My solution as follows

Step 1
Run the 32-bit odbc driver using
WinKey+R, then copy-paste the below command
C:\Windows\SysWOW64\odbcad32.exe
Step 2
Make a dsn named AccessDB or whatever name you want to.

Step 3
Create a new project in eclipse.
Step 4
Change the jre to the java installed inside
C:\Program Files (x86)\java
Use this as JRE System Library

Step 5
Use the below code to connect to connect mdb file named library.mdb(choose ur mdb file),
having the path as
D:\Study\library.mdb
import java.sql.Connection;
import java.sql.DatabaseMetaData;
public class Main {
/**
* @param args
*/
public static void main(String[] args) {
// TODO Auto-generated method stub
Connection con = null;
try {
// Setting up the DataSource object
sun.jdbc.odbc.ee.DataSource ds
= new sun.jdbc.odbc.ee.DataSource();
ds.setDatabaseName("AccessDB");
ds.setDataSourceName("D:\\Study\\library.mdb");
// Getting a connection object
con = ds.getConnection();
// Getting database info
DatabaseMetaData meta = con.getMetaData();
System.out.println("Server: "
+ meta.getDatabaseProductName());
System.out.println("Serverion: "
+ meta.getDatabaseProductVersion());

// Closing the connection

con.close();
} catch (Exception e) {
System.err.println("Exception.getMessage());
}
}

Viola
Output
Server name: ACCESS
Server version: 04.00.0000
(2)2nd Way

Using the JDBC Driver

This section provides quick start instructions for making a simple connection to a SQL Server
database by using the Microsoft JDBC Driver for SQL Server. Before you connect to a SQL
Server database, SQL Server must first be installed on either your local computer or a server,
and the JDBC driver must be installed on your local computer.

Choosing the Right JAR file

The Microsoft JDBC Driver for SQL Server provides sqljdbc.jar and sqljdbc4.jar class library
files to be used depending on your preferred Java Runtime Environment (JRE) settings. For
more information about which JAR file to choose, see System Requirements for the JDBC
Driver.

Setting the Classpath

The JDBC driver is not part of the Java SDK. If you want to use it, you must set the classpath
to include the sqljdbc.jar file or the sqljdbc4.jar file. If the classpath is missing an entry for
sqljdbc.jar or sqljdbc4.jar, your application will throw the common "Class not found"
exception.
The sqljdbc.jar file and sqljdbc4.jar file are installed in the following location:
<installation directory>\sqljdbc_<version>\<language>\sqljdbc.jar
<installation directory>\sqljdbc_<version>\<language>\sqljdbc4.jar
The following is an example of the CLASSPATH statement that is used for a Windows
application:
CLASSPATH =.;C:\Program Files\Microsoft JDBC Driver 4.0 for SQL
Server\sqljdbc_4.0\enu\sqljdbc.jar
The following is an example of the CLASSPATH statement that is used for a Unix/Linux
application:
CLASSPATH =.:/home/usr1/mssqlserverjdbc/Driver/sqljdbc_4.0/enu/sqljdbc.jar
You must make sure that the CLASSPATH statement contains only one Microsoft JDBC
Driver for SQL Server, such as either sqljdbc.jar or sqljdbc4.jar.

Note
On Windows systems, directory names longer than 8.3 or folder names with spaces may
cause problems with classpaths. If you suspect these types of issues, you should temporarily
move the sqljdbc.jar file or the sqljdbc4.jar file into a simple directory name such as
C:\Temp, change the classpath, and determine whether that addresses the problem.

Applications that are run directly at the command prompt

The classpath is configured in the operating system. Append sqljdbc.jar or sqljdbc4.jar to the
classpath of the system. Alternatively, you can specify the classpath on the Java command
line that runs the application by using the java -classpath option.

Applications that run in an IDE

Each IDE vendor provides a different method for setting the classpath in its IDE. Just setting
the classpath in the operating system will not work. You must add sqljdbc.jar or sqljdbc4.jar
to the IDE classpath.

Servlets and JSPs

Servlets and JSPs are run in a servlet/JSP engine such as Tomcat. The classpath must be set
according to the servlet/JSP engine documentation. Just setting the classpath in the operating
system will not work. Some servlet/JSP engines provide setup screens that you can use to set
the classpath of the engine. In that situation, you must append the correct JDBC Driver JAR
file to the existing engine classpath and restart the engine. In other situations, you can deploy
the driver by copying sqljdbc.jar or sqljdbc4.jar to a specific directory, such as lib, during
engine installation. The engine driver classpath can also be specified in an engine specific
configuration file.

Enterprise Java Beans

Enterprise Java Beans (EJB) are run in an EJB container. EJB containers are sourced from
various vendors. Java applets run in a browser but are downloaded from a Web server. Copy
sqljdbc.jar or sqljdbc4.jar to the Web server root and specify the name of the JAR file in the
HTML archive tab of the applet, for example, <applet ... archive=sqljdbc.jar>.

Making a Simple Connection to a Database

Using the sqljdbc.jar class library, applications must first register the driver as follows:
Class.forName("com.microsoft.sqlserver.jdbc.SQLServerDriver");
When the driver is loaded, you can establish a connection by using a connection URL and the
getConnection method of the DriverManager class:
String connectionUrl = "jdbc:sqlserver://localhost:1433;" +
"databaseName=AdventureWorks;user=MyUserName;password=*****;";

Connection con = DriverManager.getConnection(connectionUrl);

In the JDBC API 4.0, the DriverManager.getConnection method is enhanced to load JDBC
drivers automatically. Therefore, applications do not need to call the Class.forName method
to register or load the driver when using the sqljdbc4.jar class library.
When the getConnection method of the DriverManager class is called, an appropriate
driver is located from the set of registered JDBC drivers. sqljdbc4.jar file includes "METAINF/services/java.sql.Driver" file, which contains the
com.microsoft.sqlserver.jdbc.SQLServerDriver as a registered driver. The existing
applications, which currently load the drivers by using the Class.forName method, will
continue to work without modification.
Note
sqljdbc4.jar class library cannot be used with older versions of the Java Runtime
Environment (JRE). See System Requirements for the JDBC Driver for the list of JRE
versions supported by the Microsoft JDBC Driver for SQL Server.
For more information about how to connect with data sources and use a connection URL, see
Building the Connection URL and Setting the Connection Properties.