Beruflich Dokumente
Kultur Dokumente
S0143-7208(15)00361-7
DOI:
10.1016/j.dyepig.2015.09.014
Reference:
DYPI 4925
To appear in:
9 September 2015
Please cite this article as: Jose S, Jayaprakash A, Laha S, Natarajan S, Nishanth KG, Reddy MLP,
YIn0.9Mn0.1O3-ZnO nano-pigment exhibiting intense blue color with impressive solar reflectance, Dyes
and Pigments (2015), doi: 10.1016/j.dyepig.2015.09.014.
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Highlights
A blue colored nano-pigment was synthesized by a sol-gel combustion method.
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The nano-pigment exhibits superior blue hue and high solar reflectance.
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Academy
of
Scientific
and
Innovative
research
Thiruvananthapuram, India
b
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(AcSIR),
CSIR-NIIST
Campus,
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Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012,
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India
ABSTRACT
The current study reports on the synthesis and characterization of a new inorganic nano-
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pigment with an intense blue color and high solar radiation reflective properties (70%). The
nano-pigment YIn0.9Mn0.1O3-ZnO was synthesized by a sol-gel combustion method and
characterized with the aid of X-Ray diffraction, Raman spectroscopy, Magnetic susceptibility,
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Transmission electron microscopy, UV-vis-NIR diffuse reflectance spectroscopy and CIE1976 L*a*b* color measurements. The Rietveld refinement of the XRD patterns of the
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developed nano-pigment disclosed the existence of YIn0.9Mn0.1O3 and ZnO in a 1:1 ratio with
hexagonal crystal structures. For comparison, YIn0.9Mn0.1O3 was also synthesized by the solgel combustion route and its optical properties compared with that of YIn0.9Mn0.1O3-ZnO. It is
interesting to note that the developed YIn0.9Mn0.1O3-ZnO nano-pigment exhibits superior blue
hue (b* = -40.55) and solar reflectance (R* = 70%) values as compared to the YIn0.9Mn0.1O3
nano-pigment (b* = -22.28, R* = 50%). Most importantly, the potential utility of the nano-
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pigment as a Cool Pigment was demonstrated by coating onto roofing materials like
aluminium roofing sheets.
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1.
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Introduction
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Nowadays much effort has been made to minimize the use of toxic cobalt aluminate
(CoAl2O4) in pigment formulations and also to produce cost-effective inorganic blue pigments
[1-6]. With the exception of the turquoise blue pigment of vanadium-zircon, known traditional
blue inorganic pigments are generally based on the cobalt ion incorporated into different
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some of the important issues that remain as a challenge in the inorganic pigment industry.
Recently, Smith et al. have shown that intense bright blue colors occur in most of the
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YIn1-xMnxO3 solid-state solutions. The Mn3+ ions substituted into the indium site exhibits an
intense blue color because of an allowed d-d transition [10]. In later studies, Ocana and coworkers have developed Mn3+ doped YInO3 blue pigments at much lower temperatures
(1000C) than required by the traditional solid state method (1400C) [11]. The developed
procedure is based on the pyrolysis at 600C of aerosols generated from aqueous solutions of
Y, In, and Mn nitrates followed by an annealing treatment at 1000C. The technological
performance of these YIn1-xMnxO3 blue pigments has also been evaluated by testing their
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efficiency for coloring of ceramic glazes. Kim and co-workers have disclosed the synthesis
and structural characterization of the blue chromophore Sr2(MgMn)Ge2O7, which has a
melilite-type structure [12]. The blue color of the pigment has been attributed to the d-d
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electronic transition in Mn3+ (d4), which has trigonal bipyramidal coordination [12]. A series
of new blue inorganic oxide materials LaGaGe2O7 with the introduction of Mn3+ in the
trigonal bipyramidal site has also been reported [13]. However, many of these known blue
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inorganic pigments have not been explored for their solar reflective properties [12,13].
