged in alphabetical order = 6!
c
There are two vowels in the word GARDEN. Total number of ways in which these two vowels
g.
can be arranged = 2!
ng
6!
∴ Total number of required ways = = 360
2!
ye
8-1
13. The required number of ways = C3-1
7!
= 7 C2 =
.m
2! 5!
w
7.6
= = 21
2.1
w
14. Since 4 is one of the roots of equation x2 + px + 12 = 0. So it must satisfied the equation.
w
∴ 16 + 4p + 12 = 0
⇒ 4p = -28
⇒ p = -7
The other equation is x2 - 7x + q = 0 whose roots are equal. Let roots are α and α of above
equation.
7
∴ Sum of roots = α + α =
1
⇒ 2α = 7 ⇒ α = 7 / 2 and product of roots α . α = q
⇒ α2 = q
2
 7
⇒   =q
2
49
⇒ q=
4
15. The coefficient of x in the middle term of expansion of (1 + αx) 4 = 4C2 . α 2
The coefficient of x in middle term of the expansion of (1 − αx)6 = 6 C3 (−α) 3

According to question
4
C 2 α 2 = 6 C 3 ( −α ) 3
4! 2 6! 3
α =− α
2! 2! 3! 3!
⇒ 6α 2 = −20 α 3
6
⇒ α=−
20
3
⇒ α=−
10
16. The coefficient of xn in the expansion of (1 + x)(1 - x)n
om
= coefficient of xn + coefficient of xn-1
n! n!
= (−1) n −
n! 0! 1!(n − 1)!
c
g.
 n! n! 
= ( −1) n  − 
 n!. 0! 1!(n − 1)! 
ng
= (-1)n [1 - n]
ye
∑
1
17. Given that, sn = n
r=0 Cr
.m
∑
1
sn = (Q n Cr = n Cn − r )
w
n
r=0 Cn−r
w
∑
n
n sn =
w
n
r =0 Cn−r
n
 n−r r 
n sn = ∑ n
+n 
r =0  Cn − r Cn −r 
n
n−r n
∑ ∑
r
n sn = n
+ n
r =0 Cn−r r =0 Cr
 n n −1 1  n
∑
r
n sn =  n + n + ........... + n  + n
 Cn C n −1 Cn  r =0 Cr
nsn = tn + tn
nsn = 2tn
tn n
=
sn 2
1
18. Given that, Tm =
n
1
⇒ a + (m − 1) . d = ....... (i)
n
1
and Tn =
m
1
⇒ a + (n − 1)d = ...... (ii)
m
On solving equation (i) and (ii), we get
1 1
a= and d =
mn mn
1 1
So, a −d= − =0
mn mn
om
n( n + 1)2
19. The sum of n terms of given series = if n is even.
2
Let n is odd i.e. n = 2m + 1
Then, S2m+1 = S2m + (2m + 1)th term
c
g.
(n − 1)n 2
= + n th term
ng
2
(n − 1)n 2
ye
= + n2 (Q n is odd = 2m + 1)
2
.m
 n − 1 + 2  ( n + 1) n 2
= n2  =
 2  2
w
20. We know that

w
1 1 1 1
e = 1+ + + + + ........... ∞ ........ (i)
1! 2! 3! 4!
w
1 1 1 1
e −1 = 1 − + − + − ......... ∞ .......... (ii)
1! 2! 3! 4!
On adding equation (i) and (ii)
2 2
e + e −1 = 2 + + + ..........∞
2! 4!
e2 + 1 2 2
− 2 = + + ...........∞
e 2! 4!
e 2 + 1 − 2e 1 1 
= 2  + + ........∞ 
e  2! 4! 
(e − 1) 2 1 1
= + + ........∞
2e 2! 4!
21
21. Given that, sin α + sinβ = − .......... (i)
65
27
and cos α + cosβ = − ........... (ii)
65
Squaring equation (i) and (ii) then adding, we get
2 2
 21   27 
(sin α + sin β) 2 + (cos α + cosβ) 2 =  −  +  − 
 65   65 
1170
sin2 α + sin2 β + 2 sin α sinβ + cos2 α + cos2 β + 2 cos α cosβ =
4225
1170
⇒ 2 + 2(cosα cosβ + sin α sin β) =
4225
1170
⇒ 2 + 2 cos(α − β) =
4225
om
1170
⇒ 2(1 + cos(α − β)) =
4225
⇒
  α − β  1170
2 2 cos2   =
c
g.
  2  4225
ng
 α − β  1170
⇒ cos2  =
 2  4 × 4225
ye
 α −β 9
⇒ cos2  =
.m
 2  130
 α −β 3
cos  =−
w
⇒ (Q π < α − β < 3π)

