Beruflich Dokumente
Kultur Dokumente
R. Setnescu, T. Setnescu
I.
INTRODUCTION
W
v R v0 exp a ,
RT
(1)
b
,
T
(2)
EXPERIMENTES
Fig. 3 - Example of a DSC curve of the studied oil (heating rate 4 K/min.) and
determination of the kinetic parameters of oxidation
Equation (no.)
T f2
Ea
C1 (3)
RT f
ln 1,0518
Ea
C 2 (4)
RT f
ln
a C3 (5)
Tf
RT f
ln
T 1f .8
f ( 1 / Tf )
T f2
is obtained a straight line
with the slope - Wa/R
Plotting
ln f ( 1 / T f )
is obtained a straight line
with the slope
-(Wa/R) 1.0518
Plotting
ln
ln
Reference
Tf
[10,11]
[11,12]
Ea
C 4 (6)
RT f
ln
T f1.8
[11,13]
12
10
11
10
1 2
Q1
Q3
Q2
[11]
1
10
10
Q3
Q2
Q1
III.
10
f ( 1 / Tf )
f ( 1 / Tf )
13
10
Loss factor
ln
Wa calculation
Plotting
(K/min.)
OOT
(oC)
T0.6
(oC)
177.6
186.4
185.6
197.4
190.5
204.5
196.4
214.0
Hox
(J/g)
-281
-109
-202
-154
-166
-161
-188
-96
Tm
(oC)
195.3
212.6
214.6
230.1
222.7
265.0
241.3
276.6
IV.
[2]
[3]
[4]
[5]
TABLE III.
FITTING PARAMETERS OF THE LINEAR RELATIONSHIPS (Y = M
+ NX) CORRESPONDING TO DIFFERENT METHODS AND THE ACTIVATION
ENERGY
[6]
Temp.
parameter
T0.6
Tm
Method
Correlation
Kissinger
Ozawa
Bosswell
Starink
ASTM
E698
0.9997
0.99978
0.99986
0.99971
14.81
29.17
22.01
16.23
-12096
-13080
-12569
-12210
Wa
(kJ/
mol)
100.5
103.3
104.4
100.5
0.9962
19.45
-8795
73
Wa,a
(kJ/
mol)
[7]
102.4
[8]
73
[9]
CONCLUSIONS
[10]
[11]
[12]
[13]
[14]
International
- 17th I.EEE
Conference
on Diete.i;i; liquics
rcDL 2011
Tiondheim, Norway
June 26 - 30, 201i
.,*r-N[n"ffif,"r"r..n
rrrr
ItrEts
University;s.j;;."
and rechnorogy
Sponsored by;
@ srrurer
ISBN
NT1{U
nWffi
I 978-82-594-3S2s-5
4,rmmm
./