In this paper, YIn0.9Mn0.1O3 blue nano-pigments have been synthesized in the presence
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and absence of ZnO nanoparticles through sol-gel combustion route at 850 C using citric acid
as a fuel. The developed pigments were well characterized and their optical properties were
investigated. Superior blue hue and high solar radiation reflectivity has been achieved in the
presence of ZnO nanoparticles as compared to YIn0.9Mn0.1O3 blue nano-pigment.
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Experimental section
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2.
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2.1. Materials
manganese(III) acetate (Sigma Aldrich, 97%), ZnO (Acros Organics, 99.999%) and citric acid
(Sigma-Aldrich, 99.5%) are analytical grade and used without further purification.
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Stoichiometric amounts of yttrium oxide (1.66 mmol), manganese(III) acetate (0.33 mmol),
indium oxide (1.49 mmol) and zinc oxide (3.33 mmol) were dissolved in 4.0 M nitric acid
(100 mL) with constant stirring and heated on a hot plate. To this solution, citric acid was
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added. The molar ratio of citric acid to metal was maintained as 3.5:1. The resultant pale
yellow solution was then evaporated on a hot plate to obtain a dried gel. The gel was then
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heated at 250C for 2 h to decompose the nitrates. The optimized calcination temperature
required for the formation of the typical pigment sample YIn0.9Mn0.1O3ZnO was ascertained
by calcining the dried gel at various temperatures ranging from 600C to 900C for 2h in an
air atmosphere. The typical blue color of the sample was observed only when the dried gel
was calcined at 850C for 2h. The calcination of the powder samples were carried out in a
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and ZnO.
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XRD pattern of the calcined powder indicates the presence of 1:1 mixture of YIn0.9Mn0.1O3
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A similar procedure has been followed for the preparation of YIn0.9Mn0.1O3 powders.
Stoichiometric quantities of yttrium oxide (1.66 mmol), manganese(III) acetate (0.33 mmol)
and indium oxide (1.49 mmol) were dissolved in 4.0 M nitric acid (100 mL) with constant
stirring and heating on a hot plate. Citric acid was then added to the above metal nitrate
solution (The molar ratio of citric acid to metal was maintained as 1.67:1). The resulting pale
yellow solution was evaporated at 80 C on a water bath to obtain a dried gel. The dried gel
was then heated at 250 C to decompose the nitrates. The resultant powders were then
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calcined at 850C for 2h to obtain the pigment powders. Examination of the product by
powder XRD pattern revealed that heating the dried gel at 850 C for 2h resulted in a single
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Thermogravimetry and differential thermal analysis (TG-DTA) was carried out in the
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temperature range of 50-1000C using an SII Nanotechnology Inc., TG/DTA 6200 in an air
atmosphere at a heating rate of 20C/min. The powder X-ray diffraction pattern of the
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synthesized pigment powder was recorded using the diffractometer (Philips Xpert Pro) with
Nifiltered Cu K ( = 0.154060 nm) radiation. Data were collected by step scanning over a
2 range from 10 - 70 with a step size of 0.08 and 5 s counting time at each step. Powder Xray diffraction (PXRD) data for structure refinement were collected by means of a
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patterns were typically refined for lattice parameters, atomic coordinates, scale, factors,
background (Fourier polynomial background function), pseudo-Voigt (U, V, W and X) and
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calibration with a silicon standard (Raman peak centered at 520 cm1) was performed. WITec
Project Plus (v 2.1) software package was used for data evaluation.
Magnetic measurements were carried out as a function of temperature using PPMS
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(Quantum Design, Dynacool) in an applied field of 500 Oe. The measurement was performed
in the temperature range 5 K to 300 K. Dynamic Light Scattering experiment was conducted
using Malvern Instruments Zeta sizer nano Zis Model No: ZEN 3600 to determine the particle
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size of the nano-pigment. Transmission electron microscopy (TEM) [JEOL 2010 (300 kV)]
was used to understand the morphology and particle size of the synthesized samples.