 2  130
w
22. u = a 2 cos2 θ + b 2 sin2 θ + a 2 + sin2 θ + b 2 cos2 θ

w
u 2 = a 2 cos2 θ + b2 sin2 θ + a 2 sin2 θ + b 2 cos2 θ + 2 (a 2 cos2 θ + b 2 sin2 θ) . (a 2 sin2 θ + b 2 cos2 θ)
u 2 = a 2 + b 2 + 2 x(a 2 + b2 − x) [where x = a 2 cos2 θ + b2 sin2 θ ]
u 2 = (a 2 + b 2 ) + 2 (a 2 + b 2 )x − x 2
du 2 1 dx
= (a 2 + b 2 − 2 x ) = ( b 2 − a 2 ) sin 2θ
dx (a + b ) x − x
2 2 2 dθ
du 2 (a 2 + b2 − 2x)
= × ( b2 − a 2 ) sin2 θ
dθ (a + b ) x − x
2 2 2
du 2
Put = 0 for maxima and minima and a 2 + b 2 = 2 [a 2 cos2 θ + b 2 sin2 θ]
dθ
sin 2θ = 0, cos 2θ ( b 2 − a 2 ) = 0
⇒ θ = 0, cos 2θ = 0
2θ = π / 2
θ = π/4
u2 will be minimum at θ = 0 and will be maximum at θ = π / 4
∴ u 2min = (a + b)2 and u 2max = 2(a 2 + b 2 )
Hence, u 2max − u 2min = 2(a 2 + b2 ) − (a + b) 2 = (a − b)2
23. Let a = sin α, b = cos α, c = 1 + sin α cos α then
a 2 + b2 − c2
cos C =
2ab
sin 2 α + cos2 α − 1 − sin α cos α

⇒ cos C =
2 sin α cos α
om
sin α cos α
⇒ cos C = −
2 sin α cos α
⇒
1
cos C = − = cos1200
c
g.
2
⇒ ∠C = 1200
ng
24. Let CD (= h) be the height of the tree and BC (= x) be the width of river. D
Now in ∆BCD
ye
CD
tan 600 = h
.m
BC
h
⇒ 3= ⇒ h = x 3 .............(i)
w
300 600
x A C
B
40 x
w
Now in ∆ACD
w
CD
tan 300 =
AC
1 h
= ⇒ h 3 = 40 + x
3 40 + x
⇒ 3x = 40 + x [using equation (i)]
⇒ 2x = 40
⇒ x = 20 m
25. Since − 2 ≤ sin x − 3 cos x ≤ 2
− 1 ≤ sin x − 3 cos x + 1 ≤ 3
∴ Range of f(x) = [-1, 3]
26. Since graph is symmetrical about the line x = 2.
⇒ f(2 + x) = f(2 - x)
(x − 3)
27. The function f (x) = sin−1 will be defined if
9 − x2
(I) − 1 ≤ (x − 3) ≤ 1 ⇒ 2 ≤ x ≤ 4 ....... (i)
(II) 9 − x 2 ≥ 0 ⇒ −3 < x < 4 ....... (ii)
From relation (i) and (ii), we get
2<x<3
∴ Domain of the given function = [2, 3)
2x
 a b 
28. lim
x →∞ 1 + + 2 
 x x 
 a / x + b / x2 
2 x  
 a b   a / x + b / x2 

= lim
x →∞ 1 + + 2 
 x x 
= lim
x →∞ e
2 x (a / x + b / x 2 )
(Q lim
x →∞ (1 + x)1 / x = e )
om
= lim
x →∞ (e ) 2 ( a + b / x ) = e 2 a
2x
 a b 
1 + + 2  = e2
c
lim
But x →∞
 x x 
g.
⇒ e2a = e2
ng
⇒ a = 1, and b ∈ R
1 − tan x
ye
29. f ( x) =
4x − π
.m
 1 − tan x 
lim
x → π / 4 f (x) = lim
x→π / 4  
 4x − π 
w
By L'Hospital's rule
w
 − sec2 x  − sec2 π / 4 2
 
 4 = =−
lim
x→π / 4
w
  4 4
⇒ lim
x → π / 4 f ( x) = −1 / 2
Also f(x) is continuous in [0, π / 2] , so f(x) will be continuous at π / 4 .
∴ Value of function = Value of limit
⇒ f (π / 4) = −1 / 2
y+.......∞
30. x = e y +e
x = ey+x
Taking log on both sides log x = (y + x)
1 dy dy 1 − x
Differentiate w.r. to x = +1⇒ =
x dx dx x
31. Equation of parabola is y2 = 18x
Differentiate w.r.t t
dy dx
2y = 18
dt dt
 dy dx 
2.2y = 18 Q =2 
 dt dt 
9
y=
2
∴ From equation of parabola
2
9
  = 18x
2
81 81
= 18x ⇒x=
4 4 × 18
9
⇒ x=
om
8
∴ Point is (9/8, 9/2)
32. f''(x) = 6(x - 1)
f'(x) = 3(x - 1)2 + c
c ........ (i)
g.
At the point (2, 1) the tangent to graph is
y = 3x - 5
ng
Slope of tangent = 3
∴ f'(2) = 3(2 - 1)2 + c = 3
ye
3+c=3 ⇒ c=0
∴ From equation (i)
.m
f'(x) = 3(x - 1)2

f'(x) = 3(x - 1)2
w
f(x) = (x - 1)3 + k ...... (ii)

