Mock IIT Advanced Test - 3/2014/paper-1: Read The Following Instructions Very Carefully Before You Proceed

Vidyamandir Classes
Mock IIT Advanced Test - 3/2014/Paper-1

11/05/2014
10:00 AM - 01:00 PM
M.M. : 225
TEST CODE : ACEG
TIME : 3.00 Hrs
Read the following Instructions very carefully before you proceed.

1.
The question paper consists of 3 parts (Part I : Chemistry, Part II : Physics, Part III : Mathematics).
Each Part has 3 sections (Section I, Section II, Section III & Section IV).
2.
Section I contains 10 Straight Objective type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONLY ONE Choice is Correct.
3.
Section II contains 5 Multiple Objective type Questions. Each question has 4 choices (A), (B), (C) and
(D), out of which ONE or MORE Choices may be Correct.
4.
Section III contains 5 Integer (Subjective) type Questions. Each question has an integer answer lying
between 0 and 9.
5.
Section IV contains 3 Match the following type Questions. Each question contains statements given in
2 lists. Statements in the first list have to be matched with statements in the second list and then for
each element of list -1, corresponding bubbles (from list-2) should be filled in the answer sheet.
6.
For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately. Please fill your
Test Code, Roll No. and Group Properly in the space given in the ANSWER SHEET.
7.
For each question in Section I, you will be given 2 Marks if you have darkened only the bubble
corresponding to all correct answers and zero mark if no bubble is darkened. There is NO NEGATIVE
MARKING.
8.
For each question in Section II, you will be given 4 Marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases,
minus ONE (1) mark (NEGATIVE MARKING) will be given.
9.
For each question in Section III, you will be given 4 Marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. In all other cases,
minus ONE (1) mark (NEGATIVE MARKING) will be given.
10.
For each question in Section IV, you will be given 5 Marks if you have darkened only the bubble
corresponding to the correct answer and zero mark if no bubble is darkened. There is NO NEGATIVE
MARKING.
11.
No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile
phone, any electronic device, etc., except the Admit Card inside the examination hall/room.
12.
On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator on duty
in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.
13.
No one will be permitted to leave the test room before the end of the test, i.e. 01.00 PM
VMC/JEE-2014/Paper-1
Mock IIT ADVANCED - 3/ACEG
Vidyamandir Classes
PART - I (CHEMISTRY)
75 MARKS
SECTION - I
SINGLE CORRECT ANSWER TYPE
This section contains 10 Single Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONLY ONE Choice is Correct.
1.
Two separate bulbs are filled with ideal gases A and B respectively. The density of gas A is three times
that of gas B and the molar mass of gas B is twice that of gas A. Calculate the ratio of pressure of gas
A to B if the two gases are at the same temperature.
(A)
3/2
(B)
2/3
(C)
6/1
(D)
1/6
2.
If H 2S2 (g) H 2 + 2S(g) ; H = 240k cal and H 2S(g) H 2 (g) + S(g) ; H = 160k cal
Then enthalpy change for the reaction 8S(g) S8 (g) is :
(A)
3.
320 k cal
(B)
560 k cal
(C)
640 k cal
(D)
800 k cal
Consider the following gaseous equilibria given below:

I.
III.
2NH 3 ; K1
N 2 + 3H 2
1
H 2O ; K 3
H 2 + O 2
2
II.
2NO ; K 2
N 2 + O 2
5
2NO + 3H 2O in terms of K1 , K 2 and
The equilibrium constant for the reaction 2NH3 + O 2
2
K 3 will be :
(A)
K1K 32
K3
(B)
K1K 2
K3
(C)
K1K 32
K2
(D)
K 2 K 33
K1
SPACE FOR ROUGH WORK
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4.
If four moles of electrons are transferred from anode to cathode in an experiment on electrolysis of
water. The total volume of the two gases produced at S.T.P will be :
(A)
22.4 L
(B)
72.6 L
(C)
67.2L
(D)
89.4 L
5.
(A)
6.
7.
(C) of the above sequence is :
(B)
(C)
(D)
Which is the major organic product of the following reaction?
(A)
(B)
(C)
(D)
0.2 molal acid HX is 20% ionized in solution. K f = 1.86 K kg mol 1. The freezing point of the solution
is :
(A)
0.45C
(B)
0.90C
(C)
0.31C
(D)
0.53C
Vidyamandir Classes
8.
On the basis of reaction 4Al + 3O 2 2Al2O3 , G = 827 kJ mol1 of O 2 .

