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Exercise Sheet 5
This work can be done in groups of up to four people. Enter student numbers for
those submitting here. Will be returned via first listed person.
This sheet must be attached to each submitted script.
1.
3.
2.
4.
A system has three levels of energy 0, 100 kB and 200 kB, with degeneracies of 1, 3 and 5
respectively, is in contact with a heat bath at a temperature of 100 K.
a) Calculate the partition function (for a single particle).
b) Obtain numerical values for the relative population of each level.
(Note: remember the degeneracy of each level and check that the probabilities add up
to one.)
c) Calculate the average energy per particle at this temperature using U
p j j .
levels j
2.
exp / 2 where 1/ k T
Z sp exp i
B
kBT 1 exp
(Hint: You may find it useful to note that the infinite sum
x
n 0
1
for 0< x <1.)
1 x
1
U N
2 exp 1
and derive an expression for the heat capacity at constant volume CV.
c) Explain how this expression may be used as a basis to describe the temperature
dependence of the heat capacity of solids.
P.T.O.
3.
3N 2
exp N 2 2 VkB T
4.
Consider a large number N of particles, each of spin in an external magnetic field. Each
spin can be oriented either along or opposite to the external field direction z, so assume there
are n up and N n down respectively.
a) Show the resulting z-component of the spin of the system will therefore be
1
m s ( 2n N )
2
b) Give an expression for the number of possible states of the system as a function of
n.
c) Hence (using Stirlings approximation) show that the entropy S kB ln can be
written:
S k [ N ln N N nlnN n n lnn]
d) By differentiating with respect to n, deduce the value of the z-component of the spin
for which the entropy is maximum.
T
i
S k B ln Z k B T
U
CV
T V
Z N Z sp