Since graph passes through (2, 1)
w
∴ 1 = (2 - 1)2 + k
w
k=0
∴ Equation of function is
f(x) = (x - 1)3
33. x = a(1 + cos θ), y = a sin θ
dx dy
= a(− sin θ), = a cos θ
dθ dθ
dy dy / dθ cos θ
= =−
dx dx / dθ sin θ
∴ Equation of normal at [a (1 + cos θ), a sin θ]
sin θ
(y − a sin θ) = [x − a(1 + cos θ)]
cos θ
It is clear that in the given options normal passes through the point (a, 0).
34. Let f'(x) = ax2 + bx + c
ax 3 bx 2
⇒ f (x) = + + cx + d
3 2
2ax 3 + 3bx2 + 6cx + 6d

f (x) =
6
2a + 3b + 6c + 6d 6d
f (l) = = =d (Q 2a + 3b + 6c = 0)
6 6
6d
f (1) = =d
6
Q f(0) = f(1)
⇒ f'(x) = 0
∴ One of the roots of ax2 + bx + c = 0 lies between 0 and 1.
[ ]
n
∑
1 r/n 1
∫
1
35. lim
x →∞ e = e x dx = e x 0
n 0
om
r =1
=e-1
sin x
∫ sin(x − α) dx
36. I=
c
g.
Let x − α = t ⇒ dx = dt
ng
x = (t + α )
sin(t + α)
I= ∫
ye
dt
sin t
.m
sin t cos α + cos t sin α

I= ∫ sin t
dt
w
cos t
∫
I = cos αdt + sin α ∫ dt
w
sin t
w
cos t
∫
I = cos α 1.dt + sin α. ∫ sin t dt
I = cos α( t ) + sin α log sin t + c1
I = cos α(x − α) + sin α log sin t + c1
I = x cos α + sin α log sin t − α cos α + c1
I = x cos α + sin α. log sin(x − α) + c
sin x
But ∫ sin(x − α)dx = Ax + B logsin(x − α) + c
∴ x cos α + sin α log sin(x − α) + c = Ax + B log sin(x − α) + c
On comparing, we get
A = cos α
B = sin α
dx
37. t= ∫ cos x − sin x
1 dx
2 ∫
=
1 1 
 cos x − sin x 
 2 2 
1 dx 1  π
2 ∫ 2∫ 
= = sec x +  dx
 π 4
cos x + 
 4
1
= log| tan(π / 4 + x / 2 + π / 8) | + c
2
1  x 3π 
= log tan  +  + c
2 2 8 
om
3 −1 1 3
∫ | 1 − x 2 | dx = ∫ (x 2 − 1) dx + ∫ (x 2 − 1)dx + ∫ (x − 1)dx
2
38.
−2 −2 −1 1
c
−1 1 3
 x3   x3   x3 
=  − x  + x −  +  − x 
g.
3  −2  3  −1  3 1
ng
2 2 1 1  1
= + + 1 − + 1 − + (9 − 3) +  1 − 
3 3 3 3  3
ye
10 28
= +6=
.m
3 3
π/2 (sin x + cos x)2

t= ∫
w
39. dx
0
sin2 x + cos2 x + 2 sin x cos x
w
π/2 (sin x + cos x)2

t= ∫
w
dx
0
(sin x + cos x)2
π/2
t= ∫
0
(sin x + cos x)dx
I = [− cos x + sin x ]0
π/2
I = − cos π / 2 + sin π / 2 + cos 0 − sin 0

I=-0+1+1-0=2
π
40. I= ∫
0
xf(sin x)dx ....... (i)
π
I= ∫
0
(π − x) f[sin(π − x)]dx
π
I= ∫
0
(π − x) f (sin x) dx ...... (ii)
On adding equation (i) and equation (ii)
π
2I = ∫
0
(x + π − x) f (sin x)dx
π
2I = π ∫ 0
f (sin x)dx
π/ 2
2I = 2π ∫ 0
f (sin x)dx
π/2
I=π ∫
0
f (sin x)dx
π/ 2 π/2
⇒A ∫ 0
f (sin x)dx = π ∫ 0
f (sin x)dx ⇒ A=π
ex
41. Given that f (x) =
1 + ex
ea 1
∴ f (a ) = and f (−a ) =
om
1+ e a
1 + ea
⇒ f(a) + f(-a) = 1
⇒
c
f(a) = 1 - f(-a) g.
Let f(-a) = t
⇒ f(a) = 1 - t
ng
1− t
Now, I1 = ∫
t
xg[x(1 − x)]dx ...... (i)
ye
1− t
I1 = ∫
t
(1 − x) g ([x(1 − x)]) dx ...... (ii)
.m
Adding equation (i) and equation (ii)