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The optical properties of the powdered pigment samples were measured (380-780 nm) with
a UV-vis Spectrophotometer (Shimadzu UV-3600 with an integrating sphere attachment, ISR3100) using barium sulfate as a reference. The measurement conditions were as follows: an
illuminant D65, 10 complementary observer and measuring geometry d/8. The color
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coordinates were determined by coupling with analytical software (UVPC Color Analysis
Personal Spectroscopy Software V3, Shimadzu) to the UV-3600 spectrophotometer. The CIE
1976 L*a*b* colorimetric method was used, as recommended by the Commission
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Internationale de IEclairage (CIE). In this method, L* is the color lightness (L* = 0 for black
and L* = 100 for white), a* is the green (-)/red (+) axis, and b* is the blue (-)/yellow (+) axis.
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The parameter C* (chroma) represents the saturation of the color and is defined
as C* = (a*)2 + (b*) 2 . The hue angle, h is expressed in degrees and ranges from 0 to 360
b*
and is calculated by using the formula h = tan1 . For each colorimetric parameter of a
a *
sample, measurements were made in triplicate and an average value was taken as the result.
Typically, for a given sample, the standard deviation of the measured CIEL*a*b* values is
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less than 0.10, and the relative standard deviation 1%, indicating that the measurement error
can be ignored. The nearinfrared reflectance spectrum of the powdered pigment samples and
the aluminium roofing sheet coatings were recorded with a UVvisNIR spectrophotometer
UV-3600
with
an
integrating
sphere
attachment,
ISR
3100)
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(Shimadzu,
using
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was calculated according to ASTM standard number E89187 as reported elsewhere [15-20].
The NIR solar reflectance or the fraction of solar radiation incident at wavelengths between
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700 and 2500 nm that is reflected by a surface is the irradiance-weighted average of its
spectral reflectance, r(), and can be determined using the relationship,
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r ( ) i ( ) d ( )
R* =
700
2500
i ( ) d ( )
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where r() is the experimentally obtained spectral reflectance (Wm2) and i() is the solar
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resultant viscous paint formulation was coated onto the surface of aluminium roofing sheets
and was allowed to dry in air. The thickness of the pigment coating on aluminium roofing
sheet surface was measured by employing LEICA DMRX optical microscope.
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Fig. 1 shows the typical FT-IR spectra of the synthesized citrate gel as well as calcined
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pigment powders (850C). The broad band observed in the spectrum of citrate gel at 3400 cmcan be assigned to OH stretching frequencies of the intermolecular hydrogen-bonded water
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[23,24]. Further, the FT-IR spectrum of the citrate gel evidenced intense absorption bands
characteristic of the carboxylate groups at 1380 and 1560 cm-1, which are assigned to the
symmetric s (C=O) and asymmetric as (C=O) vibrations, respectively [24]. The difference
between the asymmetric and symmetric stretching vibration modes falls in the range 180 cm-1,
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which indicates that carboxylate groups are coordinated to metal ions in either bridging or
chelating modes [25,26]. The band at 1378 cm-1 observed can be assigned to vibrations of free
nitrate ion [11,24]. However, this band is overlapped with the citrate ion absorption bands.
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The absence of the broad absorption band at 3400 cm-1 in the FT-IR spectrum of calcined
pigment powder indicates the absence of moisture in the pigment powder. Further, the
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absence of absorption bands corresponding to citrate and nitrate ions clearly indicates the
decomposition of nitrate and citrate ions after the calcination of the gel at 850C.
