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8. THERMODYNAMICS
PREVIOUS EAMCET BITS
C( s ) + O2 ( g ) → CO2 ( g )
3. Calculate Δ H in kJ for the following reaction Given that,
H 2O( g ) + C( g ) → CO( g ) + H 2( g ) ΔH = +131kJ
CO( g ) + 1/ 2O2( g ) → COe( g ) ΔH = −282kJ
H 2( g ) + 1/ 2O2( g ) → H 2O( g ) ΔH = −242 kJ
(2008 E)
1) -393 2) +393 3) +655 4) -655
Ans : 1
H 2O( g ) + C( g ) → CO( g ) + H 2( g ) ΔH = +131kJ
Sol:
CO( g ) + 1/ 2O2( g ) → COe( g ) ΔH = −282kJ
H 2( g ) + 1/ 2O2( g ) → H 2O( g ) ΔH = −242 kJ
-------------------------------------------------------------
C( s ) + O2( g ) → CO2( g ) ΔH = −393 kJ
-------------------------------------------------------------
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1
Thermodynamics
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4. 100cm3 of 0.1M HCl and 100cm3 of 0.1M NaOH solutions are mixed in a calorimeter. If the heat liberated is
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2
Thermodynamics
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1
H 2 ( g ) + Cl2 ( g ) → 2 HCl ( g ) CO ( g ) + O2 ( g ) → CO2 ( g )
3) 4) 2
Ans : 4
1
CO ( g ) + O2 ( g ) → CO2 ( g )
Sol: 2
1
Δn = −
2
∴ΔH ≠ ΔE
8. Identify the reaction in which the heat liberated corresponds to the heat of formation ( ΔH )
(2006 M)
C ( diamond ) + O2 ( g ) → CO2 ( g ) + heat
1)
2 H 2 ( g ) + O2 ( g ) → 2 H 2O ( g ) + heat
2)
C ( diamond ) + 2 H 2 ( g ) → CH 4 ( g ) + heat
3)
S ( r hom bic ) + O2 ( g ) → SO2 ( g ) + heat
4)
Ans : 4
S ( r hom bic ) + O2 ( g ) → SO2 ( g ) + heat
Sol:
10. The heat of formation of CO(g) and CO2(g) are ΔH =-110 and ΔH =-393 kJ.mol-1 respectively. What is the
heat of reaction ( ΔH ) (in kJ mol-1) for the following reaction?
(2005 M)
CO ( g ) + 1/ 2 O2 ( g ) → CO2 ( g )
1) - 504 2) -142.5 3) -283 4) 504
Ans . 3
C( s ) + O2( g ) → CO2( g ) ΔH = −393KJ / mol
Sol:
1
− ⎡⎣C( s ) + O2( g ) → CO2( g ) ΔH = −110 KJ / mol
2
1
CO( g ) + O2( g ) → CO2( g ) ΔH = −283KJ / mol
2
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3
Thermodynamics
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Ans : 2
Sol: In an endothermic reaction heat energy is absorbed.
13. When 10 grams of methane is completely burnt in oxygen, the heat evolved in 560 kJ. What is the heat of
combustion (in kJ. Mole-1) of methane ? [2003 E]
1) -1120 2) -968 3) -896 4) -560
Ans : 3
560 × 16
= 896
Sol: Heat of combustion of CH4 = 10 KJ
14. Calculate the heat of combustion (in kJ) of methane from the following date :
C ( graphite ) + 2 H 2 ( g ) → CH 4 ; ΔH = 74.8kJ
i)
C ( graphite ) + O2 ( g ) → CO2 ; ΔH = −393.5kJ
ii)
H 2 ( g ) + 1/ 2 O2 ( g ) → H 2O; ΔH = −286.2kJ
iii) (2002 E )
1) – 891.1 2) -816.3 3) -965.9 4) -1040.7
Ans : 1
ΔH ( f )CH 4 = −74.8kJ
Sol: Date given
ΔH ( f )CO2 = −393.5kJ
;
ΔH f H 2O = −286.2kJ
Combustion Reaction
CH 4 ( g ) + 2O2 ( g ) → CO2 ( g ) + 2 H 2O ( l ) ΔH = ?
( )
ΔH = ⎡ ΔH ( f )CO2 + 2 ΔH ( f ) H 2O ⎤ − ⎡⎣ ΔH f CH 4 + 2 ( ΔH f O2 ) ⎤⎦
⎣ ⎦
⎡⎣ −393.5 + 2 ( −286.2 ) ⎤⎦ − ⎡⎣ −74.8 + 2 × ( 0 ) ⎤⎦
=
ΔH = −393.5 − 572.4 + 74.8
= -891.1KJ
15. Which one of the following is an example of exothermic reaction (2002 M )
H + Cl2( g ) → 2 HCl( g ) ΔH = −184.6 KJ
1) 2( g )
N 2( g ) + O2( g ) → 2 NO( g ) ΔH = 180.8KJ
2)
C( graphite ) + H 2O( g ) → CO( g ) + H 2( g ) ΔH = +131.4 KJ
3)
C( graphite ) + 2 S( s ) + 91.9 KJ → CS 2( l )
4)
Ans :1
Sol: Negative sign for ΔH means exothermic reaction.
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4
Thermodynamics
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CH 2COOH aq + OH ( aq ) → CH 3COO − + H 2O( l ) ; ΔH = −55.2kJ .mol−1
16. In the reaction What is the heat of
dissociation (in kJ mol-1) of acetic acid? (2001 E)
1) +2.1 2) -57.3 3) -35.1 4) -176.1
Ans : 3
CH 2COOH + OH − → CHCOO − + H 2O
17. Heat of combustion of carbon is 96 Kcal. When some quantityt of carbon is burnt in oxygen, 48 K cal of heat is
liberated. What is the volume (in lit) of oxygen at STP reacted with this carbon [2000 M]
1. 48 2. 22.4 3. 11.2 4. 1
Ans : 3
Sol:
C + O2 → CO2 + 96 K .Cal
1 1 1
C + O2 → CO2 + 48K .Cal
2 2 2
Half mole of O2 required i.e, 11.2 lit, at S.T.P.
DDD
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