The minimum emf required to carry out electrolysis of molten Al2O3 is :
(A)
2.14 V
(B)
8.5 V
(C)
1.42 V
(D)
2.83 V
9.
A stupid chemist, Kivid Ajin, forgot to label three test tubes, each of them containing a different
4 membered hydrocarbon. To identify them, he performed some tests. Following are the result :
Test-Tube 1 gives white ppt with amm. AgNO3, other two do not. All test tubes give positive bromine
water test. Test-Tube 3 on reaction with HBr gave a racemic mixture but Test-Tube 2 does not. Test
Tube 3 on reaction with O3/H2O2 does not release CO2 gas but Test-Tube 2 does. The possible
constituents of test tubes are :
Test Tube 1
Test Tube 2
Test Tube 3
(A)
Isobutene
But-1-yne
But-2-ene
(B)
Butyne
But-2-ene
Butene
(C)
But-2-yne
Butene
Butane
(D)
Butyne
Isobutene
But-2-ene
10.
Which of the following is the strongest acid?

(A)
(B)
ClOH
ClO2 (OH)
(C)
ClO3 (OH)
(D)
ClO(OH)
Vidyamandir Classes
SECTION - II
MULTIPLE CORRECT ANSWERS TYPE
This section contains 5 Multiple Choice Questions. Each Question has 4 choices A, B, C & D, out of which
ONE or MORE Choices may be Correct.
11.
12.
Which of the following compounds show cis-trans isomerism?
(A)
2-methyl-1-heptene
(B)
(C)
2-heptene
(D)
Which of the following species are isostructural to N3 ?
(A)
13.
NCO
(B)
ClO 2
(C)
I3
(D)
CNO
(D)
POCl3
Which of the following species have sp3 hybridized central atom?

(A)
BF4
(B)
H 3O +
(C)
XeOF4
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14.
Which of the following is/are correctly matched?

(A)
(B)
(C)
(D)
15.
When some amount of mercuric iodide is added to an aqueous solution of potassium iodide :
(A)
Boiling point is raised
(B)
Osmotic pressure is lowered
(C)
Boiling point is lowered
(D)
Freezing point is lowered
Vidyamandir Classes
SECTION - III
SUBJECTIVE INTEGER TYPE
This section contains 5 Subjective Questions. Each question has an integer answer between 0 and 9. Fill the
answer bubbles in the OMR Sheet APPROPRIATELY and CAREFULLY.
16.
Assuming that ms has four values rather than two and that the normal rules apply for n, l and ml
quantum numbers, how many electrons could an orbital hold? ( ms = spin quantum number)
17.
How many isomers (excluding stereoisomers) of C5H 6 will give white precipitate with ammonical
AgNO3 solution?
18.
How many of the following are intensive properties?

Standard cell potential, Specific gravity, Viscosity, specific heat capacity, color, Melting point,
Pressure, Concentration.
19.
The composition predicted on the basis of the eighteen electron rule for the most simple binary
chromium(0) nitrosyl compound is [Cr(NO) x ] . What is value of x? [Atomic number of Cr = 24]
20.
How many of the following compounds contain the peroxo group (O22 ) ?
2
H 2 O2 , Na 2O 2 , BaO2 , H 2SO5 , H 2S2 O8 , K 2 C2 O6 , CrO5 ,[VO 2 ]3+ , Cr2O12
Vidyamandir Classes
SECTION - IV
MATRIX MATCH TYPE
This section contains 3 Match type Choice Questions. Each question has matching lists. For each element of
list-1, match the elements from list-2 and then fill the answer bubbles in the OMR Sheet APPROPRIATELY
and CAREFULLY.
21.
MATCH THE FOLLOWING LISTS :

List 1
List 2
(A)
(p)
Intermolecular migration.
(B)
(q)
Intramolecular migration.
(C)
(r)
Carbocation intermediate.
(D)
(s)
Rearrangement by phenyl shift.
(t)
Free radical mechanism
Vidyamandir Classes
22.