As shown in Fig. 2, there are weight loss processes at 80-130C, 180-290C, 350-500C
and 500-800C. The observed endothermic peak in the DTA curve between 80 and 135C
with respective weight loss for the citrate gel indicates the removal of absorbed water
molecules [23]. The exothermic peak in the DTA curve at 180-290C was related to the
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nitrate decomposition process [11]. The other strong exothermic process noted at 400C
corresponds to the citric acid decomposition [27], which the liberation of combustion gases
and dissipation of the heat reduces the sinterization of particles [27]. The thermogravimetric
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analysis showed that the major part of the weight loss that is associated with the
decomposition and oxidation of citrate precursors was completed at 600C [27]. However,
when the thermal treatment is performed at 800C, the color of the YIn0.9Mn0.1O3-ZnO
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powder was dark grey due to the presence of residual carbon. On the other hand, blue color
was noted for the pigment sample when the gel calcined at 850C. The thermal analysis
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results of the citrate gel are found to be in good agreement with the FT-IR data of the calcined
The optimized calcination temperature required for the formation of the typical pigment
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sample YIn0.9Mn0.1O3ZnO was ascertained by calcining the dried gel at various temperatures
ranging from 600C to 900C for 2h in an air atmosphere. The typical blue color of the
sample was observed only when the dried gel was calcined at 850C for 2h. Fig. 3 displays the
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pattern of YIn0.9Mn0.1O3 indicates the formation of single phase hexagonal YInO3 structure
[28]. This is in good agreement with the earlier reports, where YIn0.9Mn0.1O3 calcined at
1400C exhibits d4 cation in trigonal bipyramidal sites of hexagonal YInO3 [10]. It is
important to note that the calcination temperature (850C) used in the preparation of the
YIn0.9Mn0.1O3-ZnO compound by the sol-gel combustion route in the current study is found
to be significantly lower than that involved in the traditional ceramic procedure using oxide
precursors (1400C) [10]. On the contrary, the PXRD pattern of YIn0.9Mn0.1O3ZnO exhibits
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a mixture of hexagonal YInO3 phase and ZnO [28, 29]. Rietveld refinement was carried out
on the PXRD data of YIn0.9Mn0.1O3ZnO on both the phases (Fig. 4). The refinement reveals
that YIn0.9Mn0.1O3ZnO is almost 1:1 molar mixture of two constituents, YIn0.9Mn0.1O3 and
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ZnO. In hexagonal (space group P63cm) YIn0.9Mn0.1O3, In/Mn ions are trigonal bipyramidally
coordinated by oxide ions (Fig. 5 (left) and Table 1). The three equatorial In/MnO bonds are
almost equal and relatively shorter compared to the two axial bonds. Each In/MnO5 trigonal
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bipyramid (TBP) shares corners with three neighbouring In/MnO5 TBPs along the equatorial
directions (crystallographic ab-plane) to form a two dimensional layer of In/MnO5 TBPs. The
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layers of In/MnO5 TBPs are stacked alternately along the crystallographic c-direction with the
YO7 polyhedral layers (not shown in the figure for clarity). The ZnO crystallizes in hexagonal
wurtzite (space group P63mc) structure where zinc ions are tetrahedrally coordinated by oxide
ions (Fig. 5 (right) and Table 1) and vice versa. These tetrahedra share all the four corners
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the results are depicted in Fig. 6. The Raman spectrum of the biphasic sample is assumed to
be the signature of the hexagonal phase [30,31]. The band occurs at around 364 cm-1, which
can be attributed to the (Fg + Ag, where Ag is the Raman active symmetric stretching vibration
and Fg is the Raman active triply degenerate symmetric stretching vibration) mode of the
(YIn)O6 octahedra [30]. The highest band at 612 cm-1 may be assigned to (YIn)-O stretch
[31]. The sharp peak observed in the Raman spectrum at 450 cm-1 clearly indicates the E2
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mode of ZnO nanoparticles. The position of this peak is practically the same as in the bulk
material [31].