1− t
2 I1 = ∫ g [x(1 − x)] (1 − x + x) dx
w
t
w
1− t
2I1 = ∫
t
g [x(1 − x)]dx = I 2
w
I2 2
⇒ = =2
I1 1
3
42. Required Area = ∫ y dx
1
3
= ∫ | x − 2 | dx
1
2 3
∫ (x − 2) dx = ∫ ∫
2 3
= ∫
1
− (x − 2) dx +
2
1
(2 − x)dx + (x − 2)dx
2
2 3
 x2   x2 
= 2 x −  +  − 2 x 
 2 1  2 2
= (4 - 2) - (2 - 1/2) + (9/2 - 6) - (2 - 4) = 2 - 3/2 - 3/2 + 2 = 4 - 3 = 1
43. The equation of the family of curves is
x2 + y2 - 2ay = 0 ................ (i)
Differentiate w.r. to x
2x + 2yy' - 2ay' = 0
2x + 2yy' = 2ay'
2x + 2yy'
= 2a ................ (ii)
y'
x2 + y2
From equation (i) 2a =
y
On putting this value in equation (ii)
2x + 2yy' x 2 + y 2
=
y' y
2xy + 2y2y' = x2y' + y2y'

(x2 - y2)y' = 2xy
om
44. ydx + (x + x2y)dy = 0
ydx + xdy = -x2ydy
y dx + xdy 1
= − dy
c
2 2
y
g.
x y
ng
 1  1
d −  = − dy
 xy  y
ye
On integration, we get
.m
1
− = − log y + c
xy
w
1
− + log y = c
w
xy
w
45. Let (x, y) be coordinate of vertex C and (x1, y1) be coordinate of centroid of the triangle.
x+2−2 y − 3+1
∴ x1 = and y1 =
3 3
x y−2
x1 = and y1 = the centroid lies on the line 2x + 3y = 1. So x1 and y1 satisfied the equation
3 3
of line 2x1 + 3y1 = 1
 x y−2
⇒ 2  + 3  =1
 3  3 
⇒ 2x + 3y = 9
The above equation is the locus of the vertex C.
46. Let a and b be the intercepts on the co-ordinate axes.
a + b = -1
⇒ b = - a - 1 = - (a + 1)
Equation of line is x/a + y/b = 1 y
x y
⇒ − =1 ........ (i)
a a +1
Since this line passes through (4, 3). b
4 3 4a + 4 − 3a
∴ − = 1⇒ =1
a a +1 a(a + 1)
x
a + 4 = a2 + a O a
⇒ a2 = 4 ⇒ a = + 2
∴ Equation of line [from equation (i)]
x y x y
− = 1 or + =1
2 3 −2 1
47. The given pair of line is x2 - 2cxy - 7y2 = 0
On comparing with ax2 + 2hxy + by2 = 0,
we get, a = 1, 2h = -2c, b = -7
om
2h 2c a −1
m1 + m 2 = − = − and m1m 2 = =
b 7 b 7
Given that, m1 + m 2 = 4m1m 2
− 2c / 7 = −4 / 7, c = 4 / 2 = 2
c
g.
48. The pair of lines is 6x 2 − xy + 4cy 2 = 0
ng
On comparing with ax 2 + 2hxy + by 2 = 0 , we get