List 1
(A)
List 2
(p)
ZnCl2
Gives white precipitate with Na 2HPO4 in

presence of NH 4Cl and NH 4OH
(B)
FeSO 4
(q)
Gives reddish brown precipitate with

NaOH
(C)
FeCl3
(r)
Gives white precipitate with NaOH which

dissolve in excess of NaOH
(D)
MgCl 2
(s)
Gives green precipitate with NH 4OH as

well as with NaOH
(t)
23.
Amphoteric salt

List 1
List 2
(A)
A compound which cannot form isomers
(p)
[Pt(NH3)2NO2Cl]
(B)
A compound in which metal involve six

orbitals in hybridization
(q)
[Pt(NH3)4ClBr]SO4
(C)
Complex can show ionization isomerism
(r)
[Pt(NH3)3Cl]Br
(D)
A compound which can form cis trans

isomers
(s)
[Pt(NH3 )Cl5 ]
(t)
[PtCl4 ]2
Vidyamandir Classes
PART - II (PHYSICS)
75 MARKS
SECTION - I
24.
25.
(A)
R/4
(B)
R/2
(C)
(D)
4R
Consider the circuit shown in figure; r is the winding resistance of

each of the two coils. If switch S is closed at t = 0, effective
resistance in the circuit at t = 0 is :
L,r
E
R
L,r
E
E
S
E
Consider a general, non-uniform electric field produced by some source charges. Suppose that the

electric field at a point P is E0 . There is vacuum everywhere.
A dielectric material of arbitrary shape with relative permittivity r is now placed around point P as
shown. Electric field at P now:
(A)
Remains unchanged
(B)

Becomes E0 / r
(C)
Increase in magnitude
(D)
None of these
10
Vidyamandir Classes
26.
Graphs I and II give coordinates x (t ) and y (t ) of a particle moving in the x-y plane, starting from rest.
Acceleration of the particle is constant and the graphs are drawn to the same scale. Which of the vectors
shown in options best represents the acceleration of the particle?
(A)
27.
(B)
(C)
(D)
The graph shown gives the temperature along an x axis that extends directly through a wall consisting
of three layers A, B and C. The air temperature on one side of the wall differs from that on the other
side. Thermal conduction through the wall is steady. Out of the three layers A, B and C, thermal
conductivity is greatest of layer :
(A)
B C
(B)
(C)
(D)
None, all have same
11
Vidyamandir Classes
28.
An open pan filled with water (density w ) is placed on a vertical rod, maintaining equilibrium.
A block of density is placed on one side of the pan as shown. Water depth is more than height of the
block.
(A)
Equilibrium will be maintained only if < w
29.
(B)
Equilibrium will be maintained only if w
(C)
Equilibrium will be maintained for all relations between and w
(D)
Equilibrium will not be maintained in all cases
Four possible orbital paths for a satellite around the Earth are
shown as 1, 2, 3 and 4. Out of these, which path the satellite
cannot take without continuous adjustments by booster rockets?
30.
(A)
(B)
(C)
(D)
When a spherical ball is released from rest in a very long column of viscous liquid, its downward
acceleration is a just after release. Find its acceleration when it has acquired two third of the
maximum velocity:
(A)
a
3
(B)
2a
(C)
a
6
(D)
None of these
12
Vidyamandir Classes
31.
For black body radiation, consider the graph between spectral radiance
(dE / d) and . The temperature of body is now increased such that the
peak shifts to 0 / 2. Total area under the curve increases
(A)
(C)
Two times
Sixteen times
(B)
(D)
Four times
Remains same
32.
The two-gear combination shown in the drawing is being used to lift

the load L with a constant upward speed of 2.50 m/s. The rope that is
attached to the load is being wound onto a cylinder behind the big
gear. The depth of the teeth of gears is negligible compared to the
radii. Determine the angular velocity (magnitude) of the smaller
gear.
17
30
(A)
rad/s
(B)
25
rad/s
250
17
250
17
(C)
rad/s
(D)
25 rad/s
17
30
33.
At t = 0, a transverse wave pulse, travelling in the positive x direction with a speed of 2 m/s in a wire is
6
described by the function y = 2 where x 0. Transverse velocity of a particle at x = 2 m and
x
t = 2 second is :
(A)
3 m/s
(B)
3 m/s
(C)
8 m/s
(D)
8 m/s
13
Vidyamandir Classes
SECTION - II
34.
Two masses m and 2m are attached by an ideal spring and placed at rest on a horizontal frictionless
ground. A constant horizontal force F is now applied on m as shown :
For the subsequent motion, choose the correct option(s) :

(A)
2m performs simple harmonic motion
(B)
2m performs simple harmonic motion in a reference frame attached to center of mass of m
and 2m
(C)
Mechanical energy (i.e. KE + PE) of system continuously increases
(D)
Maximum compression in spring is equal to maximum extension in spring (in magnitude)
35.
A particle of mass m rests on top of a smooth hemisphere as shown.