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The magnetic susceptibility measurements were carried out to confirm the presence of
Mn3+ in the YIn0.9Mn0.1O3-ZnO sample. Fig. 7 illustrates the temperature dependence of and
inverse per Mn for YIn0.9Mn0.1O3-ZnO. It is clear from the results that the susceptibility
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increases in the low-temperature region, indicating the spin alignment. Further, this curve
obeys the Curie-Weiss law, = C/(T-), in the measured temperature region. The theoretical
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effective Bohr magneton, eff, was calculated from the equation eff = 2[S(S + 1)]1/2 to be 5.92,
4.90, and 3.87 for S=5/2 (d5), 4/2 (d4), and 3/2 (d3), respectively [32]. Thus the experimental
eff value (4.80 BM) for YIn0.9Mn0.1O3-ZnO is close to 4.90, indicating Mn3+ 3d4 (high spin)
in the present designed composite material.
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The TEM and High resolution transmission electron microscopic (HRTEM) images of
YIn0.9Mn0.1O3-ZnO (Fig. 8(a) and 8(b)) indicate the presence of well dispersed and
homogeneous nanoparticles. As shown in Fig. 8(a) the developed YIn0.9Mn0.1O3-ZnO pigment
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powders are granular in nature and present a homogeneous nanoscale particle size. Excellent
dispersion is observed with a narrow grain sizes with the distribution in the range of 80-150
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nm. The HRTEM image clearly shows ordered fringes corresponding to the crystalline planes.
The spacing of the lattice fringes equals 2.0 which corresponds to a lattice constant of c
12.17 assigned to the (006) plane, in agreement with the XRD data of YIn0.9Mn0.1O3. The
selected area electron diffraction (SAED) pattern presented in Fig. 8(c) also pointed out a
relatively high crystallinity degree of the sample. The energy dispersive spectroscopy (EDS)
analyses (Fig. 8(d)) of YIn0.9Mn0.1O3-ZnO showed a high purity and suitable stoichiometry of
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the investigated powder. The particle size of the pigment sample is found to be 180 nm from
dynamic light scattering (DLS) analysis (Fig. 9).
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the visible spectrum, centered at 1.9 eV has been observed in the case of YIn0.9Mn0.1O3
powders at a low doping concentration of Mn3+ (5.0 mol%). Then the absorption decreases
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between 2.5-3 eV. The residual absorption noted in the blue region (2.5-3 eV) of the spectrum
clearly indicates the poor blue hue of the synthesized YIn0.9Mn0.1O3 compound (Fig. 11) with
a band gap of 2.63 eV. On the other hand, the presence of ZnO particles dramatically
decreases the absorption of YIn0.9Mn0.1O3-ZnO at 1.9 eV. Further, the absence of absorption
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between 2.5-3.0 eV attests the intense blue color of the compound YIn0.9Mn0.1O3-ZnO (Fig.
11). The band gap of the blue nano-pigment sample is found to be 2.74 eV. The blue colored
nano-pigments YIn0.9Mn0.1O3 and YIn0.9Mn0.1O3-ZnO samples have a strong absorption band
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at 1.9 eV, which can be ascribed to an allowed transition from 3dx2-y2,xy to 3dz2 in D3h symmetry
of Mn3+ [32, 33]. A weak transition noted at 2.2 eV originates from 3dxz,yz to 3dz2 is forbidden.
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Further, both of the samples show a charge transfer transition in the region 3.5-5.5 eV from
O2p to 3dz2 [10].
For better understanding of the optical properties of the developed pigment powders, the
diffuse reflectance spectra of YIn0.9Mn0.1O3 and YIn0.9Mn0.1O3-ZnO have been measured and
the results are depicted in Fig. 12. The results demonstrated that the optical reflectance of
YIn0.9Mn0.1O3 in the presence of ZnO powders significantly enhances in the region 400-500
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nm. The chromatic properties of the developed pigment particles have been evaluated based
on CIE 1976 color coordinates values and are summarized in Table 2. The presence of ZnO in
YIn0.9Mn0.1O3 lattice results in an increase in the magnitude of the b* value from -22.28 to -
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pigment has also been improved significantly (from L* = 39.71 to 49.94). The observed hue
angle values of these pigments lie in the blue region of the cylindrical color space (ho for blue
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= 190-280). It is interesting to note that the color coordinates of the typical pigment sample
YIn0.9Mn0.1O3-ZnO (L* = 49.94, a* = -0.88, b* = -40.55) are found to be appreciably higher
than the traditional blue pigments such as CoAl2O4 (L* = 44.80, a* = 2.10, b* = -32.70) [11]
and currently developed pigment YIn0.9Mn0.1O3 (L* = 39.71, a* = -5.78, b* = -22.28).