ye
a = 6, 2h = -1, b = 4c
2h 1 a 6
∴ m1 + m 2 = − = and m1m 2 = =
.m
b 4c b 4c
One line of given pair of lines is
w
3x + 4y = 0
Slope of line = -3/4 = m1 (say)
w
∴ -3/4 + m2 = 1/4c
w
m2 = 1/4c + 3/4
 1  6
∴ (−3 / 4)  + 3 / 4  =
 4c  4c
3  1 + 3c  6
=−  =
4  4c  4c
− 6× 4
1 + 3c =
4
1 + 3c = -8
3c = -9 ⇒ c = -3
49. Let the equation of circle is
x2 + y2 + 2gx + 2fy + c = 0
It cut the circle x2 + y2 = 4 orthogonally
if 2g.0 + 2f.0 = c - 4
⇒ c=4
∴ Equation of circle is
x2 + y2 + 2gx + 2fy + 4 = 0
Q It passes through the point (a, b)
∴ a2 + b2 + 2ag + 2f + 4 = 0
Locus of centre (-g, -f) will be a2 + b2 - 2xa - 2yb + 4 = 0
2ax + 2by - (a2 + b2 + 4) = 0
50. In a circle AB is as a diameter where the co-ordinate of A is (p, q) and let the co-ordinate of B is
(x1, y1).
Equation of circle in diameter form is
(x - p)(x - x1) + (y - q)(y - y1) = 0
x2 - (p + x1)x + px1 + y2 - (y1 + q)y + qy1 = 0
x2 - (p + x1)x + y2 - (y1 + q)y + px1 + qy1 = 0
Since this circle touches X-axis
∴ y=0
om
⇒ x2 - (p + x1)x + px1 + qy1 = 0
Also the discriminant of above equation will be equal to zero because circle touches X-axis.
∴ (p + x1)2 = 4(px1 + qy1)
p2 + x21 + 2px1 = 4px1 + 4qy1
c
g.
x21 - 2px1 + p2 = 4qy1
ng
Therefore the locus of point B is,
(x - p)2 = 4qy
51. The lines 2x + 3y + 1 = 0 and 3x - y - 4 = 0 are diameters of circle.
ye
On solving these equations we get

x = 1, y = -1
.m
Therefore the centre of circle = (1, -1) and circumference = 10 π

2πr = 10π
w
⇒ r=5
w
∴ Equation of circle
(x - x1)2 + (y - y1)2 = r2
w
(x - 1)2 + (y + 1)2 = 52
x2 + 1 - 2x + y2 + 2y + 1 = 25
x2 + y2 - 2x + 2y - 23 = 0
52. The equation of line is y = x ........... (i)
and equation of circle is x2 + y2 - 2x = 0 ........... (ii)
On solving equation (i) and equation (ii), we get
x2 + x2 - 2x = 0
2x2 - 2x = 0 = 2x(x - 1) = 0
x = 0, x = 1
when x = 0, y = 0
when x = 1, y = 1
Let coordinate of A is (0, 0) and co-ordinate of B is (1, 1)
∴ Equation of circle (AB as a diameter)
(x - x1)(x - x2) + (y - y1)(y - y2) = 0
(x - 0)(x - 1) + (y - 0)(y - 1) = 0
x(x - 1) + y(y - 1) = 0
x2 - x + y2 - y = 0
x2 + y2 - x - y = 0
53. The equation of parabolas are y2 = 4ax and x2 = 4ay
On solving these we get x = 0 and x = 4a
Also y = 0 and y = 4a
∴ The point of intersection of parabolas are A(0, 0) and B(4a, 4a).
Also line 2bx + 3cy + 4d = 0 passes through A and B.
∴ d=0 ............ (i)
or 2b . 4a + 3c . 4a + 4d = 0
2ab + 3ac + d = 0
a(2b + 3c) = 0 (Q d = 0)
⇒ 2b + 3c = 0 ............ (ii)
On squaring equation (i) and (ii) and then adding, we get
d2 + (2b + 3c)2 = 0
om
54. Since the directrix is x = 4 then ellipse is parallel to X-axis.
a 1
⇒ = 4 ⇒ a = 4e = 4 ×
c
e 2 g.
⇒ a=2 (Q e = 1/2)
Also we know that
ng
b2 = a2(1 - e2)
b2 = 4(1 - 1/4) = 4 × 3/4
ye
b2 = 3
x2 y2
.m
∴ Equation of ellipse is + =1
4 3
⇒ 3x2 + 4y2 = 12
w
55. A line makes angle θ with x-axis and z-axis and β with y-axis.
w
∴ l = cos θ, m = cosβ, n = cos θ

w
We know that, l2 + m2 + n2 = 1
cos2 θ + cos2 β + cos2 θ = 1
2 cos2 θ = 1 − cos2 β
2 cos2 θ = sin2 β ...... (i)
But sin2 β = 3 sin2 θ ...... (ii)

∴ From equation (i) and (ii)
3 sin 2 θ = 2 cos2 θ
3(1 − cos2 θ) = 2 cos2 θ
3 − 3 cos2 θ = 2 cos2 θ
3 = 5 cos2 θ
cos2 θ = 3 / 5
56. The distance between 4x + 2y + 4z - 16 = 0 and 4x + 2y + 4z + 5 = 0 is
5 + 16 21 21 7
= = =
16 + 4 + 16 36 6 2
57. Let the equation of line AB is

x−0 y+a z−0
= = = k (say)
1 1 1
∴ Coordinate of E is (k, k - a, k)
Also the equation of other line CD is
x+a y−0 z−0
= = = λ (say)
2 1 1
∴ Coordinate of F is (2λ − a, λ, λ) Direction Ratio of EF are ( k − 2λ + a ), ( k − λ − a ), ( k − λ)
k − 2λ + a k − λ − a k − λ
∴ = =
2 1 2
om
k − 2λ + a k − λ − a
On solving first and second fraction, =
2 1
k − 2λ + a = 2 k − 2λ − 2a
k = 3a
c
g.
On solving second and third fraction
ng
k −λ−a k −λ
=
1 2
ye
2 k − 2λ − 2a = k − λ
k − λ = 2a
.m
λ = k − 2a = 3a − 2a
λ=a
w
∴ Coordinate of E = (3a, 2a, 3a) and coordinate of F = (a, a, a)