If m is slightly disturbed it will obviously slide down of
hemisphere and lose contact with hemisphere at some point.
For this motion, choose the correct option(s). Here N represents the
normal reaction between m and hemisphere.
(A)
Work done by N on m in ground reference frame is zero
(B)
Work done by N reaction on m is same in all inertial reference frames
(C)
Work done by N on m is non-zero in ground reference frame
(D)
Network done by N on both m and M is zero in ground reference frame
14
Vidyamandir Classes
36.
Consider the collision of a particle moving on a smooth horizontal

plane with a rough vertical wall. Let the angles of incidence and
reflection be and as shown in figure.
Choose the correct option(s) :
(A)
If the collision is perfectly elastic, will be equal to
(B)
If the coefficient of restitution is 0.5, may be equal to
(C)
can be less than
(D)
can be less than
37.
A point source of light is placed on the common optic axis of a thin lens and a convex mirror as shown.
Focal length of lens is 20 cm and focal length of mirror is 10 cm. The value/s of x for which the final
image of O will coincide with O is(are) :
(A)
10 cm
(B)
30 cm
(C)
40 cm
(D)
Infinity
38.
A particle of mass m is placed on a wedge of mass 2m and

angle . Wedge is in turn placed on a horizontal plane.
All surfaces are frictionless.

The system is now released from rest. Let a1 and a2 denote accelerations of m and 2m respectively,
before m leaves wedge. Choose the correct option(s) :

(A)
a1 makes an angle with horizontal such that >

(B)
Angle between a1 and a2 is same in all reference frames

(C)
Velocity of m is always parallel to a1 (till m is on wedge)
(D)
If is increased, for some value of < 90, m loses contact with 2m immediately after the
system is released
15
Vidyamandir Classes
SECTION - III
39.
An ideal gas (cp/cV = =1.25) follows the cycle ABCDA shown in the
figure. Determine the ratio of the heat energy given out by the gas to its
surroundings during the isochoric section of the cycle to the expansion
work done by gas during the isobaric section of the cycle.
40.
A square loop of side ' l ' having uniform linear charge density '' is placed in
'xy' plane as shown in the figure. There is a non uniform electric field
a
E = (x + l) i where a and l are constants and x is the position of the point
from origin along x-axis. Find the resultant electric force on the loop
(in Newtons), if l = 10 cm, = 20 C/m and a = 5 105 N/C.
41.
A radioactive sample contains two radio nuclides A and B having decay constant hr1 and
2 hr1. Initially 25% of total decay comes from A. How long (in hr) will it take before 75% of total
decay comes from A. [Take = ln 3]
42.
In the given LCR series circuit find the reading (in A) of the hot
wire ammeter. (Here all hot wire meters are ideal)
43.
In a given system of units, 1 unit of mass = 2kg, 1 unit of length = 5m and 1 unit of time = 5sec.
Then in this new system, 2N is equal to_________ new units.
16
Vidyamandir Classes
SECTION - IV
MATRIX MATCH TYPE
and CAREFULLY.
44.
In left column some of the situations are shown and in right column some statements are given.
Match the following Lists :
List 1
(A)
< tan y
=0
List 2
(p)
Momentum is conserved in
x-direction
(q)
Momentum is conserved in
y-direction
(r)
Mechanical
conserved
(s)
Work done by
forces is zero
(t)
Net external force on

system
in
horizontal
direction is zero
Consider both mass a system
(B)
=0
=0
Consider both mass as system
(C)
Both charges are free to move on smooth level ground.

q1 is moving directly towards charge q2.
energy
is
q1
v0
q2
Consider both charge as system

(D)
q1 free to move on smooth level ground and q2 fixed on

level ground. q1 is moving directly towards charge q2.
internal
q1
v0
q2
Consider both charges as system
17
Vidyamandir Classes
45.