Infrared reflectance and solar reflectance of the blue nano- pigments
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3.5.
Fig. 13 depicts the IR reflectance and the corresponding solar reflectance spectra (inset
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of Fig. 13) of YIn0.9Mn0.1O3 and YIn0.9Mn0.1O3-ZnO powdered pigment samples. The average
reflectance of the intense blue inorganic pigment based on YIn0.9Mn0.1O3-ZnO in the IR
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region (80%) is found to be much higher than that of UV-vis region (16%). Further, the
average IR reflectance in the presence of ZnO sample is found to be 12% greater than that of
currently designed YIn0.9Mn0.1O3 blue nano-pigment sample (68%). The observed high
reflectance may be due to the presence of ZnO nanoparticles, which is known to have high IR
reflectance (90%) [35]. The solar reflectance of the YIn0.9Mn0.1O3-ZnO pigment sample (R*=
70%) is also found to be notably higher than that of ZnO free pigment sample (R*= 50%).
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Thus, the present results clearly demonstrate the potential utility of the designed intense blue
inorganic pigment powders as Cool pigments for various surface coating applications.
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The IR reflectance and the corresponding solar reflectance spectra of the blue nanopigment sample YIn0.9Mn0.1O3-ZnO coated on the aluminium roofing sheet are shown in Figs.
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14 and 15, respectively. The corresponding photograph of the typical coating is displayed in
Fig. 16. The CIE 1976 color coordinates and average reflectance in UV-vis and IR region of
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the blue nano-pigment coatings are given in Table 3. The IR reflectance as well as the
corresponding solar reflectance of the blue nano-pigment YIn0.9Mn0.1O3-ZnO coated on the
aluminium roofing sheet (R at 1100 nm = 84%, R* = 67%) is found to be higher than that of
bare aluminium roofing sheet (R at 1100 nm = 41%, R* = 38%). These findings reveal the
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potential application of the currently developed blue inorganic pigments as Cool pigments
for building roofing materials.
3.7. Thermal and chemical stability studies of the designed blue pigment powders
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50-1000 C in an air atmosphere and the results are given in Fig. 17. The results clearly
demonstrate that there is negligible weight loss and phase transition up to 1000 C. Thus, it
can be concluded from the above study that the designed intense blue pigment is found to be
thermally stable.
The chemical stability of the typical pigment sample YIn0.9Mn0.1O3-ZnO was also
investigated. 2.0 g of the pigment sample was treated with H2O/aqueous solution having
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different pH values (pH = 3.0 and pH = 13.0) and soaked for 30 min with constant stirring on
a magnetic stirrer. The resultant pigment was then filtered, washed with water, dried, and
weighed. Negligible weight loss of pigment was noticed at all the conditions tested. The color
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coordinates of the pigments were measured after acid/alkali and water treatment and the total
*
of the pigments are found to be negligible as evident from the data
color difference, Eab
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*
*
reported in Table 4. The industrially acceptable limits of Eab
1
are as follows: when Eab
unit indicates that the color change is almost indistinguishable from the original color,
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*
2 units are considered to be good [36]. The above studies highlight that the
whereas, Eab
4.