58. The given straight line is x = 1 + s, y = -3 - λ s, z = 1 + λ s
w
x −1 y + 3 z −1
w
= = =s
1 −λ λ
Also given equation of another straight line is
t x − 0 y −1 z − 2
x = , y = 1 + t, z = 2 − t = = =t
2 1 2 −2
These two lines are coplanar if
1− 0 − 3 −1 1− 2
1 −λ λ =0
1 2 −2
1 − 4 −1
⇒ 1 − λ λ =0
1 2 −2
−λ λ 1 λ 1 −λ
⇒1 +4 −1 =0
2 −2 1 −2 1 2
⇒ (2λ − 2λ) + 4 (−2 − λ) − 1(2 + λ) = 0

⇒ − 8 − 4λ − 2 − λ = 0
⇒ − 10 = 5λ ⇒ λ = −2
59. Equation of two spheres are
x2 + y2 + z2 + 7x - 2y - z - 13 = 0 and x2 + y2 + z2 - 3x + 3y + 4z - 8 = 0. If these sphere intersect,
then S - S' = 0 represents the equation of common plane of intersection.
∴ (x2 + y2 + z2 + 7x - 2y - z - 13) - (x2 + y2 + z2 - 3x + 3y + 4z - 8) = 0
⇒ x2 + y2 + z2 + 7x - 2y - z - 13 - x2 - y2 - z2 + 3x - 3y - 4z + 8 = 0
⇒ 10x - 5y - 5z - 5 = 0
⇒ 2x - y - z = 1
r r r r r r
60. If a + 2 b is collinear with c , then a + 2b = tc .......... (i)
r r r r r r
Also if b + 3c is collinear with a , then b + 3c = λa
r r r
⇒
om
b = λ a − 3c
On putting this value in equation (i)
r r r r
a + 2(λa − 3c) = tc
r r r r
a + 2λa − 6c = tc
c
g.
r r r r
(a − 6 c) = tc − 2λa
ng
1 = −2λ ⇒ λ = −1 / 2
ye
and − 6 = t ⇒ t = −6
From equation (i)
.m
r r r
a + 2 b = −6 c
r r r
a + 2b + 6 c = 0
w
62. Total force

w
= (4 î + ĵ − 3k̂ ) + (3î + ĵ − k̂ )
w
= 7 î + 2 ĵ − 4k̂
The particle is displaced from A( î + 2 ĵ + 3k̂ ) to B(5î + 4 ĵ + k̂ )

∴ Displacement
AB(5î + 4 ĵ + k̂ ) − ( î + 2 ĵ + 3k̂)
= 4 î + 2 ĵ − 2 k̂
Work done = F . AB
= (7 î + 2 ĵ − 4k̂ ) .(4 î + 2 ĵ − 2 k̂)
= 28 + 4 + 8 = 40 units
1 2 3
r r r r r r
62. The three vectors (a + 2b + 3c), (λb + 4c) and (2λ − 1) c are coplanar if, 0 λ 4 =0
0 0 2λ − 1
⇒ (2λ − 1) (λ) = 0
⇒ λ = 0, 1/2
∴ These three vectors are non-coplanar for all except two values of λ (i.e. 0, 1/2)
63. | u | = 1, | v | = 2, | w | = 3
rr
r v.u r
The projection of v along u = and the projection of u along
|u|
rr
r w.u
w= r
|u|
rr r r
v.u w.u
So, = r
|u| |u|
rr r r
⇒ v.u = w.u
r r
and v, w are perpendicular to each other
r r
∴ v.w = 0
r r r r r rr r r r r
| u − v + w |2 = | u |2 + | v |2 + | w |2 −2u.v + 2u.w − 2v.w
om
r r r r r rr
| u − v + w | 2 = 1 + 4 + 9 − 2u . v + 2v.u
r r r
| u − v + w |2 = 1 + 4 + 9
c
r r r
g.
| u − v + w | = 14
ng
1 r r r r r r
64. Since | b | | c | a = (a × b) × c
3
ye
We know that
r r r rr r rr r
(a × b) × c = (a.c)b − ( b.c)a
.m
1 r r r rr v rr r
∴ | b | | c | a = (a.c) . b − ( b.c).a
3
w
w
1 r r rr rr
| b | | c | = − b.c and a.c = 0
w
1
⇒ bc = − bc cos θ
3
1
⇒ cos θ = −
3
1 1
⇒ cos2 θ = ⇒ 1 − sin2 θ =
3 9
1 8 2 2
⇒ sin2 θ = 1 − = ⇒ sin θ =
9 9 3
65. In the given statements only first and second statements are correct.
66. In the 2n observations, half of them equal to a and remaining half equal to -a. Then the mean of
total 2n observations is equal to zero.
Σ( x − x ) 2
∴ S.D. =
N
Σx 2
2=
2n
Σx 2 2na 2
4= ⇒4= ⇒ a2 = 4
2n 2n
⇒ |a| = 2
67. The probability of speaking truth of A, P(A) = 4/5.
The probability of not speaking truth of A, P( A) = 1 − 4. / 5 = 1/5.
3
The probability of speaking truth of B, P(B) = .
4
1
The probability of not speaking truth of B, P( B) = .
4
om
The probability of that they contradict each other
= P(A).P( B) + P( A).P(B)
4 1 1 3 1 3 7
c
= × + × = + =
g.
5 4 5 4 5 20 20
ng
68. E = {x is a prime number} = {2, 3, 5, 7}
P(E) = P(X = 2) + P(X = 3) + P(X = 5) + P(X = 7)
ye
P(E) = 0.23 + 0.12 + 0.20 + 0.07 = 0.62