List 1
List 2
(A)
Velocity of its centre of mass changes
(p)
A stone is tied to one end of a string and

is doing uniform circular motion in a
horizontal circle having centre O.
(B)
Its angular momentum about point O is

constant
(q)
A block is projected horizontally on a

rough level ground from point O.
(C)
Its kinetic energy is constant
(r)
A ball is dropped from a plane flying

horizontally with constant velocity.
Neglect air resistance. Point O is point of
projection on plane from which the ball
is dropped.
(D)
Its angular velocity changes about point O.
(s)
A uniform sphere is in pure rolling,

rolling down an inclined plane where O
is the centre of the sphere.
(t)
A satellite is moving in elliptical orbit

around sun. Point O is centre of the sun.
18
Vidyamandir Classes
46.
In List 1, statement about heat given to the system, work and internal energy are given. Symbols have
their usual meaning use first law of thermodynamics in form Q = U + W. Match the situations in
List 2 with statements in List 1.
List 1
(A)
Q > 0
List 2
(p)
v0
Rough ground
Block is the system. Assume no heat is lost to surrounding

till the block comes to rest
(B)
Q < 0
(q)
A block is released from rest from massless elastic string at

natural length. After a few oscillations, block comes to rest.
The string is the system
(C)
W > 0
steam
(r)
Water is boiled in a closed container with a movable light

piston. The container with its contents is the system
(D)
U > 0
(s)
A monatomic ideal gas undergoes a process PT = constant.

Gas is the system. Pressure increases during the process
(t)
In isothermal expansion of an ideal gas
19
Vidyamandir Classes
PART - III (MATHEMATICS)
75 MARKS
SECTION - I

47.
If the normal to a parabola y 2 = 4ax at P meets the curve again in Q and if PQ and the normal at
Q makes angle and , respectively, with the x-axis then tan (tan + tan ) has the value equal to :
(A)
48.
(B)
(C)
If two points P and Q on the hyperbola

CQ, a < b, then the value of
(A)
49.
b2 a 2
2ab
(B)
1
2
(D)
x2 y2
= 1, whose centre C be such that CP is perpendicular to

a2 b2
1
1
is :
+
CP 2 CQ 2
1
1
+ 2
2
a
b
(C)
2ab
b a2
2
(D)
1
1
2
2
a
b
The co-ordinates of two points P and Q are ( x1, y1 ) and ( x2 , y2 ) and O is the origin. If circles be
described on OP and OQ as diameters then length of their common chord is :
| x1 y2 + x2 y1 |
| x1 y2 x2 y1 |
| x1 x2 + y1 y2 |
(A)
(B)
(C)
(D)
PQ
PQ
PQ
| x1 x2 y1 y2 |
PQ
20
Vidyamandir Classes
50.
If 5 x + 2 3
(A)
2x
13x , then solution set for x is :
[2, )
[0, 2]
(B)
(C)
(, 2]
[ 4, )
(D)
1+ cos 2 t
51.
For
tR
any
let
be
continuous
function,
and
let
I1 =
x. f ( x(2 x ))dx,
sin 2 t
1+ cos 2 t
I2 =
f ( x (2 x))dx. Then
sin t
(A)
52.
53.
(B)
I1
is equal to :
I2
(C)
(D)
Solution of (1 + x x 2 + y 2 )dx + (1 + x 2 + y 2 ) ydy = 0 is :
(A)
1
x + ( x 2 + y 2 )3/2 = c
3
(C)
y2 1 2
+ ( x + y 2 )3/2 = c
2 3
(B)
x+
y2 1 2
+ ( x + y 2 )3/2 = c
2 3
(D)
x+
y2
+ ( x 2 + y 2 )1 2 = c
2
The number of positive integral solutions of the equation x1 x2 x3 = 60 is :
(A)
54
(B)
27
(C)
81
(D)
90
21
Vidyamandir Classes
54.
Sardar Khan is studying in VIDYAMANDIR. Every Sunday he analyses his work and he is either up to
date or fallen behind. If he is up to date in a given week the probability that he will be up to date in the
next week is 0.8. If he is behind the probability that he will be up to date next week is 0.6. If he is up to
date on 1st Sunday, then the probability that he will be up to date after 3 weeks is :
(A)
0.648
(B)
0.668
(C)
0.752
(D)
0.54
10
55.
x +1
x 1
In the expansion of 2 / 3 1/ 3
, the term which does not contain x, is equal to :