Conclusions
An intense blue nano-pigment (particle size :180 nm) with impressive NIR reflectance (79%
derived from 1:1 mixtures of YIn0.9Mn0.1O3 and ZnO by a sol-gel
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combustion method at relatively lower temperatures (850 C). Most importantly, the
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developed blue nano-pigment powder sample exhibits excellent solar reflectance (R* = 67%),
when coated onto an aluminium roofing sheet. Thus, the developed blue nano-pigment
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powder has potential applications as Cool materials used for building roofing materials with
energy saving performance. Further, the designed pigment powder not only exhibit a rich blue
color (b*= -40.55: R* = 70%) and high solar reflectance properties as compared to the
existing commercial blue based on CoAl2O4 (b*= -32.70: R* = 29%) as well as the currently
developed Mn3+ doped YInO3 nano-pigments (b*= -22.28: R* = 50%).
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of the authors Sheethu Jose also acknowledges CSIR, New Delhi for the award of Senior
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Figure captions
Fig. 1. FT-IR spectra of YIn0.9Mn0.1O3-ZnO-citrate gel and calcined pigment powder at
850C.
of TG-DTA curves.
Fig. 3. PXRD patterns of blue pigments calcined at 850C/2h.
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Fig. 2. TG-DTA curves of the YIn0.9Mn0.1O3-ZnO-citrate gel. The inset shows enlarged view
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Fig. 4. Rietveld refinement of YIn0.9Mn0.1O3-ZnO from PXRD data. Observed (o), calculated
(redline) and difference (bottom blue line) profiles are shown. The red and black vertical bars
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Fig. 8. (a) TEM image, (b) HRTEM image (inset shows the corresponding SAED pattern)
(c) diffraction pattern and (d) Energy dispersive spectrum of YIn0.9Mn0.1O3-ZnO synthesized
pigment powder.
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Table 1
Crystallographic data for YIn0.9Mn0.1O3-ZnO.
YIn0.9Mn0.1O3 - phase
Atom
Site
Uiso(2)
Y1
2a
0.0
0.0
0.266(1)
0.002(1)
Y2
4b
0.333
0.667
0.234(1)
0.028(1)
In/Mn
6c
0.334(1)
0.0
0.002(1)
0.021(1)
0.90(3)/0.10(3)
O1
6c
0.324(5)
0.0
0.171(1)
O2
6c
0.632(3)
0.0
0.330(3)
O3
2a
0.0
0.0
O4
4b
0.333
0.667
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Occupancy
0.072(5)
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0.002(2)
0.485(5)
0.286(1)
0.032(2)
0.011(4)
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ZnO - phase
Site
Uiso(2)
Occupancy
Zn
2b
0.333
0.667
0.265(1)
0.032(1)
2b
0.333
0.667
0.382(2)
0.022(4)
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Table 2
Color coordinates, band gap values, IR reflectance and solar reflectance of blue pigments.
Color coordinates
L*
a*
Band
b*
C*
ho
IR
Solar
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Gap
reflectance
reflectance,
(eV)
at 1100 nm
R* (%)
39.71
-5.78 -22.28
23.21
255
2.63
63
50
YIn0.9Mn0.1O3-ZnO
49.94
-0.88 -40.55
40.56
269
2.74
79
70
*CoAl2O4[11, 34]
44.80
2.10
29
-32.70
-3.90 -15.62
16.10
*YIn0.9Mn0.1O3 [11]
0.50
49.50
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Table 3
Solar reflectance and color coordinates of YIn0.9Mn0.1O3-ZnO pigment synthesized by sol-gel
Parameter
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blue pigment
alone
14
66
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Thickness (m)
84
67
L*
44.84
a*
4.78
C*
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Table 4
tests.
Color coordinates
b*
49.94
-0.88
-40.55
H2O
49.90
-0.87
Aqueous solution of pH = 3
49.92
Aqueous solution of pH = 13
49.99
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0.05
-0.93
-40.49
0.11
-0.91
40.60
0.17
*
Eab
= [(L*)2+(a*)2+(b*)2]
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Eab
-40.52
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The color coordinates of the YIn0.9Mn0.1O3-ZnO powder pigments after chemical resistance
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