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ACCURACY
Percent error is used to estimate the accuracy of a
measurement.
PRECISION
Precision is the agreement between repeated measurements of the
same sample. Precision is usually expressed as a standard deviation.
For example, the precision of a method for measuring arsenic (As) was
determined by measuring 7 different solutions each containing 14.3 g/L of
As.
Measured
Concentration
(g/L)
18.4
13.6
13.6
14.2
16.0
13.6
17.8
Accurate, and
precise
Precise, but
not accurate
Accurate, but
not precise
Not accurate,
and not
precise
ERRORS
Systematic (or determinate) errors are reproducible and
cause a bias in the same direction for each measurement.
For example, a poorly trained operator that consistently makes
the same mistake will cause systematic error. Systematic error
can be corrected.
Random (or indeterminate) errors are caused by the natural
uncertainty that occurs with any measurement.
Random errors obey the laws of probability. That is, random
error might cause a value to be over predicted during its first
measurement and under predicted during its second
measurement. Random error cannot be corrected.
Number of
Significant
Figures
Datum
(milliliters)
Number of
Significant
Figures
10,034
1.908
0.32
0.00046
150
0.0000160
5
4
2
2
2
3
150.
0.705
0.054
5.86 x 10-7
3040
0.0000730
3
3
2
3
3
3
2 Significant
Figures
Significant Figures
1 Significant Figure
1 Significant Figure
2 Significant Figures
1 Significant Figure
0 Significant Figures
SOURCES
American Public Health Association, American Water Works Association,
Water Environment Federation. 1995. Standard Methods for the Examination
of Water and Wastewater. 19th ed. Washington, DC: American Public Health
Association.
Barnes, D.S., J.A. Chandler. 1982. Chemistry 111-112 Workbook and
Laboratory Manual. Amherst, MA: University of Massachusetts.
Christian, G.D. 1986. Analytical Chemistry, 3rd ed. New York, NY: John
Wiley & Sons, Inc.
Frisbie, S.H., E.J. Mitchell, A.Z. Yusuf, M.Y. Siddiq, R.E. Sanchez, R. Ortega,
D.M. Maynard, B. Sarkar. 2005. The development and use of an innovative
laboratory method for measuring arsenic in drinking water from western
Bangladesh. Environmental Health Perspectives. 113(9):1196-1204.
Morrison Laboratories. 2006. Meniscus Madness. Available:
http://www.morrisonlabs.com/meniscus.htm [accessed 25 August 2006].