1/ 2
x x +1 x x
(A)
56.
10
C0
(B)
10
C7
(C)
10
For A = a 2 + b 2 + c 2 , B = ab + bc + ca, a 3 + b3 + c3 3abc
(A)
B A B
B B A
A B B
(B)
A B B
B B A
B A B
(C)
C4
(D)
10
(D)
C2
is equal to :
B B A
B A B
A B B
22
Vidyamandir Classes
SECTION - II
57.
Point M moved on the circle ( x 4)2 + ( y 8) 2 = 20. Then it broke away from it and moving along a
tangent to the circle, cuts the x-axis at the point (2, 0). The co-ordinates of a point on the circle at
which the moving point broke away is :
(A)
58.
42 36
,
5 5
(B)
(C)
(6, 4)
(D)
(2, 4)
If the normal at P to the rectangular hyperbola x 2 y 2 = 4 meets the axes in G and g and C is the center
of the hyperbola, then :
(A)
(B)
PG = PC
59.
2 44
,
5 5
If f ( x ) =
(A)
(B)
(C)
(D)
Pg = PC
(C)
PG = Pg
(D)
Gg = 2 PC
1
(where [.] denotes the greatest integer function), then :
[| sin x | + | cos x |]
f (x) is an even function

f (x) is an odd function
Range of f (x) contains only one element
f (x) is continuous and differentiable x R
23
Vidyamandir Classes
1
60.
dx
, then :
1 + x /2
0
If I =
(A)
61.
I > ln2
(B)
I < ln2
(C)
I < /4
(D)
I > /4
If (1 + x + x 2 ) n = a0 + a1 x + a2 x 2 + ... + a2 n x 2 n , then the value of a0 + a3 + a6 + .... is :
(A)
a1 + a4 + a7 + ....
(B)
a2 + a5 + a8 + ....
(C)
3n 1
(D)
24
Vidyamandir Classes
SECTION - III
62.
The absolute maximum value of f ( x ) =
1
1
p
+
is
(HCF (p, q) = 1) then |p q|
| x 4 | +1 | x + 8 | +1
q
is equal to _________.
63.
The remainder when ( 3053)
64.
Consider two concentric circles C1 : x 2 + y 2 = 1, C2 : x 2 + y 2 = 4. Tangent are drawn to C1 from any point
456
( 2417 )
333
is divided by 9 is _________.
P on C2 . These tangents again meet circles C2 at A and B. The locus of the point of intersection of
tangents drawn to C2 at A and B is a circle then the radius of this circle is _________.
65.
Let = cos
2
2
and let Ak = x + y k + p 2 k + w3k + f 4 k , where x, y, p, w, f are points on the
+ i sin
5
5
circle |z| = 1, if | A0 |2 + | A1 |2 + | A2 |2 + | A3 |2 + | A4 |2 = k 2 then k is _________.

66.
The angles of a triangle ABC satisfy the relation (cosec 2A) (cosec 2B) = 1 + cos C and A + B cant be
obtuse. Then the value of
a
2b
(cos 2C + 3) +
is _________.
b
a
25
Vidyamandir Classes
SECTION - IV
MATRIX MATCH TYPE
and CAREFULLY.
67.

List 1
(A)
(B)
List 2
The serial numbers of lottery tickets are 7 digit integers. It is

known that the serial number of winning ticket has seven distinct
digits and is divisible by each of its digit, let N be the largest
possible serial number; the number at ten thousandth place is
2014
Consider z = ( x + iy ) If z 0 then
(p)
(q)
(r)
(s)
(t)
[arg | z |]dx is
2014
(C)
If is a non-real complex constant such that z 2 + z + = 0 has

| + + 1| + | z |
real roots then
may be equal to
|+|
(D)
If x1 , x2 ,....x10 are real numbers

A = [ x1 + x2 + ..... + x10 ] , B = [ x1 ] + [ x2 ] + ..... + [ x10 ]
Then
( A B ) maximum = {here [.] is G.I.F}
26
Vidyamandir Classes
68.