F = {X < 4}= {1, 2, 3}
P(F) = P(X = 1) + P(X = 2) + P(X = 3)
.m
P(F) = 0.15 + 0.23 + 0.12 = 0.5

E ∩ F = {X is prime number as well as < 4 }
w
= {2, 3}
w
P (E ∩ F) = P(X = 2) + P(X = 3)
= 0.23 + 0.12 = 0.35
w
∴ Required probability
P (E ∪ F) = P(E) + P(F) - P(E ∩ F)
P (E ∪ F) = 0.62 + 0.5 - 0.35
P (E ∪ F) = 0.77
69. Given that mean = 4
np = 4
and variance = 2
npq = 2
⇒ 4q = 2
⇒ q = 1/2
∴ p = 1 - q = 1 - 1/2 = 1/2 also n = 8
Probability of 2 successes P(X = 2) = 8C2p2q6
8!
= × (1 / 2)2 × (1 / 2) 6
2!×6!
1 28
= 28 × 8
=
2 256
70. Let P and Q are forces. We know that
R = p 2 + Q 2 + 2PQ cos θ
When θ = 0 0 , R = 4N
R = 4N = P 2 + Q 2 + 2PQ
P+Q=4 .............. (i)
when θ = 90 0 , R = 3N
P2 + Q2 = 9 ............. (ii)
From equation (1) (P + Q)2 = 16
P2 + Q2 = 2PQ = 16
om
9 + 2PQ = 16
9 + 2PQ + 16 [using (ii)]
2PQ = 7
Now, (P - Q)2 = P2 + Q2 - 2PQ
c
g.
(P - Q)2 = 9 - 7
ng
P − Q= 2 ............... (iii)
On solving equation (i) and equation (iii)
ye
 1 
P = 2 + 2 N
 2 
.m
 1 
and Q = 2 − 2 N
w
 2 
r
w
71. Moment about A of force F = 0

r
w
Moment about B of force F = 9

⇒ F.3 cos θ = 9 4
5
⇒ F cos θ = 3
r
Moment about C of force F = 16 A B
3
F.4 sin θ = 16
⇒ F. sin θ = 4
On squaring equation (i) and equation (ii) and then adding
F2 = 32 + 42
F=5
r r r
72. Three forces P, Q and R acting along IA, IB and IC are in equilibrium
∠A + ∠B
∠AIB = π −
2
= π − ( π / 2 − c / 2) = π / 2 + C / 2
Similarly ∠BIC = π / 2 + ∠A / 2 and ∠AIC = π / 2 + ∠B / 2 A
P Q R r
By Lami's theorem = = P
sin ∠BIC sin ∠AIC sin ∠AIB
r r
P Q R Q R
⇒ = =
sin(π / 2 + A / 2) sin(π / 2 + B / 2) sin(π / 2 + C / 2) B C
P Q R
⇒ = = = λ(say)
cos A / 2 cos B / 2 cos C / 2
⇒ P = λ cos A / 2, Q = λ cos B / 2, R = λ cos C / 2
A B C
∴ P : Q : R = cos : cos : cos
2 2 2
73. Given AB = 12 km (s1)
and BC = 5 km (s2)
Speed from A to B = 4 km/h y
C
om
12
Time taken t1 = = 3 hr
4
Speed from B to C = 5 km/h
Time taken to complete distance from B to C
c A
x
g.
5
t2 = = 1 hr
ng
5
total dis tan ce s1 + s2