List 1
(A)
Function
List 2
y = f ( x ) satisfies the condition
(p)
k where k R +
(q)
(r)
k, where k is some negative real

number
(s)
(t)
f (2014 x + f (0)) = 2014 x 2 for each real x if

sum of all possible values of f (2014) is

is : (Here [.] is G.I.F.)
then
2014
(B)
Define
a1, a2 .....an
a1 = 0, a2 = 1,
as
an = 5an 1 an 2 for n > 2 . If a p be the third
term divisible by 15 then number of prime

less than p is
(C)
Consider
n =
n r =1
function
f ( x) =
n 1
1
r
f and n =
n r =0
n
1
1+ x
let
r
f ; n N ,
n

= lim ( n ) & = lim ( n ) then. n n
n
n

will always be
(D)
The perimeter of a ABC is 6 times the AM

of the sine of its angles if side (BC) is 1 unit
then [cot A] is {Here [.] is G.I.F}, where A is
an acute angle.
27
Vidyamandir Classes
69.

List 1
(A)
Let
and
(k )
be
( k )
List 2
the
roots
of
equation
(p)
(q)
(r)
(s)
(t)
( 3 1 + k 1) x + ( 1 + k 1) x + ( 6 1 + k 1) = 0 where k > 1 and

2
l+m
l = lim ( (k )), m = lim ((k )) then
is
+
+
k 0
k 0
|l | |m|
(B)
P is a 3 3 matrix such that PT = 2 P + I ; where PT is the

transpose of P and I is 3 3 unit matrix then there exists a
x 0
column matrix x = y 0 such that Px = x then (scalar) is
z 0
equal to
(C)
Image of ellipse
x2 y 2
+
=1
25 16
( x ) 2 ( y ) 2
+
= 1 then
A
B
(D)
x + y = 10
in the line
( A + B)
is
is
Let f be a real-valued function whose inverse is given by
) (
f 1 ( x ) = x 1 + x 2 + 1 x 2 , then f f 1 ( f ( 2 ) ) is equal to
End of Mock IIT Advanced - 3/PAPER-1/JEE-2014
28

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Vidyamandir Classes

Mock IIT Advanced Test - 3/2014/Paper-1

TEST CODE : ACEG

TIME : 3.00 Hrs

Read the following Instructions very carefully before you proceed.

Mock IIT ADVANCED - 3/ACEG

Consider the following gaseous equilibria given below:

SPACE FOR ROUGH WORK

Mock IIT ADVANCED - 3/ACEG

(C) of the above sequence is :

Which is the major organic product of the following reaction?

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Mock IIT ADVANCED - 3/ACEG

On the basis of reaction 4Al + 3O 2 2Al2O3 , G = 827 kJ mol1 of O 2 .

Which of the following is the strongest acid?

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Mock IIT ADVANCED - 3/ACEG

Which of the following compounds show cis-trans isomerism?

Which of the following species are isostructural to N3 ?

Which of the following species have sp3 hybridized central atom?

SPACE FOR ROUGH WORK

Mock IIT ADVANCED - 3/ACEG

Which of the following is/are correctly matched?

Mock IIT ADVANCED - 3/ACEG

How many of the following are intensive properties?

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Mock IIT ADVANCED - 3/ACEG

MATCH THE FOLLOWING LISTS :

Rearrangement by phenyl shift.

Free radical mechanism

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Mock IIT ADVANCED - 3/ACEG

MATCH THE FOLLOWING LISTS :

Gives white precipitate with Na 2HPO4 in

Gives reddish brown precipitate with

Gives white precipitate with NaOH which

Gives green precipitate with NH 4OH as

MATCH THE FOLLOWING LISTS :

A compound which cannot form isomers

A compound in which metal involve six

Complex can show ionization isomerism

A compound which can form cis trans

SPACE FOR ROUGH WORK

Mock IIT ADVANCED - 3/ACEG

Consider the circuit shown in figure; r is the winding resistance of

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Mock IIT ADVANCED - 3/ACEG

None, all have same

SPACE FOR ROUGH WORK

Mock IIT ADVANCED - 3/ACEG

Equilibrium will be maintained only if w

Equilibrium will be maintained for all relations between and w

Equilibrium will not be maintained in all cases

SPACE FOR ROUGH WORK

Mock IIT ADVANCED - 3/ACEG

The two-gear combination shown in the drawing is being used to lift

Mock IIT ADVANCED - 3/ACEG

For the subsequent motion, choose the correct option(s) :

A particle of mass m rests on top of a smooth hemisphere as shown.

Mock IIT ADVANCED - 3/ACEG

Consider the collision of a particle moving on a smooth horizontal

A particle of mass m is placed on a wedge of mass 2m and

All surfaces are frictionless.