Average speed = =
ye
total time t1 + t 2
12 + 5 17
.m
= = km / h
3+1 4
w
AC = (AB)2 + (BC) 2 = 144 + 25

w
= 169
w
AC = 13 km
dis tan ce AC
Average velocity =
total time
13
= km / h
4
74. V = 1/4 m/sec2
Component of V along OB
B
1 / 4 sin 30 0 1 / 4 sin 30 0
= = V
sin(30 0 + 450 ) sin 750
1 / 4 .1 / 2 2 3 −1 45 0
= = × 30 0 A
3 +1 4( 3 + 1) 3 −1 O
2 2
2 ( 3 − 1) 1
= = ( 6 − 2)
4(3 − 1) 8
75. If two particles having same initial velocity u and range R then their direction must be opposite. i.e.
the direction of projection of them are α and 900 - α .
2u sin α 2u sin (90 0 − α)

∴ t1 = and t 2 =
g g
2u cos α
t2 =
g
Now, = t12 + t 22
(2u sin α) 2 (2u cos α) 2

= +
g2 g2
4u 2 4u 2
= (sin 2
α + cos 2
α ) =
om
g2 g2
c
g.
ng
ye
.m
w
w
w

Physics&Chemistry Solutions Solutions of AIEEE 2004 Paper: Mathiit

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Physics&Chemistry Solutions Solutions of AIEEE 2004 Paper: Mathiit

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Today’s Mathiitians..... Tomorrow’s IITians.

Solutions of AIEEE 2004 Paper

dim ensions of force

where vi and vf respectively are initial and final velocities of particle.

where a = retardation of body in both the cases

11. Let the mass of block be m.

F = mg sin 300 m g sin 30 0 m g cos30 0

= (5î + 3 ĵ + 2 k̂) . (2 î − ĵ)

20. Gravitational potential energy of body on earth's surface

22. Work done in stretching the wire = potential energy stored

l, being the length of simple pendulum, In water, effective weight of bob

where ρ = density of bob, ρ′ = density of water

26. Time period of spring

k, being the force constant of spring.

∴ Time period of combination

From equations (i) and (ii), we obtain

y = 10 −6 sin  100t + 20x +  ............. (i)

y = a sin(ωt + kx + φ) ............. (ii)

External force F = m (ω20 − ω2 ) x .............. (ii)

∴ From eq. (ii) m(ω20 − ω2 ) x ∝ cos ωt .............. (iii)

Therefore, using above two relations, we find

P1V1 + P2V2 = P(V1 + V2)

35. Initial momentum of surface

So, refractive index µ = ε / ε0

r, being the distance between them.

becomes 2v, the closest distance will be r

Hence, current supplied by the battery is

47. Let R1 and R2 be the two resistances.

So, S = R1 + R2 (in series)

1st case: R = X, S = Y, l1 = 20 cm,

Hence, no neutral temperature is possible for this thermocouple.

53. Mass of substance liberated at cathode

where, z = electro-chemical equivalent

i = current flowing = 3A.

µ 0 i = 1500 ............... (ii)

Now, putting x = 0 in equation (i), magnetic field at the centre of loop is

Putting the given values in eq. (i), we get

Comparing above two equations

hc 6.6 × 10 −34 × 3 × 108

∴ r = 5.3 × 10 −14 m = 10 −12 cm

72. For a transistor amplifier in common emitter configuration, current again

where h fe and h oe are hybrid parameters of a transistor.

O2- and F- each has two orbits.

Thus ionic radius of O2-, F- > Li+, B3+

period left to right, acidic nature increases.

Thus, Al2O3 < SiO2 < P2O3 < SO2

83. Bond length is inversely proportional to bond-order. Bond-order in NO + = 3

CH3 CH3 CH3

98. (a) pA = XA p0A true

2.303 log 2 2.303 0.1 2.303

2.303 log 2 2 × 2.303 log 2

105. N2(g) + O2(g) 2NO(g)

Thus unit of k is M-1 s-1

107. Sn(s) + 2Fe3+ (aq) → 2Fe2+ (aq) + Sn2+ (aq)

E 0Fe3+ / Fe2+ = 0.77 V

∴ E 0cell = 0.14 + 0.77 = 0.91 V

^0NaBr = ^0NaCl + ^0KBr - ^0KCl

= 128 S cm2 mol-1

Zn | Zn2+ (C1) || H+ (aq) | Pt (H2)

α − Sn has a much lower density.

Thus CuI2 is not formed.

124. (a) Fe2+ [A r] ↑↓ ↑ ↑ ↑ ↑

Fe2+ in strong ligand CN- [A r] ↑↓ ↑↓ ↑↓